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Chinese Chemical Letters 2020年第7期31卷 1851-1854页

作者： mustapha ait el had Abdelouahd Oukhrib Mohamed Zaki Martine Urrutigoity Ahmed Benharref Remi Chauvin Laboratoire de Chimie Biomoleculaire Substances Naturelies et Reactivite(URAC 16)Faculte des Sciences SemlaliaUniversite Cadi AyyadB.P.2390MarrakechMorocco CNRS LCC(Laboratoire de Chimie de Coordination)BP 4409931077Toulouse Cedex 4France INP-ENSIACET 4 allee Emile Monso31030Toulouse CedexFrance Universite de Toulouse UPSICT-FR 259931062Toulouse Cedex 9France

From a mixture of α-,β-and y-himachalenes extracted from waste wood of Atlas cedar(Cedrus atlantica),cadalene(1,6-dimethyl-4-isopropylnaphthalene)and iso-cadalene(1,6-dimethyl-3-isopropylnaphthalene)were produced in two steps with up to 71%±5%yield through the ar-himachalene intermediate using I2 and/or AlCl3 as *** selectivity is shown to sharply depend on the operating conditions:while I2/AlCl3 in dichloromethane promotes the formation of cadalene,the formation of iso-cadalene is favored in the presence of AlCl3 in *** bicyclic aromatic compounds were thus obtained through unique rearrangements involving sequential C—C bond cleavage/fo rmation and hydride transfer *** the absence of AlCl3 or I2,dihydrocurcumene was also found to be formed with up to 70%selectivity.A tentative mechanism is proposed and discussed.

关键词： Aromatic reactivity Cadalenes Dihydrocurcumene Himachalenes Rearrangements

Enhancing sustainability in phosphate ore processing:Performance of frying oil as alternative flotation collector for carbonate removal

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International Journal of Mining Science and Technology 2024年第4期34卷 557-571页

作者： Asmae el-bahi Yassine Taha Yassine ait-Khouia Abdellatif elghali Mostafa Benzaazoua Geology&Sustainable Mining Institute(GSMI) Mohammed VI Polytechnic UniversityBen Guerir 43150Morocco

Recycling waste frying oils for the synthesis of flotation reagents presents a promising avenue for sustainable waste ***,it offers a cost-effective solution for crafting a specialized collector designed to efficiently remove carbonates and enhance phosphate enrichment in froth flotation *** study focuses on the synthesis of an anionic collector using the saponification reaction of a frying oil sample,subsequently applied to the flotation of calcite and *** elucidate the adsorption mechanisms of the frying oil collector(FrOC)and sodium oleate,a reference collector,on fluorapatite,calcite,dolomite,and quartz surfaces,comprehensive experiments were conducted,including zeta potential measurements and Fourier transform infrared *** revealed diverse adsorption affinities of the molecules towards these *** assess the practical performance of the collector,flotation tests were conducted using a natural phosphate ore mixture,employing a BoxBehnken experimental ***,under optimized conditions(pH 9,1000 g/t of FrOC,3.5 min of conditioning,and 6 min of flotation),FrOC exhibited excellent performance,with calcite and dolomite recoveries exceeding 80%,while apatite recovery in the concentrate fraction remained below 10%.This work exemplifies both circular economy practices and the distinctive approach to sustainable mineral processing.

关键词： Frying oils recycling Phosphate beneficiation Flotation separation Green surfactants Sustainability

Performance Evaluation of an Evaporative Cooling Pad for Humidification-Dehumidification Desalination

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Fluid Dynamics & Materials Processing 2024年第10期20卷 2323-2335页

作者： Ibtissam el Aouni Hicham Labrim elhoussaine Ouabida Ahmed ait Errouhi Rachid el Bouayadi Driss Zejli Aouatif Saad Advanced Systems Engineering Laboratory National School of Applied SciencesIbn Tofail UniversityKenitra14000Morocco

The perfect combination of renewable energy and desalination technologies is the key to meeting water demands in a cost-effective,efficient and environmentally friendly *** desalination technique by humidificationdehumidification is non-conventional approach suitable for areas with low infrastructure(such as rural and decentralized regions)since it does not require permanent *** this study,this technology is implemented by using solar energy as a source of thermal power.A seawater desalination unit is considered,which consists of a chamber with two evaporators(humidifiers),a wetted porous material made of a corrugated cellulose cardboard and a condenser(dehumidifier).The evaporation system is tested with dry bulb temperature and relative air humidity *** results of numerical simulations indicate that higher inlet air velocities(from 0.75 to 3 m/s)lead to a decrease in theΔT,ΔRH,and *** the air remaining within the evaporator for 30 cm,the temperature differential increases to 5.7°C,accompanied by a 39%rise in relative humidity *** changes result in a significant enhancement in humidification efficiency,achieving a remarkable efficiency level of 78%.However,a wettability value of 630 m^(2)/m^(3)leads to a smaller reduction of these *** the pad thickness,particularly to 0.3 m,improves performance by boostingΔT,ΔRH,and effectiveness,especially for pads with a wettability of 630 m^(2)/m^(3),for which superior performances are predicted by the numerical tests.

关键词： Desalination humidification dehumidification porous material solar energy evaporator

Capparis spinosa L waste activated carbon as an efficient adsorbent for crystal violet toxic dye removal: Modeling, optimization by experimental design, and ecological analysis

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Chinese Journal of Chemical Engineering 2024年第7期71卷 283-302页

作者： Mohammed Benjelloun Youssef Miyah Salma Ssouni Soulaiman Iaich Mohamed el-habacha Salek Lagdali Khadija Saka el Mustafa Iboustaten Abdelaziz ait Addi Sanae Lairini Rabia Bouslamti Laboratory of Materials ProcessesCatalysisand EnvironmentHigher School of TechnologySidi Mohamed Ben Abdellah UniversityFez 30070Morocco Ministry of Health and Social Protection Higher Institute of Nursing Professions and Health TechniquesFez/Meknes 30070Morocco Laboratory of Biochemistry Faculty of MedicinePharmacy and DentistrySidi Mohamed Ben Abdellah UniversityFez 30070Morocco Laboratory of Applied Chemistry and Environment Faculty of SciencesIbnou Zohr UniversityAgadir 80322Morocco Research Team of Energy and Sustainable Development Higher School of TechnologyIbnou Zohr UniversityGuelmim 81000Morocco Organic Chemistry and Physical Chemistry Laboratory Faculty of SciencesIbnou Zohr UniversityAgadir 80322Morocco

Textile dyes are dramatic sources of pollution and non-aesthetic disturbance of aquatic life and therefore represent a potential risk of bioaccumulation that can affect living *** is imperative to reduce or eliminate these dyes from liquid effluents with innovative biomaterials and ***,this research aims to highlight the performance of Capparis spinosa L waste-activated carbon(CSLW-AC)adsorbent to remove crystal violet(CV)from an aqueous *** mechanism of CV adsorption on CSLW-AC was evaluated based on the coupling of experimental data and different characterization *** efficiency of the CSLW-AC material reflected by the equilibrium adsorption capacity of CV could reach more than 195.671 mg·g^(–1) when 0.5 g·L^(–1) of CSLW-AC(Particle size≤250μm)is introduced into the CV of initial concentration of 100 mg·L^(–1) at pH 6 and temperature 65℃ and in the presence of potassium ions after 60 min of contact time according to the one parameter at a time *** adsorption behavior of CV on CSLW-AC was found to be consistent with the pseudo-second-order kinetic model and Frumkin's linear isothermal *** thermodynamic aspects indicate that the process is physical,spontaneous,and *** optimization of the process by the Box Behnken design of experiments resulted in an adsorption capacity approaching 183.544 mg·g^(–1)([CV]=100 mg·L^(–1) and[CSLW-AC]=0.5 g·L^(–1) at 35 min).The results of the Lactuca sativa seeds germination in treated CV(70%),adsorbent solvent and thermal regeneration(more than 5 cycles),and process cost analysis(1.0484 USD·L^(–1))tests are encouraging and promising for future exploitations of the CSLW-AC material in different industrial fields.

关键词： Box Behnken Capparis spinosa L waste-activated carbon Cost analysis Isotherm Kinetic Regeneration

海岸结构及海浪作用力对海岸侵蚀情况影响的数值模拟研究

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海岸结构及海浪作用力对海岸侵蚀情况影响的数值模拟研究

作者： MAHAMOUD AHAMADI el-had 海南热带海洋学院

学位级别：硕士

海岸侵蚀是一种复杂的流体动力学现象,是波浪、水流和潮汐等自然力以及城市改造和气候变化等人为因素相互作用的结果。了解这一进程对于沿海地区的可持续发展管理至关重要,特别是降低基础设施建设和环境修复带来的生态风险有指导意义。... 详细信息

海岸侵蚀是一种复杂的流体动力学现象,是波浪、水流和潮汐等自然力以及城市改造和气候变化等人为因素相互作用的结果。了解这一进程对于沿海地区的可持续发展管理至关重要,特别是降低基础设施建设和环境修复带来的生态风险有指导意义。在这项研究中,我们集中在两个主要的问题研究:一个涉及梯形海岸结构,另一个具有简单的矩形形状。利用Ansys Fluent的先进功能,进行了数值模拟,以模拟波浪形态和不同海岸结构之间的相互作用,从而更好地了解和预测各种条件下的海岸侵蚀。Ansys Fluent软件采用Navier-Stokes方程和k-ωSST湍流模型捕捉流体动力学和波浪结构相互作用。流体体积元（VOF）模型也用于处理空气—水界面问题。模拟影响因素包括波浪高度、速度、压力、湍流动能和壁面剪应力等变量,应用于不同的波浪条件和力,如波浪形状、波浪高度、倾角、作用方向和海岸结构。研究中,这些变量也在不同的点A、B、C和D进行监测,范围从最低点到最高点。主要结论如下:（1）在海岸结构的最低监测点A,记录到最高压力和最高波浪,表明海岸结构承受了很大的载荷。B点是一个中间点,记录了最高的壁面剪切应力,并突出了波浪和海岸结构之间的强烈相互作用。在高点C,湍流动能显著,水流速度高,表明了在这一点上侵蚀风险的增加。（2）由于波浪的直接冲击,低角度的倾斜导致波浪高度升高。同时,拐角处显着增加波高,表明波浪方向以及海岸结构设计中构筑物结构分析十分重要。（3）在拐角处,压力增加有显着影响,因此需要加固沿海结构以承受更强烈的水动力影响。（4）波浪形状对水流速度有显著影响,形状F与形状F差异显著,F产生的平均流速更高。（5）不同波形对壁面剪应力的影响也有显著差异,F波形诱导的剪应力高于F2波形。适度的倾角也有利于较高的剪切力。（6）波高越高,湍流动能越大。急转弯也会加剧这种能量,从而影响侵蚀和沉积。像SC这样的海岸结构也通过与自然波浪动力学相互作用来强化这种能量。

关键词：海岸结构数值模拟波浪作用 Ansys Fluent VOF 传输方程海岸管理

Juvenile Systemic Sclerosis: About 9 Cases

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Open Journal of Pediatrics 2024年第2期14卷 320-326页

作者： Kaoutar Danaoui Houda Nassih Khadija Oujennane Rabiy el Qadiry Aicha Bourrahouat Said Amal Imane ait Sab B Pediatric Ward Mohammed VI University Hospital Center Marrakesh Morocco Dermatology Ward Mohammed VI University Hospital Center Marrakesh Morocco

Scleroderma is a rare disease with two primary forms: localized scleroderma (LS) and systemic sclerosis (SSc). Both are chronic conditions that can manifest in various patterns (subtypes) and are linked to extracutaneous involvement in pediatric patients. Juvenile SSc poses a higher risk of morbidity and mortality, with patients facing life-threatening complications such as lung, heart, and visceral organ fibrosis, and vasculopathy. In contrast, mortality is extremely rare in juvenile LS, but patients are susceptible to significant morbidity, leading to severe disfigurement and functional impairment. Treatment for scleroderma aims to control inflammation and address specific issues. An early diagnosis significantly enhances the overall outcome. This study conducts a retrospective descriptive analysis aiming to document the clinical manifestations, management approaches, and outcomes of systemic sclerosis in a cohort of nine children receiving treatment for juvenile systemic sclerosis at Pediatric B department of Mohammed VI University, Hospital Center in Marrakech, Morocco.

关键词： Scleroderma Systemic Sclerosis Children Pediatric

Sliding mode approach applied to sensorless direct torque control of cage asynchronous motor via multi-level inverter

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Protection and Control of Modern Power Systems 2020年第1期5卷 166-175页

作者： Soukaina el Daoudi Loubna Lazrak mustapha ait Lafkih Laboratory of Automatic Energy Conversion and MicroelectronicsFaculty of Sciences and TechnologySultan Moulay Slimane UniversityBeni MellalMorocco

To improve the robustness and performance of the dynamic response of a cage asynchronous motor,a direct torque control(DTC)based on sliding mode control(SMC)is adopted to replace traditional proportional-integral(PI)and hysteresis *** combination of the proposed strategy with sinusoidal pulse width modulation(SPWM)applied to a three-level neutral point clamped(NPC)inverter brings many advantages such as a reduction in harmonics,and precise and rapid tracking of the *** are performed for a three-level inverter with SM-DTC,a two-level inverter with SM-DTC and the three-level inverter with *** results show that the SM-DTC method achieves better performance in terms of reference tracking,while adoption of the threelevel inverter topology can effectively reduce the *** the SM-DTC to the three-level inverter presents the best solution for achieving efficient and robust *** addition,the use of a sliding mode speed estimator eliminates the mechanical sensor and this increases the reliability of the system.

关键词： Asynchronous cage motor Direct torque control Sinusoidal pulse width modulation Sliding mode control Speed estimator Three-level inverter

Eco-toxicity and health risk assessment of polycyclic aromatic hydrocarbons in surface sediments of Burullus Lake in Egypt

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China Geology 2024年第3期7卷 460-468页

作者： Hanan E Osman Mohamed H E el-Morsy Hazem T Abd el-Hamid Department of Biology Faculty of Applied ScienceUmm Al-Qura UniversityMecca 24382Saudi Arabia Deanship of Scientific Research Umm Al-Qura UniversityMakkah 24372Saudi Arabia National Institute of Oceanography and Fisheries(NIOF) Cairo 11865Egypt Botany and Microbiology Department Faculty of ScienceAl-Azhar UniversityCairo 11651Egypt

Polycyclic aromatic hydrocarbons(PAHs)are ubiquitous environmental contaminants of growing concern due to their potential ecological and human health *** study presents a comprehensive assessment of PAHs contamination in the surface sediments of Burullus Lake,a vital and second largest delta lake in *** aim was to evaluate the eco-toxicity and potential health risks associated with the presence of these *** seven sediment samples were collected from various drains in the southern part of Burullus *** extraction method was employed to extract PAHs(16PAHs)from the sediment ***,target compounds were located using *** results showed that samples contained PAHs levels ranging from 0.038×10^(-6)to 0.459×10^(-6),which is considered heavily polluted by the European standard for PAHs ***,there was no apparent source of PAHs in the elKhashah drain or the Brinbal Canal,as HPLC found none of the *** most prevalent compound in sediment samples along the study area was *** diagnostic indices in the present study indicated that the hydrocarbons in the region originated from pyrolytic and man-made sources along the drains of Burullus *** principal component analysis(PCA)and diagnostic ratios revealed that coal combustion and pyrolytic sources were responsible for the PAHs contamination in the surface *** non-carcinogenic risk(HI),which is the product of the HQs for the adult and child populations,respectively,was *** values under 1,therefore,demonstrated that they had no carcinogenic effects on human *** and MEQs in the sediments of Burullus Lake do not have a cancer-causing impact on *** the safety of nearby wildlife,aquatic life,and people,all activities that raise petroleum hydrocarbon levels in Burullus Lake must be adequately regulated and *** to the ecological risk assessment,there is little chance that PAHs will be found

关键词： Polycyclic aromatic hydrocarbons Diagnostic indices Toxicity Delta lake sediment Burullus Lake Human health risk Aquatic ecosystem HPLC Coal combustion

Genetic Variability and Phenotypic Correlations Study among Grain Quality Traits and Mineral elements Concentrations in Colored and Non-Colored Rice (Oryza sativa L.)

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Phyton-International Journal of Experimental Botany 2024年第7期93卷 1733-1748页

作者： Adel A.Rezk Mohamed M.el-Malky Heba I.Mohamed Hossam S.el-Beltagi Agricultural Biotechnology Department College of Agricultural and Food ScienceKing Faisal UniversityAl-Ahsa31982Saudi Arabia Plant Pathology Research Institute Agriculture Research CenterGiza12619Egypt Rice Research and Training Center Field Crop Research InstituteAgriculture Research Center33717Egypt Biological and Geological Sciences Department Faculty of EducationAin Shams UniversityCairo11511Egypt Biochemistry Department Faculty of AgricultureCairo UniversityGiza12613Egypt

Twenty-four rice genotypes were examined to assess genetic variability,heritability,and correlations for seven-grain quality traits,eight nutritional elements,and *** revealed signiﬁcant differences for the quality traits *** every trait under study,the phenotypic coefﬁcient of variation was higher than the correspon-dence genotypic coefﬁcient of *** in a broad sense varied from 29.75%for grain length to 98.31%for the elongation *** percentage recovery had a highly signiﬁcant positive correlation with milling and head rice ***,milling percentage had a highly positive correlation with head rice *** amylose percentage,all the genotypes belonged to low amylose except the Hassawi-1 variety,which had intermediate amylose *** nutrition contents of magnesium(Mg),sodium(Na),potas-sium(K),calcium(Ca),copper(Cu),manganese(Mn),zinc(Zn),iron(Fe),or protein percentage gave different variations for 24 rice genotypes under all the nutritional *** the 24 genotypes,ten rice genotypes–HighNutrient-1,HighNutrient-2,HighNutrient-9,HighNutrient-8,HighNutrient-3,Hassawi-2,HighNutrient-7,HighNutrient-6,Hassawi-1,and HighNutrient-4–had the highest heist value for all nutritional and protein con-tents,and could be used as a donor to improving new *** was a positive and signiﬁcant correlation between magnesium Mg,K,Zn and ***,K had a positive correlation with zinc Zn,Fe,and protein *** analysis was divided into two groups:theﬁrst group included all genotypes rich in nutri-ents,while the remaining genotypes with low nutritional content were included in the second group.

关键词： Amylose cluster analysis genotypes grain quality mineral nutrition rice

Intravesical instillation of platelet-rich plasma for treatment of interstitial cystitis/bladder pain syndrome:A pilot study

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Current Urology 2024年第1期18卷 49-54页

作者： Ahmed S.el Hefnawy Mohamed Attya Ahmed Hasan Esam el Sawy Mohamed Abdel-Razik Nasr el-Tabey Mansoura Urology and Nephrology Center Faculty of MedicineMansoura UniversityMansouraEgypt

Objective:The aim of this study was to evaluate the feasibility of intravesical instillation of platelet-rich plasma(PRP)to treat interstitial cystitis/bladder pain syndrome(IC/BPS).Materials and methods:Twenty PRP samples were tested in vitro for stability after exposure to urine samples with different pH.A pilot study involving 21 female patients with IC/BPS was conducted,and 6 weekly doses of autologous PRP(50 mL)were *** were followed up at the 2nd,4th,8th,and 12th weeks after terminating *** primary endpoint was the visual analog scale(VAS)for pain,and the secondary endpoints included the IC symptom index,IC problem index of the O'Leary-Sant questionnaire and global response assessment,urine culture,and *** was defined as a reduction in VAS by 30%or more compared with basal level,and adverse events were ***:The mean±SD of VAS was significantly reduced compared with basal level(4.4±2.6 vs.8.8±1.1,respectively,p=0.001).Meanwhile,80%of cases were considered successful,with a 50.1%reduction in the mean score compared with the basal *** mean±SD of IC symptom index and IC problem index significantly improved compared with the basal *** response assessment was markedly,moderately,and slightly improved in 2(10%),10(50%),and 5(25%)patients,respectively,and showed no change in 3(15%).Three patients had positive urine cultures at follow-up,but 1 withdrew after 2 sessions because of a lack of ***:Repeated intravesical instillation of PRP could be considered an effective and safe approach for treating IC/BPS.

关键词： Bladder pain syndrome Interstitial cystitis Platelet-rich plasma