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Preparation and photocatalytic property of Fe_(2)O_(3)/ZnO composites with superhydrophobicity

international Journal of Minerals,Metallurgy and Materials 2021年第6期28卷 1072-1079页

作者： muntadher i.rahmah Raad S.Sabry Wisam J.Aziz Physics Department College of ScienceMustansiriyah UniversityBaghdad 10052Iraq

A facile approach was developed to construct Fe_(2)O_(3)-modified ZnO micro/nanostructures with excellent superhydrophobicity and photocatalytic *** effects of stearic acid(SA)and Fe_(2)O_(3) on the morphological characteristics,water contact angle(WCA),and photocatalytic degradation were *** results showed that WCA increased from 144°±2°to 154°±2°when the weight of SA increased from 5 to 20 mg because of the formation of a hierarchical or rough ***,Fe_(2)O_(3)-modified ZnO micro/nanostructure surfaces before and after SA treatment(20 mg)were chosen to evaluate the photodegradation of methylene blue(MB)dye under the support of visible *** degraded after 80 min of irradiation,and its photodegradation efficiencies were 91.5%at the superhydrophobic state and 92%at the hydrophilic *** improvement in photocatalytic activity at both states might be attributed to an increase in surface area and improvement in charge carrier separation.

关键词： nano composites stearic acid superhydrophobic photocatalytic self-cleaning

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Preparation and Antibacterial Activity of Superhydrophobic Modified ZnO/PVC Nanocomposite

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Journal of Bionic Engineering 2022年第1期19卷 139-154页

作者： muntadher ismail rahmah Raad Saadon Sabry Wisam Jafer Aziz Medical instrumentation Engineering Department Al-Esraa University CollegeBaghdad10001Iraq Physics Department College of ScienceMustansiriyah UniversityBaghdad10001Iraq

We fabricated a superhydrophobic modified ZnO/PVC nanocomposite cluster with antibacterial properties using the chemical precipitation method and selected solvent/non-solvent(THF/ethanol)to *** effects of ethanol content(47%,50%,53%,and 56%)on nanocomposite morphology and Water Contact Angles(WCAs)were *** measurements confirmed the polycrystalline structure of ZnO with a wurtzite hexagonal phase,and EDX results indicated the presence of all element *** analysis of specimens revealed a rough surface structure resembling a cluster of NPs,and that structure was dominant when the ethanol content increased to 56%.The WCA increased on the superhydrophobic nanocomposite as ethanol content increased,and an optimum WCA(160°±2°)was obtained at an ethanol content of 56%.Antibacterial activity was tested on the superhydrophobic and hydrophobic states,and the superhydrophobic specimens showed good inhibition against Klebsiella *** Staphylococcus ***,the hydrophobic specimens demonstrated no antibacterial activity against *** promising results can inform the development of nanocomposites for many environmental applications.

关键词： ZnO PVC Superhydrophobicity Antibacterial WCA

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