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Structural and dielectric properties of doped ferrite nanomaterials suitable for microwave and biomedical applications

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Progress in Natural Science:Materials International 2015年第5期25卷 419-424页

作者： Imran Sadiq Shahzad Naseem muhammad naeem ashiq M.A.Khan Shanawer Niaz M.U.Rana Centre of Excellence in Solid State Physics University of the Punjab Institute of Chemical Sciences Bahauddin Zakariya University Department of Physics BUITEMS 4. Department of Physics University of Sargodha

The sol-gel auto-combustion method was adopted to synthesize nanomaterials of single-phase X-type hexagonal ferrites with the composition of Sr;Gd;Ni;Fe;Cd;O;（x=0.00,0.02,0.04,0.06,0.08,0.10 and y = 0,0.1,0.2,0.3,0.4,0.5）.The structural properties were carried out by XRD analysis and the lattice parameters show variation with the doping of *** average particle size measured by TEM was in the range of 8-10 nm which is beneficial in obtaining suitable signal-to-noise ratio in recording media and biomedical *** room temperature resistivity enhanced with the increase of the dopant *** increase in resistivity indicates that the synthesized materials can be considered good for the formation of the multilayer chip inductors（MLCIs） as well as for the reduction of eddy current *** dielectric constant decreased with the increase in the frequency which is the general reported trend of the hexagonal ferrites and can be explained on the basis of Koop’s theory and Maxwell-Wagner *** abnormal dielectric behavior indicates the formation of small polarons in the *** maximum value of tangent loss at low frequencies reflects the application of these materials in medium frequency devices（MF）.

关键词： Sol–gel Nanocrystalline materials Thermal properties Electrical properties Dielectric properties

Preparation and characterization of doubly substituted microwave absorbing material by sol-gel technique for super high frequency applications

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Progress in Natural Science:Materials International 2018年第4期28卷 478-482页

作者： Imran Sadiq Shahzad Naseem Saira Riaz S.Sajjad Hussain muhammad naeem ashiq Mazhar Rana Centre of Excellence in Solid State Physics University of the Punjab Institute of Chemical sciences Bahauddin Zakariya University

Rare earth Dy;and divalent Mn;elements substituting W-type hexagonal ferrites Ba;Dy;Zn;Fe;Mn;O;（x=0,0.02,0.06,0.1 and y=0,0.1,0.3,0.5）were prepared by sol-gel *** thermo-gravimetric analysis（TGA）and differential scanning calorimetry（DSC）was carried out to find the temperature at which single phase can be *** patterns indicate the presence of the single phase for all the synthesized samples with the absence of any extra peak due to unreacted material and secondary *** occurrence of absorption bands at low wave numbers(563 and 446 cm;),can be assigned to the stretching vibration of metal and oxygen ions in FTIR spectra,which also confirms the single hexagonal phase for prepared *** grains are of platelet like structure,which enhances the microwave absorption properties of hexagonal *** synthesized material exhibits the minimum reflection loss of-20.9 dB at 11.8 GHz frequency,which reflects the applications of this material in super high frequency *** microwave conductivity of the material increases with frequency.

关键词： Sol-Gel synthesis XRD Microwave absorption properties Microwave conductivity

Construction of robust and durable Cu_(2)Se-V_(2)O_(5) nanosheet electrocatalyst for alkaline oxygen evolution reaction

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Frontiers of Chemical Science and Engineering 2024年第6期18卷 71-83页

作者： Tauseef Munawar Ambreen Bashir Khalid Mujasam Batoo Saman Fatima Faisal Mukhtar Sajjad Hussain Sumaira Manzoor muhammad naeem ashiq Shoukat Alim Khan Muammer Koc Faisal Iqbal Institute of Physics The Islamia University of BahawalpurBahawalpur 63100Pakistan King Abdullah Institute for Nanotechnology King Saud UniversityRiyadh 11451Saudi Arabia Hybrid Materials Center(HMC) Sejong UniversitySeoul 05006Republic of Korea Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Institute of Chemical Sciences Bahauddin Zakariya UniversityMultan 60800Pakistan Division of Sustainable Development College of Science and EngineeringHamad Bin Khalifa UniversityQatar FoundationDoha 34110Qatar

Reducing the production costs of clean energy carriers such as hydrogen through scalable water electrolysis is a potential solution for advancing the hydrogen *** the various material candidates,our group demonstrated transition-metal-based materials with tunable electronic characteristics,various phases,and ***,electrochemical water oxidation using Cu_(2)Se-V_(2)O_(5) as a non-precious metallic electrocatalyst via a hydrothermal approach is *** water-splitting performance of all the fabricated electrocatalysts was evaluated after direct growth on a stainless-steel *** electrochemically tuned Cu_(2)Se-V_(2)O_(5) catalyst exhibited a reduced overpotential of 128 mV and provided a reduced Tafel slope of 57 mV·dec^(−1) to meet the maximum current density of 250 mA·cm^(−2).The optimized strategy for interfacial coupling of the fabricated Cu_(2)Se-V_(2)O_(5) catalyst resulted in a porous structure with accessible active sites,which enabled adsorption of the intermediates and afforded an effective charge transfer rate for promoting the oxygen evolution ***,the combined effect of the catalyst components provided long-term stability for over 110 h in an alkaline solution,which makes the catalyst promising for large-scale practical *** aforementioned advantages of the composite catalyst overcome the limitations of low conductivity,agglomeration,and poor stability of the pure catalysts(Cu2Se and V2O5).

关键词： oxygen evolution reaction Cu_(2)Se-V_(2)O_(5)composite nanosheets metal-diffused ions accessible adsorption sites

Photoreduction of carbon dioxide using strontium zirconate nanoparticles

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Science China Materials 2015年第8期58卷 634-639,593页

作者： muhammad naeem ashiq 王艳杰 muhammad Fahad Ehsan 贺涛 CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology Institute of Chemical Sciences Bahauddin Zakariya University

The utilization of CO2 and solar energy have drawn much attention due to global warming and fuel crisis. Of particular interest in our research, we prepared strontium zirconate(Sr Zr O3) nanoparticles as the photocatalyst to convert CO2 into value-added products. Sr Zr O3 nanoparticles were successfully synthesized via a sonochemical method and applied to the photoreduction of CO2. The samples were characterized by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, Brunauere Emmette Teller measurement, X-ray photoelectron spectroscopy and UV-vis absorption spectroscopy. Ethanol, methane and carbon monoxide were the major products with the yield respectively as follows, 41 μmol g-1, 2.57 μmol g-1 and 1.6 μmol g-1 after 4 h of reaction. The reason for the multiple photoreduction products is briefly discussed. Our work indicates that the as-prepared Sr Zr O3 nanoparticles can be used as a promising photocatalyst in turning CO2 into value-added chemicals.

关键词：光催化还原 Zr 二氧化碳 CO2 工业气体 XPS 催化剂 XRD 纳米颗粒

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Spherical uncertain linguistic Hamacher aggregation operators and their application on achieving consistent opinion fusion in group decision making

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International Journal of Intelligent Computing and Cybernetics 2021年第4期14卷 550-579页

作者： muhammad Qiyas Saleem Abdullah muhammad naeem Mathematics Abdul Wali Khan UniversityMardanPakistan Abdul Wali Khan University MardanPakistanand Department of Preparatory Year Umm Al-Qura UniversityMakkahSaudi Arabia

Purpose-The aim of this research is to establish a new type of aggregation operator based on Hamacher operational law of spherical uncertain linguistic numbers(SULNs).Design/methodology/approach-First,the authors define spherical uncertain linguistic sets and develop some operational laws of ***,the authors extended these operational laws to the aggregation operator and developed spherical uncertain linguistic Hamacher averaging and geometric aggregation ***-The authors were limited in achieving a consistent opinion on the fusion in group decision-making problem with the SULN ***/value-In order to give an application of the introduced operators,the authors first constrict a system of multi-attribute decision-making algorithm.

关键词： Multi-attribute group decision making Spherical fuzzy set Spherical uncertain linguistic Hamacher averaging operators Spherical uncertain linguistic Hamacher geometric operators

Radio resource management in energy harvesting cooperative cognitive UAV assisted IoT networks:A multi-objective approach

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Digital Communications and Networks 2024年第4期10卷 1088-1102页

作者： muhammad Rashid Ramzan muhammad naeem Omer Chughtai Waleed Ejaz Mohammad Altaf Department of Electrical and Computer Engineering COMSATS University Islamabad(CUI)Wah CampusPakistan Department of Electrical Engineering Lakehead UniversityBarrieONL4M 3X9Canada

Cooperative communication through energy harvested relays in Cognitive Internet of Things(CIoT)has been envisioned as a promising solution to support massive connectivity of Cognitive Radio(CR)based IoT devices and to achieve maximal energy and spectral efficiency in upcoming wireless *** this work,a cooperative CIoT system is contemplated,in which a source acts as a satellite,communicating with multiple CIoT devices over numerous *** Aerial Vehicles(UAVs)are used as relays,which are equipped with onboard Energy Harvesting(EH)*** adopted a Power Splitting(PS)method for EH at relays,which are harvested from the Radio frequency(RF)*** conjunction with this,the Decode and Forward(DF)relaying strategy is used at UAV relays to transmit the messages from the satellite source to the CIoT *** developed a Multi-Objective Optimization(MOO)framework for joint optimization of source power allocation,CIoT device selection,UAV relay assignment,and PS ratio *** formulated three objectives:maximizing the sum rate and the number of admitted CIoT in the network and minimizing the carbon dioxide *** MOO formulation is a Mixed-Integer Non-Linear Programming(MINLP)problem,which is challenging to *** address the joint optimization problem for an epsilon optimal solution,an Outer Approximation Algorithm(OAA)is proposed with reduced *** simulation results show that the proposed OAA is superior in terms of CIoT device selection and network utility maximization when compared to those obtained using the Nonlinear Optimization with Mesh Adaptive Direct-search(NOMAD)algorithm.

关键词： Cooperative communication Energy harvesting Power splitting Unmanned aerial vehicles Cognitive radio Internet of things Multi-objective optimization Relay assignment Power allocation

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Effect of different catalysts and growth temperature on the photoluminescence properties of zinc silicate nanostructures grown via vapor-liquid-solid method

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Chinese Physics B 2022年第5期31卷 657-665页

作者： Ghfoor muhammad Imran Murtaza Rehan Abid naeem Ahmad Department of Physics International Islamic UniversityIslamabad 44000Pakistan

We explore the photoluminescence properties of zinc silicate(Zn_(2)SiO_(4)) nanostructures synthesized by vapor-liquidsolid(VLS)mode of growth using three different catalysts(Sn,Ag,and Mn).Different catalysts significantly influence the growth rate which in turn has an impact on the structure and hence the photoluminescence of the prepared zinc silicate ***_(2)SiO_(4) has a wide bandgap of about 5.5 eV and in its pure form,it does not emit in visible region due to its inner shell electronic transitions between the 3 d5 energy ***,the incorporation of different catalysts(Sn,Ag and Mn)at different growth temperatures into the Zn_(2)SiO_(4) crystal growth kinetics provides wide visible spectral range of photoluminescence(PL)*** analysis shows broad multi-band spectrum in the visible region and distinct colors(red,yellow,green,blue,cyan and violet)are obtained depending on the crystalline structure of the prepared *** allowed transitions due to the effect of different catalysts on zinc silicate lattice offer a huge cross-section of absorption that generates strong *** correlation between the structural and optical properties of the synthesized nanostructures is discussed in *** synthesized photoluminescent nanostructures have potential applications in solidstate lighting and display devices.

关键词： nanostructures vapor-liquid-solid growth mode photoluminescence spectra fluorescence microscopy

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Aggregation operators and CRITIC-VIKOR method for confidence complex q-rung orthopair normal fuzzy information and their applications

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CAAI Transactions on Intelligence Technology 2023年第1期8卷 40-63页

作者： Tahir Mahmood Zeeshan Ali muhammad naeem Department of Mathematics and Statistics International Islamic University IslamabadIslamabadPakistan Umm Al-Qura University MakkahSaudi Arabia

Supply chain management is an essential part of an organisation's sustainable *** the concentration of natural environment,public,and economic influence and feasibility of your suppliers and purchasers is becoming progressively familiar as all industries are moving towards a massive sustainable *** handle such sort of developments in supply chain management the involvement of fuzzy settings and their generalisations is playing an important *** in mind this role,the aim of this study is to analyse the role and involvement of complex q-rung orthopair normal fuzzy(CQRONF)information in supply chain *** major impact of this theory is to analyse the notion of confidence CQRONF weighted averaging,confidence CQRONF ordered weighted averaging,confidence CQRONF hybrid averaging,confidence CQRONF weighted geometric,confidence CQRONF ordered weighted geometric,confidence CQRONF hybrid geometric operators and try to diagnose various properties and ***,with the help of the CRITIC and VIKOR models,we diagnosed the novel theory of the CQRONF-CRITIC-VIKOR model to check the sensitivity analysis of the initiated ***,in the availability of diagnosed operators,we constructed a multi-attribute decision-making tool for finding a beneficial sustainable supplier to handle complex ***,the initiated operator's efficiency is proved by comparative analysis.

关键词： averaging/geometric aggregation operators complex q-rung orthopair normal fuzzy information confidence levels strategic decision-making methods

Numerical Simulation of Reiner–Rivlin Nanofluid Flow under the Influence of Thermal Radiation and Activation Energy over a Rotating Disk

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Computer Modeling in Engineering & Sciences 2022年第6期131卷 1669-1692页

作者： Arfan Shahzad muhammad Imran muhammad Nawaz naeem Mohsan Raza Department of Mathematics Government College University FaisalabadFaisalabad38000Pakistan Department of Sciences&Humanities National University of Computer and Emerging SciencesChiniot-Faisalabad CampusFaisalabad38000Pakistan

In current study,the numerical computations of Reiner–Rivlin nanofluid flow through a rotational disk under the influence of thermal radiation and Arrhenius activation energy is *** innovative physical situations,the motile microorganisms are incorporated *** multiple slip effects are considered in the boundary *** bioconvection of motile microorganism is utilized alongside nanofluids to provide stability to enhanced thermal *** Bioconvection pattern in various nanoparticles accredits novel applications of biotechnology like the synthesis of biological polymers,biosensors,fuel cells,petroleum engineering,and the natural *** deploying some suitable similarity transformation functions,the governing partial differential equations(PDEs)of the flow problem are rehabilitated into dimensionless *** accomplished ordinary differential equations(ODEs)are solved numerically through the bvp4c scheme via a built-in function in computational MATLAB *** upshots of some prominent physical and bioconvection parameters including wall slip parameters,thermophoresis parameter,Brownian motion parameter,Reiner–Revlin nanofluid parameter,Prandtl number,Peclet number,Lewis number,bioconvection Lewis number,and the mixed convection parameter against velocity,temperature,nanoparticles concentration,and density of motile microorganism profiles are dichotomized and pondered through graphs and *** presented computations show that the velocity profiles are de-escalated by the wall slip parameters while the thermal and solutal fields are upgraded with augmentation in thermophoresis number and wall slip *** presence of thermal radiation enhances the temperature profile of *** concentration profile of nanoparticles is boosted by intensification in activation ***,the increasing values of bioconvection Lewis number and Peclet number decay the motile microorganisms’field.

关键词： Reiner-Rivlin nanofluid bioconvection motile swimming microorganisms rotational disk multiple slip conditions bvp4c