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m_(4)X_(3) mXenes:Application in Energy Storage Devices

Nano-micro Letters 2024年第10期16卷 522-542页

作者： Iftikhar Hussain Waqas Ul Arifeen Shahid Ali Khan Sikandar Aftab muhammad Sufyan Javed Sajjad Hussain muhammad Ahmad Xi Chen Jiyun Zhao PRosaiah Khaled Fahmi Fawy Adnan Younis Sumanta Sahoo Kaili Zhang Department of mechanical Engineering City University of Hong Kong83 Tat Chee AvenueKowloon TongHong KongPeople's Republic of China School of mechanical Engineering Yeungnam UniversityDaehak-roGyeongsan-siGyeongbuk-do 38541South Korea Department of Semiconductor Systems Engineering and Clean Energy Sejong UniversitySeoul 05006Republic of Korea School of Physical Science and Technology Lanzhou UniversityLanzhou 730000People's Republic of China Department of Nanotechnology and Advanced materials Engineering Sejong UniversitySeoul 05006Republic of Korea Department of Physics Saveetha School of EngineeringSaveetha Institute of Medical and Technical Sciences(SIMATS)ThandalamChennai 602105India Department of Chemistry Faculty of ScienceKing Khalid UniversityP.O.Box 900461413 AbhaSaudi Arabia Department of Physics College of ScienceUnited Arab Emirates UniversityP.O.Box 15551Al-AinUnited Arab Emirates School of Chemical Engineering Yeungnam UniversityGyeongsanGyeongbuk 38541South Korea

mXene has garnered widespread recognition in the scientific com-munity due to its remarkable properties,including excellent thermal stability,high conductivity,good hydrophilicity and dispersibility,easy processability,tunable surface properties,and admirable *** have been categorized into different families based on the number of m and X layers in m_(n+1)X_(n),such as m_(2)X,m_(3)X_(2),m_(4)X_(3),and,recently,m_(5)X_(4).Among these families,m_(2)X and m_(3)X_(2),par-ticularly Ti_(3)C_(2),have been greatly explored while limited studies have been given to m_(5)X_(4)mXene ***,studies on the m_(4)X_(3)mXene family have developed recently,hence,demanding a compilation of evaluated ***,this review provides a systematic overview of the latest advancements in m_(4)X_(3)mXenes,focusing on their properties and applications in energy storage *** objective of this review is to provide guidance to researchers on fostering m_(4)X_(3)mXene-based nanomaterials,not only for energy storage devices but also for broader applications.

关键词： mXene m_(4)X_(3)mXenes 2D materials Energy storage Properties

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Cervical Cancer Prediction Empowered with Federated machine Learning

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Computers, materials & Continua 2024年第4期79卷 963-981页

作者： muhammad Umar Nasir Omar Kassem Khalil Karamath Ateeq Bassam Sale.mAllah Almogadwy m.A.Khan Khan muhammad Adnan Department of Computer Sciences Bahria University Lahore CampusLahore54000Pakistan Faculty of Information Technology Liwa CollegeAbu Dhabi20009UAE Department of Computing Skyline University CollegeSharjah999041UAE Department of Computer Science Taibah UniversityMedina42315Saudi Arabia Riphah School of Computing and Innovation Faculty of ComputingRiphah International UniversityLahore54000Pakistan Department of Software Faculty of Artificial Intelligence and SoftwareGachon UniversitySeongnam13120Korea

Cervical cancer is an intrusive cancer that imitates various women around the world. Cervical cancer ranks in thefourth position because of the leading death cause in its premature stages. The cervix which is the lower end of thevagina that connects the uterus and vagina forms a cancerous tumor very slowly. This pre-mature cancerous tumorin the cervix is deadly if it cannot be detected in the early stages. So, in this delineated study, the proposed approachuses federated machine learning with numerous machine learning solvers for the prediction of cervical cancer totrain the weights with varying neurons empowered fuzzed techniques to align the neurons, Internet of medicalThings (IomT) to fetch data and blockchain technology for data privacy and models protection from hazardousattacks. The proposed approach achieves the highest cervical cancer prediction accuracy of 99.26% and a 0.74%misprediction rate. So, the proposed approach shows the best prediction results of cervical cancer in its early stageswith the help of patient clinical records, and all medical professionals will get beneficial diagnosing approachesfrom this study and detect cervical cancer in its early stages which reduce the overall death ratio of women due tocervical cancer.

关键词： Cervical cancer federated machine learning neurons blockchain technology

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The first record of a Konservat-Lagerstätten in which early post-settlement stages of fossil archaeobalanids(Cirripedia:Balanomorpha)are preserved

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Integrative Zoology 2024年第2期19卷 200-223页

作者： Tomáš KOCÍ Rok GAŠPARIC John BUCKERIDGE martina KOCOVÁ VESELSKÁ aleš ŠOSTER Ivancická581 PragueCzech Republic Palaeontological Department Natural History MuseumNational MuseumPragueCzech Republic Oertijdmuseum Bosscheweg 80Boxtel5293 WBThe Netherlands Institute for Palaeobiology and Evolution Novi TrgKamnikSlovenia Earth and Oceanic Systems Group RMIT UniversityMelbourneAustralia museums Victoria CarltonVictoriaAustralia Department of Paleobiology and Paleoecology Institute of Geology of the Czech Academy of SciencesPragueCzech Republic Institute of Geology and Palaeontology Charles UniversityPragueCzech Republic Faculty of Natural Sciences and Engineering University of LjubljanaLjubljanaSlovenia

A diverse sessile barnacle fauna from a miocene shallow-water deposit at Dolnja Stara vas in Slovenia is *** includes the first descriptions of early post settlement juveniles of Actinobalanus sloveniensis attached to mangrove *** represent three distinct growth phases,the earliest being interpreted as being less than 24 h post settlement,the others being 1 to 2 days post *** assessment of their taphonomy is *** adult balanomorphs are attached to a variety of organic substrates,including mangrove leaves and branches,fragments of the conifers?Taxodioxylon,Carapoxylon,pine cones,molluscs,and cetacean *** barnacles include ***,Amphibalanus venustus,and Perforatus perforatus—many with opercula retained within the *** retains some of the original shell *** is the second record of barnacle–plant associations from the Central Paratethys from Kamnik and *** paleoecology and paleogeography of the site are discussed.

关键词： acorn barnacles barnacle metamorphosis epibiont paleoecology taxonomy

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Source parameters and aftershock pattern of the October 7,2021,m5.9 Harnai earthquake,Pakistan

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Earthquake Science 2024年第4期37卷 304-323页

作者： mohammad Tahir Zeeshan Ahmad Sadia Sabahat muhammad Naveed mushtaq Talat Iqbal muhammad Ali Shah Alam Aftab Centre for Earthquake Studies National Centre for PhysicsIslamabad 44000Pakistan

On October 7,2021,a magnitude 5.9 earthquake struck the Harnai(Baluchistan)region of Pakistan,causing several fatalities and injuries within the epicentral ***-order tectonic deformation in this region is caused by the convergence of the Indian Plate with respect to the Eurasian *** Katwaz Block hinders the motion of the Indian Plate,resulting in the formation of strike-slip *** this study,the P-wave first-motion polarity technique was used to determine the mainshock faulting *** scanning of the polarity solutions was applied to determine the most suitable focal mechanism solution among the available solutions generated by the FOCmEC(focal mechanism)*** nodal planes correspond to different faulting styles(i.e.,thrust and strike-slip faulting).A nodal plane oriented in the NW-SE direction corresponded to a strike-slip mechanism,which was considered to be the fault ***,this earthquake was associated with the Harnai-Karahi strike-slip fault zone owing to the fault strike and direction of *** apparent stress drop,fault length,and moment magnitude of the Harnai earthquake were 35.4 bar,6.1 km,and 5.9,respectively.A lower b-value for the Gutenberg-Richter law was observed prior to the ***α-than b-values(α>b)indicate that this earthquake was governed by large events as opposed to small-magnitude *** Harnai sequence had a decay exponent close to unity,lasted for 145 days,and produced few *** study will help the future hazard mitigation in the region.

关键词： focal mechanism solution selection of fault plane FPFIT stress inversion oblique slip mechanism

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Correlation of tumor-associated macrophage density and proportion of m2 subtypes with the pathological stage of colorectal cancer

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World Journal of Gastrointestinal Oncology 2024年第5期16卷 1878-1889页

作者： Fouzia Fazal muhammad Arsalan Khan Sumayya Shawana Rahma Rashid muhammed mubarak Department of Pathology Jinnah Medical and Dental CollegeKarachi 74800SindhPakistan Department of General Surgery Sindh Institute of Urology&Transplantation(SIUT)Karachi 74200SindhPakistan Department of Pathology Bahria University of Health SciencesKarachi 74400SindhPakistan Department of Pathology SIUTKarachi 74200SindhPakistan

BACKGROUND Colorectal cancer(CRC)is a prevalent global malignancy with complex prognostic ***-associated macrophages(TAms)have shown paradoxical associations with CRC survival,particularly concerning the m2 *** We aimed to establish a simplified protocol for quantifying m2-like TAms and explore their correlation with clinicopathological *** A cross-sectional study included histopathological assessment of paraffinembedded tissue blocks obtained from 43 CRC *** CD68 and CD163 immunohistochemistry,we quantified TAms in tumor stroma and front,focusing on m2 ***,histopathological,and clinical parameters were *** TAm density was significantly higher at the tumor front,with the m2 proportion three times greater in both *** tumor front had a higher m2 proportion,which correlated significantly with advanced tumor stage(P=0.04),pathological nodal involvement(P=0.04),and lymphovascular invasion(LVI,P=0.01).However,no significant association was found between the m2 proportion in the tumor stroma and clinicopathological *** Our study introduces a simplified protocol for quantifying m2-like TAms in CRC tissue *** demonstrated a significant correlation between an increased m2 proportion at the tumor front and advanced tumor stage,nodal involvement,and *** suggests that m2-like TAms might serve as potential indicators of disease progression in CRC,warranting further investigation and potential clinical application.

关键词： Colorectal cancer macrophages Tumor stroma m2 subset Tumor front Tumor stage Lymphovascular invasion Prognosis Tumor-associated macrophages Immunohistochemistry

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Tuning structural,electrical,dielectric and magnetic properties of mg-Cu-Co ferrites via dysprosium(Dy^(3+))doping

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Journal of Rare Earths 2024年第1期42卷 137-146,I0005页

作者： maria Akhtar m.S.Hasan Nasir Amin N.A.morley muhammad Imran Arshad Department of Physics Government College UniversityFaisalabad38000Pakistan Department of Physics The University of Lahore53700Pakistan Department of materials Science and Engineering The University of SheffieldS13JDUK Department of Physics&Astronomy University College LondonUK

In current research work,Dy3+substituted mg0.5Cu0.25Co0.25Fe2-xDyxO4(0.0≤x≤0.04 with the step interval of 0.01)soft ferrites were synthesized by the sol-gel auto combustion *** prepared samples were characterized by the techniques using X-ray diffraction(XRD),scanning electron microscopy(SEm),energy dispersive X-ray spectroscopy(EDS),Fourier transform infrared(FTIR)spectroscopy,curre nt-voltage(Ⅰ-Ⅴ)measurement,LCR meter,vibrating sample magnetometer(VSm)and *** data reveal that the average crystallite size is 49.71 nm and the lattice constant is 0.83703 nm for sample x=*** non-uniform grain growth was demonstrated by micrographs and impurity-free elemental composition was observed from EDX *** DC resistivity has an increasing and decreasing trend in ferromagnetic and paramagnetic regions with an increase in ***,the high resistivity is observed with the order of 1010Ω·cm,and the activation energy is 0.944 eV for samples x=*** dielectric parameters including dielectric constant,dielectric losses,and impedance gradually decrease with the increase in frequency from 8 Hz to 8 *** minimum dielectric loss at high frequency is found for sample x=*** coercivity(Hc)and saturation magnetization(ms)are found in the ranges of 520.82-544.02 Oe and 20.5841-21.1473 emu/g,*** observations confirm that dysprosium(x=0.03)doped mCC-soft ferrites may be applicable in transformer cores,microwave absorbance,and telecommunication devices.

关键词： Soft ferrites DC resistivity Dielectric loss Impedance Coercivity Rare earths

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A new fractional order 6D chaotic model:Study of model dynamics,system structure graph,electronic circuit realization and fractional control

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Journal of Ocean Engineering and Science 2024年第2期9卷 112-125页

作者： m.Higazy Norah Almalki Shabbir muhammad A.Al-Ghamdi Department of mathematics and Statistics College of ScienceTaif UniversityP.O.Box 11099Taif 21944Saudi Arabia Department of Physics and Engineering mathematics Faculty of Electronic EngineeringMenoufia UniversityMenouf 32952Egypt Research Center for Advanced materials Science(RCAmS) King Khalid UniversityP.O.Box 9004Abha 61413Saudi Arabia Department of Chemistry College of ScienceKing Khalid UniversityP.O.Box 9004Abha 61413Saudi Arabia Department of Physics Faculty of ScienceKing Abdulaziz UniversityP.O.Box 80203Jeddah 21589Saudi Arabia

A new fractional 6D chaotic model is constructed in this *** new fractional 6D chaotic model has six positive parameters plus the fractional order with eight nonlinear *** complicated chaotic dy-namics of the new fractional 6D model is presented and *** basic properties of this model are studied and its chaotic attractors,dissipative feature,symmetry,equilibrium points,Lyapunov Exponents are *** new dynamics of the 6D fractional model is numerically simulated using matlab *** addition,utilizing the graph theory tools certain structural characteristics are *** electrical circuit is built to implement the new 5.4 fractional order 6D ***,an active fractional order controller is proposed to control the new model at different fractional *** chaos of the new model is very useful and can be used to produce random keys for data encryption.

关键词： Chaotic systems Fractional calculus Lyapunov exponents Chaotic attractors Adjacency matrix Hermitian matrix Electronic circuit realization

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Al^(3+) doped CeO_(2) for proton conducting fuel cells

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International Journal of minerals,metallurgy and materials 2024年第10期31卷 2253-2262页

作者： Sarfraz Shahzad Rasool muhammad Khalid mAKYousaf Shah Bin Zhu Jung-Sik Kim muhammad Imran Asghar Nabeela Akbar Wenjing Dong Jiangsu Provincial Key Laboratory of Solar Energy Science and Technology/Energy Storage joint Research Center School of Energy and EnvironmentSoutheast UniversityNanjing 210096China School of microelectronics Hubei UniversityWuhan 430062China Sino-French Engineer School/School of General Engineering Beihang UniversityBeijing 100191China Renewable Energy Technologies Group Faculty of Engineering and Natural SciencesTampere UniversityFI-33014Finland

Developing high ionic conducting electrolytes is crucial for applying proton-conducting fuel cell(PCFCs)*** cur-rent study investigates the effect of alumina on the structural,morphological,electrical,and electrochemical properties of CeO_(2).Lattice oxygen vacancies are induced in CeO_(2) by a general doping concept that enables fast ionic conduction at low-temperature ranges(300-500℃)for *** refinement of the X-ray diffraction(XRD)patterns established the pure cubic fluorite structure of Al-doped CeO_(2)(ADC)samples and confirmed Al ions’fruitful integration in the CeO_(2) *** electronic structure of the alumina-doped ceria of the materials(10ADC,20ADC,and 30ADC)has been *** a result,it was found that the best composition of 30ADC-based electrolytes induced maximum lattice oxygen *** corresponding PCFC exhibited a maximum power output of 923 mW/cm^(2)at 500℃.moreover,the investigation proves the proton-conducting ability of alumina-doped ceria-based fuel cells by using an oxide ion-blocking layer.

关键词： proton ceramic fuel cells oxygen vacancies higher fuel cell performance doping fast ions transportation

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Ir single atoms on NiFeZn-LDH matrix for exceptional oxygen evolution reaction

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Nano Research 2024年第8期17卷 7039-7044页

作者： muhammad Israr muhammad Humayun Jiaqi Zhang Khadim Shah Xin Tan Chen Chen Yadong Li Department of Chemistry Tsinghua UniversityBeijing 100084China Energy Water and Environment LabCollege of Humanities and SciencePrince Sultan UniversityRiyadh11586Saudi Arabia

To address the sluggish kinetics of the oxygen evolution reaction(OER),a potential approach is to rationally design and fabricate extremely effective single atom catalysts(SACs).Using an appropriate matrix to stabilize single-atom active centers with optimal geometric and electronic structures is crucial for enhancing catalytic ***,we report the design and fabrication of Ir single atoms on NiFeZn layered double hydroxide(Ir-SAC/NiFeZn-LDH)electrocatalyst for highly efficient and stable *** is investigated that the NiFeZn support exhibits abundant defect sites and unsaturated coordination *** sites function to anchor and stabilize single Ir single atoms on the *** strong synergetic electronic interaction between the Ir single atoms and the NiFeZn matrix resulted in remarkable OER performance of the as-fabricated Ir-SAC/NiFeZn *** a loading Ir content of 1.09 wt.%,this catalyst demonstrates a highly stable OER activity,with an overpotential of 196 mV at 10 mA·cm^(−2) and a small Tafel slope of 35 mV·dec^(−1) for the OER in a 1 m KOH *** results significantly surpass the performance of the commercially available IrO_(2) catalyst.

关键词： Ir single atoms layered double hydroxides rational design geometric optimization oxygen evolution reaction

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Recent progress in two-dimensional metallenes and their potential application as electrocatalyst

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Journal of Energy Chemistry 2024年第7期94卷 577-598页

作者： Umer Shahzad mohsin Saeed muhammad Fazle Rabbee Hadi m.marwani Jehan Y.Al-Humaidi muhammad Altaf Raed H.Althomali Kwang-Hyun Baek md.Rabiul Awual mohammed m.Rahman Department of Chemistry Faculty of ScienceKing Abdulaziz UniversityJeddah 21589Saudi Arabia Department of Biotechnology Yeungnam UniversityGyeongsanSouth Korea Center of Excellence for Advanced materials Research(CEAmR) King Abdulaziz UniversityJeddah 21589Saudi Arabia Department of Chemistry College of SciencePrincess Nourah Bint Abdulrahman UniversityP.O.BOX 84428Riyadh 11671Saudi Arabia Department of Chemistry Center of Excellence for Innovation in Chemistry(PERCH-CIC)Center of Excellence in Materials Science and TechnologyFaculty of ScienceChiang Mai UniversityChiang Mai 50200Thailand Department of Chemistry College of Art and SciencePrince Sattam Bin Abdulaziz UniversityWadi Al-Dawasir 11991Saudi Arabia Western Australian School of mines:minerals Energy and Chemical EngineeringCurtin UniversityGPO Box U 1987PerthWA 6845Australia

In this article,we looked at metallenes,a novel class of two-dimensional(2D)metals that are attracting interest in the energy and catalysis *** is one area where their exceptional physicochemical and electrical characteristics might be *** are unique because they include several metal atoms that are not in a coordinated *** makes them more active and improves their atomic uti-lization,which in turn increases their catalytic *** article delves into the potential of two-dimensional metals as electrocatalysts for carbon dioxide reduction,fuel oxidation,oxygen evolution,and oxygen reduction reactions in the context of sustainable energy *** to the exception-ally high surface-to-volume ratio,large surface area as well as their optimized atomic use efficiency,2D materials defined by atomic layers are crucial for surface-related sustainable energy *** to its exceptional properties,such as high conductivity and the ability to enhance the exposure of active metal sites,2D metallenes have recently attracted a lot of interest for use in catalysis,electronics,and energy-related *** their highly mobility,adjustable surface states,and electrical struc-tures that can be fine-tuned,2D metallenes are promising nanostructure materials for use in energy con-version with the sustainable applications.

关键词： metallenes Electrocatalysts Electrochemical processes Atomically thin structure

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