检索结果-南通市图书馆

Oxygen/Sulfur Atom Exchange Copolymerization of Carbon Disulfide and Propylene Oxide by a Highly Effective Heterogeneous Berlin Green Catalyst

引用

Chemical Research in Chinese Universities 2023年第5期39卷 790-796页

作者： Munir Ullah KHAN Safir Ullah KHAN CAO Xiaohan muhammad USMAN muhammad naeem shah Abdul GHAFFAR muhammad HASSAN ZHANG Chengjian ZHANG Xinghong State Key Laboratory of Motor Vehicle Biofuel Technology International Research Center for X PolymersDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027P.R.China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Shanxi 030013P.R.China Hefei National Laboratory for Physical Science at the Microscale School of Life SciencesUniversity of Science and Technology of ChinaHefei 230027P.R.China Key Laboratory of Macromolecular Synthesis and Functionalization(Ministry of Education) International Research Center for X PolymersDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027P.R.China College of Information Science and Electronic Engineering Zhejiang UniversityHangzhou 310027P.R.China Advanced Materials Research Center Zhejiang University-University of Illinois at Urbana-Champaign Institute(ZJU-UIUC)Haining 314400P.R.China

In this study,we report that Berlin Green(FeFe-BG)framework exhibits superior performance in the catalytic coupling of carbon disulfide(CS_(2))and propylene oxide(PO)to generate a random copolymer containing thioether,propylene monothiocarbonate and ether *** and sulfur atom exchange was detected in polymeric and cyclic thiocarbonate byproducts and utilized to modulate the copolymerization of CS_(2)and propylene *** coupling of PO and CS_(2)was selective for copolymer formation under various reaction conditions.^(1)H and^(13)C NMR spectroscopy determined two distinct polymer linkages and two cyclic *** number average molecular weights ranged from 6.4 kg/mol to 10.5 kg/mol,with a comparatively low polydispersity of *** CS_(2)/PO molar feed ratio had a significant impact on the O/S exchange process;the ratio of cyclic thiocarbonate byproducts could be efficiently regulated by tuning the CS_(2)molar feed ratio.

关键词： Carbon disulfide Copolymerization Prussian Blue analogue Heterogeneous catalysis Berlin Green

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Ir single atoms on NiFeZn-LDH matrix for exceptional oxygen evolution reaction

引用

Nano Research 2024年第8期17卷 7039-7044页

作者： muhammad Israr muhammad Humayun Jiaqi Zhang Khadim shah Xin Tan Chen Chen Yadong Li Department of Chemistry Tsinghua UniversityBeijing 100084China Energy Water and Environment LabCollege of Humanities and SciencePrince Sultan UniversityRiyadh11586Saudi Arabia

To address the sluggish kinetics of the oxygen evolution reaction(OER),a potential approach is to rationally design and fabricate extremely effective single atom catalysts(SACs).Using an appropriate matrix to stabilize single-atom active centers with optimal geometric and electronic structures is crucial for enhancing catalytic ***,we report the design and fabrication of Ir single atoms on NiFeZn layered double hydroxide(Ir-SAC/NiFeZn-LDH)electrocatalyst for highly efficient and stable *** is investigated that the NiFeZn support exhibits abundant defect sites and unsaturated coordination *** sites function to anchor and stabilize single Ir single atoms on the *** strong synergetic electronic interaction between the Ir single atoms and the NiFeZn matrix resulted in remarkable OER performance of the as-fabricated Ir-SAC/NiFeZn *** a loading Ir content of 1.09 wt.%,this catalyst demonstrates a highly stable OER activity,with an overpotential of 196 mV at 10 mA·cm^(−2)and a small Tafel slope of 35 mV·dec^(−1)for the OER in a 1 M KOH *** results significantly surpass the performance of the commercially available IrO_(2)catalyst.

关键词： Ir single atoms layered double hydroxides rational design geometric optimization oxygen evolution reaction

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

The Spherical q-Linear Diophantine Fuzzy Multiple-Criteria Group Decision-Making Based on Differential Measure

引用

Computer Modeling in Engineering & Sciences 2024年第2期138卷 1925-1950页

作者： Huzaira Razzaque shahzaib Ashraf muhammad naeem Yu-Ming Chu Institute of Mathematics Khwaja Fareed University of Engineering&Information TechnologyRahim Yar Khan64200Pakistan Department of Mathematics Deanship of Applied SciencesUmm Al-Qura UniversityMeccaSaudi Arabia Department of Mathematics Huzhou UniversityHuzhou313000China

Spherical q-linearDiophantine fuzzy sets(Sq-LDFSs)provedmore effective for handling uncertainty and vagueness in multi-criteria decision-making(MADM).It does not only cover the data in two variable parameters but is also beneficial for three parametric *** Pythagorean fuzzy sets,the difference is calculated only between two parameters(membership and non-membership).According to human thoughts,fuzzy data can be found in three parameters(membership uncertainty,and non-membership).So,to make a compromise decision,comparing Sq-LDFSs is *** measures of different fuzzy sets do,however,can have several flaws that can lead to counterintuitive *** instance,they treat any increase or decrease in the membership degree as the same as the non-membership degree because the uncertainty does not change,even though each parameter has a different *** the Sq-LDFSs comparison,this research develops the differentialmeasure(DFM).Themain goal of the DFM is to cover the unfair arguments that come from treating different types of FSs opposing criteria *** to their relative positions in the attribute space and the similarity of their membership and non-membership degrees,two Sq-LDFSs formthis preference connectionwhen the uncertainty remains same in both *** to the degree of superiority or inferiority,two Sq-LDFSs are shown as identical,equivalent,superior,or inferior over one *** suggested DFM’s fundamental characteristics are *** on the newly developed DFM,a unique approach tomultiple criterion group decision-making is *** suggestedmethod verifies the novel way of calculating the expert weights for Sq-LDFSS as in *** proposed technique in three parameters is applied to evaluate solid-state drives and choose the optimum photovoltaic cell in two applications by taking uncertainty parameter *** method’s applicability and validity shown by the findings are contrasted with those obtained using various

关键词： Multi-criteria group decision-making spherical q-linear Diophantine fuzzy sets differencemeasures photovoltaic cells medical diagnosis

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Donor-acceptor(D-A)terpolymers based on alkyl-DPP and t-BocDPP moieties for polymer solar cells

引用

Chinese Chemical Letters 2017年第12期28卷 2223-2226页

作者： Fateh Ullah Sun Qian Weitao Yang muhammad naeem shah Zhongqiang Zhang Hongzheng Chen Chang-Zhi Li MOE Key Laboratory of Macromolecular Synthesis and Functionalization State Key Laboratory of Silicon MaterialsDepartment of Polymer Science andEngineeringZhejiang UniversityHangzhou 310027China

A series of low band gap terpolymers based on 4,8-bis（5-（2-ethylhexyl）thiophen-2-yl）benzo[l,2-b：4,5- b＇]dithiophene （BDTr） and diketopyrrolopyrrole （DPP） with varied solubilizing groups （i.e., tert- butoxycarbonyl, t-Boc and 2-octyldodecyl） are developed as electron donors for bulk heterojunction （BHJ） polymer solar cells （PSCs）. The results reveal that the one with 50% t-Boc concentration （P3） performs better than the other terpolymers used in this study in conventional PSC devices with a power conversion efficiency of 2.92%.

关键词： Conjugated polymerOrganic semiconductorPolymer solar cellsBulk heterojunctionDiketopyrrolopyrrole

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Efficient and 1,8-diiodooctane-free ternary organic solar cells fabricated via nanoscale morphology tuning using small-molecule dye additive

引用

Nano Research 2017年第11期10卷 3765-3774页

作者： Shuhua Zhang muhammad naeem shah Feng Liu Zhongqiang Zhang Qin Hu Thomas P. Russell Minmin Shi Chang-Zhi Li Hongzheng Chen MOE Key Laboratory of Macromolecular Synthesis and Functionalization State Key Laboratory of Silicon Materials Department of Polymer Science amp Engineering Zhejiang University Hangzhou 310027 China Department of Physics and Astronomy Shanghai Jiao Tong University Shanghai 200240 China Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

The ternary strategy for incorporating multiple photon-sensitive components into a single junction has emerged as an effective method for optimizing the nanoscale morphology and improving the device performance of organic solar cells （OSCs）.In this study,efficient and stable ternary OSCs were achieved by introducing the small-molecule dye （5E,5＆#39;E）-5,5＆#39;-（4＆#39;,4″-（1,2-diphenylethene-1,2-diyl）bis（biphenyl-4＆#39;,4-diyl））bis（methan-1-yl-1-ylidene）bis（3-ethyl-2-thioxothia zolidin-4-one）（BTPERn） into poly[4,8-bis（5-（2-ethylhexyl）thiophen-2-yl）benzo[1,2-b：4,5-b＆#39;]dithiopheneco-3-fluorothieno[3,4-b]thiophene-2-carboxylate] （PTB7-Th）：[6,6]-phenyl C71 butyric acid methyl ester （PC71BM） blend films processed using a 1,8-diiodooctane （DIO）-free *** incorporation of BTPE-Rn enhanced the short-circuit current density and fill factor of the ternary OSCs compared with those of binary *** investigation of the optical,electronic,and morphological properties of the ternary blends indicated that the third component of BTPE-Rn not only promoted the photon utilization of blends through the energy-transfer process but also improved the electron mobility of the blends owing to the fullerene-rich nanophase *** importantly,this ternary strategy of utilizing a small-molecule dye to replace the photounstable DIO additive enhanced the operational stability of the OSCs.

关键词： ternary organic solar cell energy transfer mobility 1 8-diiodooctane (DIO)-free

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Diabetes mellitus:Is Pakistan the epicenter of the next pandemic?

引用

Chronic Diseases and Translational Medicine 2024年第1期10卷 75-77页

作者： muhammad Bilal shahid Mahnoor Saeed Hamza naeem Usha Kumari King Edward Medical University LahorePakistan Dow University of Health Sciences KarachiPakistan

To the Editor,Diabetes mellitus(DM)is an endocrine disorder of chronic hyperglycemia diagnosed by fasting blood sugar levels of≥126 mg/dL or glycated hemoglobin(HbA1c)levels of≥6.5%.Type 1 DM involves a lack of insulin secretion by the pancreas,whereas the human body's resistance to insulin combined with impaired function of beta cells causes type 2 DM.

关键词： impaired Diabetes mellitus

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Variable range hopping transport and dielectric relaxation mechanism in GdCrO_(3) rare-earth orthochromite perovskite

引用

Journal of Rare Earths 2024年第7期42卷 1304-1316,I0004页

作者： muhammad Javed Ayaz Arif Khan Jamal Kazmi naeem Akbar Said Nasir Khisro Amanullah Dar Aleem Dad Khan Tareen Mohd Ambri Mohamed Department of Physics The University of Azad Jammu and KashmirMuzaffarabad13100Pakistan Department of Physics University of Kotli Azad Jammu and KashmirKotli11100Pakistan Institute of Microengineering and Nanoelectronics Universiti Kebangsaan Malaysia43600BangiSelangorMalaysia Department of Mathematics University of Kotli Azad Jammu and KashmirKotli11100Pakistan

The polycrystalline GdCrO_(3)(GCO)perovskite orthochromite was synthesized by the sol-gel auto-combustion *** Rietveld refined X-ray diffraction(XRD)profile of GCO confirms that the orthorhombic phase crystallizes in perovskite crystal structure with space group *** transmission electron microscopy and selected area electron diffraction divulge the polycrystalline nature of the perovskite *** field emission scanning electron microscopy(FESEM)images reveal the microstructural polyhedral growth of grains separated by sharp grain *** chemical states of the ions present in the compound were investigated by X-ray photoelectron spectroscopy(XPS)studies,and the electrical pathways were *** impedance studies were carried out in the experimental frequency and temperature ranges of 40 Hz-4 MHz and 178-408 K,*** equivalent circuit model(RGQG)(RGBQGB)resolves the impedance response into two contributions originating from the intra-grain and inter-granular micro-constituents of the *** electrical conduction mechanism is based on the Mott variable range hopping *** complex electric modulus studies demonstrate the short-and long-range mobility of the charge carriers and rule out the presence of electrode effects on the dielectric relaxation mechanism of the *** decreasing pattern of dielectric permittivity with frequency is explained by the Maxwell-Wagner type of *** frequency dependence of the loss factor exhibits the presence of thermally activated relaxation time distribution in the material.

关键词： Auto-combustion Perovskite Electro-ceramic Dielectric Electrical transport Impedance

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Deep Learning Based Efficient Crowd Counting System

引用

Computers, Materials & Continua 2024年第6期79卷 4001-4020页

作者： Waleed Khalid Al-Ghanem Emad Ul Haq Qazi muhammad Hamza Faheem Syed shah Amanullah Quadri Department of Computer Engineering College of Computer and Information SciencesKing Saud UniversityRiyadh12372Saudi Arabia Centre of Excellence in Cybercrime and Digital Forensics Naif Arab University for Security SciencesRiyadh14812Saudi Arabia Center of Excellence for Information Assurance(COEIA) King Saud UniversityRiyadh12372Saudi Arabia

Estimation of crowd count is becoming crucial nowadays,as it can help in security surveillance,crowd monitoring,and management for different *** is challenging to determine the approximate crowd size from an image of the crowd’s *** in this research study,we proposed a multi-headed convolutional neural network architecture-based model for crowd counting,where we divided our proposed model into two main components:(i)the convolutional neural network,which extracts the feature across the whole image that is given to it as an input,and(ii)the multi-headed layers,which make it easier to evaluate density maps to estimate the number of people in the input image and determine their number in the *** employed the available public benchmark crowd-counting datasets UCF CC 50 and ShanghaiTech parts A and B for model training and testing to validate the model’s *** analyze the results,we used two metrics Mean Absolute Error(MAE)and Mean Square Error(MSE),and compared the results of the proposed systems with the state-of-art models of crowd *** results show the superiority of the proposed system.

关键词： Crowd counting EfficientNet multi-head attention convolutional neural network transfer learning

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Construction of robust and durable Cu_(2)Se-V_(2)O_(5) nanosheet electrocatalyst for alkaline oxygen evolution reaction

引用

Frontiers of Chemical Science and Engineering 2024年第6期18卷 71-83页

作者： Tauseef Munawar Ambreen Bashir Khalid Mujasam Batoo Saman Fatima Faisal Mukhtar Sajjad Hussain Sumaira Manzoor muhammad naeem Ashiq Shoukat Alim Khan Muammer Koc Faisal Iqbal Institute of Physics The Islamia University of BahawalpurBahawalpur 63100Pakistan King Abdullah Institute for Nanotechnology King Saud UniversityRiyadh 11451Saudi Arabia Hybrid Materials Center(HMC) Sejong UniversitySeoul 05006Republic of Korea Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Institute of Chemical Sciences Bahauddin Zakariya UniversityMultan 60800Pakistan Division of Sustainable Development College of Science and EngineeringHamad Bin Khalifa UniversityQatar FoundationDoha 34110Qatar

Reducing the production costs of clean energy carriers such as hydrogen through scalable water electrolysis is a potential solution for advancing the hydrogen *** the various material candidates,our group demonstrated transition-metal-based materials with tunable electronic characteristics,various phases,and ***,electrochemical water oxidation using Cu_(2)Se-V_(2)O_(5) as a non-precious metallic electrocatalyst via a hydrothermal approach is *** water-splitting performance of all the fabricated electrocatalysts was evaluated after direct growth on a stainless-steel *** electrochemically tuned Cu_(2)Se-V_(2)O_(5) catalyst exhibited a reduced overpotential of 128 mV and provided a reduced Tafel slope of 57 mV·dec^(−1) to meet the maximum current density of 250 mA·cm^(−2).The optimized strategy for interfacial coupling of the fabricated Cu_(2)Se-V_(2)O_(5) catalyst resulted in a porous structure with accessible active sites,which enabled adsorption of the intermediates and afforded an effective charge transfer rate for promoting the oxygen evolution ***,the combined effect of the catalyst components provided long-term stability for over 110 h in an alkaline solution,which makes the catalyst promising for large-scale practical *** aforementioned advantages of the composite catalyst overcome the limitations of low conductivity,agglomeration,and poor stability of the pure catalysts(Cu2Se and V2O5).

关键词： oxygen evolution reaction Cu_(2)Se-V_(2)O_(5)composite nanosheets metal-diffused ions accessible adsorption sites

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Analysis of Genetic Alterations in TP53 Gene in Breast Cancer - A Secondary Publication

引用

Proceedings of Anticancer Research 2024年第3期8卷 25-35页

作者： Baqaur Rehman muhammad Abubakar muhammad naeem Kiani Rooma Ayyoub Department of Biosciences COMSATS University IslamabadPark RdIslamabad Capital Territory 45550Pakistan Guangdong Key Laboratory of Biomedical Measurements and Ultrasound Imaging School of Biomedical EngineeringShenzhen University Medical SchoolShenzhen UniversityShenzhen 518060China

Tumor protein p53 (TP53) mediates DNA repair and cell proliferation in growing cells. The TP53 gene is a tumor suppressor that regulates the expression of target genes in response to multiple cellular stress factors. Key target genes are involved in crucial cellular events such as DNA repair, cell cycle regulation, apoptosis, metabolism, and senescence. TP53 genetic variants and the activity of the wild-type p53 protein (WT-p53) have been linked to a wide range of tumorigenesis. Various genetic and epigenetic alterations, including germline and somatic mutations, loss of heterozygosity, and DNA methylation, can alter TP53 activity, potentially resulting in cancer initiation and progression. This study was designed to screen three reported mutations in the DNA-binding domain of the p53 protein in breast cancer, to evaluate the relative susceptibility and risk associated with breast cancer in the local population. Genomic DNA was isolated from 30 breast tumor tissues along with controls. Tetra and Tri ARMS PCR were performed to detect mutations in the TP53 coding region. For SNPs c.637C>T and c.733C>T, all analyzed cases were homozygous for the wild-type allele ‘C,’ while for SNP c.745A>G, all cases were homozygous for the wild-type allele ‘A.’ These results indicate no relevance of these three SNPs to cancer progression in our study cohort. Additionally, the findings from whole exon sequencing will help to predict more precise outcomes and assess the importance of TP53 gene mutations in breast cancer patients.

关键词： Breast cancer p53 Gene expression Mutation SNPs

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：