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Chinese Chemical Letters 2024年第4期35卷 106-123页

作者： Wei Zhou Xi Chen Lin Lu Xian-Rong Song mu-Jia Luo Qiang Xiao Key Laboratory of Organic Chemistry of Jiangxi Province Jiangxi Science&Technology Normal UniversityNanchang 330013China

Indole-derived radical cations, open-shell reactive species, display distinctive dual reactivity due to the carbon-centered radical and more electrophilic carbocation, which frequently appear in a variety of single electron oxidation reactions for synthesizing structurally diverse functionalized indoles and indolines. Electrocatalysis is considered as a synthetically attractive and environmentally friendly alternative for driving the single electron oxidation of indoles. Remarkable achievements in electrocatalytic indolederived radical cation-mediated indole functionalization have been realized so far. This review comprehensively summarizes the recent progresses in the applications of electrocatalytic indole radical cations,including C(sp~2)–H functionalization, dearomative 2,3-difunctionalization, and ring-opening reaction, emphasizing the vital single electron oxidation steps of indoles, the substrates scope and limitations, and the reaction mechanisms.

关键词： Electrocatalysis Indole radical cation C-H functionalizatin Dearomative 2 3-difunctionalization

A high-performance electrochromic device assembled with WO_(3)/Ag and TiO_(2)/NiO composite electrodes towards smart window

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Frontiers of Materials Science 2024年第1期18卷 123-135页

作者： Haorui Liu Jikai Yang Decai Nie Chunlei Liu Liumenghan Zheng Yining mu Weijun Chen Chongqing Research Institute Changchun University of Science and TechnologyChongqing 400000China School of Physics Changchun University of Science and TechnologyChangchun 130022China

The choice of cathode and anode materials for electrochromic devices plays a key role in the performance of electrochromic smart *** this research,WO_(3)/Ag and TiO_(2)/NiO composite thin films were separately prepared by the hydrothermal method combined with *** electrochromic properties of the single WO_(3) thin film were optimized,and TiO_(2)/NiO composite films showed better electrochromic performance than that of the single NiO ***_(3)/Ag and TiO_(2)/NiO composite films with excellent electrochromic properties were respectively chosen as the cathode and the anode to construct a WO_(3)/Ag‒TiO_(2)/NiO electrochromic *** response time(tc=4.08 s,tb=1.08 s),optical modulation range(35.91%),and coloration efficiency(30.37 cm^(2)·C^(-1))of this electrochromic device are better than those of WO_(3)-NiO and WO_(3)/Ag-NiO electrochromic *** work provides a novel research idea for the performance enhancement of electrochromic smart windows.

关键词： WO_(3)/Ag composite film TiO_(2)/NiO composite film electrochromic device

Self-adaptive hydrogel for breast cancer therapy via accurate tumor elimination and on-demand adipose tissue regeneration

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Chinese Chemical Letters 2024年第1期35卷 371-378页

作者： Ran Tian Xinyu Qiu Wenyun mu Bolei Cai Zhongning Liu Shiyu Liu Xin Chen School of Chemical Engineering and Technology Department of Chemical EngineeringShaanxi Key Laboratory of Energy Chemical Process IntensificationXi'an Jiao Tong UniversityXi'an 710049China School of Stomatology State Key Laboratory of Military Stomatology&National Clinical Research Center for Oral Diseases&Shaanxi Clinical Research Center for Oral DiseasesDepartment of Preventive DentistryThe Fourth Military Medical UniversityXi'an 710032China School of Stomatology State Key Laboratory of Military StomatologyDepartment of Oral and Maxillofacial SurgeryThe Fourth Military Medical UniversityXi'an 710032China Department of Prosthodontics Peking University School and Hospital of StomatologyNational Clinical Research Center for Oral DiseasesNational Engineering Laboratory for Digital and Material Technology of StomatologyBeijing Key Laboratory of Digital StomatologyBeijing 100081China School of Stomatology State Key Laboratory of Military StomatologyNational Clinical Research Center for Oral DiseasesShaanxi International Joint Research Center for Oral DiseasesCenter for Tissue EngineeringThe Fourth Military Medical UniversityXi'an 710032China

The irregular defects and residual tumor tissue after surgery are challenges for effective breast cancer ***,a smart hydrogel with self-adaptable size and dual responsive cargos release was fabricated to treat breast cancer via accurate tumor elimination,on-demand adipose tissue regeneration and effective infection *** hydrogel consisted of thiol groups ended polyethylene glycol(SH-PEG-SH)and doxorubicin encapsulated mesoporous silica nanocarriers(DOX@MSNs)double crosslinked hyaluronic acid(HA)after loading of antibacterial peptides(AP)and adipose-derived stem cells(ADSCs).A pH-cleavable unsaturated amide bond was pre-introduced between MSNs and HA frame to perform the tumor-specific acidic environment dependent DOX@MSNs release,meanwhile an esterase degradable glyceryl dimethacrylate cap was grafted on MSNs,which contributed to the selective chemotherapy in tumor cells with over-expressed *** bond cleavage between MSNs and HA would also cause the swelling of the hydrogel,which not only provide sufficient space for the growth of ADSCs,but allows the hydrogel to fully fill the irregular defects generated by surgery and residual tumor atrophy,resulting in the on-demand regeneration of adipose ***,the sustained release of AP could be simultaneously triggered along with the size change of hydrogel,which further avoided bacterial infection to promote tissue regeneration.

关键词： Smart hydrogel with self-adaptable size Breast cancer therapy Dual responsive cargoes release Selective tumor elimination On-demand adipose tissue regeneration Effective bacteria inhibition

Cobalt-loaded carbon nanotubes boosted aerobic ciprofloxacin transformation driven by sulfide:A comprehensive mechanism investigation

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Chinese Chemical Letters 2024年第3期35卷 127-134页

作者： Han-Qing Zhao Peili Lu Fei Chen Chen-Xuan Li Rui Yan Yang mu State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing 400044China CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment College of Environment and EcologyChongqing UniversityChongqing 400045China College of Resources and Environmental Engineering Hefei University of TechnologyHefei 230009China

Sulfide oxidation under aerobic conditions can produce active oxygen for the transformation of organic pollutants in aquatic ***,the catalytic performance of transition metal-supported carbon material on this process is poor *** study found that Co-loaded carbon nanotubes(CNTs)was able to realize the efficient aerobic transformation of antibiotic ciprofloxacin(CIP)by sulfide,with the pseudo-first order reaction rate constant improved from 0.013 h^(-1)without catalyst to 0.44–0.71 h^(-1)with 100 mg/L Co-loaded *** oxygen(^(1)O_(2))was the main active specie playing key roles in the process of CIP aerobic transformation with presence of Co-loaded *** studies indicated that the excellent electron transfer ability of Co-loaded CNTs might play an important role to promote the electron transfer and facilitate the formation of intermediate H_(2)O_(2)and^(1)O_(2).Additionally,the Co-loaded CNTs/sulfide system effectively reduced the acute toxicity of organic pollutant,and Co-loaded CNTs showed remarkable cycling stability and negligible *** study gives a better understanding for the Co-loaded CNTs mediated aerobic antibiotics transformation by sulfide,and provide a reference for the application of Co-loaded carbon materials on organics aerobic transformation by sulfide.

关键词： Ciprofloxacin Aerobic transformation Co-loaded carbon nanotubes Sulfide Singlet oxygen

Highly efficient through-space charge transfer TADF molecule employed in TADF-and TADF-sensitized organic light-emitting diodes

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Science China Chemistry 2024年第4期67卷 1270-1276页

作者： Jiasen Zhang Deli Li Wei Li Yujie Wu Xilin mu Chunyu Liu Kaibo Fang Ziyi Ge Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China State Key Laboratory of Luminescent Materials and Devices and Institute of Polymer Optoelectronic Materials and Devices South China University of TechnologyGuangzhou 510640China

The inception and harnessing of excitons are paramount for the electroluminescence performance of organic light-emitting devices(OLEDs).Through-space charge transfer(TSCT)via intramolecular interaction has proved to be one of the most potent techniques employed to achieve 100% internal quantum ***,molecular strategies utilized to comprehensively enhance the electroluminescent performance of TSCT emitters regarding improving the photoluminescence quantum yield(PLQY)and elevating the light out-coupling efficiency remain *** surmount this challenge,we deliberately designed and synthesized a proof-of-concept TSCT emitter called CzO-TRZ by incorporating an extra carbazole donor into spiroheterocyclic *** introduction of rigid spiral fragments can immensely boost the horizontal orientation dipole ratio and establish an extra through-bond charge transfer(TBCT)radiative decay *** a result,a very high PLQY of 98.7%,fast kRISCof 2.2×10^(5)s^(-1)and high k_(r)^(s) of 2.2×10^(7)s^(-1),and an ultrahigh horizontal dipolar ratio of 90%were concurrently achieved for Cz O-TRZ blended ***,corresponding thermally activated delayed fluorescence(TADF)-and TADF-sensitized fluorescence(TSF)-OLEDs based on CzO-TRZ demonstrated external quantum efficiencies(EQEs)of 33.4% and 30.3%,respectively,highlighting its versatile applications as both an emitter and sensitized host.

关键词： organic electronics organic light-emitting diodes polycyclic aromatic hydrocarbons multiple-resonance

Interfacial charge effects of supported-metal-cluster heterostructures on azo hydrogenation catalyzation

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Nano Research 2024年第5期17卷 3853-3862页

作者： Zhenhua Gu Jingli Zhang Zijun Zhang Qingxue mu Liangchong Yu Taolei Sun Lei Shen Guanbin Gao State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Key Laboratory of Nanomedicine for Neurodegenerative Diseases School of ChemistryChemical Engineering and Life ScienceWuhan University of TechnologyWuhan 430070China

The impact of interfacial charge on catalytic performance of supported-metal-cluster(SMC)heterostructures remains unclear,hindering efforts to develop high-performance SMC *** we systematically investigated interfacial charge effects of SMCs using a model system of graphene-supported gold-nanoclusters(AuNCs/rGO)for azo *** types of SMCs with different interfacial charges were synthesized by anchoring electropositive 2-aminoethanethiol(CSH),amphoteric cysteine(Cys),and electronegative 3-mercaptopropionic-acid(MPA)onto AuNCs/rGO,*** three SMCs exhibited high and selective catalytic activity to azo-hydrogenation in four representative azo *** catalytic activity of Cys@AuNCs/rGO was lower than that of CSH@AuNCs/rGO but higher than that of MPA@AuNCs/***,the cyclic stability of Cys@AuNCs/rGO was inferior to that of both CSH@AuNCs/rGO and MPA@AuNCs/*** mechanistic studies revealed that amino ligands modified CSH@AuNCs and Cys@AuNCs agglomerated into large-size gold nanoparticles on rGO surface during catalytic reaction under NaBH_(4) action,leading to reduced efficiency and cyclic ***,non-amino ligand modified MPA@AuNCs only partially detached from rGO surface without agglomeration,resulting in better cyclic *** of amino groups in ligands such as modifying-NH_(3)^(+)group in Cys into imine to form N-isobutyryl-L-cysteine(NIBC)substantially improved the cyclic stability while maintaining the high activity in the NIBC@AuNCs/rGO catalyst *** work provides an approach for developing a highly-active and stable SMC heterostructure catalyst via manipulating interfacial charges in SMC.

关键词： interfacial charge effect supported-metal-cluster catalyst azo hydrogenation graphene supported gold nanoclusters

Intelligent UAV Based Energy Supply for 6G Wireless Powered IoT Networks

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China Communications 2024年第9期21卷 321-337页

作者： Miao Jiansong Chen Haoqiang Wang Pengjie Li Hairui Zhao Yan mu Junsheng Yan Shi School of Information and Communication Engineering Beijing University of Posts and TelecommunicationsBeijing 100876China Beijing Key Laboratory of Network System Architecture and Convergence Beijing University of Posts and TelecommunicationsBeijing 100876China

In this paper,we develop a 6G wireless powered Internet of Things(IoT)system assisted by unmanned aerial vehicles(UAVs)to intelligently supply energy and collect data at the same *** our dual-UAV scheme,UAV-E,with a constant power supply,transmits energy to charge the IoT devices on the ground,whereas UAV-B serves the IoT devices by data collection as a base *** this framework,the system's energy efficiency is maximized,which we define as a ratio of the sum rate of IoT devices to the energy consumption of two UAVs during a fixed working *** the constraints of duration,transmit power,energy,and mobility,a difficult non-convex issue is presented by optimizing the trajectory,time duration allocation,and uplink transmit power of *** tackle the non-convex fractional optimization issue,we deconstruct it into three subproblems and we solve each of them iteratively using the descent method in conjunction with sequential convex approximation(SCA)approaches and the Dinkelbach *** simulation findings indicate that the suggested cooperative design has the potential to greatly increase the energy efficiency of the 6G intelligent UAV-assisted wireless powered IoT system when compared to previous benchmark systems.

关键词： 6G wireless powered network energy efficiency IoT intelligent network UAV communication

Warming and increased precipitation alter soil carbon cycling in a temperate desert steppe of Inner Mongolia

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JOURNAL OF PLANT ECOLOGY 2024年第2期17卷 161-172页

作者： Lan, mu Qiu, Xiao La, Wei Wang, Huimin Liu, Yahong Zhao, Liqing Sun, Hailian Inner Mongolia Univ Inner Mongolia Key Lab Grassland Ecol Hohhot 010021 Peoples R China Inner Mongolia Univ Sch Ecol & Environm Hohhot 010021 Peoples R China Inner Mongolia Acad Agr & Anim Husb Sci Hohhot 010031 Peoples R China Chinese Acad Sci State Key Lab Vegetat & Environm Change Inst Bot Beijing 100093 Peoples R China Baotou Teachers Coll Coll Resources & Environm Baotou 014030 Peoples R China

Warming and precipitation are key global change factors driving soil carbon (C) dynamics in terrestrial ecosystems. However, the effects of warming and altered precipitation on soil microbial diversity and functional genes involved in soil C cycling remain largely unknown. We investigated the effects of warming and increased precipitation on soil C cycling in a temperate desert steppe of Inner Mongolia using metagenomic sequencing. We found that warming reduced plant richness, Shannon-Wiener and Simpson index. In contrast, increased precipitation significantly influenced Shannon-Wiener and Simpson index. Warming reduced soil microbial species by 5.4% while increased precipitation and warming combined with increased precipitation led to increases in soil microbial species by 23.3% and 2.7%, respectively. The relative abundance of Proteobacteria, which involve C cycling genes, was significantly increased by warming and increased precipitation. Warming significantly reduced the abundance of GAPDH (Calvin cycle) and celF (cellulose degradation) while it enhanced the abundance of glxR (lignin degradation). Increased precipitation significantly enhanced the abundance of pgk (Calvin cycle), coxL (carbon monoxide oxidation), malZ (starch degradation), and mttB (methane production). Moreover, a wide range of correlations among soil properties and C cycling functional genes was detected, suggesting the synergistic and/or antagonistic relationships under scenario of global change. These results may suggest that warming is beneficial to soil C storage while increased precipitation negatively affects soil C sequestration. These findings provide a new perspective for understanding the response of microbial communities to warming and increased precipitation in the temperate desert steppe.

关键词： carbon cycling desert steppe functional genes global change soil microbes precipitation warming ALPINE GRASSLANDS NITROGEN ADDITION ORGANIC-CARBON RESPONSES ECOSYSTEM RESPIRATION FLUXES DIVERSITY CLIMATE STORAGE

Observer-based dynamic event-triggered control for distributed parameter systems over mobile sensor-plus-actuator networks

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Chinese Physics B 2024年第4期33卷 237-243页

作者：穆文英庄波邱芳 Shandong Engineering Research Center of Aeronautical Materials and Devices Shangdong University of AeronauticsBinzhou 256600China School of Information Engineering Shangdong University of AeronauticsBinzhou 256600China School of Science Shangdong University of AeronauticsBinzhou 256600China

We develop a policy of observer-based dynamic event-triggered state feedback control for distributed parameter systems over a mobile sensor-plus-actuator *** is assumed that the mobile sensing devices that provide spatially averaged state measurements can be used to improve state estimation in the *** the purpose of decreasing the update frequency of controller and unnecessary sampled data transmission, an efficient dynamic event-triggered control policy is *** an event-triggered system, when an error signal exceeds a specified time-varying threshold, it indicates the occurrence of a typical *** global asymptotic stability of the event-triggered closed-loop system and the boundedness of the minimum inter-event time can be *** on the linear quadratic optimal regulator, the actuator selects the optimal displacement only when an event occurs.A simulation example is finally used to verify that the effectiveness of such a control strategy can enhance the system performance.

关键词： distributed parameter systems event-triggered control mobile sensors mobile actuators

Comparative and Phylogenetic Analysis of the Complete Chloroplast Genomes of 19 Species in Rosaceae Family

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Phyton-International Journal of Experimental Botany 2024年第6期93卷 1203-1219页

作者： Riwa Mahai Rongpeng Liu Xiaolang Du Zejing mu Xiaoyun Wang Jun Yuan Research Center for Traditional Chinese Medicine Resources and Ethnic Minority Medicine Jiangxi University of Chinese MedicineNanchang330004China College of Life Sciences Jiangxi University of Chinese MedicineNanchang330004China

Rosaceae represents a vast and complex group of species,with its classiﬁcation being intricate and *** taxonomic placement of many species within this family has been a subject of ongoing *** study utilized the Illumina platform to sequence 19 plant species from 10 genera in the *** cp genomes,vary-ing in size from 153,366 to 159,895 bp,followed the typical quadripartite organization consisting of a large single-copy(LSC)region(84,545 to 87,883 bp),a small single-copy(SSC)region(18,174 to 19,259 bp),and a pair of inverted repeat(IR)regions(25,310 to 26,396 bp).These genomes contained 132–138 annotated genes,including 87 to 93 protein-coding genes(PCGs),37 tRNA genes,and 8 rRNA genes using MISA software,52 to 121 simple sequence repeat(SSR)loci were identiﬁ*** contained the least of SSRs and did not have hexanotides,*** contained the richest *** terminal repeats(LTRs)were primarily composed of palindromic and forward repeat sequences,meanwhile,The richest LTRs were found in Argentina *** for Argentina lineata,Fragariastrum eriocarpum,and Prunus trichostoma,which varied in gene type and position on both sides of the boundary,the remaining species were found to be mostly conserved according to IR boundary *** examination of the Ka/Ks ratio revealed that only the infA gene had a value greater than 1,indicating that this gene was primarily subjected to positive selection during ***,9 hotspots of variation were identiﬁed in the LSC and SSC *** analysis conﬁrmed the scientiﬁc validity of the genus Prunus *** lato(s.l.)within the Rosaceae *** separation of the three genera Argentina Hill,Fragariastrum *** *** Dasiphora *** Potentilla *** be a more scientiﬁc classiﬁ*** results offer fresh perspectives on the taxonomy of the Rosaceae.

关键词： Rosaceae chloroplast genomes comparative genomes phylogeny