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Novel interface engineering of LDH-based materials on Mg alloy for efficient photocatalytic systems considering the geometrical linearity of condensed phosphates

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Journal of Magnesium and Alloys 2024年第1期12卷 267-280页

作者： mosab Kaseem Ananda Repycha Safira Arash Fattah-alhosseini Department of Nanotechnology and Advanced Materials Engineering Corrosion and Electrochemistry LaboratorySejong UniversitySeoul 05006Republic of Korea Department of Materials Engineering Bu-Ali Sina UniversityHamedan 65178-38695Iran

This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'geometric linearity on their photocatalytic ***,the Mg O film,obtained by plasma electrolysis of AZ31 Mg alloys,was modified by growing an LDH film,which was further functionalized using cyclic sodium hexametaphosphate(CP)and linear sodium tripolyphosphate(LP).CP acted as an enhancer for flake spacing within the LDH structure,while LP changed flake dispersion and ***,CP@LDH demonstrated exceptional efficiency in heterogeneous photocatalysis,effectively degrading organic dyes like Methylene blue(MB),Congo red(CR),and Methyl orange(MO).The unique cyclic structure of CP likely enhances surface reactions and improves the catalyst's interaction with dye ***,the condensed phosphate structure contributes to a higher surface area and reactivity in CP@LDH,leading to its superior photocatalytic performance compared to LP@***,LP@LDH demonstrated notable degradation efficiencies of 93.02%,92.89%,and 88.81%for MB,MO,and CR respectively,over a 40 min *** highest degradation efficiencies were observed in the case of the CP@LDH sample,reporting 99.99%for MB,98.88%for CR,and 99.70%for *** underscores the potential of CP@LDH as a highly effective photocatalyst for organic dye degradation,offering promising prospects for environmental remediation and water detoxification applications.

关键词： Plasma electrolysis Layered Double Hydroxide Condensed phosphates Adsorption capacity Photocatalytic efficiency

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Surface growth of novel MOFs on AZ31 Mg alloy coated via plasma electrolytic oxidation for enhanced corrosion protection and photocatalytic performance

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Journal of Magnesium and Alloys 2024年第6期12卷 2413-2432页

作者： Ananda Repycha Safira Arash Fattah-alhosseini mosab Kaseem Corrosion and Electrochemistry Laboratory Department of Nanotechnology and Advanced Materials EngineeringSejong UniversitySeoul 05006Republic of Korea Department of Materials Engineering Faculty of EngineeringBu-Ali Sina UniversityHamedanIran

In the pursuit of multifunctional coatings,the controlled growth of materials on stationary platforms holds paramount importance for achieving superior corrosion protection and optimal photocatalytic *** study introduces a cutting-edge approach,intertwining bifunctional metal-organic frameworks(MOFs)seamlessly into defective MgO layers produced by the anodic oxidation of AZ31 *** metallic oxides of Zn,Sn,and V take center stage as metallic sources for MOF formation,complemented by the organic prowess of L-Tryptophan as anα-amino acid *** the electronic structure of metallic oxides reacting with tryptophan molecules,controlled morphologies with distinct characteristics are induced on the defective surface of the MgO layer,enabling the precise modulation of surface *** hybrid composite demonstrates an adaptive microstructure in diverse aqueous environments,offering dual functionality with electrochemical stability and visible light photocatalytic activity for crystal violet *** the samples,the SnOF complex exhibited remarkable electrochemical stability with a low corrosion current density of 7.50×10^(−10)A·cm^(−2),along with a 94.56%degradation efficiency after 90 min under visible light *** VOF complex,under similar visible light conditions,demonstrated exceptional performance with a higher degradation efficiency of 97.79%and excellent electrochemical stability characterized by a corrosion current density of 3.26×10^(−9)A·cm^(−2).Additionally,Density Functional Theory(DFT)computations shed light on the basic bonding patterns between MOFs and inorganic components,providing electronic understanding of their electrochemical and photocatalytic activities.

关键词： Electrochemical stability Defective layer Metal-organic framework Photocatalytic activity DFT

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Recent advances in flat sheet mixed matrix membrane modified by Mg-based layered double hydroxides(LDHs)for salt and organic compound separations

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Journal of Magnesium and Alloys 2024年第6期12卷 2182-2200页

作者： Payam Veisi Arash Fattah-alhosseini mosab Kaseem Department of Materials Engineering Faculty of EngineeringBu-Ali Sina UniversityHamedanIran Corrosion and Electrochemistry Laboratory Department of Nanotechnology and Advanced Materials EngineeringSejong UniversitySeoul 05006Republic of Korea

Magnesium(Mg)is a widely used and attractive metal,known for its unique physical and chemical properties,and it has been employed in the manufacture of many practical *** Double Hydroxides(LDHs),particularly Mg-based LDHs,rank among the most prevalent two-dimensional materials utilized in separation processes,which include adsorption,extraction,and membrane *** high popularity of Mg-based LDHs in separation applications can be attributed to their properties,such as excellent hydrophilicity,high surface area,ion exchangeability,and adjustable interlayer ***,polymer membranes play a pivotal role in semi-industrial and industrial separation ***,the development of polymer membranes and the mitigation of their limitations have emerged as compelling topics for *** methods exist to enhance the separation performance and anti-fouling properties of polymer *** these,incorporating additives into the membrane polymer matrix stands out as a cost-effective,straightforward,readily available,and efficient *** use of Mg-based LDHs,either in combination with other materials or as a standalone additive in the polymer membrane matrix,represents a promising strategy to bolster the separation and anti-fouling efficacy of flat sheet mixed matrix polymer *** review highlights Mg-based LDHs as high-potential additives designed to refine flat sheet mixed matrix polymer membranes for applications in wastewater treatment and brackish water desalination.

关键词： Mg-based layered double hydroxides(LDHs) Mixed matrix membrane Polymeric membrane Water and wastewater treatment Brackishwater desalination

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Advancements in enhancing corrosion protection of Mg alloys:A comprehensive review on the synergistic effects of combining inhibitors with PEO coating

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Journal of Magnesium and Alloys 2024年第2期12卷 465-489页

作者： Arash Fattah-alhosseini Abdelhameed Fardosi Minoo Karbasi mosab Kaseem Department of Materials Engineering Faculty of EngineeringBu-Ali Sina UniversityHamedanIran Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea

Magnesium(Mg)alloys are lightweight materials with excellent mechanical properties,making them attractive for various applications,including aerospace,automotive,and biomedical ***,the practical application of Mg alloys is limited due to their high susceptibility to *** electrolytic oxidation(PEO),or micro-arc oxidation(MAO),is a coating method that boosts Mg alloys'corrosion ***,despite the benefits of PEO coatings,they can still exhibit certain limitations,such as failing to maintain long-term protection as a result of their inherent *** address these challenges,researchers have suggested the use of inhibitors in combination with PEO coatings on Mg *** are chemical compounds that can be incorporated into the coating or applied as a post-treatment to further boost the corrosion resistance of the PEO-coated Mg *** inhibitors,whether organic or inorganic,can act by forming a protective barrier,hindering the corrosion process,or modifying the surface properties to reduce susceptibility to *** can be made of various materials,including polyelectrolyte shells,layered double hydroxides,polymer shells,and mesoporous inorganic *** corrosion inhibitors in containers fully compatible with the coating matrix and substrate is a promising approach for their *** studies of the combination of inhibitors with PEO coatings on Mg alloys have shown promising results,demonstrating significant corrosion mitigation,extending the service life of Mg alloy components in aggressive environments,and providing self-healing *** general,this review presents available information on the incorporation of inhibitors with PEO coatings,which can lead to improved performance of Mg alloy components in demanding environments.

关键词： Inhibitor Mg alloy Self-healing coating Plasma electrolytic oxidation(PEO) Corrosion protection

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Development of anti-corrosive coating on AZ31 Mg alloy modified by MOF/LDH/PEO hybrids

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Journal of Magnesium and Alloys 2024年第2期12卷 586-607页

作者： Muhammad Ali Khan Ananda Repycha Safira Mohammad Aadil mosab Kaseem Corrosion and Electrochemistry Laboratory Department of Nanotechnology and Advanced Materials EngineeringSejong UniversitySeoul 05006Republic of Korea

The self-assembly of hybrid inorganic-organic materials on stationary platforms plays a critical role in improving their structural stability and wide *** this work,a novel two-step hydrothermal approach is proposed for synthesizing stable and advanced hybrid coatings on metal-oxide platforms through the surface modification of layered double hydroxide(LDH)films using novel metal-organic frameworks(MOFs).Initially,Mg-Al LDH nanocontainers,grown on a magnesium oxide layer produced through plasma electrolytic oxidation(PEO)of AZ31 Mg alloy substrate,were intercalated with cobalt via an oxidation route,providing the metallic coordination center for the MOF *** the subsequent step,a pioneering technique is introduced,utilizing tryptophan as the organic linker for the first time at a pH of *** self-assembly of cobalt-tryptophan complex,driven by the strong bonding between electrophilic sites of monomers and nucleophilic sites,facilitated the formation of a MOF network having a cloud-like structure on the surface of MgAl LDH's *** resulting MOF-LDH encapsulation containers demonstrate exceptional electrochemical stability when exposed to a 3.5 wt.%NaCl solution,surpassing the performance of PEO and pure LDH *** enhanced stability is attributed to the development of a dense top layer and a stable composition within the self-assembled MOF,effectively sealing flaws and preventing the infiltration of corrosive ions into the underlying metallic *** formation mechanism of MOFs on LDH galleries is investigated using density functional theory calculations.

关键词： Mg alloy Layered double hydroxide Metal-organic frameworks Corrosion DFT

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Enhanced electrochemical and photocatalytic performance achieved through dual incorporation of SnO_(2)and WO_(3)nanoparticles into LDH layer fabricated on PEO-coated AZ31 Mg alloy

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Journal of Magnesium and Alloys 2024年第5期12卷 1880-1898页

作者： Muhammad Ali Khan Ananda Repycha Safira mosab Kaseem Arash Fattah-alhosseini Corrosion and Electrochemistry Laboratory Department of Nanotechnology and Advanced Materials EngineeringSejong UniversitySeoul 05006Republic of Korea Department of Materials Engineering Faculty of EngineeringBu-Ali Sina UniversityHamedanIran

This study explores the potential of LDH flakes decorated with metallic oxide nanoparticles to function as both anti-corrosion barriers against chloride anions and heterogeneous photocatalysts for tetracycline degradation under visible *** process involves modifying the primarily MgO-based inorganic porous film by growing a MgFe LDH film,followed by the individual and dual incorporation of SnO_(2)and WO_(3)*** dual incorporation of these nanoparticles into the LDH matrix leads to synergistic interactions,effectively sealing pre-existing defects within LDH flakes and facilitating the in-situ formation of catalytic sites through oxidation and the induction of surface oxygen vacancy defects,which synergistically contribute to the enhancement of both electrochemical and photocatalytic *** enhanced electrochemical stability is reflected in a significant reduction in corrosion current density by 4 orders of magnitude compared to unmodified porous ***,the decorated film demonstrates sustained photocatalytic functionality,achieving significant degradation(95.5%)of tetracycline within two *** study presents a novel approach,highlighting the dual effectiveness of LDHs decorated by dual metal oxides as an anti-corrosive agent and photocatalyst,with promising implications for environmental remediation and wastewater purification.

关键词： Porous film LDH film Anti corrosive Photocatalysis Oxygen vacancy Tetracycline

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Innovative approach to boosting the chemical stability of AZ31 magnesium alloy using polymer-modified hybrid metal oxides

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Journal of Magnesium and Alloys 2024年第3期12卷 1068-1081页

作者： mosab Kaseem Ananda Repycha Safira Mohammad Aadil Tehseen Zehra Muhammad Ali Khan Arash Fattah-alhosseini Corrosion and Electrochemistry Laboratory Department of Nanotechnology and Advanced Materials EngineeringSejong UniversitySeoul 05006Republic of Korea Department of Materials Engineering Bu-Ali Sina UniversityHamedan 65178-38695Iran

Meeting the demands of complex and advanced applications requires the development of high-performance hybrid materials with unique ***,the integration of polymeric frameworks with MgO/WO_(3) composite layers faces challenges due to the lack of understanding of the formation mechanism and the challenge of determining the impact of self-assembled architecture on anticorrosive *** this study,we aimed to enhance the corrosion resistance of the MgO layer produced by plasma electrolysis(PE)of AZ31 Mg alloy by incorporating WO_(3) with partially phosphorated poly(vinyl alcohol)(PPVA).Two types of porous MgO layers were produced using the PE process with an alkaline-phosphate electrolyte,one with and one without WO_(3) nanoparticles,which were subsequently immersed in an aqueous solution of *** PPVA into the WO_(3)-MgO layer resulted in hybrids being deposited in a fragmented manner,creating a“laminar reef-like structure”that sealed most of the structural defects in the *** PPVA-sealed WO_(3)-based coating exhibited superior corrosion resistance compared to the other *** analyses were employed to explore the mechanism underlying the formation of PPVA/WO_(3) hybrids on the MgO *** findings suggest that PPVA-WO_(3)-MgO hybrid coatings can potentially improve corrosion resistance in various fields.

关键词： Plasma electrolysis Poly(vinyl alcohol) Tungsten trioxide Sealing Corrosion DFT.

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Outcomes of Pregnancy with Group B Streptococcal Infections in Najran, Saudi Arabia

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Open Journal of Obstetrics and Gynecology 2023年第3期13卷 395-402页

作者： Majed Saeed Alshahrani Ali H. Alhajri Fahad Thamer Almutairi Ashwag Hassan Abdelmajed Fatima Ibrahim Abdalla Yousra Bala Babkir Abdullah mosab mohamedelamineltaib Ahmed Faroug Ahmed Abdelaal Mohamed Ahmed Mukhtar Mowafag Bushra Galaleldin Elsayed Marwa Mohamed Ahmed Elkhidir Babikir Nihal Altayeb Abdallah Selma Mohammed Abdelgadir Elhabeeb Department of Obstetrics and Gynecology College of Medicine Najran University Najran Saudi Arabia Najran Armed Forces Hospital Najran Saudi Arabia

Background: The gram-positive, beta-hemolytic, and chain-forming Group B Streptococcus (GBS), commonly known as Streptococcus agalactiae, may asymptomatically invade the human gastrointestinal and vaginal tracts. However, GBS may become very invasive and pathogenic to the mother and baby during pregnancy, having negative effects. Study Aim: This study aims to investigate the pregnancy outcomes of women who tested positive for genitourinary GBS infection during pregnancy in Najran, Saudi Arabia. Methods: Data was collected retrospectively from patient files in Armed Forces Hospital, Najran, Saudi Arabia. Data collected were entered to a Microsoft Excel sheet, then imported and analysed using the Statistical Package for Social Sciences. Results: The study included 272 women of whom 66.5% were 31 to 45 years old. Gestational diabetes was diagnosed in 8.5% of the sample, 71.7% had a normal spontaneous vaginal delivery (NSVD), 1.8% had previous abortions, and 27.2% of new-borns were admitted to the NICU after delivery. There was a significant association between NICU admissions and women employment status (p = 0.001), gravidity (p = 0.001), parity (p = 0.001), history of abortions (p = 0.001), medical conditions (p = 0.049), and mode of delivery (p = 0.049). Conclusion: According to the findings of our study, GBS infection during pregnancy is associated to more NICU admissions. NICU admissions were significantly correlated with gestational diabetes, hypertension, and hypothyroidism in mothers but not with intrapartum antibiotic use.

关键词： Pregnancy Group B Streptococcal Outcomes

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Self-assembly of coumarin molecules on plasma electrolyzed layer for optimizing the electrochemical performance of AZ31 Mg alloy

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Journal of Magnesium and Alloys 2023年第5期11卷 1618-1628页

作者： mosab Kaseem Burak Dikici Ali Dafali Arash Fattah-alhosseini Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Department of Metallurgical and Materials Engineering Ataturk UniversityErzurum 25240Turkey Faculty of Sciences Oujda Department of ChemistryMohamed the First UniversityOujdaMorocco Department of Materials Engineering Bu-Ali Sina UniversityHamedan 65178-38695Iran

A novel inorganic-organic layer with outstanding corrosion resistance in a 3.5wt.% NaCl solution was fabricated by taking advantage of the unique interactions between coumarin (COM) molecules and the porous layer formed on Mg alloy. To achieve this aim, the AZ31 Mg alloy coated via microarc oxidation (MAO) coating was placed in an ethanolic solution of COM for 6 and 12 h at 25 ℃. By reducing the surface area exposed to the corrosive species, the donor-acceptor complexes produced by the particular interactions between the COM and MAO surface would successfully prevent the corrosion of Mg alloy substrate. The MAO layer would provide the ideal sites for the charge-transfer-induced physical and chemical locking, leading to uneven organic layer nucleation and crystal growth with a thatch-like structure. To evaluate the formation mechanism of such hybrid composites and highlight the key bonding modes between the COM and MAO, theoretical simulations were conducted.

关键词： Mg alloy Hybrid coating Coumarin Porous layer Corrosion DFT

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Corrosion behavior of composite coatings containing hydroxyapatite particles on Mg alloys by plasma electrolytic oxidation: A review

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Journal of Magnesium and Alloys 2023年第9期11卷 2999-3011页

作者： Arash Fattah-alhosseini Razieh Chaharmahali Sajad Alizad mosab Kaseem Department of Materials Engineering Bu-Ali Sina UniversityHamedan 65178-38695Iran Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006South Korea

Mg and its alloys have been introduced as promising biodegradable materials for biomedical implant applications due to their excellent biocompatibility, mechanical behavior, and biodegradability. However, their susceptibility to rapid corrosion within the body poses a significant challenge and restricts their applications. To overcome this issue, various surface modification techniques have been developed to enhance the corrosion resistance and bioactivity of Mg-based implants. PEO is a potent technique for producing an oxide film on a surface that significantly minimizes the tendency to corrode. However, the inevitable defects due to discharges and poor biological activity during the coating process remain a concern. Therefore, adding suitable particles during the coating process is a suitable solution. Hydroxyapatite(HAp)has attracted much attention in the development of biomedical applications in the scientific community. HAp shows excellent biocompatibility due to its similarity in chemical composition to the mineral portion of bone. Therefore, its combination with Mg-based implants through PEO has shown significant improvements in their corrosion resistance and bioactivity. This review paper provides a comprehensive overview of the recent advances in the preparation, characterization, corrosion behavior and bioactivity applications of HAp particles on Mg-based implants by PEO.

关键词： Mg and its alloys Hydroxyapatite Corrosion behavior Composite coatings Plasma electrolytic oxidation(peo)

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