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A critical review towards the causes of the iron-based catalysts deactivation mechanisms in the selective oxidation of hydrogen sulfide to elemental sulfur from biogas

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Journal of Energy Chemistry 2024年第3期90卷 388-411,I0010页

作者： Mostafa Tarek Janaina S.Santos Victor Márquez mohammad Fereidooni mohammad Yazdanpanah Supareak Praserthdam Piyasan Praserthdam Center of Excellence on Catalysis and Catalytic Reaction Engineering(CECC) Department of Chemical EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailan High-Performance Computing Unit(CECC-HCU) Center of Excellence on Catalysis and Catalytic Reaction Engineering(CECC)Chulalongkorn UniversityBangkok 10330Thailand

Hydrogen sulfide(H_(2)S) not only presents significant environmental concerns but also induces severe corrosion in industrial equipment,even at low *** various technologies,the selective oxidation of hydrogen sulfide(SOH_(2)S) to elemental sulfur(S) has emerged as a sustainable and environmentally friendly *** to its unique properties,iron oxide has been extensively investigated as a catalyst for SOH_(2)S;however,rapid deactivation has remained a significant *** causes of iron oxide-based catalysts deactivation mechanisms in SOH_(2)S,including sulfur or sulfate deposition,the transformation of iron species,sintering and excessive oxygen vacancy formation,and active site loss,are thoroughly examined in this *** focusing on the deactivation mechanisms,this review aims to provide valuable insights into enhancing the stability and efficiency of iron-based catalysts for SOH_(2)S.

关键词： Selective oxidation of H_(2)S Iron-based Catalysts Mechanism of deactivation Sulfur or sulfate deposition Transformation of iron species Sintering SDG 7

Seismic control of multi-degrees-of-freedom structures by vertical mass isolation method using MR dampers

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Earthquake Engineering and Engineering Vibration 2024年第2期23卷 503-510页

作者： Mohamad Shahrokh Abdi Masoud Nekooei mohammad-Ali Jafari Department of Civil Engineering Marivan BranchIslamic Azad UniversityMarivan ***Iran Department of Civil Engineering Science and Research BranchIslamic Azad UniversityTehran ***Iran Structural Department of Transmission and Distribution Research Center Niroo Research Institute(NRI)Tehran ***Iran

Vertical mass isolation(VMI)is one of the novel methods for the seismic control of *** this method,the entire structure is assumed to consist of two mass and stiffness subsystems,and an isolated layer is located among *** this study,the magnetorheological damper in three modes:passive-off,passive-on,and semi-active mode with variable voltage between zero and 9 volts was used as an isolated layer between two ***-degrees-of-freedom structures with 5,10,and 15 floors in two dimensions were examined under 11 pairs of near field *** each level,the displacement of MR dampers was taken into *** responses of maximum displacement,maximum inter-story drift,and maximum base shear in controlled and uncontrolled buildings were compared to assess the suggested approach for seismic control of the *** to the results,the semi-active control method can reduce the response by more than 12%compared to the uncontrolled mode in terms of maximum displacement of the mass subsystem of the *** method can reduce more than 16%and 20%of the responses compared to the uncontrolled mode in terms of maximum inter-story drift and base shear of the structure,respectively.

关键词： seismic control vertical mass isolation base shear magnetorheological damper semi-active control

Implications of electrode modifications in aqueous organic redox flow batteries

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Journal of Energy Chemistry 2024年第8期95卷 499-510,I0011页

作者： Zahid Manzoor Bhat mohammad Furquan Muhammad Aurang Zeb Gul Sial Umair Alam Atif Saeed Alzahrani mohammad Qamar Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management(IRC-HTCM) King Fahd University of Petroleum&Minerals(KFUPM)Dhahran 31261Saudi Arabia Department of Materials Science and Engineering King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia Interdisciplinary Research Center for Sustainable Energy Systems(IRC-SES) King Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia

Aqueous organic redox flow batteries(RFBs)exhibit favorable characteristics,such as tunability,multielectron transfer capability,and stability of the redox active molecules utilized as anolytes and catholytes,making them very viable contenders for large-scale grid storage *** attention has been paid on the development of efficient redox-active molecules and their performance optimization through chemical substitutions at various places on the backbone as part of the pursuit for high-performance *** the fact that electrodes are vital to optimal performance,they have not garnered significant *** research has been conducted on the effects of electrode modifications to improve the performance of *** primary emphasis has been given on the impact of electrode engineering to augment the efficiency of aqueous organic *** overview of electron transfer at the electrode-electrolyte interface is *** implications of electrode modification on the performance of redox flow batteries,with a particular focus on the anodic and cathodic half-cells separately,are then *** each section,significant discrepancies surrounding the effects of electrode engineering are thoroughly examined and ***,we have presented a comprehensive assessment along with our perspectives on the future trajectory.

关键词： Redox flow batteries Electrode modification Organic redox molecules Outer sphere and inner sphere

Cloud Datacenter Selection Using Service Broker Policies:A Survey

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Computer Modeling in Engineering & Sciences 2024年第4期139卷 1-41页

作者： Salam Al-E’mari Yousef Sanjalawe Ahmad Al-Daraiseh mohammad Bany Taha mohammad Aladaileh Department of Information Security Faculty of ITUniversity of PetraAmman11196Jordan Department of Cybersecurity School of ITAmerican University of Madaba(AUM)Amman11821Jordan Department of Computer Science School of ITAmerican University of Madaba(AUM)Amman11821Jordan Department of Data Science and Artificial Intelligence School of ITAmerican University of Madaba(AUM)Amman11821Jordan

Amid the landscape of Cloud Computing(CC),the Cloud Datacenter(DC)stands as a conglomerate of physical servers,whose performance can be hindered by bottlenecks within the realm of proliferating CC services.A linchpin in CC’s performance,the Cloud Service Broker(CSB),orchestrates DC *** to adroitly route user requests with suitable DCs transforms the CSB into a bottleneck,endangering service *** tackle this,deploying an efficient CSB policy becomes imperative,optimizing DC selection to meet stringent Qualityof-Service(QoS)*** numerous CSB policies,their implementation grapples with challenges like costs and *** article undertakes a holistic review of diverse CSB policies,concurrently surveying the predicaments confronted by current *** foremost objective is to pinpoint research gaps and remedies to invigorate future policy ***,it extensively clarifies various DC selection methodologies employed in CC,enriching practitioners and researchers *** synthetic analysis,the article systematically assesses and compares myriad DC selection *** analytical insights equip decision-makers with a pragmatic framework to discern the apt technique for their *** summation,this discourse resoundingly underscores the paramount importance of adept CSB policies in DC selection,highlighting the imperative role of efficient CSB policies in optimizing CC *** emphasizing the significance of these policies and their modeling implications,the article contributes to both the general modeling discourse and its practical applications in the CC domain.

关键词： Cloud computing cloud service broker datacenter selection quality-of-service user request

IoT Smart Devices Risk Assessment Model Using Fuzzy Logic and PSO

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Computers, Materials & Continua 2024年第2期78卷 2245-2267页

作者： Ashraf S.Mashaleh Noor Farizah Binti Ibrahim mohammad Alauthman mohammad Almseidin Amjad Gawanmeh School of Computer Sciences Universiti Sains MalaysiaPenangMalaysia Department Computer Center Al-Balqa Applied UniversitySaltJordan Department of Information Security Faculty of Information TechnologyUniversity of PetraAmmanJordan Department of Computer Science Tafila Technical UniversityTafilaJordan College of Engineering and IT University of DubaiDubaiUnited Arab Emirates

Increasing Internet of Things(IoT)device connectivity makes botnet attacks more dangerous,carrying catastrophic *** IoT botnets evolve,their dynamic and multifaceted nature hampers conventional detection *** paper proposes a risk assessment framework based on fuzzy logic and Particle Swarm Optimization(PSO)to address the risks associated with IoT *** logic addresses IoT threat uncertainties and ambiguities *** component settings are optimized using PSO to improve *** methodology allows for more complex thinking by transitioning from binary to continuous *** of expert inputs,PSO data-driven tunes rules and membership *** study presents a complete IoT botnet risk assessment *** methodology helps security teams allocate resources by categorizing threats as high,medium,or low *** study shows how CICIoT2023 can assess cyber *** research has implications beyond detection,as it provides a proactive approach to risk management and promotes the development of more secure IoT environments.

关键词： IoT botnet detection risk assessment fuzzy logic particle swarm optimization(PSO) cybersecurity interconnected devices

Special Issue: International Conference on Sustainable Energy Sources, Technologies and Systems 2023 (ICSESTS-2023)

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CLEAN ENERGY 2024年第3期8卷 136-137页

作者： Kumar, Ravinder Ahmadi, mohammad Hossein Lovely Profess Univ Sch Mech Engn Phagwra 144411 Punjab India Shahrood Univ Technol Fac Mech Engn Shahrood Iran

Guest editorial introducing the special issue on the International Conference on Sustainable Energy Sources, Technologies and Systems 2023.

关键词： solar energy storage wind energy geothermal hydropower biofuels batteries

Detecting anomalies in blockchain transactions using machine learning classifiers and explainability analysis

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BLOCKCHAIN-RESEARCH AND APPLICATIONS 2024年第3期5卷 106-122页

作者： Hasan, mohammad Rahman, mohammad Shahriar Janicke, Helge Sarker, Iqbal H. Premier Univ Dept Comp Sci & Engn Chitagong 4000 Bangladesh United Int Univ Dept Comp Sci & Engn Dhaka 1212 Bangladesh Cyber Secur Cooperat Res Ctr Perth 6027 Australia Edith Cowan Univ Ctr Securing Digital Futures Perth 6027 Australia

As the use of blockchain for digital payments continues to rise, it becomes susceptible to various malicious attacks. Successfully detecting anomalies within blockchain transactions is essential for bolstering trust in digital payments. However, the task of anomaly detection in blockchain transaction data is challenging due to the infrequent occurrence of illicit transactions. Although several studies have been conducted in the field, a limitation persists: the lack of explanations for the model's predictions. This study seeks to overcome this limitation by integrating explainable artificial intelligence (XAI) techniques and anomaly rules into tree-based ensemble classifiers for detecting anomalous Bitcoin transactions. The shapley additive explanation (SHAP) method is employed to measure the contribution of each feature, and it is compatible with ensemble models. Moreover, we present rules for interpreting whether a Bitcoin transaction is anomalous or not. Additionally, we introduce an under-sampling algorithm named XGBCLUS, designed to balance anomalous and non-anomalous transaction data. This algorithm is compared against other commonly used under-sampling and over-sampling techniques. Finally, the outcomes of various tree-based single classifiers are compared with those of stacking and voting ensemble classifiers. Our experimental results demonstrate that: (i) XGBCLUS enhances true positive rate (TPR) and receiver operating characteristic-area under curve (ROC-AUC) scores compared to state-of-the-art under-sampling and over-sampling techniques, and (ii) our proposed ensemble classifiers outperform traditional single tree-based machine learning classifiers in terms of accuracy, TPR, and false positive rate (FPR) scores.

关键词： Anomaly detection Blockchain Bitcoin transactions Data imbalance Data sampling Explainable AI Machine learning Decision tree Anomaly rules

The Impact of Nitrogen-Fixing Bacteria, Iron, and Zinc Foliar Application on Dry Land Yellow Mustard (Brassica juncea) Grain and Oil Production

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Agricultural Sciences 2024年第7期15卷 719-728页

作者： Saeid Zehtab Salmasi Haleh Nasiri Rezvan Heshmati mohammad reza Sarikhani Yagoub Raei Sustainable Agriculture Science Center Department of Plant and Environmental Sciences New Mexico State University Alcalde New Mexico USA Department of Plant Ecophysiology University of Tabriz Tabriz Iran Department of Soil Science University of Tabriz Tabriz Iran

The study, conducted at the Research Farm of the College of Agriculture, University of Tabriz in 2021, focused on the effects of various nitrogen-fixing bacterial isolates, biofertilizers containing nitrogen and phosphorus, as well as iron and zinc foliar applications on mustard growth under rainfed conditions. The results indicated that biofertilizers, whether used alone or in combination with chemical fertilizers, produced comparable grain and oil outputs compared to chemical fertilizers alone. Additionally, the application of iron and zinc through foliar spraying significantly enhanced both grain and oil production. These findings suggest that integrating nitrogen-fixing bacteria and biofertilizers could reduce reliance on chemical nitrogenous fertilizers, leading to decreased production expenses, improved product quality, and minimized environmental impact. This study highlights the potential for sustainable agricultural practices in dry land farming as a viable alternative to traditional chemical-intensive methods. Substituting chemical nitrogenous fertilizers with nitrogen-fixing bacteria or biofertilizers could result in cost savings in mustard grain and oil production while promoting environmental sustainability.

关键词： Nitrogen Fixing Bacteria Yellow Mustard Dry Land Farming Iron Zinc Foliar Application

High-throughput computational screening and in vitro evaluation identifies 5-(4-oxo-4H-3,1-benzoxazin-2-yl)-2-[3-(4-oxo-4H-3,1-benzoxazin-2-yl)phenyl]-1H-isoindole-1,3(2H)-dione(C3),as a novel EGFR—HER2 dual inhibitor in gastric tumors

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Oncology Research 2024年第2期32卷 251-259页

作者： MESFER AL SHAHRANI REEM GAHTANI mohammad ABOHASSAN mohammad ALSHAHRANI YASSER ALRAEY AYED DERA mohammad RAJEH ASIRI PRASANNA RAJAGOPALAN Department of Clinical Laboratory Sciences College of Applied Medical SciencesKing Khalid UniversityAbhaSaudi Arabia

Gastric cancers are caused primarily due to the activation and amplification of the EGFR or HER2 kinases resulting in cell proliferation,adhesion,angiogenesis,and *** therapies are ineffective due to the intra-tumoral heterogeneity and concomitant genetic ***,dual inhibition strategies are recommended to increase potency and reduce *** this study,we have conducted computational high-throughput screening of the ChemBridge library followed by in vitro assays and identified novel selective inhibitors that have a dual impediment of EGFR/HER2 kinase ***-based High-throughput Virtual Screening(D-HTVS)was used to screen the whole ChemBridge small molecular library against EGFR and *** atomistic molecular dynamic simulation was conducted to understand the dynamics and stability of the protein-ligand ***/HER2 kinase enzymes,KATOIII,and Snu-5 cells were used for in vitro *** atomistic Molecular Dynamics simulations followed by solvent-based Gibbs binding free energy calculation of top molecules,identified compound C3(5-(4-oxo-4H-3,1-benzoxazin-2-yl)-2-[3-(4-oxo-4H-3,1-benzoxazin-2-yl)phenyl]-1H-isoindole-1,3(2H)-dione)to have a good affinity for both EGFR and *** predicted compound,C3,was promising with better binding energy,good binding pose,and optimum interactions with the EGFR and HER2 residues.C3 inhibited EGFR and HER2 kinases with IC50 values of 37.24 and 45.83 nM,*** GI50 values of C3 to inhibit KATOIII and Snu-5 cells were 84.76 and 48.26 nM,*** on these findings,we conclude that the identified compound C3 showed a conceivable dual inhibitory activity on EGFR/HER2 kinase,and therefore can be considered as a plausible lead-like molecule for treating gastric cancers with minimal side effects,though testing in higher models with pharmacokinetic approach is required.

关键词： Dual inhibitor Drug discovery EGFR/HER2 kinase Gastric cancer High-throughput screening