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Green bio-synthesis of Ni/montmorillonite nanocomposite using extract of Allium jesdianum as the nano-catalyst for electrocatalytic oxidation of methanol

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Chinese Journal of Chemical Engineering 2020年第10期28卷 2555-2565页

作者： mohammad hossein sheikh-mohseni Sajjad Sedaghat Pirouz Derakhshi Aliakbar Safekordi Department of Chemistry Science and Research BranchIslamic Azad UniversityTehranIran Department of Chemistry Shahr-e-Qods BranchIslamic Azad UniversityShahr-e-QodsIran Department of Chemistry North Tehran BranchIslamic Azad UniversityTehranIran

In this work,synthesis of Ni nanoparticles was carried out successfully by water extract of Allium jesdianum as a biochemical reducing agent in the presence of montmorillonite clay(MMT)as a natural solid support for the first *** the electrochemical activity of the synthesized nanocomposite was investigated in methanol electrocatalytic *** with high cation exchange capacity and nano layer structure was exposed to ion exchange conditions in nickel *** Ni^2+ion exchanged form was used in this process as a source of ions and also capping *** extract of Allium jesdianum used as a reducing agent due to abundant availability of phenolic and flavonoid *** synthesized Ni/MMT nanocomposite was characterized using UV–Vis spectroscopy(UV–Vis),Fourier Transform Infrared Spectroscopy(FT-IR),X-ray diffraction(XRD),Scanning Electron Microscopy(SEM),Transmission electron microscopy(TEM)and Energy-dispersive X-ray spectroscopy(EDX).The surface of prepared modified electrode has been characterized using SEM to evaluate the morphology,showing uniform dispersion of Ni nanoparticles with mean diameter of 12 to 20 *** modified carbon paste electrode was then used in methanol electrocatalytic oxidation *** oxidation on the proposed modified electrode surface occurs at 0.6 V and 0.3 V in alkaline and acidic medium ***,the results showed the better performance of modified electrode toward methanol electrocatalytic oxidation in comparison with carbon paste electrode that is modified by ion exchanged *** transfer coefficients and apparent charge transfer rate constant for the modified electrode in the absence of methanol in alkaline medium were respectively found as:αa=0.53,αc=0.37 and ks=1.6×10^-1 s^-***,the average value of catalytic rate constant for the electrocatalytic oxidation of methanol by the prepared nano-catalyst was estimated to be about 0.9 L·mol^-1·s^-1 by chronoamperometry *** prepare

关键词： Green biosynthesis Nanoparticles Montmorillonite Biocatalysis Methanol electrocatalytic oxidation Fuel cell

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Special Issue: International Conference on Sustainable Energy Sources, Technologies and Systems 2023 (ICSESTS-2023)

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CLEAN ENERGY 2024年第3期8卷 136-137页

作者： Kumar, Ravinder Ahmadi, mohammad hossein Lovely Profess Univ Sch Mech Engn Phagwra 144411 Punjab India Shahrood Univ Technol Fac Mech Engn Shahrood Iran

Guest editorial introducing the special issue on the International Conference on Sustainable Energy Sources, Technologies and Systems 2023.

关键词： solar energy storage wind energy geothermal hydropower biofuels batteries

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Multidisciplinary design optimization of a dual-spin guided vehicle

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Defence Technology（防务技术） 2024年第7期37卷 133-148页

作者： Jalal Karimi mohammad Reza Rajabi Seyed hossein Sadati Seyed Mahid hosseini Department of Aerospace Engineering Malek Ashtar University of TechnologyTehranIran

In this research,a Multidisciplinary Design Optimization approach is proposed for the dual-spin guided flying projectile design considering external and internal parts of the body as design *** this way,a parametric formulation is *** related disciplines,including structure,aerodynamics,guidance,and control are *** total mass,maximum aerodynamic control effectiveness,minimum miss distance,maximum yield stress in all subsystems,controllability and gyroscopic stability constraints are some of objectives/constraints taken into *** problem is formulated in All-At-Ones Multidisciplinary Design Optimization approach structure and solved by Simulated Annealing and minimax *** optimal configurations are evaluated in various *** resulted optimal configurations have met all design objectives and constraints.

关键词： Flying projectile optimal design All-at-ones multidisciplinary optimization Structure discipline Guidance and control discipline Aerodynamic discipline

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Analyzing the Interplay of Sintering Conditions on Microstructure and Hardness in Indirect Additive Manufacturing of 17-4PH Stainless Steel

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Acta Metallurgica Sinica(English Letters) 2024年第9期37卷 1611-1620页

作者： Erika Lannunziata mohammad hossein Mosallanejad Manuela Galati Gabriele Piscopo Abdollah Saboori Integrated Additive Manufacturing Center Department of Management and Production EngineeringPolitecnico di TorinoCorso Duca Degli Abruzzi 2410129TurinItaly

Indirect additive manufacturing(AM)methods have recently attracted attention from researchers thanks to their great potential for cheap,straightforward,and small-scale production of metallic *** diffusion additive manufacturing(ADAM),a variant of indirect AM methods,is a layer-wise indirect AM process recently developed based on fused deposition modeling and metal injection ***,there is still limited knowledge of the process conditions and material properties fabricated through this process,where sintering plays a crucial role in the final consolidation of ***,this research,for the first time,systematically investigates the impact of various sintering conditions on the shrinkage,relative density,microstructure,and hardness of the 17-4PH ADAM *** this reason,as-washed samples were sintered under different time-temperature *** sample density was evaluated using Archimedes,computed tomography,and image analysis *** outcomes revealed that sintering variables significantly impacted the density of brown 17-4PH Stainless Steel *** results indicated more than 99% relative densities,higher than the value reported by Markforged Inc.(~96%).Based on parallel porosities observed in the computed tomography results,it can be suggested that by modifying the infill pattern during printing,it would be possible to increase the final relative *** microhardness of the sintered samples in this study was higher than that of the standard sample provided by Markforged *** at 1330℃ for 4 h increased the density of the printed sample without compromising its mechanical *** to X-ray diffraction analysis,the standard sample provided by Markforged ***“1330℃—4 h”one had similar stable phases,although copper-rich intermetallics were more abundant in the microstructure of reference *** study is expected to facilitate the adoption of indirect metal AM methods by different sector

关键词： Indirect additive manufacturing Atomic diffusion additive manufacturing 17-4PH stainless steel Computed tomography Sintering

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Assessment of electrostatic discharge sensitivity of nitrogen-rich heterocyclic energetic compounds and their salts as high energy-density dangerous compounds: A study of structural variables

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DEFENCE TECHNOLOGY 2024年第9期39卷 15-22页

作者： Keshavarz, mohammad hossein Bani, Sedigheh Heydari Bakhtiari, Reza hosseini, Seyyed Hesamodin Malek Ashtar Univ Technol Fac Appl Sci Esfahan 177415875 Iran

Nitrogen-rich heterocyclic energetic compounds (NRHECs) and their salts have witnessed widespread synthesis in recent years. The substantial energy-density content within these compounds can lead to potentially dangerous explosive reactions when subjected to external stimuli such as electrical discharge. Therefore, developing a reliable model for predicting their electrostatic discharge sensitivity (ESD) becomes imperative. This study proposes a novel and straightforward model based on the presence of specific groups (-NH2 or -NH-, -N = N+ -O(- )and -NNO2, -ONO2 or -NO2) under certain conditions to assess the ESD of NRHECs and their salts, employing interpretable structural parameters. Utilizing a comprehensive dataset comprising 54 ESD measurements of NRHECs and their salts, divided into 49/5 training/test sets, the model achieves promising results. The Root Mean Square Error (RMSE), Mean Absolute Error (MAE), and Maximum Error for the training set are reported as 0.16 J, 0.12 J, and 0.5 J, respectively. Notably, the ratios RMSE(training)/RMSE(test), MAE(training)/MAE(test), and Max Error(training)/Max Error(test) are all greater than 1.0, indicating the robust predictive capabilities of the model. The presented model demonstrates its efficacy in providing a reliable assessment of ESD for the targeted NRHECs and their salts, without the need for intricate computer codes or expert involvement. (c) 2024 China Ordnance Society. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://***/ licenses/by-nc-nd/4.0/).

关键词： Electrostatic discharge sensitivity Heterocyclic energetic compounds containing azole compound Interpretable structural parameter Safety ELECTRIC SPARK SENSITIVITY THERMAL-DECOMPOSITION IMPACT SENSITIVITY NITRAMINES PERFORMANCE EXPLOSIVES PREDICTION

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Improvement of Surface Mechanical and Tribological Characteristics of L-PBF Processed Commercially Pure Titanium through Ultrasonic Impact Treatment

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Acta Metallurgica Sinica(English Letters) 2024年第6期37卷 1034-1046页

作者： Iman Ansarian Reza Taghiabadi Saeid Amini mohammad hossein Mosallanejad Luca Iuliano Abdollah Saboori Department of Materials Science and Metallurgy Imam Khomeini International University(IKIU)QazvinIran Department of Mechanical Engineering University of KashanKashanIran Integrated Additive Manufacturing Center Department of Management and Production EngineeringPolitecnico di TorinoCorso Duca Degli Abruzzi 2410129TurinItaly

Multi-pass ultrasonic impact treatment(UIT)was applied to modify the microstructure and improve the mechanical and tribological characteristics at the near-surface region of commercially pure Ti(CP-Ti)specimens produced by the laser powder bed fusion(L-PBF)*** considerably refined the L-PBF process-related acicular martensites(α′-M)and produced a well-homogenized and dense surface microstructure,where the porosity content of 1-,3-,and 5-pass UITed samples was reduced by 43,60,and 67%,*** UITed samples showed an enhancement in their near-surface mechanical properties up to a depth of about 300μ*** nanoindentation results for the 3-pass UITed sample revealed an increase of about 53,45,and 220%in its nanohardness,H/E_(r),and H_(3)/E_(r)^(2)indices,*** stylus profilometry results showed that performing the UIT removed the L-PBF-related features/defects and offered a smooth *** roughness average(R_(a))and the skewness(R_(sk))of the 3-pass UITed sample were found to be lower than those of the L-PBFed sample by 95 and 223%,*** the UIT also enhanced the material ratio,where the maximum load-bearing capacity(~100%)in as-L-PBFed(as-built)and 3-pass UITed samples was obtained at 60-and 10-µm depths,*** tribological investigations showed that applying the UIT resulted in a significant reduction of wear rate and average coefficient of friction(COF)of *** instance,under the normal pressures of 0.05 and 0.2 MPa,the wear rate and COF of the 3-pass UITed sample were lower than those of the L-PBFed sample by 65 and 58%,and 20 and 17%,respectively.

关键词： Laser powder bed fusion Ultrasonic impact treatment Commercially pure Ti(CP-Ti) Surface mechanical properties Tribological properties

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Er_(2)TiO_(5)@Ag nanocomposites:Enhanced photocatalysis and bacteria inactivation,and cytotoxicity

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Journal of Rare Earths 2024年第5期42卷 851-858,I0002页

作者： Mehdi Nazeri hossein Sedaghat Reza Rafiei mohammad Amin Farzin Seyed Mostafa hosseinpour Mashkani Department of Parasitology and Mycology Kashan University of Medical SciencesKashanIran Department of Microbiology Kashan University of Medical SciencesKashanIran General Medicine Student School of MedicineKashan University of Medical SciencesKashanIran Student Research Committee Kashan University of Medical SciencesKashanIran Institute for Biomedical Materials and Devices School of Mathematical and Physical SciencesFaculty of ScienceUniversity of Technology SydneyNSW2007Australia

In this study,we successfully synthesized Er_(2)TiO_(5)@Ag nanocomposites(NCPs) using the ultrasonicmediated sol-gel technique to create a multifunctional material with enhanced photocatalytic and antibacterial *** visible light photocatalytic activities of Er_(2)TiO_(5) nanoparticles(NPs) and Er_(2)TiO_(5)@Ag NCPs were systematically evaluated under various conditions,including different concentrations of Basic Blue 41(BB 41) dye and *** results reveal a remarkable improvement in the photocatalytic degradation efficiency of Er_(2)TiO_(5)@Ag NCPs(95%) compared to Er_(2)TiO_(5) NPs(80%).Furthermore,the antibacterial efficacy of Er_(2)TiO_(5) NPs and Er2TiO_5@Ag NCPs were extensively examined against Gram-positive and Gram-negative ***,Er_(2)TiO_(5)@Ag NCPs exhibit significantly higher minimum bactericidal concentration(MBC) values compared to Er_(2)TiO_(5) *** antibacterial effect of Er_(2)TiO_(5)@Ag NCPs is particularly pronounced against *** and Pseudomonas aeruginosa,while demonstrating moderate effects on Escherichia coli and Enterococcus *** assess the biocompatibility of the synthesized materials,we investigated their internalization by MCF-7 ***,both Er_(2)TiO_(5) NPs and Er_(2)TiO_(5)@Ag NCPs are found to be effectively internalized by the cells,suggesting their potential application in biomedical ***,our study unveils the exceptional potential of Er_(2)TiO_(5)@Ag NCPs as a dual-action solution,simultaneously possessing enhanced photocatalytic efficiency and potent antibacterial *** multifunctional nanocomposite not only outperforms Er_(2)TiO_(5) and Ag but also paves the way for innovative applications in sustainable environmental remediation and advanced biomedical technologies,promising a brighter and cleaner future.

关键词： Rare earth catalysis Nanocomposite Er_(2)TiO_(5)@Ag Antibacterial activity Photocatalysis Cytotoxicity

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Using Longitudinal Fins to Improve the Melting Performance of Stearic Acid in Thermal Energy Storage Devices

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Journal of Thermal Science 2024年第5期33卷 1672-1687页

作者： YAN Suying LIU Yiran AO Ci ZHAO Xiaoyan ZHANG Na ZHANG Ruiying AHMADI mohammad hossein School of Energy and Power Engineering Inner Mongolia University of TechnologyHohhot 010051China Institute of Engineering Thermophysics Chinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100190China School of Materials Science and Engineering Inner Mongolia University of TechnologyHohhot 010051China Faculty of Mechanical Engineering Shahrood University of TechnologyShahroodIran

The heat transfer efficiency of a thermal energy storage unit(TESU)can be improved by the addition of novel longitudinal fins.A series of TESUs are analyzed using the finite volume method(FVM)to determine the effect of fin angle on the heat transfer *** the fin angle increases,the TES rate first increases,then decreases,reaching a maximum rate at 60°,where the melting time is less by 30.9%,28.58%,21.99%,9.02%,and 18.1%than at 0°,15°,30°,45°,and 80°,*** addition,it is found that the melting time of the phase change material is significantly greater at the bottom of the *** time percentage of this stage decreases as the fin angle increases through these percentages by 7%,14%,23%,33%,and 20%,***,the response surface methodology(RSM)is applied to optimize the longitudinal fin by minimizing the total melting *** analysis concludes that a fin angle of 58.68°reduces the complete melting time of the stearic acid by 44%below the time at 0°.These findings fill a gap in knowledge of the effect on melting performance of the design angle of longitudinal fins and provide a reference for the design of horizontally placed longitudinal finned thermal energy storage units.

关键词： thermal energy storage melting rate enhancement longitudinal fins fin angle phase change materials

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Insight into small eyes: a practical description from phenotypes presentations to the management

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International Journal of Ophthalmology(English edition) 2024年第2期17卷 380-391页

作者： Sana Niazi Sorcha NíDhubhghaill Farideh Doroodgar Zisis Gatzioufas mohammad hossein Dehghan Translational Ophthalmology Research Center Tehran University of Medical SciencesTehran ***Iran Antwerp University Hospital Edegem 2650Belgium Faculty of Health Sciences Antwerp UniversityAntwerpen 2000EdegemBelgium Negah Aref Ophthalmic Research Center Shahid Beheshti University of Medical SciencesTehran 16666Iran University Eye Hospital Basel Basel 4031Switzerland

This narrative review aimed to have an algorithmic approach to microphthalmos by a systematic *** definition can be related to a number of special *** the more challenging cases of complex microphthalmos,relative anterior microphthalmos,and nanophthalmos,the surgeon can approach these cases more safely if they have a deep understanding of the anatomical variations and ideal formulae for intraocular lens computation and knows how to avoid intra-and post-operative *** this article,we review the criteria by which we recognize and describe pre-,intra-,and post-operative considerations,as well as discuss the ideal intraocular lenses for microphthalmos,given the intricate varieties of small eye phenotypes.

关键词： microphthalmos nanophthalmos lenses intraocular anterior chamber axial length eye cataract microcornea syndrome

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Green bio-synthesis of Ni/montmorillonite nanocomposite using extract of Allium jesdianum as the nano-catalyst for electrocatalytic oxidation of methanol

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中国化学工程学报（英文版） 2020年第10期

作者： mohammad hossein sheikh-mohseni Sajjad Sedaghat Pirouz Derakhshi Aliakbar Safekordi

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