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Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams

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International Journal of Minerals,Metallurgy and Materials 2014年第8期21卷 806-812页

作者： Vesna Nikolic Zeljko Kamberovic Zoran Antic Marija Korac miroslav sokic Vesna Maksimovic Innovation Center of the Faculty of Technology and Metallurgy University of Belgrade Karnegijeva 4 11120 Belgrade Serbia Faculty of Technology and Metallurgy University of Belgrade Karnegijeva 4 11120 Belgrade Serbia Innovation Center of the Faculty of Chemistry University of Belgrade Studentski trg 12-16 11000 Belgrade Serbia Institute for Technology of Nuclear and other Raw Materials Bulevar Frans d'Eperea 86 11000 Belgrade Serbia Institute for Nuclear Sciences ‘Vinca’ Mike Petrovica Alasa 12-14 11001 Belgrade Serbia

A method of synthesizing Ni-based catalysts supported on α-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation ofa Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness （533 and 633 K） were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.

关键词： catalysts nickel ceramic foams modification aerosol process catalytic properties

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Increasing Production Efficiency through Casting Quality Improving by Electromagnetic Field Applying

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Journal of Mechanics Engineering and Automation 2012年第1期2卷 59-62页

作者： Marija Mihailovic Aleksandra Pataric Zvonko GuliSija miroslav sokic Institute for Technology of Nuclear and Other Mineral Raw Materials Belgrade 11000 Serbia

The increased production efficiency of heat treatable A1 alloys, as the result of applied electromagnetic field during continuous casting process was investigated. The applied frequency of the electromagnetic field （EMF） during the AI alloys continuous casting was changing from 30 Hz to 50 Hz, while some castings were obtained without the EMF influence. The mechanical characterization of continuous casted AI alloys EN AW 2007 and En AW 2024 was done on testing machine Zwick/Roell Z 100. The microstructure of as-cast samples was examined, as well. When the frequency decreases （from 50 Hz to 30 Hz）, the grain size decreases as well, what is noticeable through the finer microstructure and its uniformity throughout the cross-section. These results have shown that low frequency electromagnetic field significantly influenced the microstructure and therefore the mechanical properties of as cast ingots. Thus, through improved castings quality, operation time and energy savings, the production efficiency was increased.

关键词： AI alloys electromagnetic field casting production efficiency.

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Pressure Oxidative Leaching of Complex Sulphide Concentrate

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Journal of Chemistry and Chemical Engineering 2011年第9期5卷 828-831页

作者： Vladislav Lj. Matkovie miroslav D. sokic Branislav R. Markovic Institute for Technology of Nuclear and Other Mineral Raw Material 86 Franehet dEsperey Street Belgrade 11000 Serbia

The presented results are related to the leaching of Pb-Zn-Cu-Fe sulphide concentrate, obtained from barite-sulphide ores, under the elevated temperatures and pressures in an autoclave. The leaching process was performed using the sulphur acid solution with the oxygen addition for the separation of the targeted metals from the polymetallic concentrate. In this process influences of various parameters were discussed and then correlated to the leached metals, zinc, copper and iron. Zinc, copper and iron were dissolved in a solution, while lead remained as insoluble in the leach residue. The best leaching results were determined under the temperature of 210 ℃ during the 240 min. Obtained leaching degrees were 98% zinc, 95% copper and 96% iron.

关键词： Complex concentrate presure leaching sulphuric acid oxygen.

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Mechanism of Chalcopyrite Leaching in Oxidative Sulphuric Acid Solution

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Journal of Chemistry and Chemical Engineering 2011年第1期5卷 37-41页

作者： miroslav D. sokic Branislav R. Markovic Vladislav Lj. Matkovic Nada D. Strbac Dragana T. Zivkovic Institute for Technology of Nuclear and Other Mineral Raw Materials 86 Franchet d ＇Esperey Street Belgrade 11000 Serbia Technical Faculty at Bor University of Belgrade Bor 19210 Serbia

The mechanism of the leaching process of chalcopyrite concentrate with sodium nitrate in sulphuric acid solution were studied and discussed. Chemical reactions of leaching and their thermodynamic probabilities are predicted based on the calculated Gibbs energies and analysis of E-pH diagrams. Experimental data, thermodynamic analysis, chemical, XRD, and SEM/EDX analyses of concentrate and the leach residues, were performed to develop a better understanding of the chemical reactions that took place in the system. Elemental sulphur was formed as the main leaching product, precipitated at the particle surfaces and tended to inhibit the leaching rate.

关键词： Chalcopyrite leaching mechanism sulpruric acid sodium nitrate.

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Exploring Deep Learning Methods for Computer Vision Applications across Multiple Sectors:Challenges and Future Trends

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Computer Modeling in Engineering & Sciences 2024年第4期139卷 103-141页

作者： Narayanan Ganesh Rajendran Shankar miroslav Mahdal Janakiraman SenthilMurugan Jasgurpreet Singh Chohan Kanak Kalita School of Computer Science and Engineering Vellore Institute of TechnologyChennai600127India Department of Computer Science and Engineering Koneru Lakshmaiah Education FoundationVaddeswaram522502India Department of Control Systems and Instrumentation Faculty of Mechanical EngineeringVSB-Technical University of OstravaOstrava70800Czech Republic Department of Computer Science and Engineering Vel Tech High Tech Dr.Rangarajan Dr.Sakunthala Engineering CollegeChennai600062India Department of Mechanical Engineering and University Centre for Research&Development Chandigarh UniversityMohali140413India Department of Mechanical Engineering Vel Tech Rangarajan Dr.Sagunthala R&D Institute of Science and TechnologyAvadi600062India

Computer vision(CV)was developed for computers and other systems to act or make recommendations based on visual inputs,such as digital photos,movies,and other *** learning(DL)methods are more successful than other traditional machine learning(ML)methods *** techniques can produce state-of-the-art results for difficult CV problems like picture categorization,object detection,and face *** this review,a structured discussion on the history,methods,and applications of DL methods to CV problems is *** sector-wise presentation of applications in this papermay be particularly useful for researchers in niche fields who have limited or introductory knowledge of DL methods and *** review will provide readers with context and examples of how these techniques can be applied to specific areas.A curated list of popular datasets and a brief description of them are also included for the benefit of readers.

关键词： Neural network machine vision classification object detection deep learning

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New strategies in the diagnosis and treatment of immune-checkpoint inhibitor-mediated colitis

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World Journal of Clinical Cases 2024年第6期12卷 1050-1062页

作者： Tsvetelina Velikova Boris Krastev Milena Gulinac miroslav Zashev Vasko Graklanov Milena Peruhova Medical Faculty Sofia University St.Kliment OhridskiSofia 1407Bulgaria Medical Center Nadezhda Medical Center NadezhdaSofia 1407Bulgaria General and Clinical Pathology Medical University of PlovdivPlovdiv 4002Bulgaria Department of General Surgery University Hospital“Heart and Brain”Burgas 8000Bulgaria First Department of Internal Diseases Medical University of PlovdivPlovdiv 4000Bulgaria Department of Hematology University Hospital“St.George”Plovdiv 4000Bulgaria Division of Gastroenterology University Hospital“Heart and Brain”Burgas 1000Bulgaria

Immune-checkpoint inhibitor-mediated colitis(IMC)is an increasingly recognized adverse event in cancer immunotherapy,particularly associated with immune checkpoint inhibitors(ICIs)such as anti-cytotoxic T-lymphocyte antigen-4 and anti-programmed cell death protein-1 *** this revolutionary immunotherapy gains prominence in cancer treatment,understanding,diagnosing,and effectively managing IMC becomes *** represents a unique challenge due to its immune-mediated nature and potential for severe ***,a precise picture of IMC pathophysiology is currently ***,we aimed to summarize the existing data while acknowledging the need for further *** comprehensive review explores the mechanisms underlying ICIs,gastrointestinal adverse effects,and,in particular,IMC’s incidence,prevalence,and *** review also emphasizes the importance of recognizing IMC’s distinct clinical and histopathological features to differentiate it from other forms of ***,this paper highlights the urgentneed for evolving diagnostic methods,therapeutic strategies,and a multidisciplinary approach to effectively manage IMC.

关键词： Immune-checkpoint inhibitors Immune-checkpoint inhibitor-mediated colitis Inhibitor-mediated colitis management Immunotherapy-associated colitis Checkpoint inhibitor-induced colitis Gastrointestinal adverse effects Checkpoint inhibitor toxicity Inhibitor-mediated colitis therapy

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Cyberbullying Sexism Harassment Identification by Metaheurustics-Tuned eXtreme Gradient Boosting

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Computers, Materials & Continua 2024年第9期80卷 4997-5027页

作者： Milos Dobrojevic Luka Jovanovic Lepa Babic miroslav Cajic Tamara Zivkovic Miodrag Zivkovic Suresh Muthusamy Milos Antonijevic Nebojsa Bacanin Technical Faculty Singidunum UniversityBelgrade11000Serbia Informatics and Computing Singidunum UniversityBelgrade11000Serbia Business Economics Singidunum UniversityBelgrade11000Serbia Computing and Informatics Sinergija UniversityBijeljina76300Bosnia and Herzegovina Department for Information Systems and Technologies University“Union Nikola Tesla”Cara DusanaBelgrade11080Serbia Department for Computer Science and Informatics School of Electrical EngineeringUniversity of BelgradeBelgrade11000Serbia Department of Electrical and Electronics Engineering Kongu Engineering College(Autonomous)PerunduraiErode638060India Department of Mathematics Saveetha School of Engineering(Deemed to be University)SIMATS ThandalamChennai602105India MEU Research Unit Middle East UniversityAmman11831Jordan

Cyberbullying is a form of harassment or bullying that takes place online or through digital devices like smartphones,computers,or *** can occur through various channels,such as social media,text messages,online forums,or gaming *** involves using technology to intentionally harm,harass,or intimidate others and may take different forms,including exclusion,doxing,impersonation,harassment,and ***,due to the rapid growth of malicious internet users,this social phenomenon is becoming more frequent,and there is a huge need to address this ***,the main goal of the research proposed in this manuscript is to tackle this emerging challenge.A dataset of sexist harassment on Twitter,containing tweets about the harassment of people on a sexual basis,for natural language processing(NLP),is used for this *** algorithms are used to transform the text into a meaningful representation of numbers for machine learning(ML)input:Term frequency inverse document frequency(TF-IDF)and Bidirectional encoder representations from transformers(BERT).The well-known eXtreme gradient boosting(XGBoost)ML model is employed to classify whether certain tweets fall into the category of sexual-based harassment or ***,with the goal of reaching better performance,several XGBoost models were devised conducting hyperparameter tuning by *** this purpose,the recently emerging Coyote optimization algorithm(COA)was modified and adjusted to optimize the XGBoost ***,other cutting-edge metaheuristics approach for this challenge were also implemented,and rigid comparative analysis of the captured classification metrics(accuracy,Cohen kappa score,precision,recall,and F1-score)was ***,the best-generated model was interpreted by Shapley additive explanations(SHAP),and useful insights were gained about the behavioral patterns of people who perform social harassment.

关键词： Coyote optimization algorithm NLP TF-IDF BERT XGBoost online harassment and cyberbullying metaheuristics

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In vivo femtosecond laser nanosurgery of the cell wall enabling patch-clamp measurements on filamentous fungi

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Microsystems & Nanoengineering 2024年第2期10卷 251-267页

作者： Tanja Pajić Katarina Stevanović Nataša V.Todorović Aleksandar J.Krmpot miroslav Živić Svetlana Savić-Šević Steva M.Lević Marina Stanić Dejan Pantelić Brana Jelenković Mihailo D.Rabasović Institute of Physiology and Biochemistry“Ivan Djaja” Faculty of BiologyUniversity of BelgradeStudentski trg 1611158BelgradeSerbia Institute for Biological Research“Siniša Stanković” University of BelgradeNational Institute of the Republic of SerbiaBulevar Despota Stefana 14211000BelgradeSerbia Institute of Physics Belgrade University of BelgradeNational Institute of the Republic of SerbiaPregrevica 11811080BelgradeSerbia University of Belgrade Faculty of AgricultureNemanjina Street 611080BelgradeSerbia Institute for Multidisciplinary Research University of BelgradeKneza Višeslava 111030BelgradeSerbia

Studying the membrane physiology of filamentous fungi is key to understanding their interactions with the environment and crucial for developing new therapeutic strategies for disease-causing ***,their plasma membrane has been inaccessible for a micron-sized patch-clamp pipette for pA current recordings due to the rigid chitinous cell ***,we report the first femtosecond IR laser nanosurgery of the cell wall of the filamentous fungi,which enabled patch-clamp measurements on protoplasts released from hyphae.A reproducible and highly precise(diffraction-limited,submicron resolution)method for obtaining viable released protoplasts was *** release from the nanosurgery-generated incisions in the cell wall was achieved from different regions of the *** plasma membrane of the obtained protoplasts formed tight and high-resistance(GΩ)contacts with the recording *** entire nanosurgical procedure followed by the patch-clamp technique could be completed in less than 1 *** to previous studies using heterologously expressed channels,this technique provides the opportunity to identify new ionic currents and to study the properties of the ion channels in the protoplasts of filamentous fungi in their native environment.

关键词： patch recording laser

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Sustaining forest biodiversity:Exploring the effect of long-term natural disturbance dynamics on contemporary lichen communities in primary forest ecosystems

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Forest Ecosystems 2024年第4期11卷 556-567页

作者： Rhiannon Gloor Marek Svitok Martin Mikolas Jenyk Hofmeister Josef Halda Pavel Janda Francesco Maria Sabatini Lucie Zemanova Arne Buechling Daniel Kozak Matej Ferencik Michal Frankovic Martin Dusatko miroslav Svoboda Department of Forest Ecology Faculty of Forestry and Wood SciencesCzech University of Life Sciences PragueKamycka 129Praha 6–Suchdol16500Czech Republic Faculty of Ecology and Environmental Sciences Technical University in ZvolenT.G.Masaryka 2496001ZvolenSlovakia Institute of Botany Plant Science and Biodiversity CenterSlovak Academy of SciencesDúbravska cesta 984523BratislavaSlovakia PRALES Odtrnovie 56301322RosinaSlovakia Faculty of Science University of Hradec KraloveHradecka 1285Hradec KraloveⅢ50003Czech Republic BIOME–Biogeography and Macroecology Department of BiologicalGeological and Environmental Sciences(BIGEA)Alma Mater Studiorum-University of Bolognavia Irnerio 42BolognaItaly

In this era of biodiversity loss and climate change,quantifying the impacts of natural disturbance on forest communities is imperative to improve biodiversity conservation *** and epixylic lichens are effective forest quality bioindicators,as they are generally long-lived organisms supported by continuity of specific forest structures and their associated microclimatic ***,how lichen communities respond to the effects of fluctuating historical disturbances remains *** a dendrochronological approach,this study investigates how natural disturbance dynamics indirectly influence various lichen community metrics in some of Europe's best-preserved primary mixed-beech *** modelling revealed that natural historical disturbance processes have decades-long effects on forest structural attributes,which had both congruent and divergent impacts on lichen community richness and *** species richness indirectly benefited from both historical and recent higher-severity disturbances via increased standing dead tree basal area and canopy openness respectively-likely through the presence of both pioneer and late-successional species associated with these ***-listed species richness showed a dependence on habitat continuity(old trees),and increased with disturbance-related structures(standing dead trees)whilst simultaneously benefiting from periods without severe disturbance events(old trees and reduced deadwood volume).However,if the disturbance occurred over a century in the past,no substantial effect on forest structure was ***,while disturbance-mediated forest structures can promote overall richness,threatened species appear vulnerable to more severe disturbance events-a concern,as disturbances are predicted to intensify with climate ***,the high number of threatened species found reinforce the critical role of primary forest structural attributes for biodiversity ***

关键词： Mixed-beech forests Species richness Old-growth forests Carpathian mountains Biodiversity conservation Dendroecology Fagus sylvatica

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Photometric and Spectroscopic Study of Ten Low Mass Ratio Contact Binary Systems:Orbital Stability,O'Connell Effect and Infrared Calcium Line Filling

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Research in Astronomy and Astrophysics 2024年第8期24卷 212-222页

作者： Surjit S.Wadhwa Adam Popowicz Raúl Michel Petar Kostić Oliver Vince Nick F.H.Tothill Ain Y.De Horta miroslav D.Filipović School of Science Western Sydney UniversityLocked Bag 1797PenrithNSW 2751Australia Department of Electronics Electrical Engineering and MicroelectronicsSilesian University of TechnologyAkademicka 1644120 GliwicePoland Instituto de Astronomía UNAM.A.P.87722800 EnsenadaBCMéxico Astronomical Observatory Volgina 711060 BelgradeSerbia

Low mass ratio contact binary systems are more likely to have unstable orbits and potentially *** addition,such systems exhibit characteristics such as starspots and high energy emissions(UV)suggestive of chromospheric and magnetic *** curve modeling of ten contact binary systems is *** were found to be of extreme low mass ratio ranging from 0.122 to 0.24 and three were found to be potentially unstable and possible merger *** of the infrared calcium absorption lines is a marker of increased chromospheric *** use the available Large Sky Area Multi-Object Fiber Spectroscopic Telescope spectra along with matched standard spectra(broadened for rotation)to measure the excess filling of the central core depression flux of the two main infrared calcium absorption linesλ8542 andλ*** find that all reported contact binaries have excess filling of the core flux in the infrared calcium *** of the systems reported were also observed by the Galaxy Evolution Explorer mission and we find that all three have features of excess ultraviolet emissions further adding evidence for increased chromospheric activity in low mass ratio contact *** of both orbital stability and absorption line filling is dependent on the determination of geometric and absolute parameters from light curve *** an insignificant number of contact binary light curves exhibit the O’Connell effect,usually attributed to *** discuss the inclusion of starspots in light curve solutions and how they influence the geometric and absolute parameters.

关键词： (stars)binaries eclipsing-techniques photometric-stars chromospheres

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