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Experimental study on the working performance of different milling tools for multistage fracturing ball seats

Petroleum Science 2020年第6期17卷 1699-1716页

作者： Jia-Qi Che Han-Xiang Wang Yan-Wen Zhang ming-chao du Shao-Hua Ma College of Mechanical and Electronic Engineering China University of Petroleum(East China)Qingdao 266580ShandongPeople’s Republic of China

To achieve the secondary production in multistage fracturing wells of tight oil,milling tools are usually used to remove the multistage fracturing ball seats to achieve production with a large diameter in *** this paper,first of all,the working mechanism of milling tools for multistage fracturing ball seats was studied and a mechanical analysis model of single abrasive grain was ***,an experimental system for milling tools was developed,and the experimental tests of the flat,the blade,and the slope milling tool were conducted in ***,the morphology of chips and the surface morphology of the workpiece after the experiment were ***,the working performance of milling tools was evaluated from the perspectives of working safety,working efficiency,and wear resistance of the milling *** results show that the torque of the milling tool increases nonlinearly with the increase in the cutting depth of the abrasive grain and increases linearly with the increase in the cutting ***,the chips are irregular particles and the size is mainly from 10 to 50μ***,the chips should be pumped up with a small pump pressure and a large *** this,the cutting depths of the abrasive grains are from 216.20 to 635.47μm and the bottom surface of the milling tool should be eccentric to avoid the zero point of cutting ***,the torque of the slope milling tool is 23.8%larger than that of the flat milling tool,which is also 30.4%smaller than that of the blade milling *** with the flat milling tool,the working efficiency of the blade milling tool improves by 79.9%and the slope milling tool improves by 111.1%.Also,the wear resistance of the blade milling tool decreases by 102.7%,while the slope milling tool declines by 32.6%when compared with the flat milling ***,the slope milling tool has the characteristics of moderate torque,stable working conditions,the highest working efficiency,and fine wear resistan

关键词： Multistage fracturing ball seat Milling tool Working performance Tight oil Experimental system Single abrasive grain

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Multi-objective optimization and experiment of nylon cord rubber in expandable packer

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Petroleum Science 2021年第1期18卷 269-284页

作者： Yan-Wen Zhang Han-Xiang Wang Jia-Qi Che ming-chao du Hong-Jie Zhang College of Mechanical and Electronic Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina

Nylon cord rubber has the advantages of small residual deformation and is easy to lift and lower the tubing string in low-permeability oil and gas ***,it is associated with low-pressure resistance and poor sealing *** enhance the performance of nylon cord rubber,a three-dimensional numerical model of the nylon cord rubber was established and its accuracy experimentally *** Plackett-Burman test,the Steepest climbing test and the Response surface method were used to acquire the polynomial response surface model connecting structural parameters with bearing and sealing *** genetic algorithms,optimal structural parameters of nylon cord rubber were determined depending on field *** reliability of the optimized results was verified by laboratory *** was shown that after optimization,the bearing capacity of the expandable packer increased by 25%while the sealing performance increased by 66%.In addition,the bearing pressure was 70 MPa while the sealing pressure was 50 *** measurements effectively met the on-site requirements of high-pressure and fine fracturing in low-permeability oil and gas reservoirs.

关键词： Low-permeability reservoirs Nylon cord rubber Numerical simulation Response surface method Multi-objective genetic algorithm Laboratory test

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Mechanical characteristic and failure mechanism of joint with composite sucker rod

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Petroleum Science 2023年第5期20卷 3172-3183页

作者： Yan-Wen Zhang Jia-Qi Che Han-Xiang Wang Jin Zhang Feng Li ming-chao du Yu-Ting Wang College of Mechanical and Electronic Engineering China University of Petroleum(East China)Qingdao266580ShandongChina National Petroleum Corporation Offshore Engineering(Qingdao)Company Limited Qingdao266520ShandongChina Technical Testing Center of SINOPEC Shengli Oilfield Co.Dongying257088ShandongChina College of Electrical Engineering and Automation Shandong University of Science and TechnologyQingdao266590ShandongChina

Composite sucker rods are widely used in oil fields because of light weight,high strength,and corrosion *** technology becomes the primary connection method of ***,the joints with composite sucker rods are prone to debone and *** connected characteristics are less considered,so the failure mechanism of the joint is still *** on the cohesive zone model(CZM)and the Johnson-Cook constitutive model,a novel full-scale numerical model of the joint with composite sucker rod was established,and verified by pull-out *** mechanical properties and slip characteristics of the joint were studied,and the damaged procession of the joint was *** results showed that:a)the numerical model was in good agreement with the experimental results,and the error is within 5%;b)the von Mises stress,shear stress,and interface stress distributed symmetrically along the circumferential path increased gradually from the fixed end to the loading end;c)the first-bonded interface near the loading end was damaged at first,followed by debonding of the second-bonded interface,leading to the complete shear fracture of the epoxy,and resulted in the debonding of the joint with composite sucker rod,which can provide a theoretical basis for the structural design and optimization of the joint.

关键词： Joint with composite sucker rod Numerical model Connected characteristics Failure mechanism Tensile tests

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Investigation of bubbles escape behavior from low basicity mold flux for high-Mn high-Al steels using 3D X-ray microscope

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 102-110页

作者： Qiang Liu Xiang Li Shen du ming Gao Yanbin Yin Jiongming Zhang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

during the continuous casting process of high-Mn high-Al steels,various types of gases such as Ar need to escape through the top of the *** which,the behavior of bubbles traversing the liquid slag serves as a restrictive link,closely associated with viscosity and the thickness of liquid *** contrast to two-dimensional surface observation,three-dimensional(3D)analysis method can offer a more intuitive,accurate,and comprehensive ***,this study employs a 3D X-ray microscope(3D-XRM)to obtained spatial distribution and 3D morphological characteristics of residual bubbles in mold flux under different basicity of liquid slag,different temperatures,and different holding *** results indicate that as basicity of slag increases from 0.52 to 1.03,temperature increases from 1423 to 1573 K,the viscosity of slag decreases,the floating rate of bubbles *** addition,when holding time increases from 10 to 30 s,the bubbles floating distance increases,and the volume fraction and average equivalent sphere diameter of the bubbles solidified in the mold flux gradually *** one word,increasing the basicity,temperature,and holding time leading to an increase in the removal rate of bubbles especially for the *** findings of bubbles escape behavior provide valuable insights into optimizing low basicity mold flux for high-Mn high-Al steels.

关键词： mold flux low basicity bubbles three-dimensional X-ray microscope viscosity

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A Mn-porphyrinic metal–organic framework immobilizing glucose oxidase for combined photodynamic/chemodynamic/starvation therapy

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Tungsten 2025年第1期7卷 183-194页

作者： Xin-Ran Sun Hao-ming Yuan Guo-Da Zhang chao Wang Shu-Juan Sun Peng-Fei Shi Shandong Provincial Key Laboratory of Detection Technology for Tumor Markers School of Chemistry and Chemical Engineering Linyi University

The combination of photodynamic therapy（PDT） and chemodynamic therapy（CDT） in tumor treatment has attracted considerable ***,tumor hypoxia and glutathione（GSH） overproduction in the tumor tissue restricted the progress of their ***,a Mn-porphyrinic metal-organic framework（Mn-TCPP） was constructed by the one-pot method and further used for immobilizing glucose oxidase（GOx） to obtain GOx@*** would rapidly exhaust endogenous glucose into hydrogen peroxide（H2O2） and gluconic acid,thus shutting off the energy supply of tumor cells for starvation ***-TCPP catalyzed H2O2to produce oxygen,regulating the hypoxic tumor microenvironment and in turn improving1O2generation under laser ***,Mn-TCPP can reduce reactive oxygen species consumption owing to the redox reaction between Mn3+and GSH,thus greatly enhancing ***,benefiting from GOx-mediated starvation therapy,Mn2+produced by Mn3+reduction can react with sufficient intracellular H2O2to generate ·OH with high cytotoxicity through a Fenton-like *** treatment by GOx@Mn-TCPP under laser irradiation in vitro,the cell viability of 4T1 and A549 tumor cells reached to 20%,reflecting GOx@Mn-TCPP could give full play to the advantages of PDT/CDT/starvation *** results in vivo demonstrated that GOx@Mn-TCPP mediated synergistic cascade therapy could significantly inhibit tumor growth and improve the therapeutic effect.

关键词： Chemodynamic therapy Immobilizing enzyme Metal–organic frameworks Photodynamic therapy Starvation therapy

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Enantio-divergent C–H borylation with two different ligands from a single chiral source

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Science China Chemistry 2025年第1期68卷 226-232页

作者： Rongrong du Senmiao Xu State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics Chinese Academy of Sciences College of Material Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Material TechnologyMinistry of Education Hangzhou Normal University University of Chinese Academy of Sciences

Reported here is an iridium-catalyzed enantio-divergent C（sp3）–H borylation of α-gem-dimethyl groups of trifluoromethyl ketone-derived hydrazones to construct a series of acyclic all-carbon quaternary stereocenters with a high level of chiral induction. Two different chiral bidentate boryl ligands from a common chiral source not only can switch the enantioselectivity but also are complementary in terms of the substrate scope.

关键词： asymmetric catalysis C–H borylation all-carbon quaternary stereocenters synthetic methods

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Ca2+ cation-mediated microenvironment for electrochemical hydrodimerization of furfural

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Science China Chemistry 2025年

作者： Wei du Shuangshuang Cha Can Lei Mengxin Qu Zhongqiang Deng ming Gong Xinhe Bao Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University State Key Laboratory of Catalysis National Laboratory for Clean Energy Collaborative Innovation Center of Chemistry for Energy Materials Dalian Institute of Chemical Physics Chinese Academy of Sciences

Furfural is one of the most important biomass-based platform molecules as sustainable precursors for chemicals and fuels. The electrochemical hydrodimerization of furfural can generate hydrofuroin, which is a promising precursor for gasoline or jet ***, steering the selectivity toward hydrodimerization under near-neutral conditions that suppress polymerization and disproportionation of furfural remains challenging. Herein, we discovered that tuning the electrolyte cations could be an effective and alternative strategy for modulating furfural reduction to the traditional electrocatalyst design. Under the optimal Ca2+cations,hydrofuroin yield could be much improved from other cations with hydrofuroin selectivity of 95.5%. The systematic characterization of the ion-centered double layer reflected the suitable sizes and charges of hydrated Ca2+for suppressing the hydrogen evolution reaction from activation of surrounding water molecules as well as encouraging furfural accumulation via non-covalent interaction for directing the electron transfer to furfurals. Ions with smaller or larger sizes can either activate local water molecules or form a crowded ionic interface that casts an adverse effect on furfural enrichment. This work not only presents an effective strategy for facilitating biomass valorization via hydrodimerization but also emphasizes the essential role of the ion-centered microenvironment for steering the electrocatalytic pathways.

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From text to image:challenges in integrating vision into ChatGPT for medical image interpretation

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Neural Regeneration Research 2025年第2期20卷 487-488页

作者： Shunsuke Koga Wei du Department of Pathology and Laboratory Medicine Hospital of the University of PennsylvaniaPhiladelphiaPAUSA

Large language models(LLMs),such as ChatGPT developed by OpenAI,represent a significant advancement in artificial intelligence(AI),designed to understand,generate,and interpret human language by analyzing extensive text *** potential integration into clinical settings offers a promising avenue that could transform clinical diagnosis and decision-making processes in the future(Thirunavukarasu et al.,2023).This article aims to provide an in-depth analysis of LLMs’current and potential impact on clinical *** ability to generate differential diagnosis lists underscores their potential as invaluable tools in medical practice and education(Hirosawa et al.,2023;Koga et al.,2023).

关键词： image diagnosis text

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Crustal magma oxidation state and endowments in porphyry copper deposits

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Science China Earth Sciences 2025年第1期68卷 226-236页

作者： Yumin AI Massimo CHIARADIA chao WU Huayong CHEN Key Laboratory of Mineralogy and Metallogeny Guangzhou Institute of Geochemistry Chinese Academy of Sciences University of Chinese Academy of Sciences Department of Earth Sciences University of Geneva Guangdong Provincial Key Laboratory of Mineral Physics and Materials

Porphyry copper deposits（PCDs） supply the majority of the world's copper（Cu） as well as significant amounts of molybdenum（Mo） and gold（Au）. The formation of these deposits is controlled by a variety of geological factors, among which the magmatic oxidation is one of the focuses of current research. This study investigates the redox characteristics of arc magmas by analyzing the ratio of vanadium（V） to scandium（Sc） and its correlation with the oxygen fugacity （fO2） of magmas from arcs of various crustal thicknesses globally. We compiled an extensive dataset of published V/Sc values and studied the partition coefficients of Vand Sc between minerals and silicate melts across various magmatic environments. The results demonstrate that fractional crystallization of magnetite markedly reduces V/Sc values of the residual melt. Furthermore, magnesium number（Mg#） at the onset of magnetite fractionation is strongly positively correlated with fO2of the equilibrium magma. Based on this,the oxidation of arc magmas from different crustal thicknesses can be evaluated. The result suggests that magmas generated in crusts thicker than 20 km tend to be more oxidized with increasing crust thickness. This trend is attributed to enhanced intracrustal differentiation processes involving garnet and amphibole, particularly in mature island and continental arcs. In contrast,magmas in thinner arc crusts（ducted slab materials, display higher oxidation states than most of their thicker crust counterparts. These findings suggest that both subduction dynamics and crustal thickness play a vital role in determining the oxidation state of arc magmas and, consequently, their capacity to generate PCDs. Highly oxidized, primitive arc magmas are less favorable for PCD formation due to that they tend to experience magnetite fractionation and thus sulfide saturation in the early stage of magma evolution, a process leading to copper depletion. On the contra

关键词： Magma evolution V/Sc systematics Magnetite Oxygen fugacity Porphyry copper deposits

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Effect of a Carbon Fibre-steel Fibre-graphite Conductive Filler on the Electrothermal Properties of Cementitious Materials

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期40卷 141-151页

作者： FAN Yanan WEI Hong ZHENG Hongyong du Hongxiu Department of Architecture and Environmental Engineering Taiyuan UniversityTaiyuan 030032China College of Civil Engineering Taiyuan University of TechnologyTaiyuan 030032China

Carbon fibre,steel fibre and graphite were used as conductive fillers to prepare cementitious materials with excellent electrothermal *** electrically conductive cementitious materials with different volume dosages were analysed through compressive and flexural strength,electrochemical impedance spectroscopy and temperature rise *** equivalent circuit model was established to study the electrically conductive heat generation mechanism in the electrically conductive cementitious *** results indicate that the mechanical properties of cementitious composite materials with a ternary conductive phase are better than those of pristine cementitious materials because the fibrous filler improves their mechanical ***,the incorporation of graphite in the material reduces its *** fibrous and point-like conductive phase materials into the cementitious material enhances the overall conductive pathway and considerably reduces the electrical resistance of the cementitious material,enhancing its conductive *** volume ratios of carbon fibre,steel fibre and graphite that achieve an optimal complex doping in the cementitious material were 0.35%,0.6%and 6%,*** was determined using the mutation point of each circuit element parameter as the percolation *** addition,at a certain safety voltage,there is a uniform change between the internal and surface temperatures of the conductive cementitious material,and the heating effect in this materialis is considerably better than that in the pristine cementitious material.

关键词： cementitious composites conductive fillers electrothermal properties electrochemical impedance spectroscopy

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