检索结果-南通市图书馆

LaNi_(0.6)Fe_(0.4)O_(3)阴极接触材料导电特性调控及其对SOFC电化学性能的影响

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

无机材料学报 2024年第4期39卷 367-373页

作者：张琨王宇朱腾龙孙凯华韩敏芳钟秦南京理工大学化学与化工学院南京210094 徐州华清京昆能源有限公司徐州221005 清华大学能源与动力工程系北京100084

鉴于平板式固体氧化物燃料电池(SOFC)电堆对低面电阻、高稳定性阴极接触材料的需求,本研究阐明了LaNi_(0.6)Fe_(0.4)O_(3)(LNF)颗粒尺寸调控对导电和SOFC单电池性能演变的影响机制,优化了LNF预处理工艺,降低了接触组件面电阻,提升了SOF... 详细信息

鉴于平板式固体氧化物燃料电池(SOFC)电堆对低面电阻、高稳定性阴极接触材料的需求,本研究阐明了LaNi_(0.6)Fe_(0.4)O_(3)(LNF)颗粒尺寸调控对导电和SOFC单电池性能演变的影响机制,优化了LNF预处理工艺,降低了接触组件面电阻,提升了SOFC单电池性能及热循环稳定性。结果表明:预压造粒的样品(LNF-2)与高温烧结预处理的样品(LNF-3)的面电阻更小,分别为0.074和0.076Ω·cm^(2);在750℃施加1 A/cm^(2)电流负载后,能够更快地进入稳态,并保持颗粒尺寸稳定。其中,LNF-2单电池在750℃下的峰值功率密度0.94 W/cm^(2)较未处理的LNF的0.66 W/cm^(2)高,但在热循环过程中性能衰减较大,下降了20%;而LNF-3单电池在20次热循环后峰值功率密度仅下降了4%。本研究对高可靠SOFC电堆装配及其长寿命稳定运行具有指导及参考价值。

关键词：固体氧化物燃料电池(SOFC) 阴极接触材料 LaNi_(0.6)Fe_(0.4)O_(3) 热循环

集流体对平板型固体氧化物燃料电池性能的影响机制

在线全文

学校读者我要写书评

暂无评论

硅酸盐学报 2024年第1期52卷 19-29页

作者：张纪豪权蒙豪孙凯华韩敏芳中国矿业大学低碳能源与动力工程学院江苏徐州221116 徐州华清京昆能源有限公司江苏徐州221005 清华大学能源与动力工程系北京100084

工业尺寸固体氧化物燃料电池面积大、且存在翘曲,可靠集电是SOFC高效输出的重要保障。以长条形阳极支撑半电池为基体,分割阴极制备成4个面积2.0 cm×2.1 cm的绝缘阴极区域,每个区域覆盖不同面积银网构成差异性集电。在各绝缘区域分别开... 详细信息

工业尺寸固体氧化物燃料电池面积大、且存在翘曲,可靠集电是SOFC高效输出的重要保障。以长条形阳极支撑半电池为基体,分割阴极制备成4个面积2.0 cm×2.1 cm的绝缘阴极区域,每个区域覆盖不同面积银网构成差异性集电。在各绝缘区域分别开展电化学阻抗谱测试和电流-电压特性曲线扫描,结果表明:开路下25%银网覆盖区域阻抗实部显著高于其他区域,拉载时同等输出电压下电池电流密度随银网面积的减少而单调递减。测量同类电池阴阳极电导率,并表征微观构造。相关参数代入模型,得出沿流道方向电流与电压分布:无银网覆盖阴极存在累积的水平电流,造成总输出电流减小及电流密度分布不均,影响电极极化过程,恶化电池输出性能。

关键词：固体氧化物燃料电池集流体接触电阻分割电池水平电流

Cell-protecting regeneration from anode carbon deposition using in situ produced oxygen and steam:A combined experimental and theoretical study

在线全文

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2018年第12期34卷 2375-2383页

作者： Zongying han Zhibin Yang minfang han Union Research Center of Fuel Cell School of Chemical and Environmental EngineeringChina University of Mining and Technology Department of Energy and Power Engineering Tsinghua University College of Chemical and Environmental Engineering Shandong University of Science and Technology

Carbon deposition is a primary concern during the operation of solid oxide fuel cells（SOFCs） fueled with hydrocarbon fuels, leading to cell degradation and even cell damage. Carbon elimination is expected to be a promising approach to prolong cell life. This work reports on a combined experimental and theoretical investigation of cell regeneration from anode carbon deposition of tubular SOFCs fabricated by phase-inversion and co-sintering techniques. The as-prepared cell exhibits a maximum power density of 0.20 W cm;at 800 ℃ fueling with wet CH;, but fails to stable operation due to severe carbon *** on thermodynamic predictions, a successive cell-protecting regeneration process is proposed to eliminate deposited carbon without oxidizing Ni catalysts, during which CH;and H;fuels are provided in circulation. Through a total of 35 cycling tests, cell performance can always successfully restore to the initial *** possible carbon elimination mechanism is investigated in detail based on thermodynamic and first-principle calculations. The feasibility of carbon elimination using in situ produced oxygen or steam through electrochemical reaction has been revealed, providing a novel continuous operation mode for hydrocarbon-based SOFCs.

关键词： Solid oxide fuel cells Carbon deposition Cell regeneration Carbon elimination First-principle

Significant potential of Solid Oxide Fuel Cell systems for distributed power generation and carbon neutrality

在线全文

学校读者我要写书评

暂无评论

Frontiers in Energy 2022年第6期16卷 879-882页

作者： Ziyuan TENG minfang han Fuel Cell and Energy Storage Center Department of Energy and Power EngineeringState Key Laboratory of Control and Simulation of Power Systems and Generation EquipmentTsinghua UniversityBeijing 100084China

Energy is important for human survival and *** September 2020,the Chinese government announced that“China aims to have their CO_(2) emissions peak before 2030 and achieve carbon neutrality before 2060.”As China’s reformation and opening-up proceeds into its fifth decade,this new vision for its future is in line with that of the world’s major economies in terms of the need to reach net zero emissions globally by the mid-21stcentury[1].However,coal-fueled thermal power generation is currently dominant and accounts for more than 70%of the total amount of power generated in China,making it the world’s largest energy consumer and carbon *** on the country’s domestic resources,namely the abundance of coal and scarcity of oil and gas,it would be difficult to fundamentally change this coal-based energy structure in the short *** 2021,the global total energy sector was responsible for 36.3 Gt of CO_(2) emissions,including approximately 12 Gt from China,which thus accounts for one-third of the total global emissions[2].The demand for efficiency,energy savings,and emissions reduction in the power generation industry has become increasingly *** need has arisen to enhance ways in which to use coal cleanly and efficiently,reduce the consumption thereof,and replace coal with other forms of *** addition,carbon emissions need to be lowered by promoting the adoption of alternative power generation technologies that are more energy *** would require transformation away from coal power and the exploration of clean,efficient,flexible,and safe forms of energy as the main future development directions[3].

关键词： neutral carbon replace

Evaluation of La_(0.7)Ca_(0.3)Cr_(0.95)Zn_(0.05)O_(3-δ)-Gd_(0.1)Ce_(0.9)O_(2-δ) Dual-phase Material and its Potential Application in Oxygen Transport Membrane

在线全文

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2014年第10期30卷 954-958页

作者： Tenglong Zhu Zhibin Yang minfang han Union Research Center of Fuel Cell State Key Laboratory of Coal Resources and Safe MiningChina University of Mining & Technology

In this work, a dual-phase material consisting Gd0.1Ce0.9O2-δ （GDC, 60 wt%） was synthesized. of La0.7Ca0.3Cr0.95Zn0.05O3-δ （LCCZ, 40 wt%） and Properties including phase structure, sintering behavior, electrical conductivity and oxygen permeability for LCCZ-GDC were evaluated. The results show that dense LCCZ-GDC dual-phase disks were obtained at the sintering temperature of 1250, 1300, 1350 and 1400 ℃ by tape casting and high temperature sintering method. The grain sizes of both GDC and LCCZ grew up with the increasing of sintering temperature. The average grain size of GDC was about 0.5, 0.8, 1.4, 1.8 μm while the average grain size of LCCZ was about 0.8, 1.5, 1.8 and 2 pm after sintering at 1250, 1300, 1350 and 1400℃, respectively. Oxygen flux of LCCZ-GDC decreased with the increase of sintering temperature from 1250 to 1400 ℃. The oxygen flux of LCCZ-GDC sintered at 1250 ℃ reached 0.079 mL/min/cm2 at 975℃ with a membrane thickness of 800 μm. Dual-phase material of LCCZ-GDC will be a promising oxygen transport membrane material for its low sintering temperature and good microstructure.

关键词： Dual-phase material Tape casting Sintering temperature Oxygen transport membrane

Electrochemical Properties of Tubular SOFC Based on a Porous Ceramic Support Fabricated by Phase-Inversion Method

在线全文

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2016年第7期32卷 681-686页

作者： Zongying han Yuhao Wang Zhibin Yang minfang han Union Research Center of Fuel Cell School of Chemical and Environmental Engineering China University of Mining and Technology State Key Laboratory of Power Systems Department of Thermal Engineering Tsinghua University

In this work, a tubular ceramic-supported solid oxide fuel cell （SOFC） was successfully fabricated by a low cost and simple process involving phase-inversion, brush coating and co-sintering. Properties in- cluding sintering behavior, microstructure of the tubular support as well as the electrochemical properties of single cell were investigated. The results show that a porous tubular support with finger-like pores and macrovoids was obtained after phase-inversion process. The tubular support is proved to be gaspermeable after sintering at 1400 ℃ with shrinkage of about 34%. The maximum power density of single tubular SOFC is 100 mW/cm2 and 122 mW/cm2 at 850 ℃ when fed with wet methane and hydrogen, respectively. The current collection, thickness of electrolyte and gas permeability of tubular support should account for the large total resistance. The present tubular design could be expected to deliver a higher voltage for longer support with several segmented-in-series cell stacks.

关键词： Phase-inversion method Ceramic support Tubular solid oxide fuel cell Segmented-in-series

Research on sintering process of YSZ electrolyte

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2006年第z2期25卷 209-212页

作者： han minfang TANG Xiuling PENG Suping Union Research Center of Fuel Cell School of Chemical & Environment Engineering China University of Mining & Technology Beijing 100083 China Union Research Center of Fuel Cell School of Chemical & Environment Engineering China University of Mining & Technology Beijing 100083 China Union Research Center of Fuel Cell School of Chemical & Environment Engineering China University of Mining & Technology Beijing 100083 China

Yttria stabilized zirconia (YSZ) has widely been used as electrolyte in solid oxide fuel cell (SOFC). The microstructure of YSZ related to the fabrication process was discussed in the paper. With YSZ nano-powders about 40-100 nm as raw material, the YSZ adobe was manufactured by tape calendering process. The named three-step sintering process was performed at 1000 ℃ for 2 h, then raised the temperature with normal rate and as soon as up to 1400 ℃, the furnace was controlled at 1250-1300 ℃ for 10-20 h. The high dense YSZs with the relative density of 96%-99% were obtained; the grain size of YSZ could be reduced to 0.5-3 μm. The above result is benefited to co-fired in the electrode-supported SOFCs.

关键词： yttria stabilized zirconia (YSZ) electrolyte sintering process

Fabrication and optimization of La_(0.4)Sr_(0.6)Co_(0.2)Fe_(0.7)Nb_(0.1)O_(3-δ) electrode for symmetric solid oxide fuel cell with zirconia based electrolyte

在线全文

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2017年第11期33卷 1329-1333页

作者： Na Xu Tenglong Zhu Zhibin Yang minfang han Union Research Center of Fuel Cell School of Chemical and Environmental Engineering China University of Mining and Technology State Key Laboratory of Power Systems Department of Thermal Engineering Tsinghua University

La（0.4）Sr（0.6）Co（0.2）Fe（0.7）Nb（0.1）O（3-δ）（LSCFN）was applied as both anode and cathode for symmetrical solid oxide fuel cells（SSOFCs）with zirconia based *** cell with LSCFN electrode was fabricated by tape-casting and screen *** process was optimized firstly by comparing co-sintering and separate-sintering of electrode and *** further improve the LSCFN electrode properties,oxygen ionic conductor of Gd（0.1）Ce（0.9）O（2-δ）（GDC）was added into the LSCFN *** preferred composition of LSCFN-GDC composite electrode was found to be 1：1 in weight ratio with polarization resistance of 0.16Ωcm^2at 800~℃.The maximum power densities of LSCFN-GDC｜｜GDC/YSZ/GDC｜｜LSCFN-GDC tested in H2and CH4with 3%H2O were 395 m W cm^（-2）and 124 m W cm^（-2）at 850~？C,respectively,which were much higher than that of LSCFN｜｜GDC/YSZ/GDC｜｜LSCFN cells at same condition,possibly due to the extension of the triple phase boundary induced by the addition of *** cell showed reasonable stability using H2and CH4with 3%H2O as fuels and no significant power output degradation was observed after total 200 h operation.

关键词： LSCFN electrode Triple phase boundary Solid oxide fuel cells

Influence of Lithium Oxide Addition on the Sintering Behavior and Electrical Conductivity of Gadolinia Doped Ceria

在线全文

学校读者我要写书评

暂无评论

Journal of Materials Science & Technology 2011年第5期27卷 460-464页

作者： minfang han Ze Liu Su Zhou Lian Yu Union Research Center of Fuel Cell School of Chemical & Environment Engineering University of Mining & Technology(CUMTB) Beijing 100083 China

Ceria-based electrolytes have been widely researched in intermediate-temperature solid oxide fuel cell （SOFC）, which might be operated at 500-600℃. Sintering behavior with lithium oxide as sintering additive and electrical conductivity of gadolinia doped ceria （GdonCe0.902-σ, GDC10） electrolyte was studied in this paper by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and electrochemical impedance spectroscopy （EIS）. As the results,, the fully dense GDC10 electrolytes are obtained at a low temperature of 800℃ with 2.5 mol% Li20 as sintering additive （called 5LiGDCS00）. During sintering process, lithium oxides adsorbed by around GDC10 surface help to sinter at 800~C and are kept at the grain boundary of GDC10 in the end. The fine grains of 100-400 nm and high electrical conductivity of 0.014 S/cm at 600~C in 5LiGDC800 were achieved, which contributed to the lower sintering temperature and enhanced grain boundary conductivity, respectively. Lithium, staying at grain boundary, reduces the depletion of oxygen vacancies in the space charge layers and increases the oxygen vacancy concentration in the grain boundary, which leads to improve the total electrical conductivity of 5LiGDC800.

关键词： Gadolinia doped ceria Sintering additive Electrical conductivity