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Ordered SnO nanoparticles in MWCNT as a functional host material for high-rate lithium-sulfur battery cathode

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Nano Research 2017年第6期10卷 2083-2095页

作者： A-Young kim min kyu kim Ji Young kim Yuren Wen Lin Gu Van-Duong Dao Ho-Suk Choi Dongjin Byun Joong Kee Lee Center for Energy Convergence Korea Institute of Science and Technology Seoul02792 Republic of Korea Department of Material Science and Engineering Korea University Seoul 02841 Republic of Korea Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China Department of Chemical Engineering & Applied Chemistry Chungnam National University Daejeon 34134 Republic of Korea

Lithium-sulfur battery has become one of the most promising candidates for next generation batteries, and it is still restricted due to the low sulfur conductivity, large volume expansion and severe polysulfide shuttling. Herein, we present a novel hybrid electrode with a ternary nanomaterial based on sulfur-impregnated multiwalled carbon nanotubes filled with ordered tin-monoxide nanoparticles （MWCNT-SnO/S）. Using a dry plasma reduction method, a mechanically robust material is prepared as a cathode host material for lithium-sulfur batteries. The MWCNT-SnO/S electrode exhibits high conductivity, good ability to capture polysulfides, and small volume change during a repeated charge-discharge process. In situ transmission electron microscopy and ultraviolet-visible absorption results indicate that the MWCNT-SnO host efficiently suppresses volume expansion during lithiation and reduces polysulfide dissolution into the electrolyte. Furthermore, the ordered SnO nanoparticles in the MWCNTs facilitate fast ion/electron transfer during the redox reactions by acting as connective links between the walls of the MWCNTs. The MWCNT-SnO/S cathode with a high sulfur content of 70 wt.% exhibits an initial discharge capacity of 1,682.4 mAh·g^-1 at 167.5 m·g^-1 （0.1 C rate） and retains a capacity of 530.1 mAh·g^-1 at 0.5 C after 1,000 cycles with nearly 100% Coulombic efficiency. Furthermore, the electrode exhibits the high capacity even at a high current rate of 20 C.

关键词： hybrid nanomaterial multiwalled carbonnanotube (MWCNT) ordered tin monoxide cathode high loading lithium-sulfur battery

Survival benefit of adjuvant treatment for ampullary cancer with lymph nodal involvement:A systematic review and meta-analysis

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Hepatobiliary & Pancreatic Diseases International 2024年第6期23卷 559-565页

作者： min kyu kim Jin Ho Choi In Rae Cho Sang Hyub Lee Ji Kon Ryu Yong-Tae kim Woo Hyun Paik Department of Gastroenterology Asan Medical CenterUniversity of Ulsan College of MedicineSeoulKorea Department of Internal Medicine Liver Research InstituteSeoul National University HospitalSeoul National University College of MedicineSeoulKorea

Background:The efficacy of adjuvant treatment(AT)in ampullary cancer(AmC)remains *** systematic review and meta-analysis aimed to evaluate the role of AT for *** sources:A comprehensive systematic search was performed in PubMed,EMBASE,Cochrane Library,and Web of Science *** comparing overall survival(OS)and recurrence-free survival(RFS)of patients who underwent AT or not following AmC resection were ***:A total of 3971 patients in 21 studies were *** pooled data showed no significant difference in effect on the OS by AT[hazard ratio(HR)=0.998,95%confidence interval(CI):0.768–1.297].No significant difference in recurrence between the AT and non-AT(nAT)groups was noted(HR=1.158,95%CI:0.764–1.755).In subgroup analysis,patients who received AT showed favorable outcomes in the OS compared with those who received nAT in nodal-positive AmC(HR=0.627,95%CI:0.451–0.870).Neither AT consisted of adjuvant chemotherapy with radiotherapy(HR=0.804,95%CI:0.563–1.149)nor AT with adjuvant chemotherapy(HR=0.883,95%CI:0.642–1.214)showed any significant effect on the ***:The effect of AT in AmC on survival and recurrence did not show a significant ***,effectiveness according to AT strategies did not show enhancement in *** had an advantage in survival compared with nAT strategy in nodal-positive *** cases of AmC with positive lymph nodal involvement,AT may be warranted regardless of detailed strategies.

关键词： Ampulla of Vater Adjuvant chemotherapy Adjuvant chemoradiotherapy Meta-analysis

FEA technique of hot plate forming process using cell-typed die with cooling device

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中国有色金属学会会刊：英文版 2012年第S3期22卷 831-837页

作者： Jung-min LEE In-kyu LEE kyung-Hun LEE Dae-Soon kim Byung-min kim Dongnam Regional Division Korea Institute of Industrial Technology School of Mechanical Engineering Pusan National University Industrial Technology Division Hyundai Heavy Industries

Hot plate forming using a cell-typed die is a process for forming a large thick plate with a spherical shape for the manufacture of a large spherical LNG ***-typed upper and lower dies made of a framework of steel plates fitted to make a grid pattern are used in this process,and an air-cooling device is separately installed inside the lower die.A finite element analysis (FEA) technique was developed,which included hot forming,air flow,cooling and thermal deformation analysis for the hot plate forming process using the cell-typed ***,the convective and interface heat transfer coefficients were used to reproduce analytically the effects of the cooling device in the hot plate forming analysis.A small-scale model test of the process was conducted to verify the FEA *** analysis results show that the curvature of the final plate agrees well with that of the designed experiment within a maximum relative error of 0.03% at the corner of the plate.

关键词： cell-typed die hot plate forming spherical LNG tank heat transfer coefficient

Management of symptomatic cervical facet cyst with cervical interlaminar epidural block: A case report

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World Journal of Clinical Cases 2022年第32期10卷 11936-11941页

作者： Seong min Hwang min kyu Lee Saeyoung kim Department of Anesthesiology and Pain Medicine School of MedicineKyungpook National UniversityDaegu 41944South Korea

BACKGROUND Symptomatic cervical facet cysts are relatively rare compared to those in the lumbar *** cysts are usually located in the 7th cervical and 1st thoracic vertebral(C7/T1)area,and surgical excision is performed in most ***,facet cysts are associated with degenerative conditions,and elderly patients are often ineligible for surgical *** interlaminar epidural block has been used in patients with cervical radiating symptoms and achieved good ***,cervical interlaminar epidural block may be the first-choice treatment for symptomatic cervical facet *** SUMMARY A 70-year-old man complained of a tingling sensation in the left hand,focused on the 4th and 5th fingers,for 1 year,and posterior neck pain for over 5 *** patient’s numeric rating scale(NRS)score was 5/*** patient was diagnosed with symptomatic cervical facet cyst at the left C7/T1 facet *** cervical interlaminar epidural block at the C7/T1 level with 20 mg triamcinolone and 5 mL of 0.5%lidocaine was *** patient's symptoms improved immediately after the block,with an NRS score of 3 *** 3 mo,his left posterior neck pain and tingling along the left 8th cervical dermatome were relieved,with an NRS score of *** A cervical interlaminar epidural block is a good alternative for managing symptomatic cervical facet cysts.

关键词： Cervical vertebrae Cysts Epidural Injections Neck pain Therapeutics Zygapophyseal joint Case report

Impregnation approach for poly(vinylidene fluoride)/tin oxide nanotube composites with high tribological performance

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Journal of Materials Science & Technology 2020年第2期37卷 19-25页

作者： min Su Park Jin kyu kim Tong-Seok Han Jung Tae Park Jong Hak kim Department of Chemical and Biomolecular Engineering Yonsei University50 Yonsei-roSeodaemun-guSeoul03722Korea Department of Civil and Environmental Engineering Yonsei University50 Yonsei-roSeodaemun-guSeoul03722Korea Department of Chemical Engineering Konkuk University120 Neungdong-roGwangjin-guSeoul05029Korea

We report a composite material with the high tribological performance,which consists of onedimensional SnO2 nanotubes(ST)and a high molecular weight poly(vinylidene fluoride)(PVDF)matrix in terms of *** of PVDF in N,N-dimethylformamide(DMF)resulted in a facile penetration of PVDF into the inner hollow voids of ST,leading to the close *** between PVDF and ST results in a beneficial effect on the chain arrangement of PVDF,providing anα-phase with better tribological *** ST incorporation,the friction coefficient decreased by 85.0%to 0.408,and the specific wear rate decreased by 69.1%to 0.412,demonstrating the pivotal role of ST as a self-lubricating material due to a large interactive area and PVDF chain rearrangement.

关键词： SnO2 nanotube Composite Friction coefficient Wear rate

Effect of Sub-T_g Annealing on the Corrosion Resistance of the Cu–Zr Amorphous Alloys

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Acta Metallurgica Sinica(English Letters) 2018年第3期31卷 273-280页

作者： Sang-Soo Shin Hong-kyu kim Jae-Chul Lee Ik-min Park Department of Materials Science and Engineering Pusan National University Advanced Analysis Center Korea Institute of Science and Technology Department of Materials Science and Engineering Korea University

Despite the economy of material cost and excellent toughness of Cu-based amorphous alloys,especially CusoZrso,their poor corrosion resistance to a chloride medium limits their widespread *** this study,corrosion tests were performed on the CusoZrso amorphous alloy with different degrees of short-range order,which were prepared by annealing below the glass transition temperature（Tg）.It was found that the corrosion resistance of amorphous alloys is improved to a significant level when the alloys were heated below *** studies showed that thermally activated relaxation process of created disorder,which occurs during sub-Tg annealing,is responsible for the improvement in the corrosion *** dynamics simulations performed on the Cu-Zr amorphous alloys demonstrated that the relaxation process of the alloys is associated with the formation of energetically stable icosahedra and icosahedron-like *** study highlights the effects of sub-Tg annealing on the improvement in the corrosion resistance of the amorphous alloys from the viewpoint the relaxation process of the short-range orders.

关键词： Amorphous alloys Corrosion Annealing Molecular dynamics Electrochemical performance

Enhancement of ballistic performance enabled by transformation-induced plasticity in high-strength bainitic steel

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Journal of Materials Science & Technology 2021年第25期84卷 219-229页

作者： min Cheoljo Selim kim Dong Woo Suh Hong kyu kim Yongjin kim Seok Su Sohn Sunghak Lee Center for Advanced Aerospace Materials Pohang University of Science and TechnologyPohang37673South Korea Graduate Institute of Ferrous Technology Pohang University of Science and TechnologyPohang37673South Korea Materials Directorate Agency for Defense DevelopmentDaejeon305-600South Korea Department of Materials Science and Engineering Korea UniversitySeoul02841South Korea

High-strength bainitic steels have created a lot of interest in recent times because of their excellent combination of strength,ductility,toughness,and high ballistic mass *** steels have great potential in the fabrication of steel armor *** various approaches and methods have been conducted to utilize the retained austenite(RA)in the bainitic matrix to control mechanical properties,very few attempts have been conducted to improve ballistic performance utilizing transformationinduced plasticity(TRIP)*** this study,high-strength bainitic steels were designed by controlling the time of austempering process to have various volume fractions and stability of RA while maintaining high *** dynamic compressive and ballistic impact tests were conducted,and the relation between the effects of TRIP on ballistic performance and the adiabatic shear band(ASB)formation was *** results show for the first time that an active TRIP mechanism achieved from a large quantity of metastable RA can significantly enhance the ballistic performance of high-strength bainitic steels because of the improved resistance to ASB ***,the ballistic performance can be effectively improved by a very short austempering time,which suggests that the utilization of active TRIP behavior via tuning RA acts as a primary mechanism for significantly enhancing the ballistic performance of high-strength bainitic steels.

关键词： High-strength bainitic steel Ballistic performance Split Hopkinson pressure bar(SHPB) Adiabatic shear band(ASB) Retained austenite(RA) Transformation-induced plasticity(TRIP)

Technical advances in external radiotherapy for hepatocellular carcinoma

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World Journal of Gastroenterology 2016年第32期22卷 7311-7321页

作者： Shin-Hyung Park Jae-Chul kim min kyu Kang Department of Radiation Oncology Kyungpook National University Hospital Department of Radiation Oncology Kyungpook National University School of Medicine

Radiotherapy techniques have substantially improved in the last two decades. After the introduction of 3-dimensional conformal radiotherapy, radiotherapy has been increasingly used for the treatment of hepatocellular carcinoma(HCC). Currently, more advanced techniques, including intensity-modulated radiotherapy(IMRT), stereotactic ablative body radiotherapy(SABR), and charged particle therapy, are used for the treatment of HCC. IMRT can escalate the tumor dose while sparing the normal tissue even though the tumor is large or located near critical organs. SABR can deliver a very high radiation dose to small HCCs in a few fractions, leading to high local control rates of 84%-100%. Various advanced imaging modalities are used for radiotherapy planning and delivery to improve the precision of radiotherapy. These advanced techniques enable the delivery of high dose radiotherapy for early to advanced HCCs without increasing the radiation-induced toxicities. However, as there have been no effective tools for the prediction of the response to radiotherapy or recurrences within or outside the radiation field, future studies should focus on selecting the patients who will benefit from radiotherapy.

关键词： Hepatocellular carcinoma Radiotherapy 3D-conformal Radiotherapy Intensity-modulated Radiotherapy stereotactic ablative body Radiotherapy Charged particle therapy Image-guided Radiotherapy

Sensitivity of Snowfall Characteristics to Meteorological Conditions in the Yeongdong Region of Korea

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Advances in Atmospheric Sciences 2021年第3期38卷 413-429页

作者： Yoo-Jun kim So-Ra IN Hae-min kim Jin-Hwa LEE kyu Rang kim Seungbum kim Byung-Gon kim High Impact Weather Research Department National Institute of Meteorological SciencesGangneung 25457Korea Operational Systems Development Department National Institute of Meteorological SciencesSeogwipo 63568Korea Department of Atmospheric Environmental Sciences Gangneung-Wonju National UniversityGangneung 25457Korea

This study investigates the characteristics of cold clouds and snowfall in both the Yeongdong coastal and mountainous regions under different meteorological conditions based on the integration of numerical modeling and three-hourly rawinsonde observations with snow crystal photographs for a snowfall event that occurred on 29−30 January *** found that rimed particles predominantly observed turned into dendrite particles in the latter period of the episode when the 850 hPa temperature decreased at the coastal site,whereas the snow crystal habits at the mountainous site were largely needle or rimed *** soundings showed a well-defined,two-layered cloud structure along with distinctive wind-directional shear,and an inversion in the equivalent potential temperature above the low-level cloud *** first experiment with a decrease in lower-layer temperature showed that the low-level cloud thickness was reduced to less than 1.5 km,and the accumulated precipitation was decreased by 87%compared with the control *** difference in precipitation amount between the single-layered experiment and control experiment(two-layered)was not so significant to attribute it to the effect of the seeder−feeder *** precipitation in the last experiment by weakening winddirectional shear was increased by 1.4 times greater than the control experiment specifically at the coastal site,with graupel particles accounting for the highest proportion(~62%).The current results would improve snowfall forecasts in complicated geographical environments such as Yeongdong in terms of snow crystal habit as well as snowfall amount in both time and space domains.

关键词： Yeongdong snow crystal rawinsonde cloud-resolving model