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Porosity on External Surface of H-Clinoptilolite Sorption of CCI4 and n-C6H14

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Journal of Chemistry and Chemical Engineering 2013年第10期7卷 901-909页

作者： miguel Angel Hernandez Fernando Rojas Roberto portillo Martha Alicia Salgado Gabriela Perez Zeolites Research Department and Postgrade of Agroecology Sciences Institute Puebla 72570 Mexico Chemistry Departament Metropolitan Autonomous University-lztapalapa Mexico 09340 Mexico Faculty of Chemistry Department of Physical Chemistry Autonomous University of Puebla Puebla 72570 Mexico Faculty of Chemical Engineering Autonomous University of Puebla Puebla 72570 Mexico

CCl4 （carbon tetrachloride） and n-C6H14 （n-hexane） sorption studies have been carried out on natural and dealuminated clinoptilolite-type zeolites. External surface area of the materials has been assessed using the αs-plots method. The high resolution αs-plots show that the isotherms are divided into four parts corresponding to adsorption in ultramicropores, intersections, supermicropores and external surface area, respectively. The mineralogies of natural zeolites are determined by X-ray analysis. N： low-pressure hysteresis loops, displayed by some substrata, are related to the micropore structure and to the ion-exchange treatment at which the natural precursors were subjected. The adsorption behavior of these substrata was examined in the range of relative pressures between 10^-5-1. Natural samples were used as reference materials to carry out the sorption analyses of the dealuminated samples. The effect of narrow micropore constrictions on the adsorption behavior of clinoptilolites was explored. The occurrence of a low-pressure hysteresis loop on the sorption isotherm of a modified sample is associated to the strong adsorption of the adsorbate molecules at the entrance of the necked-shape micropores, which interfere with the diffusion of the adsorbate molecules inside the porous structure.

关键词： Porosity zeolite clinoptilolite adsorption dealuminated

Investigation of Chemical Bath Deposition of ZnO Nanocrystals Thin Films Using Different ZnNO3 Concentration

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材料科学与工程（中英文A版） 2012年第5期2卷 442-453页

作者： miguel Hemandez Hernandez Martin Lazcano Hernendez Juan Hernandez Tecorralcol Gabriel Juarez Diaz Melissa Chavez portillo Salvador Rosas Castilla L. Chaltel Lima Oscar portillo Moreno Facultad de Ciencias Quimicas Benemerita Universidad Autonoma de Puebla Moxico Puebla Mexico CIDS-ICUAP Benemerita Universidad A utonoma de Puebla Moxico

Experiment and Modeling of Low Coverage Uptake of N2 and 02 on H-Clinoptilolite Zeolite from Tehuacan, Puebla, Mexico

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Journal of Chemistry and Chemical Engineering 2014年第1期8卷 1-10页

作者： miguel Angel Hemández Karla Quiroz Fernando Rojas: Roberto portillo Martha Alicia Salgado Fernando Hernándezl Antonio Rivera Chemistry Departament Metropolitan Autonomous University-Iztapalapa Mdxico 09340 México Faculty of Chemistry Autonomous University of Puebla Puebla 72570 México Chemistry Center Autonomous University of Puebla Puebla 72570 México Microbiology Center Autonomous University of Puebla Puebla 72570 México Zeolites Research Department and Postgrade of Agroecology Autonomous University of Puebla Puebla 725 70 México

Adsorption isotherms of N2 and 02 on dealuminated clinoptilolite zeolites were measured by the inverse gas chromatography method at zero-coverage. This type of microporous solids such as natural （CLINA） and dealuminated clinoptilolite zeolites （CLIDA1-CLIDA5） were conditioned by means of acid treatment of the natural zeolitic precursor （CLINA） with HCI at different concentration. Adsorption of selected gases （N2 and 02） on clinoptilolite zeolites were studied in the temperature range from 398 K to 498 K. The Langmuir adsorption model was found to approximately fit the gases adsorption data, within the selected temperature range. The uptake amount of these gases by the diverse adsorbents was temperature dependent. Additionally, the energies of interaction between of these gases with clinoptilolite microporous walls were realized from the evaluation of the isosteric heats of adsorption （qst）. These isosteric heats were found to obey in the following decreasing order： qst （N2）： CLIDA1 〉 CLIDA3 〉 CLIDA2 〉 CLIDA4 〉 CLIDA5 〉 CLINA; while qst （02）： CLIDA3 〉 CLIDA2 〉 CL1DA1 〉 CLIDA5 〉 CLIDA4 〉 CLINA.

关键词： Zeolite clinoptilolite sorption Langmuir isosteric heats.

Optical and Structural Properties CdSe： Ni^2＋ Nanocrystals

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材料科学与工程（中英文A版） 2014年第9期4卷 309-314页

作者： Marcial Zamora Tototzintle Martin Lazcano Hemandez Arturo Sosa Sanchez Leslie Chaltel Lima Estephani Balderrabano Perdomo MoisesAraiza Garcia miguel Hernadez Hemandez Rey Baltazar Lopez Oscar portillo Moreno Laboratory Materials Science Faculty of Chemical Sciences Autonomous University of Puebla Puebla 72001 Pue Mexico CIDS-ICUAP C. U Puebla M~xico.AutonomousUniversity of Puebla Puebla 72001 Pue Mexico ITSM Campus Puebla Via Atlixcayolt 2301 Col. Reserva Territorial. Atlixcayolt Puebla 72001 Pue Mexico Faculty of Electronic Sciences Autonomous University of Puebla Puebla 72001 Pue Mexico