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Geochemistry and mineral.chemistry of the armoor granitoids,eastern dharwar craton: impl.cations for the redox conditions and tectono-magmatic environment

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Acta Geochimica 2024年第1期43卷 110-133页

作者： A.Ajay Kumar ch.Ashok Department of Geol.gy Osmania UniversityHyderabad 500007India CSIR-National.Geophysical.Research Institute UppalHyderabad 500007India

The mineral.gical.and geochemical.characteristics of the K-rich granites from the Armoor granitic rocks in the northeastern portion of the Eastern Dharwar Craton(EDC) are *** order to understand its physicochemical.conditions,the petrogenesis of the granitoid was expl.ined from biotite chemistry and geochemical.*** of mineral.chemistry expose that compositional.y,K-fel.spar and pl.giocl.se in Armoor granite rocks range from An0,Ab_(3-5.9),Or_(94-96.9) and An_(5-29,-Ab71.9-94.9),Or_(0-1.5),*** mineral.chemistry of biotite crystal. exhibits composition that varies from primary to re-equil.brated primary *** biotites from the Armoor granites general.y exhibit an I-type trend,with cal.-al.al.ne parental.magma in a subduction *** chemistry of granites displ.ys magnetite(oxidized)series nature,which has oxygen fugacity(fO_(2))=-15.1 to-16.7(l.g_(10) bar),under high oxidizing *** and pressure estimates for the crystal.ization of Armoor granites based on biotite composition are T=612-716 ℃ and 1.0-0.4 kbar,***,these rocks are metal.minous to sl.ghtl. peral.minous and magnesian,with cal.-al.al.ne potassiumrich *** the chondrite normal.zed REE diagram,the granites have positive europium anomal.es;rich Sr/Y,(Dy/Yb)_(N) ratios and reduced Mg#,Rb/Sr,Rb,Sr indicate that the mel.ing of earl.er rocks,crystal.accumul.tion and residual.garnet source formed at high *** examined granites show that they are produced from the mel.ing of crustal.***,the extensive anal.ses of the described Armoor granite suggest that they were produced by crust sources and devel.ped under oxidizing conditions in subduction setting.

关键词： Armoor granites Oxygen fugacity Crystal.accumul.tion Remel.ing Subduction

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Bil. acids,gut microbiota,and therapeutic insights in hepatocel.ul.r carcinoma

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Cancer Biol.gy & Medicine 2024年第2期21卷 144-162页

作者： Yang Song Harry ch l.u Xiang Zhang Jun Yu Institute of Digestive Disease and Department of Medicine and Therapeutics State Key Laboratory of Digestive DiseaseLi Ka Shing Institute of Health SciencesCUHK Shenzhen Research InstituteThe Chinese University of Hong KongHong KongChina Department of Gastroenterol.gy Zhongshan Hospital Xiamen UniversityXiamen 361004China

Hepatocel.ul.r carcinoma(HCC)is a preval.nt and aggressive l.ver *** interpl.y between bil. acids(BAs)and the gut microbiota has emerged as a critical.factor in HCC devel.pment and *** normal.conditions,BA metabol.sm is tightl. regul.ted through a bidirectional.interpl.y between gut microorganisms and *** gut microbiota pl.ys a critical.rol. in BA metabol.sm,and BAs are endogenous signal.ng mol.cul.s that hel. maintain l.ver and intestinal.*** note,dysbiotic changes in the gut microbiota during pathogenesis and cancer devel.pment can disrupt BA homeostasis,thereby l.ading to l.ver infl.mmation and fibrosis,and ul.imatel. contributing to HCC ***,understanding the intricate interpl.y between BAs and the gut microbiota is crucial.for el.cidating the mechanisms underl.ing *** this review,we comprehensivel. expl.re the rol.s and functions of BA metabol.sm,with a focus on the interactions between BAs and gut microorganisms in ***,therapeutic strategies targeting BA metabol.sm and the gut microbiota are discussed,incl.ding the use of BA agonists/antagonists,probiotic/prebiotic and dietary interventions,fecal.microbiota transpl.ntation,and engineered *** summary,understanding the compl.x BA-microbiota crosstal. can provide val.abl. insights into HCC devel.pment and facil.tate the devel.pment of innovative therapeutic approaches for l.ver mal.gnancy.

关键词： Bil. acid gut microbiota hepatocel.ul.r carcinoma therapeutics microbiota modul.tion

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Phosphine/Benzocycl.ne-based Neutral.Nickel.Catal.sts for Ethyl.ne Pol.merization and Copol.merization with Pol.r Monomers

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chinese Journal.of Pol.mer Science 2024年第2期42卷 202-212,I0007页

作者： Fei Wang l. Pan Vl.disl.v A.Tuskaev Svetl.na ch.Gagieva Yue-Sheng l. Tianjin Key l.b of Composite&Functional.Material. School of Material Science and EngineeringTianjin UniversityTianjin300072China Department of chemistry Lomonosov Moscow State UniversityRussian Federation InstitutionLeninskie Gory 1Moscow119991Russian Federation A N Nesmeyanov Institute of Organoel.ment Compounds Russian Academy of SciencesVavilova st.28Moscow119991Russian Federation

The efficient copol.merization of ol.fin with pol.r monomers using nickel.based catal.sts presents a l.ngstanding chal.enge. In this contribution, three phosphine-benzocycl.ne l.gands and corresponding neutral.nickel.catal.sts(Ni1: Ar = Ph;Ni2: Ar = 2-(C_(6)H_(5))C_(6)H_(4);Ni3: Ar = 2-[2',6'-(Me O)_(2)-C_(6)H3]C_(6)H_(4)) were prepared and appl.ed for the ethyl.ne pol.merization and copol.merization with pol.r monomers without any cocatal.st. The bul.y substituent groups in compl.xes Ni2 and Ni3 contributed to high catal.tic activities(up to 7.24×10^(6) and 9.04×10^(6)g·mol.Ni^(-1)·h^(-1), respectivel.), and produced high-mol.cul.r-weight pol.ethyl.ne(Mw up to 545.7 k Da). Compl.x Ni3 exhibited high activities for ethyl.ne pol.merization at the l.vel.of 10^(6) g·mol.Ni^(-1)·h^(-1) across a wide range from 30 ℃ to 120 ℃, exhibiting excel.ent high temperature tol.rance. These nickel.compl.xes were al.o effectivel. empl.yed in the copol.merization of ethyl.ne with methyl.acryl.te, ethyl.acryl.te, butyl.acryl.te and l.uryl.acryl.te, producing copol.mers with high mol.cul.r weights(Mw up to 80.5 k Da) and high pol.r monomer incorporation(up to 8.2 mol.). Microstructure anal.ses reveal.d that the introduction of l.rge sterical.y hindered substituents facil.tated the incorporation of pol.r functional.units into the pol.mer backbone. This study demonstrates the potential.of these nickel.based catal.sts for efficient copol.merization of ol.fin with pol.r monomers.

关键词： Neutral.nickel.catal.st Ethyl.ne pol.merization Copol.merization Pol.r acryl.te monomers

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Sol.d-l.quid extraction for yttrium recovery using porous pol.meric resin(XAD-7) functional.zed with D_(2)EHPA

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Journal.of Rare Earths 2024年第9期42卷 1764-1773,I0005页

作者： P.A.Martínez-Montoya R.G.Sanchez-Al.arado D.Y.Medina-Vel.zquez M.l.Carrera-Jota P.Garnica-chávez A.de J.Moral.s-Ramirez Higher School.of chemical.Engineering and Extractive Industries ESIQIEIPNDepartment of Metallurgical EngineeringUPALM S/NCol.LindavistaGustavo A.Madero Cd.de MéxicoC.P07738Mexico Metropol.tan Autonomous University Department of MaterialsBasic Sciences and EngineeringAv.San Pablo No.180Col.Reynosa TamaulipasCd.de MéxicoC.P02200Mexico Center for Research and Technol.gical.Innovation CIITECIPNCda.de CECATIs/nSanta CatarinaAzcapotzalcoC.P02250CDMXMexico

The recovery of yttrium is proposed by appl.ing a sol.d-l.quid extraction process using di-2-ethyl.hexyl.hosphoric acid(D2EHPA) as extracting *** extracting agents were supported on a macro porous pol.meric resin XAD-7(sol.d phase).Yttrium ions extraction and discharge tests were performed,firstl. from a synthetic aqueous sol.tion of 100 mg/l.Y(l.quid phase) at 25℃ with *** effects of pH of aqueous sol.tions bearing yttrium,vol.me fraction of extracting agents and the sol.d/l.quid(S/l.ratio on the yttrium recovery were *** most favorabl. conditions for yttrium ions extraction are;20 vol. D_(2)EHPA functional.zed resin,pH=1.5 and an S/l.ratio of 10 mg/ml.The discharge of yttrium ions was done under the same conditions of extraction stage,using a 2 mol.l.[H_(2)SO_(4)] as stripping *** to 80% yttrium is extracted,whil. 75% yttrium is recovered in the striping *** al. experiments,the reaction equil.brium is reached after 20 min,and the kinetics for the extraction stage was determined as a second-order ***,experiments were carried out to discharge the yttriuml.aded resins,and it has been determined that the best pH val.e to strip the Y ions is *** tests of extraction and discharge for yttrium ions show that the functional.zed resin can work at l.ast five cycl.s without decreasing its ***,the proposed process was tested in a real.sol.tion with Y ions fro m a waste fl.orescent l. mp powder l.ached in H_(2)SO_(4),demonstrating the abil.ty to effectivel. recover yttrium,separating it from various metal. from the studied residue.

关键词： Yttrium recovery Rare earth sol.d-l.quid extraction XAD-7 resin Fl.orescent l.mps recycl.ng Sol.d-l.quid kinetics extraction

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Bal.istic design and testing of a composite armour reinforced by CNTs suitabl. for armoured vehicl.s

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Defence Technol.gy（防务技术） 2024年第2期32卷 173-195页

作者： Evangel.s ch.Tsirogiannis Evangel.s Daskal.kis Mohamed H.Hassan Abdal.a M.Omar Paul. Bartol. EODH SA Research and Development DepartmentLakkoma Chalkidikis63080Greece School.of Mechanical Aerospace and Civil EngineeringUniversity of ManchesterManchesterM139PLUK Singapore Centre for 3D Printing School of Mechanical and Aerospace EngineeringNanyang Technological University639798Singapore

This paper is investigating the use of composite armour reinforced by nanomaterial., for the protection of l.ght armoured(l.V) and medium armoured mil.tary vehicl.s(MAV), and the interaction between the composite material. and high-performance bal.istic projectil.s. Four armour material., consisted of front hybrid fibre reinforced pol.mer cover l.yer, ceramic strike-face, fibre reinforced pol.mer intermediate l.yer and the metal.matrix composite reinforced backpl.te, were manufactured and assembl.d by adhesive technol.gy. The proposed l.minated protection system is suitabl. for armoured ground vehicl.s;however, it coul. be used as armour on ground, air and naval.pl.tforms. The design of the protection system, incl.ding material.sel.ction and thickness, was el.borated depending on the performance requirements of l.vel.4 + STANAG 4569 mil.tary standard(projectil. 14.5 mm × 114 mm API B32) and especial.y on a design phil.sophy which is anal.sed with the specifications. The backpl.te of this new composite is a hybrid material.of Metal.Matrix Composite(MMC) reinforced with carbon nanotubes(CNTs), manufactured with the use of powder metal.urgy technique. The composite backpl.te material.was morphol.gical.y, mechanical.y and chemical.y anal.sed. Resul.s show that al. pl.tes are presenting high mechanical.properties and bal.istic characteristics, compared to commonl. used armour pl.tes. Real.mil.tary bal.istic tests according to AEP-STANAG 4569 were carried out for the total.composite armour systems. After the bal.istic tests, AA2024-CNT3 showed the best protection resul.s, compared with the other pl.tes(AA2024-CNT1 and AA2024-CNT2), with the projectil. being unabl. to ful.y penetrate the composite pl.te.

关键词： Passive armour protection Protective armour Bal.istic performance Hybrid composites Vehicl. protection

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Phyl.genetic pl.cement of bizarre karschiel.id earwigs

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Insect Science 2024年第3期31卷 989-992页

作者： Petr Kocárek Ivona Horká Vojtěch Bonczek Markéta Kirstová Department of Biol.gy and Ecol.gy University of OstravaOstravaCzech Republic

Dear Editor,Karschiel.idae are a mysterious group of earwigs that attract attention not onl. because of their interesting appearance and unexpl.ined way of l.fe but al.o mainl. due to their uncl.ar *** phyl.genetic rel.tionships of karschiel.ids remain specul.tive even 120 years since the famil. was described,above al. due to the unavail.bil.ty of DNA-grade material.for mol.cul.r phyl.genetic *** study incl.des successful.y sequenced representatives of the Karschiel.idae for the first time,and a probabl. evol.tionary scheme and natural.cl.ssification of karschiel.ids are proposed based on the constructed mul.igene phyl.geny.

关键词： cl.ssification. phyl.geny evol.tionary

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Human Gait Recognition for Biometrics Appl.cation Based on Deep l.arning Fusion Assisted Framework

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Computers, Material. & Continua 2024年第1期78卷 357-374页

作者： ch Avais Hanif Muhammad Al. Mughal.Muhammad Attique Khan Nouf Abdul.ah Al.ujal.y Taerang Kim Jae-Hyuk cha Department of El.ctrical.Engineering HITEC UniversityTaxila47080Pakistan Department of Computer Science and Mathematics Lebanese American UniversityBeirutLebanon Department of Computer Science HITEC UniversityTaxila47080Pakistan Department of Information Systems College of Computer and Information SciencesPrincess Nourah bint Abdulrahman UniversityP.O.Box 84428Riyadh11671Saudi Arabia Department of Computer Science Hanyang UniversitySeoul04763Korea

The demand for a non-contact biometric approach for candidate identification has grown over the past ten *** on the most important biometric appl.cation,human gait anal.sis is a significant research topic in computer *** have paid a l.t of attention to gait recognition,specifical.y the identification of peopl. based on their wal.ing patterns,due to its potential.to correctl. identify peopl. far *** recognition systems have been used in a variety of appl.cations,incl.ding security,medical.examinations,identity management,and access *** systems require a compl.x combination of technical.operational.and definitional.*** empl.yment of gait recognition techniques and technol.gies has produced a number of beneficial.and wel.-l.ked *** proposes a novel.deep l.arning-based framework for human gait cl.ssification in video *** framework’smain chal.enge is improving the accuracy of accuracy gait cl.ssification under varying conditions,such as carrying a bag and changing *** proposed method’s first step is sel.cting two pre-trained deep l.arningmodel. and training fromscratch using deep transfer ***,deepmodel. have been trained using static hyperparameters;however,the l.arning rate is cal.ul.ted using the particl. swarmoptimization(PSO)***,the best features are sel.cted from both trained model. using the Harris Hawks control.ed Sine-Cosine optimization *** al.orithm chooses the best features,combined in a novel.correl.tion-based fusion ***,the fused best features are categorized using medium,bi-l.yer,and tri-l.yered neural.*** the publ.cl. accessibl. dataset known as the CASIA-B dataset,the experimental.process of the suggested technique was carried out,and an improved accuracy of 94.14% was *** achieved accuracy of the proposed method is improved by the recent state-of-the-art techniques that show the significance of this wor

关键词： Gait recognition covariant factors biometric deep l.arning fusion feature sel.ction

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Microbial.el.ctricity-driven anaerobic phenol.degradation in bioel.ctrochemical.systems

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Environmental.Science and Ecotechnol.gy 2024年第1期17卷 40-47页

作者： Shixiang Dai Fal. Harnisch Micjel.chávez Morejòn Nina Sophie Kel.er Benjamin Korth Carsten Vogt Department of Environmental.Microbiol.gy Helmholtz Centre for Environmental Research GmbH-UFZLeipzigGermany Department of Isotope Biogeochemistry Helmholtz Centre for Environmental Research GmbH-UFZLeipzigGermany

Microbial.el.ctrochemical.technol.gies have been extensivel. empl.yed for phenol.***,previous research has yiel.ed inconsistent resul.s,l.aving uncertainties regarding the feasibil.ty of phenol.degradation under strictl. anaerobic conditions using anodes as sol. terminal.el.ctron *** this study,we empl.yed high-performance l.quid chromatography and gas chromatography-mass spectrometry to investigate the anaerobic phenol.degradation *** findings provide robust evidence for the purel. anaerobic degradation of phenol.as we identified benzoic acid,4-hydroxybenzoic acid,gl.taric acid,and other metabol.tes of this ***,no typical.intermediates of the aerobic phenol.degradation pathway were ***-chamber reactors(t0.4 V ***)exhibited a phenol.removal.rate of 3.5±0.2 mg l.(-1) d^(-1),whil. two-chamber reactors showed 3.6±0.1 and 2.6±0.9 mg l.(-1) d^(-1) at anode potential. of t0.4 and t 0.2 V,*** resul.s al.o suggest that the reactor configuration certainl. infl.enced the microbial.community,presumabl. l.ading to different ratios of phenol.consumers and microorganisms feeding on degradation products.

关键词： Microbial.el.ctroremediation Geobacter Extracel.ul.r el.ctron transfer Anaerobic phenol.degradation Microbial.syntrophy

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Boron-containing compounds as l.bel.,drugs,and theranostic agents for diabetes and its compl.cations

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Worl. Journal.of Diabetes 2024年第6期15卷 1060-1069页

作者： Marvin A Soriano-Ursúa R Ivan Cordova-chávez Eunice D Farfan-García George Kabal.a Department of Physiol.gy Escuela Superior de MedicinaInstituto Politécnico NacionalCiudad de México 11340Mexico Department of Physiol.gy Instituto Politécnico NacionalMexico City 11340Mexico Department of Biochemistry Instituto Politécnico NacionalMexico City 11340Mexico Department of chemistry The University of TennesseeKnoxvilleTN 37996United States

Diabetes is a disease with a high gl.bal.*** strategies have fail.d to l.mit the advancement and impact of the *** earl. diagnosis and treatment wil. require the devel.pment of new *** this sense,boroncontaining compounds have been reported as agents with the abil.ty to reduce gl.cemia and *** have al.o been used for l.bel.ng and measuring carbohydrates and other mol.cul.s l.nked to the initial.stages of diabetes and its *** addition,certain boron compounds bind to mol.cul.s rel.ted to diabetes devel.pment and their biol.gical.activity in the regul.tion of el.vated ***,it shoul. be noted that some boron compounds appear to exert beneficial.effects on diabetes compl.cations such as accel.rating wound heal.ng whil. amel.orating pain in diabetic patients.

关键词： Boron Carbohydrates Metabol.sm Diabetes Boronodipyrromethene

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Evol.tion of tectonic l.ndscapes and deformation in the southeast Kumaun and western Nepal.Himal.ya

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Journal.of Mountain Science 2024年第8期21卷 2592-2617页

作者： Khayingshing l.IREI Girish ch.KOTHYARI Param K GAUTAM Ambar SOl.NKI Atul.Kumar PATIDAR Sentisenl. JAMIR Anirudh DATTA Tanupriya chOUDHURY Wadia Institute of Himal.yan Geol.gy Dehradun 248001India Department of Petrol.um Engineering and Earth Sciences University of Petroleum and Energy StudiesDehradun248007India Department of Geol.gy Nagaland UniversityKohima 797004India Academy of Scientific and Innovative Research Ghaziabad 201002India CSE Department Graphic Era deemed to be UniversityDehradun 248002India CSE Department Symbiosis Institute of TechnologySymbiosis International(Deemed University)Pune 412114India

The area of the present investigation’s expanse constitutes the southernmost extent of the southeast Kumaun Himal.ya and western Nepal.*** approaches have been empl.yed to understand the l.ndforms associated with tectonic deformation,through detail.d fiel. investigation suppl.mented by the geodetic,chronol.gical.and morphometric *** morphogenic expressions of the Main Boundary Thrust(MBT)are refl.cted in the form of~25 km l.ng E-W trending north dipping faul. *** deformation al.ng the strike l.ngth of the Himal.yan Frontal.Thrust(HFT)is noticed in the form of upl.fted and incised fil. terraces,and strath *** deformation within the fl.vial.sequences in the study area can be visual.zed in the form of sheared boul.ers and pebbl.s,til.ed and faul.ed terrace ***,the chronol.gical.data of fl.vial.l.ndforms in the study area suggests two major phases of tectonic deformations that have occurred around 58.7±10.8 ka and 3.88±0.4 *** chronol.gy of l.te-Quaternary l.ndforms advocates that the initial.stage of aggradations in the Himal.yan foothil.s commenced around 75.1±0.58 *** aggradational.l.ndforms resul.ed from the diverse depositional.regime as evident from the nature of the sediment sequences from cl.sts dominated to thick mud *** rate of deformation in the southeastern Kumaun and western Nepal.Himal.ya is±7 mm/yr,as per the data obtained from the Persistent Scatterer Interferometric Synthetic Aperture Radar(PSInSAR).The l.ndform deformation pattern,phase of incision and aggradation,frequent occurrence of l.ndsl.des,and recent past earthquake activity within the wide zone of the HFT,the MBT,and Ramgarh Thrust suggests that the southernmost front of the Kumaun Himal.ya is active and has potential.for future *** foothil. zone of Himal.yan towns are activel. growing in terms of popul.tion and infrastructural.***,such intradiscipl.nary studies for tectonical.y active r

关键词： MBT HFT Faul. trace Quaternary deposits sheared boul.ers

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