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The flame retardancy of alginate/flame retardant viscose fibers investigated by vertical burning test and cone calorimeter

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Chinese Chemical Letters 2018年第3期29卷 489-492页

作者： Xian-Sheng Zhang Yan-Zhi Xia mei-wu shi Xiong Yan Key Laboratory of Textile Science & Technology Ministry of Education College of Textiles Donghua University Shanghai 201620 China Laboratory of Fiber Materials and Modern Textile The Growing Base for State Key Laboratory Qingdao University Qingdao 266071 China The Quartermaster Equipment Research Institute of Logistical Support Department Beijing 100082 China

In this research, the flame retardancy of neat alginate fiber, flame retardant viscose fiber （FRV） and alginate/FRV （50/50） blending fibers were investigated by vertical burning and cone calorimeter tests. The vertical burning test showed that the afterflame time of alginate fiber was 0 s, but alginate presented serious smoldering behavior with the afterglow time of 605 s and damaged length of 85 mm, while the afterglow time of FRV was 0 s. When the FRV was incorporated into alginate with the weight ratio of 50/ 50, the afterglow time and damaged length were significantly reduced to 85 s and 35 mm, indicating the smoldering of alginate can be effectively decreased. The morphology and chemical structure of the alginate residual demonstrated that it was seriously destroyed during smoldering process, which was ascribed to its relative low initial thermal degradation temperature. Based on the thermal properties analysis, alginate and FRV fibers shared the concurrence of rapid degradation in the same temperature region of 250-300 ℃, through which, the compact and stable char formed by FRV can prevent the heat transmission and suppress the smoldering of alginate. Further, the cone calorimeter results demonstrated that the time to ignition （TTI） significantly increased and peak heat release rate （PHRR） decreased for alginate/FRV （50/50） compared with FRV. With this research, a new method to overcome the smoldering of alginate was proposed by blending with FRV

关键词： Alginate fibers Flame retardant viscose fibers Blending Flame retardancy Vertical burning test Cone calorimeter

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The Research on CAD/CAPP Integrated System for Welding Boxlike Parts Made of Plate

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厦门大学学报（自然科学版） 2002年第S1期41卷 131-132页

作者： wu Xiao-guang, ZHANG Guo-zhen, mei Shun-qi, wu shi-lin (wuhan Institute of Science and Technology, wuhan 430073, China)

By adopting the parameterized designing method of f ea ture assembled and feature unit, for the feature of non-conventional type parts , such as welding box and bearer, by use of Visual C++ and AutoCAD a s soft tools, the system can successfully carry out the basic function of featur e assembled, the processing of two-dimensional figure, the building of three-d imensional feature, the automatic producing of technical papers, and so on. The thoughts and design methods of this system can be served as the preference to CA D/CAPP integrated for othernon-conventional type parts. For non-conventional parts, its feature is too much, so the parameter is much. By adopting interactive entry for graphic parameter, under the control of main c ontrol module, through inputting the feature parameter and calling the feature g raphic unit, the function for modeling is completed. To reduce input of feature parameter, the description of position feature is adopted in the feature descrip tion of non-conventional parts, that is, fix position is constraint through str ucture and dimension of non-conventional parts. In such a manner, the assembled process has been transformed the coordinate conversion process, and this is ver y important in the production of three-dimensional graphics. In the one hand, b y calling the feature of parts in the library of feature-graphic unit, the two -dimensional DXF file and three-dimensional SCR file are automatically produce d in AutoCAD. On the other hand, by calling the rules and standard operational s equences in the technologic knowledge base, through inferring of inference engin e, the assembled sequence of non-conventional parts and welding sequences are a utomatically produced. The two aspects constitute overall design philosophy for system. So the CAD/CAPP integration of feature-assembled for non-conventio nal parts are completed. The principle of dividing feature is based on the thought of group technology, t hat is, according to the function fe

关键词： non-conventional type parts feature-assembled parameterized designing CAD/CAPP

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可控变色织物制备及颜色控制研究

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高分子学报 2012年第7期22卷 735-742页

作者：肖红代国亮王昊施楣梧徐坚总后军需装备研究所北京100082 中国科学院化学研究所北京100190

基于聚苯胺电致变色高聚物、采用反射型电致变色器件结构模型,以柔性导电织物作为电极,构建了可控变色织物,可在-1.0～+1.0 V低电压范围内实现颜色变化显著的黄色和绿色的可逆响应.系统研究了变色织物在不同电压、不同弛豫时间及不同颜... 详细信息

基于聚苯胺电致变色高聚物、采用反射型电致变色器件结构模型,以柔性导电织物作为电极,构建了可控变色织物,可在-1.0～+1.0 V低电压范围内实现颜色变化显著的黄色和绿色的可逆响应.系统研究了变色织物在不同电压、不同弛豫时间及不同颜色工作电极下的L*a*b*,ΔE*值及反射率曲线,且讨论了透射型电致变色器件和电致变色织物的区别.随着正电压的增加,变色织物对应的a*b*依次减小,蓝绿色加深;随着负电压的增加,变色织物对应的a*b*依次增加,变色织物黄色加深.撤去电压后变色织物发生放电弛豫,慢慢回复到未加电压时的本征态.工作电极底色对电致变色织物也有显著的影响.变色织物的断电放电弛豫时间低于透射型电致变色器件.

关键词：变色织物聚苯胺电致变色织物电极

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汽油中元素硫的GC-SCD分析方法

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石油学报（石油加工） 2017年第2期33卷 320-325页

作者：吴梅史军歌田松柏中国石化石油化工科学研究院北京100083

采用硫化学发光检测器气相色谱法(GC-SCD)建立了测定汽油中元素硫的气相色谱分析方法。考察了色谱拄温度、样品基质等因素对汽油中元素硫分析的影响,并对元素硫在高温状态下的形态进行了定性分析。结果表明,在高温环境下,元素硫存在S_2... 详细信息

采用硫化学发光检测器气相色谱法(GC-SCD)建立了测定汽油中元素硫的气相色谱分析方法。考察了色谱拄温度、样品基质等因素对汽油中元素硫分析的影响,并对元素硫在高温状态下的形态进行了定性分析。结果表明,在高温环境下,元素硫存在S_2、S_4、S_6,S_7、S_8多种形态,且温度越高,元素硫越容易形成小分子硫同素异形体。采用该方法测定质量浓度在2~70mg/L范围的元素硫时,色谱峰面积与质量浓度呈较好的线性关系,定量标准曲线的线性相关系数R2为0.9992,最低检测限为1.0mg/L,元素硫的加标回收率为93%~105%,同时具有较好的重复性,符合色谱分析的一般要求。

关键词：色谱硫化学发光检测器元素硫汽油同素异形体

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中国沙冬青属植物的地理分布及生境特征

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干旱区地理 2017年第2期40卷 380-387页

作者：刘美吴世新潘伯荣王丹中国科学院新疆生态与地理研究所新疆乌鲁木齐830011 中国科学院大学北京100049

沙冬青是我国珍稀濒危物种,掌握其地理分布范围及生境特征,有助于分析其所处境况以及展开相应的研究与保护工作。通过搜集历史文献资料与野外实地调查相结合的方法,对我国沙冬青属植物的地理分布范围、时空动态以及生境特征进行了研究,... 详细信息

沙冬青是我国珍稀濒危物种,掌握其地理分布范围及生境特征,有助于分析其所处境况以及展开相应的研究与保护工作。通过搜集历史文献资料与野外实地调查相结合的方法,对我国沙冬青属植物的地理分布范围、时空动态以及生境特征进行了研究,并从地形、气候、土壤三个方面探讨了限制沙冬青属植物生长分布的主要因子。结果表明:(1)新疆沙冬青分布范围为38°55′~40°09′N,74°42′~76°43′E;蒙古沙冬青分布范围为36°27′~42°01′N,102°36′~108°49′E,两种沙冬青在地理分布上不连续,以条带或块状方式呈现小聚集分布状态。(2)两种沙冬青的生境特征存在显著差异,其中限制新疆沙冬青分布的生态因子主要包括气候指标中的热量因子以及土壤指标中的p H、盐分和全磷,限制蒙古沙冬青分布的生态因子主要包括气候指标中的水分因子和土壤指标中的有机质、全氮。

关键词：新疆沙冬青(A.nanus) 蒙古沙冬青(A.mongolicus) 地理分布生境特征

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Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption

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Nano-Micro Letters 2025年第1期17卷 507-527页

作者： Zhiqiang Guo Di Lan Zirui Jia Zhenguo Gao Xuetao shi Mukun He Hua Guo Guanglei wu Pengfei Yin College of Science Sichuan Agricultural UniversityYa’an 625014People’s Republic of China School of Materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002People’s Republic of China Institute of Materials for Energy and Environment State Key Laboratory of Bio‑Fibers and Eco‑TextilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071People’s Republic of China Shaanxi Key Laboratory of Macromolecular Science and Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’anShaanxi 710072People’s Republic of China

Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly ***-component interface engineering is considered an effective means to achieve high-efficiency EMW ***,interface modulation engineering has not been fully discussed and has great potential in the field of EMW *** this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal *** utilizing the different properties of different substances,rich heterogeneous interfaces are *** effectively promotes charge transfer and enhances interfacial polarization and conduction *** prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy *** minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 ***,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel ***,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.

关键词： Electrostatic spinning Component regulation Heterogeneous interfaces Electromagnetic wave absorption Corrosion protection

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Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang Zhang Danyang wu Linke Cai Youluan Lu Fanpeng Cheng Lijuan shi Qun Yi Yao Liu Yi Huang Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering & Pharmacy Wuhan Institute of Technology Key Laboratory of Pesticide & Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of Education College of Chemistry Central China Normal University College of Materials Science and Engineering Fuzhou University

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction（OER）. Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER process. However, most of them undergo incomplete reconstruction with limited thickness of reconstruction layer, leading to low component utilization and arduous exploration of real catalytic mechanism. Herein, we identify the dynamic behaviors in complete reconstruction of Co-based complexes during OER. The hollow phytic acid（PA） cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability, in favor of the fast and complete reconstruction. A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co（Fe）(OH)xand subsequent potential-driven oxidation to Co（Fe）OOH. The obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm-2and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER activity. The work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Oxygen evolution reaction

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Tailor-made high elasticity and low-hysteresis hydrogels based on asymmetric H-bonding crosslinking for wearable applications

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Science China Chemistry 2025年

作者： Xiaofang shi Nan shi Miaomiao Dang Chengyu Ji Yingjie Li Peiyi wu Zhiguo Hu Collaborative Innovation Centre of Henan Province for Green Manufacturing of Fine Chemicals Henan Engineering Laboratory of Chemical Pharmaceutical and Biomedical Materials School of Chemistry and Chemical Engineering Henan Normal University State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry Chemical Engineering and Biotechnology & Center for Advanced Low-dimension Materials Donghua University

The conventional method of fabricating hydrogels constantly confronts the conflict between elasticity and toughness, limiting their repetitive application. Achieving the desired elasticity through a simple and low-cost approach is a significant challenge for hydrogels, particularly through rational molecular design. Here, low-hysteresis and high-toughness hydrogels are developed from the design of a new feature monomer, N-acryloylethylsemicarbazide (NACE). Based on a concept of “asymmetric Hbonding design”, the unique double and triple H-bonding of NACE can result in a novel asymmetric crosslinking polymer with alternating strong and weak H-bonding regions. The NACE is copolymerized with acrylamide (AM) to regulate the mechanical properties of hydrogel via H-bonding density. The P(NACE-AM) ionic hydrogels are obtained simply and rapidly via one-step photopolymerization without a chemical cross-linking agent. The P(NACE-AM) hydrogels combine superb mechanical elasticity and toughness, and excellent ionic conductivity, showing great potential as durable ionic conductive devices for wearable utilization.

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Brain region-specific roles of brain-derived neurotrophic factor in social stress-induced depressive-like behavior

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Neural Regeneration Research 2025年第1期20卷 159-173页

作者： Man Han Deyang Zeng Wei Tan Xingxing Chen Shuyuan Bai Qiong wu Yushan Chen Zhen Wei Yufei mei Yan Zeng Brain Science and Advanced Technology Institute Wuhan University of Science and TechnologyWuhanHubei ProvinceChina Geriatric Hospital Affiliated to wuhan University of Science and Technology WuhanHubei ProvinceChina School of Public Health Wuhan University of Science and TechnologyWuhanHubei ProvinceChina

Brain-derived neurotrophic factor is a key factor in stress adaptation and avoidance of a social stress behavioral *** studies have shown that brain-derived neurotrophic factor expression in stressed mice is brain region–specific,particularly involving the corticolimbic system,including the ventral tegmental area,nucleus accumbens,prefrontal cortex,amygdala,and *** how brain-derived neurotrophic factor participates in stress processing in different brain regions will deepen our understanding of social stress *** this review,we discuss the expression and regulation of brain-derived neurotrophic factor in stress-sensitive brain regions closely related to the pathophysiology of *** focused on associated molecular pathways and neural circuits,with special attention to the brain-derived neurotrophic factor–tropomyosin receptor kinase B signaling pathway and the ventral tegmental area–nucleus accumbens dopamine *** determined that stress-induced alterations in brain-derived neurotrophic factor levels are likely related to the nature,severity,and duration of stress,especially in the above-mentioned brain regions of the corticolimbic ***,BDNF might be a biological indicator regulating stress-related processes in various brain regions.

关键词： amygdala chronic mild stress chronic social defeat stress corticolimbic system depression hippocampus medial prefrontal cortex nucleus accumbens social stress models ventral tegmental area

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Regulation and function of endoplasmic reticulum autophagy in neurodegenerative diseases

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Neural Regeneration Research 2025年第1期20卷 6-20页

作者： Xiu-Yun Zhao De-En Xu Ming-Lei wu Ji-Chuan Liu Zi-Ling shi Quan-Hong Ma Department of Neurology and Clinical Research Center of Neurological Disease the Second Affiliated Hospital of Soochow UniversitySuzhouJiangsu ProvinceChina Institute of Neuroscience&Jiangsu Key Laboratory of Translational Research and Therapy for Neuro-Psycho-Diseases Soochow UniversitySuzhouJiangsu ProvinceChina Department of Neurology Jiangnan University Medical CenterWuxiJiangsu ProvinceChina

The endoplasmic reticulum,a key cellular organelle,regulates a wide variety of cellular *** reticulum autophagy,one of the quality control systems of the endoplasmic reticulum,plays a pivotal role in maintaining endoplasmic reticulum homeostasis by controlling endoplasmic reticulum turnover,remodeling,and *** this review,we briefly describe the endoplasmic reticulum quality control system,and subsequently focus on the role of endoplasmic reticulum autophagy,emphasizing the spatial and temporal mechanisms underlying the regulation of endoplasmic reticulum autophagy according to cellular *** also summarize the evidence relating to how defective or abnormal endoplasmic reticulum autophagy contributes to the pathogenesis of neurodegenerative *** summary,this review highlights the mechanisms associated with the regulation of endoplasmic reticulum autophagy and how they influence the pathophysiology of degenerative nerve *** review would help researchers to understand the roles and regulatory mechanisms of endoplasmic reticulum-phagy in neurodegenerative disorders.

关键词： autophagy endoplasmic reticulum endoplasmic reticulum autophagy endoplasmic reticulum quality control system endoplasmic reticulum receptors endoplasmic reticulum-associated degradation neurodegeneration neurodegenerative disease selective autophagy unfolded protein response

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