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Vastly Synergistic Fe_(2)CuNiS_(4)-Nanoarchitectures Anchored 2D-Nano-Sandwich Derived from Flower-Like-CuFeS_(2)/N-Graphene and Cube-Like-NiFeS_(2)/N-CNTs for Water Oxidation and Nitrophenol Reduction

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Energy & Environmental Materials 2024年第6期7卷 274-289页

作者： gopiraman mayakrishnan Ramkumar Vanaraj Junpeng Xiong Muhammad Farooq Azeem Ullah Keqin Zhang Seong Cheol Kim Ick Soo Kim Nano Fusion Technology Research Group Division of Molecules and PolymersInstitute for Fiber Engineering(IFES)Interdisciplinary Cluster for Cutting Edge Research(ICCER)Shinshu UniversityTokida 3-15-1UedaNagano 386-8567Japan School of Chemical Engineering Yeungnam UniversityGyeongsan 38541Korea Graduate School of Medicine Scienceand TechnologyShinshu UniversityTokida 3-15-1UedaNagano 386-8567Japan National Engineering Laboratory for Modern Silk College of Textile and Clothing EngineeringSoochow UniversitySuzhou 215123China

Surface area,pore properties,synergistic behavior,homogenous dispersion,and interactions between carbon matrix and metal-nanostructures are the key factors for achieving the better performance of carbon-metal based(electro)***,the traditional hydro-or solvothermal preparation of(electro)catalysts,particularly,bi-or tri-metallic nanostructures anchored graphene(G)or carbon nanotubes(CNTs),often pose to poor metal–support interaction,low synergism,and patchy *** first,bimetallic flower-like-CuFeS_(2)/NG and cube-like-NiFeS_(2)/NCNTs nanocomposites were prepared by solvothermal *** resultant bimetallic nanocomposites were employed to derive the 2D-nano-sandwiched Fe_(2)CuNiS_(4)/NGCNTs-SW(electro)catalyst by a very simple and green urea-mediated“mix-heat”*** desired physicochemical properties of Fe_(2)CuNiS_(4)/NGCNTs-SW such as multiple active sites,strong metal-support interaction,homogenous dispersion and enhanced surface area were confirmed by various microscopic and spectroscopic *** the best of our knowledge,this is the first urea-mediated“mix-heat”method for preparing 2D-nano-sandwiched carbon-metal-based(electro)*** Fe_(2)CuNiS_(4)/NGCNTs-SW was found to be highly effective for alkaline-mediated oxygen evolution reaction at low onset potential of 284.24 mV,and the stable current density of 10 mA cm^(−2) in 1.0 m KOH for 10 ***,the Fe_(2)CuNiS_(4)/NGCNTs-SW demonstrated excellent catalytic activity in the reduction of 4-nitrophenol with good kapp value of 87.71×10^(−2)s^(-1)and excellent reusability over five ***,the developed urea-mediated“mix-heat”method is highly efficient for the preparation of metal-nanoarchitectures anchored 2D-nano-sandwiched(electro)catalysts with high synergism,uniform dispersion and excellent metal-support interaction.

关键词： (electro)catalyst metal-sulfide nanoarchitectures mix-heat N-graphene/NCNTs synergistic effect urea

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Nitrogen-and Oxygen-Containing Porous Ultrafine Carbon Nanofiber:A Highly Flexible Electrode Material for Supercapacitor

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Journal of Materials Science & Technology 2017年第5期33卷 424-431页

作者： Kai Wei Kyu-Oh Kim Kyung-Hun Song Chang-Yong Kang Jung soon Lee mayakrishnan gopiraman Ick-Soo Kim College of Textile and Clothing Engineering Soochow UniversitySuzhou215021China Nano Fusion Technology Research Group Division of Frontier FibersInstitute for Fiber Engineering(IFES)Interdisciplinary Cluster for Cutting Edge Research(ICCER)Shinshu UniversityTokida 3-15-1UedaNagano Prefecture386-8567Japan Department of Fiber System Engineering Dankook UniversityYoungin 448-701Republic of Korea Department of Clothing&Textiles PaiChai UniversityDaejeon 302-735Republic of Korea Department of Metallurgical Engineering Pukyong National UniversityBusan 608-739Republic of Korea Department of Clothing and Textiles Chungnam National UniversityDaejeon 305-764Republic of Korea

Herein, we report a simple and effective preparation of ultrafine CNFs （u-CNFs） with high surface area via electrospinning of two immiscible polymers [polyacrylonitrile （PAN） and poly（methyl methacry- late）（PMMA）] followed by calcination at high temperature in an inert atmosphere. Various electrospinning conditions were optimized in detail. Four different kinds of PAN/PMMA ratios （10/0, 7：3, 5：5 and 3：7） were chosen and found that the PAN/PMMA ratio of 3：7 （PAN/PMMA-3：7） is the optimum one. BET anal- ysis showed the specific surface area of the u-CNFs-3：7 was 46Z57 m2/g with an excellent pore volume （1.15 cms g-l） and an average pore size （9.48 nm）： it is about 25 times higher than the conventional CNFs （c-CNFs）. TEM and FE-SEM images confirmed the ultrafine structure of the CNFs with a thinner fiber di- ameter of-50 nm. The graphitic nature and atomic arrangement of the u-CNFs were investigated by Raman and XPS analyses. For the supercapacitor application, unlike the common electrode preparation methods, the u-CNFs-3：7 was used without any activation, chemical or mechanical modifications. The u-CNFs- 3：7 showed a better specific capacitance of 86 Fig in 1 mol/L 1-12S04 when compared to pure CNFs. The excellent physicochemical properties make the u-CNFs-3：7 an alternative choice to the existing CNFs for the supercapacitors.

关键词： Carbon fiber Porosity Electron microscopy Surface analysis Supercapacitor

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A Simple Method for the Fabrication of Metallic Copper NanospheresDecorated Cellulose Nanofiber Composite

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Journal of Materials Science & Technology 2016年第7期32卷 605-610页

作者： Hyunsik Bang Ke Ma Kai Wei Chang-Yong Kang Byoung-Suhk Kim mayakrishnan gopiraman Jung Soon Lee Ick-Soo Kim Nano Fusion Technology Research Group Division of Frontier Fibers Institute for Fiber Engineering (IFES) Interdisciplinary Cluster for Cutting Edge Research (ICCER) Shinshu University College of Textile and Clothing Engineering Soochow University Department of Metallurgical Engineering Pukyong National University Department of Organic Materials & Fiber Engineering Chonbuk National University Department of Clothing & Textiles College of Human Ecology Chungnam National University

Herein, we report a new and simple method for the preparation of metallic copper nanospheres- decorated cellulose nanofiber composite （CuNSsJCNFs）. Initially, the cellulose acetate nanofibers （CANFs） were electrospun followed by deacetylation and anionization to produce functional anionic cellulose nanofibers ff-CNFs）. The CuCl2 precursor was deposited on thef-CNFs （CuC12/CNFs） by a simple dipping method. Then the CuCIdCNFs were reduced under vacuum by using aluminum foil to produce the CuNSs/ CNFs. The resultant CuNSs/CNFs composite was characterized by various microscopic and spectroscopic methods. Fourier transform infrared spectroscopy （FT-IR） confirmed the successful functionalization of anionic groups with the CNFs. The field emission scanning electron microscopy （FE-SEM） and transmission electron microscope （TEM） results confirmed the formation of CuNSs on the surface of CNFs. From the scanning electron microscopy-energy dispersive spectroscopy （SEM-EDS） analysis, the weight percentage of Cu was found to be 23.5 wt%. The successful reduction of CuO to metallic Cu was confirmed by X-ray photoemission spectroscopy （XPS） and X-ray diffraction （XRD） analyses. Mechanism has been proposed for the formation of metallic Cu sphere on CNFs.

关键词： Cellulose nanofibersCopper nanospheresNanocompositesReductionAluminum foil

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