检索结果-南通市图书馆

Particuology 2024年第8期91卷 38-49页

作者： Zeman he Shaofu Du Guanying Shao Peiyu Li Lei Sheng Gaohong he Xiaobin Jiang Wu Xiao State Key Laboratory of Fine Chemicals School of Chemical EngineeringEngineering Laboratory for Petrochemical Energy-efficient Separation Technology of Liaoning ProvinceDalian University of TechnologyDalian 116024China

Cooling crystallization is an important separation process and particuology technology that requires accurate nucleation control ***,we introduced the polymeric hollow fiber membrane with proper thermal properties as the effective nucleation induction interface during cooling *** heterogeneous nucleation control mechanism was introduced based on classical nucleation theory and the thermal transfer *** properties and the thermal conductivity of two kinds of polymeric membranes,polytetrafluoroethylene(PTFE)and polyethersulfone(PES),were measured and simulated with the developed *** two membranes possessed different nucleation induction periods,nucleation rates and crystallization performances,which validated that the hollow fiber membrane module could effectively accelerate the nucleation process compared to conventional cooling crystallization owing to the shorter nucleation induction period and the reduced solution surface *** to the higher hydrophobicity and the lower roughness of the membrane surface,the PTFE membrane possessed a more moderate performance in generating stable heterogeneous nucleation than the one of PES ***,the adjustable membrane property enabled the hollow fiber membrane-assisted cooling crystallization to possess the accurate nucleation control and desired terminal particle products.

关键词： Cooling crystallization Nucleation Particle process Hollow fiber membrane Induction period Process control

Recent progress on impact induced reaction mechanism of reactive alloys

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Defence Technology（防务技术） 2024年第7期37卷 69-95页

作者： Yansong Yang Chuanting Wang Yuanpei Meng Yue Ma Lei Guo Yuan he Zhichao Sun Yong he School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210094JiangsuChina

In recent years,in order to improve the destructive effectiveness of munitions,the use of new types of destructive elements is an important way to improve destructive *** a new type of reactive material,reactive alloy contains a large portion of reactive metal elements(Al,Mg,Ti,Zr,etc.),which breaks up under high-velocity impact conditions,generating a large number of high-temperature combustible fragments,which undergo a violent combustion reaction with *** with traditional metal polymers(Al-PTFE)and other reactive composites,it has higher density and strength,excellent mechanical properties and broader application ***,researchers have mainly investigated the impact energy release mechanism of reactive alloys through impact tests,and found that there are several important stages in the process of the material from fragmentation to reaction,i.e.,impact fragmentation of the material,rapid heating and combustion *** paper focuses on three problems that need to be solved in the impact-induced energy release process of reactive alloys,namely:the fragmentation mechanism and size distribution law of the fragments produced by the impact of the material on the target,the relationship between the transient temperatures and the size of the fragments,and the reaction temperatures and size thresholds of the fragments to undergo the chemical *** current status of the research of the above problems is reviewed,some potential directions to reveal the impact induced reaction mechanism of reactive alloy is discussed.

关键词： Reactive alloys Impact Fragmentation Mass and size distribution Shock temperature rise Adiabatic shear Combustion

Waste to treasure:Reutilization of fluid catalytic cracking coke block as photothermal conversion material for water evaporation

在线全文

学校读者我要写书评

暂无评论

Particuology 2024年第5期88卷 62-70页

作者： Zhuwei Gao Chengxin Li Jingjing he Zhuo Wang Xinyu Qi Lan he Shihao Wang Zhongxin Liu School of Chemical Engineering and Technology Hainan UniversityHaikou 570228China TJ-YZ School of Network Science Haikou University of EconomicsHaikou 570203China School of Food Science and Engineering Hainan UniversityHaikou 570228China Key Laboratory of Advanced Materials of Tropical Island Resources of Ministry of Education Hainan UniversityHaikou 570228China Hainan Provincial Key Laboratory of Fine Chemicals Hainan UniversityHaikou 570228China

This study aims to analyze the coking process and propose an effective method for the reutilization of fluid catalytic cracking(FCC)coke ***,we analyzed the basic characteristics and chemical composition of FCC coke *** results showed that the main components were carbon,oxygen,and aluminum,accounting for 60.8%,26.6%,and 11.5%,*** the conventional catalytic cracking reaction temperature from 500℃ to 600℃,the formation of the first aromatic hydrocarbon was particularly important for the formation of *** condensation of oil-gas-entrained catalyst particles and their heavy components was the physical cause of coking,while the dehydrogenation condensation reaction of oil-gas heavy components was the chemical *** addition,the membrane prepared by powdered coke had excellent photothermal conversion ability,which could be heated to more than 110℃ within 360 s under two fixed light *** evaporation rate of photothermal water was 5.89 kg m^(2) h^(−1),which has great industrial application *** works provide a novel and effective method of separation membrane for the reutilization of FCC coke blocks.

关键词： Coking process Reutilization of FCC coke Carbonaceous deposition Membrane Photothermal conversion

Nano-scale Reinforcements and Properties of Al-Si-Cu Alloy Processed by High-Pressure Torsion

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Wuhan University of Technology(Materials Science) 2024年第5期39卷 1253-1259页

作者： DONG Ying WU Siyuan he Ziyang LIANG Chen CheNG Feng he Zuwei QIAN Chenhao School of Mechanical Engineering Jiangnan UniversityWuxi 214122China Jiangsu Key Laboratory of Advanced Food Manufacturing Equipment and Technology Wuxi 214122China School of International Studies Renmin University of ChinaBeijing 100872China School of Engineering University of LiverpoolLiverpool L693GHUnited Kingdom

To improve the comprehensive mechanical properties of Al-Si-Cu alloy,it was treated by a high-pressure torsion process,and the effect of the deformation degree on the microstructure and properties of the Al-Si-Cu alloy was *** results show that the reinforcements(β-Si andθ-CuAl_(2)phases)of the Al-Si-Cu alloy are dispersed in theα-Al matrix phase with finer phase size after the *** processed samples exhibit grain sizes in the submicron or even nanometer range,which effectively improves the mechanical properties of the *** hardness and strength of the deformed alloy are both significantly raised to 268 HV and 390.04 MPa by 10 turns HPT process,and the fracture morphology shows that the material gradually transits from brittle to plastic before and after *** elements interdiffusion at the interface between the phases has also been effectively *** addition,it is found that the severe plastic deformation at room temperature induces a ternary eutectic reaction,resulting in the formation of ternary Al+Si+CuAl_(2)eutectic.

关键词： Al-Si-Cu alloy high-pressure torsion nano-scale reinforcements ternary eutectic

Large eddy simulation study of 3D wind field in a complex mountainous area under different boundary conditions

在线全文

学校读者我要写书评

暂无评论

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第7期25卷 541-556页

作者： Yan LI Lei YAN Xuhui he School of Civil Engineering Central South UniversityChangsha410075China National Engineering Research Center for High-speed Railway Construction Changsha410075China Hunan Provincial Key Laboratory for Disaster Prevention and Mitigation of Rail Transit Engineering Structures Changsha410075China

Large eddy simulations generally are used to predict 3D wind field characteristics in complex mountainous *** simulation boundary conditions,such as the height and length of the computational domain or the characteristics of inflow turbulence,can significantly impact the quality of *** this study,we examined these boundary conditions within the context of the mountainous terrain around a long-span cable-stayed bridge using a wind tunnel *** sizes of computational domains and turbulent incoming wind velocities were used in large eddy *** results show that when the height of the computational domain is five times greater than the height of the terrain model,there is minimal influence from the top wall on the wind field characteristics in this complex mountainous *** the length of the wake region of the computational domain has negligible effects on the wind *** in the inlet boundary reduces the length of the wake region on a leeward hill with a low slope,but has less impact on the mean wind velocity of steep hills.

关键词： Large eddy simulation(LES) Spectral representation method Recycling method High mountainous canyon Wind characteristics Atmospheric boundary layer Computational domain

Lifetime-tunable circularly polarized luminescent system based on triplet-to-singlet Förster resonance energy transfer

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2024年第9期67卷 2918-2922页

作者： Zhenyi he Zizhao Huang Xiang Ma Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center Institute of Fine ChemicalsSchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

Circularly polarized luminescence(CPL)materials have received widespread attention due to their remarkable performance and broad ***,current CPL material research primarily focuses on tunable color,intensity,and *** CPL with adjustable lifetime remains a significant ***,a series of CPL polymeric materials with tunable lifetime were obtained by employing phosphorescent terephthalic acid and chiral organic small molecule R/S-BNAF(a luminescent binaphthol derivative)to copolymerize with acrylamide in different *** was verified that this performance results from the different energy transfer efficiency between luminophores with varying ratios of the monomers for *** strategy to realize CPL with tunable lifetime by modulating the energy transfer efficiency will provide a new perspective to broaden the applications of CPL materials.

关键词： circularly polarized luminescence tunable lifetime Förster resonance energy transfer room temperature phosphorescence

An efficient physics-guided Bayesian framework for predicting ground settlement profile during excavations in clay

在线全文

学校读者我要写书评

暂无评论

Journal of Rock Mechanics and Geotechnical Engineering 2024年第4期16卷 1411-1424页

作者： Cong Tang Shuyu he Wanhuan Zhou State Key Laboratory of Internet of Things for Smart City and Department of Civil and Environmental Engineering University of MacaoChina

Recently,the application of Bayesian updating to predict excavation-induced deformation has proven successful and improved prediction accuracy ***,updating the ground settlement profile,which is crucial for determining potential damage to nearby infrastructures,has received limited *** address this,this paper proposes a physics-guided simplified model combined with a Bayesian updating framework to accurately predict the ground settlement *** advantage of this model is that it eliminates the need for complex finite element modeling and makes the updating framework ***,the model is physically interpretable,which can provide valuable references for construction *** effectiveness of the proposed method is demonstrated through two field case studies,showing that it can yield satisfactory predictions for the settlement profile.

关键词： Bayesian updating Excavations Ground settlement profile Simplified model Uncertainty

Dietary glycine supplementation enhances syntheses of creatine and glutathione by tissues of hybrid striped bass(Morone saxatilis ♀ × Morone chrysops ♂) fed soybean meal-based diets

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Animal Science and Biotechnology 2024年第5期15卷 1996-2011页

作者： Wenliang he Xinyu Li Guoyao Wu Department of Animal Science Texas A&M UniversityCollege StationTX 77843USA

Background We recently reported that supplementing glycine to soybean meal-based diets is necessary for the optimum growth of 5-to 40-g(Phase-I)and 110-to 240-g(Phase-II)hybrid striped bass(HSB),as well as their intestinal *** glycine serves as an essential substrate for syntheses of creatine and glutathione(GSH)in mammals(e.g.,pigs),little is known about these metabolic pathways or their nutritional regulation in *** study tested the hypothesis that glycine supplementation enhances the activities of creatine-and GSH-forming enzymes as well as creatine and GSH availabilities in tissues of hybrid striped bass(HSB;Morone saxatilis♀×Morone chrysops♂).Methods Phase-I and Phase-II HSB were fed a soybean meal-based diet supplemented with 0%,1%,or 2%glycine for 8 *** the end of the 56-d feeding,tissues(liver,intestine,skeletal muscle,kidneys,and pancreas)were collected for biochemical *** In contrast to terrestrial mammals and birds,creatine synthesis occurred primarily in skeletal muscle from all *** liver was most active in GSH synthesis among the HSB tissues *** Phase-I HSB,supplementation with 1%or 2%glycine increased(Phepatic GSH(8%–11%),while reducing(Phepatic GSH sulfide(GSSG)/GSH ratios by 14%–15%,compared with the 0-glycine group;there were no differences(P>0.05)in these variables between the 1%and 2%glycine *** Phase-II HSB,supplementation with 1%and 2%glycine increased(Phe muscle(15%–27%)and liver(11%–20%)in a dose-dependent manner,with reduced ratios of hepatic GSSG/GSH in the 1%or 2%glycine *** all HSB,supplementation with 1%and 2%glycine dose-dependently increased(Phepaticγ-glutamylcysteine synthetase(17%–37%),with elevated activities of intramuscular guanidinoacetate methyltransferase and hepatic GSH synthetase a

关键词： Amino acids Creatine Fish Glutathione Glycine Nutrition

Selective N-Methylation of N-Methylaniline with CO_(2) and H_(2) over Cu/In_(2)O_(3) Catalyst

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Chemistry 2024年第3期42卷 276-282页

作者： Huan Zheng Bo Qian Lin he State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhouGansu730000 China University of Chinese Academy of Sciences Beijing100049 China

N-Methylation of amines with CO_(2) and H2 is a potential approach for CO_(2) utilization because N-methylated amines can be used as solvents and organic intermediates. In_(2)O_(3)-supported Cu (Cu/In_(2)O_(3)) acts as an effective heterogeneous catalyst for N-methylation reaction of N-methylaniline (MA) with CO_(2) and H_(2),showing higher N,N-dimethylaniline (DMA) selectivity than other supported Cu catalysts. On one hand,the dispersion of Cu can be improved by the defective In_(2)O_(3) support. On the other hand,In_(2)O_(3) support is active in the dissociative adsorption of CO_(2) through C—O bond breaking. In addition,the H_(2) dissociation ability of In_(2)O_(3) can also be enhanced by Cu. The combination of Cu and In_(2)O_(3) is effective in the activation of CO_(2),the adsorption of intermediate N-methylformanilide (MFA),the hydrogenation of MFA to DMA and the prohibition of C—N bond cleavage side reactions,thereby enhancing the reaction rate of MA conversion and the selectivity to DMA.

关键词： N-Methylation CO_(2) Cu/In_(2)O_(3) Supported catalysts heterogeneous catalysis

Copper-mediated assembly of SO_(2)F group via radical fluorine-atom transfer strategy

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第9期35卷 4-5页

作者： Yu-Yu Tan Lin-heng he Wei-Min he School of Electrical Engineering University of South ChinaHengyang 421001China

Because of the unique reactivity of sulfonyl fluoride(SO_(2)F)group,such compound has found increasing applications in the areas of organic synthesis,new drug development,pesticide,material science and click chemistry,*** is of current interest to develop novel strategies and methods for the facile preparation of sulfonyl fluorides in a green and highly efficient manner[1,2].Although the traditional approach for the synthesis of sulfonyl fluorides relies on the nucleophilic substitution of fluoride atom with sulfonyl chlorides.

关键词： fluoride synthesis fluorine