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Metal-to-insulator transitions in 3d-band correlated oxides containing Fe compositions

International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 48-59页

作者： Yiping Yu Yuchen Cui Jiangang he Wei mao Jikun Chen Key Laboratory of Advanced Materials and Devices for Post-Moore Chips Ministry of EducationUniversity of Science and Technology BeijingBeijing 100083China School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Institute of Industrial Science The University of Tokyo4-6-1 KomabaMeguro-kuTokyo 153-8505Japan

Metal-to-insulator transitions (MITs),which are achieved in 3d-band correlated transitional metal oxides,trigger abrupt variations in electrical,optical,and/or magnetic properties beyond those of conventional *** such material families,iron(Fe:3d^(6)4s^(2.)-containing oxides pique interest owing to their widely tunable MIT properties,which are associated with the various valence states of *** potential electronic applications also show promise,given the large abundance of Fe on *** MIT properties triggered by critical temperature (TMIT) were reported for ReFe_(2.O_(4)(Fe^(2.5+)),ReBaFe_(2.O_(5)(Fe^(2.5+)),Fe_(3)O_(4)(Fe^(2.67+)),Re_(1/3)Sr_(2.3)FeO_(3)(Fe^(3.67+)),Re Cu_(3)Fe_(4)O_(12.(Fe^(3.75+)),and Ca_(1-x)Sr_(x)FeO_(3)(Fe^(4+))(where Re represents rare-earth elements).The common feature of MITs of these Fe-containing oxides is that they are usually accompanied by charge ordering transitions or disproportionation associated with the valence states of ***,we review the material family of Fe-containing MIT oxides,their MIT functionalities,and their respective *** the perspective of potentially correlated electronic applications,the tunability of the TMITand its resultant resistive change in Fe-containing oxides are summarized and further compared with those of other materials exhibiting MIT *** particular,we highlight the abrupt MIT and wide tunability of TMITof Fe-containing quadruple perovskites,such as Re ***,their effective material synthesis still needs to be further explored to cater to potential applications.

关键词： metal-to-insulator transitions Fe-containing oxides charge ordering charge disproportionation

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Channel assignment and power allocation for throughput improvement with PPO in B5G heterogeneous edge networks

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Digital Communications and Networks 2024年第1期10卷 109-116页

作者： Xiaoming he Yingchi mao Yinqiu Liu Ping Ping Yan Hong Han Hu The College of Computer and Information Hohai UniversityNanjingChina The Key Laboratory of Water Big Data Technology of Ministry of Water Resources Hohai UniversityNanjing China The School of Computer Science and Engineering Nanyang Technological UniversitySingapore The College of Textile and Clothing Engineering Soochow UniversitySuzhouChina The College of Internet of Things Nanjing University of Posts and TelecomurunicationsNanjingChina

In Beyond the Fifth Generation(B5G)heterogeneous edge networks,numerous users are multiplexed on a channel or served on the same frequency resource block,in which case the transmitter applies coding and the receiver uses interference ***,uncoordinated radio resource allocation can reduce system throughput and lead to user inequity,for this reason,in this paper,channel allocation and power allocation problems are formulated to maximize the system sum rate and minimum user achievable *** the construction model is non-convex and the response variables are high-dimensional,a distributed Deep Reinforcement Learning(DRL)framework called distributed Proximal Policy Optimization(PPO)is proposed to allocate or assign ***,several simulated agents are trained in a heterogeneous environment to find robust behaviors that perform well in channel assignment and power ***,agents in the collection stage slow down,which hinders the learning of other ***,a preemption strategy is further proposed in this paper to optimize the distributed PPO,form DP-PPO and successfully mitigate the straggler *** experimental results show that our mechanism named DP-PPO improves the performance over other DRL methods.

关键词： B5G heterogeneous edge networks PPO Channel assignment Power allocation Throughput

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Molecular investigation into the transformation of recalcitrant dissolved organic sulfur in refinery sour water during stripping process

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Petroleum Science 2024年第3期21卷 2112-2119页

作者： Yu-Guo Li Chen he Chun-mao Chen Fan Liu Quan Shi State Key Laboratory of heavy Oil Processing China University of PetroleumBeijing 102249China State Key Laboratory of Coal Mining and Clean Utilization Beijing 100013China PetroChina Ningxia Petrochemical Company Yinchuan 750021NingxiaChina

Refinery sour water primarily originates from the tops of towers in various units and coker condensate,and cannot be discharged directly to a wastewater treatment plant due to high levels of chemical oxygen demand(COD)and organic sulfur *** after the recovery of H_(2.S from the sour water by the stripping process,the effluent still contains a high concentration of dissolved organic sulfur(DOS),which can have a huge bad *** chemical composition of dissolved organic matter(DOM)in refinery wastewater has been extensively studied,the investigation of recalcitrant DOS from sour waters remains *** the present study,chemical composition of sour water DOMs(especially DOS)was investigated using fluorescence spectroscopy(excitation-emission matrix,EEM)and mass spectrometry,including gas chromatography-mass spectrometry(GC-MS)and high-resolution Orbitrap *** GC-MS and EEM results showed that volatile and low-aromaticity compounds were effectively removed during the stripping process,while compounds with high hydrophilicity and humification degree were found to be more *** Orbitrap MS results showed that weak-polar oxygenated sulfur compounds were easier to be removed than oxygenated ***,the effluent still contained significant amounts of sulfur-containing compounds with multiple sulfur atoms,particularly in the form of highly unsaturated and aromatic *** Orbitrap MS/MS results of CHOS-containing compounds from the effluent indicate that the sulfur atoms may exist as sulfonates,disulfide bonds,*** the composition and structure of sour water DOS is crucial for the development of effective treatment processes that can target polysulfide compounds and minimize their impact on the environment.

关键词： Molecular transformation Dissolved organic sulfur Stripping process Refinery sourwater Orbitrap MS

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Synthesis and molecular recognition characteristics of a tetrapodal benzene cage

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Chinese Chemical Letters 2024年第8期35卷 240-244页

作者： Caihong mao Yanfeng he Xiaohan Wang Yan Cai Xiaobo Hu Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials ScienceZhejiang Normal UniversityJinhua 321004China

In this contribution,we describe the preparation and recognition characteristics of a novel tetrapodal benzene cage(1).The cage can express a wide recognition range without losing selectivity for the object of appropriate size and functional *** key to obtaining the desired structural isomer of 1 is the synthesis and isolation of the o-bis(bromomethyl)benzene precursor(5).Three distinct guests,F^(−)(ex-tremely small size),d-lactate(appropriate size)and l-Asp(branched shape),were selected as examples to demonstrate the recognition characteristics of *** NMR titration studies,they all expressed good binding affinity(K>10^(5) L/mol)in competitive medium(10%DMSO/THF),indicating that 1 has a wide recognition *** highest binding constant was observed for d-lactate,revealing that 1 has good selectivity for d-lactate versus F^(−)and ***,the NMR titration study of F^(−)in DMSO indicates 1 can achieve different binding modes(1:1 and 2.1 guest-host)for small-sized guests,which allows for the further development of binary binding properties and thereafter applications in the field of catalysis.

关键词： Cage molecules Host-guest chemistry Multi-step organic synthesis d-Lactate recognition l-Asp recognition

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Enhanced hepatic metabolic perturbation of polystyrene nanoplastics by UV irradiation-induced hydroxyl radical generation

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Journal of Environmental Sciences 2024年第8期142卷 259-268页

作者： Shiyu he Jingran Wang Lihong Zhou Zhen mao Xiaodan Zhang Jin Cai Peili Huang School of Public health and Beijing Key Laboratory of Environmental Toxicology Capital Medical UniversityBeijing 100069China

The environmental behavior of and risks associated with nanoplastics(NPs)have attracted considerable ***,compared to pristine NPs,environmental factors such as ultraviolet(UV)irradiation that lead to changes in the toxicity of NPs have rarely been *** evaluated the changes in morphology and physicochemical properties of polystyrene(PS)NPs before and after UV irradiation,and compared their hepatotoxicity in *** results showed that UV irradiation caused particle size reduction and increased the carbonyl index(CI)and negative charge on the particle ***-aged PS NPs(aPS NPs)could induce the generation of hydroxyl radicals(·OH),but also further promoted the generation of·OH in the Fenton reaction *** pathological damage was more severe in mice exposed to aPS NPs,accompanied by a large number of vacuoles and hepatocyte balloon-like changes and more marked perturbations in blood glucose and serum lipoprotein,alanine aminotransferase and aspartate aminotransferase *** addition,exposure to PS NPs and aPS NPs,especially aPS NPs,triggered oxidative stress and significantly damaged the antioxidant capacity of mice *** with PS NPs,exposure to aPS NPs increased the number of altered metabolites in hepatic and corresponding metabolic pathways,especially glutathione *** research suggests that UV irradiation can disrupt the redox balance in organisms by promoting the production of·OH,enhancing PS NPs-induced liver damage and metabolic *** study will help us understand the health risks of NPs and to avoid underestimation of the risks of NPs in nature.

关键词： Polystyrene nanoplastics Ultraviolet-aged nanoplastics Metabolic pathway Metabolomics Hydroxyl radical

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3D printing in space:from mechanical structures to living tissues

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International Journal of Extreme Manufacturing 2024年第2期6卷 378-387页

作者： mao mao Zijie Meng Xinxin Huang Hui Zhu Lei Wang Xiaoyong Tian Jiankang he Dichen Li Bingheng Lu State Key Laboratory for Manufacturing Systems Engineering Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China National Medical Products Administration(NMPA)Key Laboratory for Research and Evaluation of Additive Manufacturing Medical Devices Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China National Innovation Platform(Center)for Industry-Education Integration of Medical Technology Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China Frontier Institute of Science and Technology Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China National Innovation Institute of Additive Manufacturing Xi’an 710000People’s Republic of China

3D printing stands at the forefront of transforming space exploration,offering unprecedented on-demand and rapid manufacturing *** adeptly addresses challenges such as mass reduction,intricate component fabrication,and resource *** the obstacles posed by microgravity and extreme environments,continual advancements underscore the pivotal role of 3D printing in aerospace *** its primary function of producing space structures,3D printing contributes significantly to progress in electronics,biomedicine,and resource *** perspective delves into the technological advantages,environmental challenges,development status,and opportunities of 3D printing in *** its crucial impact,we anticipate that 3D printing will unlock innovative solutions,reshape manufacturing practices,and foster self-sufficiency in future space endeavors.

关键词： 3D printing in space space manufacturing microgravity

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A novel method for simulating nuclear explosion with chemical explosion to form an approximate plane wave: Field test and numerical simulation

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2137-2153页

作者： Wei Ming Xiaojie Yang Yadong mao Xiang Wang Manchao he Zhigang Tao College of Civil and Architecture Engineering North China University of Science and TechnologyTangshan063210China State Key Laboratory for Tunnel Engineering China University of Mining and Technology-BeijingBeijing100083China School of Mechanics and Civil Engineering China University of Mining and Technology-BeijingBeijing100083China

A nuclear explosion in the rock mass medium can produce strong shock waves,seismic shocks,and other destructive effects,which can cause extreme damage to the underground protection *** the increase in nuclear explosion power,underground protection engineering enabled by explosion-proof impact theory and technology ushered in a new *** paper proposes to simulate nuclear explosion tests with on-site chemical explosion tests in the form of multi-hole ***,the mechanism of using multi-hole simultaneous blasting to simulate a nuclear explosion to generate approximate plane waves was *** plane pressure curve at the vault of the underground protective tunnel under the action of the multi-hole simultaneous blasting was then obtained using the impact test in the rock mass at the *** to the peak pressure at the vault plane,it was divided into three regions:the stress superposition region,the superposition region after surface reflection,and the approximate plane stress wave zone.A numerical simulation approach was developed using PFC and FLAC to study the peak particle velocity in the surrounding rock of the underground protective cave under the action of multi-hole *** time-history curves of pressure and peak pressure partition obtained by the on-site multi-hole simultaneous blasting test and numerical simulation were compared and analyzed,to verify the correctness and rationality of the formation of an approximate plane wave in the simulated nuclear *** comparison and analysis also provided a theoretical foundation and some research ideas for the ensuing study on the impact of a nuclear explosion.

关键词： Approximate plane wave Multi-hole simultaneous blasting Chemical explosion Nuclear explosion Pressure sensor inclusion

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Improving Federated Learning through Abnormal Client Detection and Incentive

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Computer Modeling in Engineering & Sciences 2024年第4期139卷 383-403页

作者： Hongle Guo Yingchi mao Xiaoming he Benteng Zhang Tianfu Pang Ping Ping College of Computer and Information Hohai UniversityNanjing211100China Key Laboratory ofWater Big Data Technology of Ministry ofWater Resources Hohai UniversityNanjing211100China

Data sharing and privacy protection are made possible by federated learning,which allows for continuous model parameter sharing between several clients and a central *** reliable and high-quality clients must participate in practical applications for the federated learning global model to be accurate,but because the clients are independent,the central server cannot fully control their *** central server has no way of knowing the correctness of the model parameters provided by each client in this round,so clients may purposefully or unwittingly submit anomalous data,leading to abnormal behavior,such as becoming malicious attackers or defective *** reduce their negative consequences,it is crucial to quickly detect these abnormalities and incentivize *** this paper,we propose a Federated Learning framework for Detecting and Incentivizing Abnormal Clients(FL-DIAC)to accomplish efficient and security federated *** build a detector that introduces an auto-encoder for anomaly detection and use it to perform anomaly identification and prevent the involvement of abnormal clients,in particular for the anomaly client detection *** them,before the model parameters are input to the detector,we propose a Fourier transform-based anomaly data detectionmethod for dimensionality reduction in order to reduce the computational ***,we create a credit scorebased incentive structure to encourage clients to participate in training in order tomake clients actively *** training models(CNN,MLP,and ResNet-18)and three datasets(MNIST,Fashion MNIST,and CIFAR-10)have been used in *** to theoretical analysis and experimental findings,the FL-DIAC is superior to other federated learning schemes of the same type in terms of effectiveness.

关键词： Federated learning abnormal clients incentive credit score abnormal score detection

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The protective role of prebiotics and probiotics on diarrhea and gut damage in the rotavirus-infected piglets

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Journal of Animal Science and Biotechnology 2024年第4期15卷 1424-1448页

作者： heng Yang Xiangqi Fan Xiangbing mao Bing Yu Jun he Hui Yan Jianping Wang Institute of Animal Nutrition Sichuan Agricultural UniversityKey Laboratory for Animal Disease-Resistance Nutrition of China Ministry of EducationKey Laboratory of Animal Disease-Resistant Nutrition and Feed of China Ministry of Agriculture and Rural AffairsKey Laboratory of Animal Disease-Resistant Nutrition of Sichuan ProvinceNo.211Gongpinghuimin RoadWenjiang DistrictChengduSichuan Province 611130People’s Republic of China

Rotavirus is one of the pathogenic causes that induce diarrhea in young animals, especially piglets, worldwide. However, nowadays, there is no specific drug available to treat the disease, and the related vaccines have no obvious efficiency in some countries. Via analyzing the pathogenesis of rotavirus, it inducing diarrhea is mainly due to disturb enteric nervous system, destroy gut mucosal integrity, induce intracellular electrolyte imbalance, and impair gut microbiota and immunity. Many studies have already proved that prebiotics and probiotics can mitigate the damage and diarrhea induced by rotavirus infection in hosts. Based on these, the current review summarizes and discusses the effects and mechanisms of prebiotics and probiotics on rotavirus-induced diarrhea in piglets. This information will highlight the basis for the swine production utilization of prebiotics and probiotics in the prevention or treatment of rotavirus infection in the future.

关键词： Diarrhea Piglet Prebiotics Probiotics Rotavirus

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Ambient electrocatalytic synthesis of urea by co-reduction of NO_(3)^(-) and CO_(2. over graphene-supported In_(2.O_(3)

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Chinese Chemical Letters 2024年第3期35卷 538-543页

作者： Yini mao Yong Jiang Hao Liu Yimin Jiang Ming Li Wei Su Rongxing he Key Laboratory of Luminescence Analysis and Molecular Sensing(Southwest University) Ministry of EducationCollege of Chemistry and Chemical EngineeringSouthwest UniversityChongqing 400715China Key Laboratory of Beibu Gulf Environment Change and Resources Utilization(Nanning Normal University) Ministry of EducationCollege of Chemistry and Life ScienceNanning Normal UniversityNanning 530000China

Urea plays a vital role in the sustainable development of mankind as it is one of the most important nitrogen *** synthesis of urea is accompanied by a high level of energy consumption while electrocatalytic methods suffer from low yields and poor *** work achieves efficient synthesis of urea by designing the graphene-In_(2.O_(3)electrocatalysts for the co-activated reduction of nitrate and carbon dioxide,where the formation rate of urea,Faraday efficiency(FE)and carbon selectivity at-0.35 V *** can reach 357.47μg mg^(-1)h^(-1),10.46%and~100%,***,the key intermediates in the C–N coupling reaction are demonstrated to be*NH_(2.and*CO_(2.,which is of novelty compared to previous *** work may provide inspiration for subsequent studies on the reaction mechanism of the electrochemical synthesis of urea,as well as theoretical guidance for the sustainable synthesis of some other important chemical substances.

关键词： Graphene-supported In_(2.O_(3) Dispersion effect Efficient C-N coupling Key intermediate Urea

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