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Comparative study on water-soluble inorganic ions in PM2.5 from two distinct climate regions and air quality

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Journal of Environmental Sciences 2020年第2期32卷 349-360页

作者： Duong Huu Huy le.tu Thanh To Thi Hien Norimichi Takenaka Faculty of Food Science and Technology Ho Chi Minh City University of Food Industry140 Le Trong Tan StreetTan Phu DistrictHo Chi Minh CityViet Nam Faculty of Environment University of ScienceVietnam National University–Ho Chi Minh City227 Nguyen Van Cu StreetDistrict 5Ho Chi Minh CityViet Nam Graduate School of Humanities and Sustainable System Sciences Osaka Prefecture University1-1 Gakuen-choNaka-kuSakai-shiOsaka 599-8531Japan

Recently, air quality has significantly improved in developed country, but that issue is of concern in emerging megacity in developing *** this study, aerosols and their precursor gas were collected by NILU filter pack at two distinct urban sites during the winter and summer in Osaka, Japan and dry and rainy seasons in Ho Chi Minh City(HCMC),*** aims are to investigate the contribution of water-soluble inorganic ions(WSIIs) to PM2.5, thermodynamic characterization and possible formation pathway of secondary inorganic aerosol(SIA).The PM2.5 concentration in Osaka(15.8 μg/m^3) is lower than that in HCMC(23.0 μg/m^3), but the concentration of WSIIs in Osaka(9.0 μg/m^3) is two times higher than that in HCMC(4.1 μg/m^3).Moreover, SIA including NH4^+, NO3^-and SO4^2-are major components in WSIIs accounting for 90% and 76%(in molar) in Osaka and HCMC,*** models were used to understand the thermodynamic characterization of urban ***, statistical analysis results indicate that very good agreement(R2> 0.8) was found for all species, except for nitrate aerosol in *** found that when the crustal species present at high amount, those compositions should be included in model calculation(*** the HCMC situation).Finally, we analyzed the characteristics of NH4^+– NO3^-– SO4^2-system.A possible pathway to produce fine nitrate aerosol in Osaka is via the homogeneous reaction between NH3 and HNO3, while nonvolatile nitrate aerosols can be formed by the heterogeneous reactions in HCMC.

关键词： Water-soluble inorganic ions Thermodynamic model PM2.5

Cutaneous leishmaniasis presenting with painless ulcer on the right forearm:A case report

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World Journal of Clinical Cases 2022年第7期10卷 2301-2306页

作者： le Zhuang Jing Su Ping tu Department of Dermatology Peking University The First HospitalBeijing 100034China Department of Dermatology Qilu Hospital of Shandong UniversityJinan 250012Shandong provinceChina Department of Pathology School of Basic Medical SciencesThe Third HospitalPeking University Health Science CenterBeijing 100034China

BACKGROUND leishmaniasis includes a range of chronic infections in humans and animals and can be caused by more than 20 species of leishmania *** manifestations of leishmaniasis are diverse and dependent on the immune response capacity of the host and the type of *** East Asia,leishmaniasis is relatively rare and prone to misdiagnosis and *** SUMMARY We report a case of a 36-year-old male with cutaneous *** patient had been misdiagnosed with a bacterial skin infection and was given a dressing change and oral levofloxacin,which proved *** examination revealed amastigote(leishman-Donovan body)in the histocytes,and nucleic acid sequencing proved that the pathogen was leishmania *** patient was treated successfully by regional injection of sodium gluconate(600 mg)three *** ulcer healed and did not recur at 1.5-year *** Skin ulcers caused by leishmaniasis are easily misdiagnosed in non-epidemic countries,yet it should not be overlooked.

关键词： leishmaniasis leishmania major Skin ulcer Protozoan Skin infection Diagnostic errors Case report

An isogeometric analysis approach for dynamic response of doubly-curved magneto electro elastic composite shallow shell subjected to blast loading

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Defence Technology（防务技术） 2024年第11期41卷 159-180页

作者： Pham Hoang tu Tran Van Ke Vu Khac Trai le Hoai Faculty of Automotive Engineering School of TechnologyVan Lang UniversityHo Chi Minh City 700000Viet Nam Faculty of Mechanical Engineering Le Quy Don Technical UniversityHanoi 100000Viet Nam Faculty of Engineering and Technology Nguyen Tat Thanh UniversityHo Chi Minh City 700000Viet Nam HUTECH Institute of Engineering HUTECH UniversityHo Chi Minh City 700000Viet Nam

For the first time, the isogeometric analysis(IGA) approach is used to model and analyze free and forced vibrations of doubly-curved magneto-electro-elastic(MEE) composite shallow shell resting on the visco-Pasternak foundation in a hygro-temperature environment. The doubly-curved MEE shallow shell types include spherical shallow shell, cylindrical shallow shell, saddle shallow shell, and elliptical shallow shell subjected to blast load are investigated. The Maxwell equation and electromagnetic boundary conditions are used to determine the vary of the electric and magnetic potentials. The MEE shallow shell's equations of motion are derived from Hamilton's principle and refined higher-order shear theory. Then, the IGA method is used to derive the laws of natural frequencies and dynamic responses of the shell under various boundary conditions. The accuracy of the model and method is verified through reliable numerical comparisons. Aside from this, the impact of the input parameters on the free and forced vibration of the doubly-curved MEE shallow shell is examined in detail. These results may be useful in the design and manufacture of military structures such as warships, fighter aircraft, drones and missiles.

关键词： IGA approach Free and forced vibration Doubly-curved MEE shallow shell Blast load

Fabrication and characterization of YVO_4:Eu^(3+) nanomaterials by the microwave technique

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Journal of Rare Earths 2011年第12期29卷 1137-1141页

作者： Tran Thu Huong Vu Duc tu Tran Kim Anh le Thi Vinh le Quoc Minh Institute of Materials Science Vietnamese Academy of Science and Technology University of Engineering and Technology National University Hanoi Departments of Chemistry Hanoi University of Mining and Geology

Fabrication and characterization of YVO4：Eu^3＋ nanophosphors prepared by microwave （MW） irradiation assisted soft template synthesis were reported. The effects of synthesis conditions such as different powers of MW irradiation, pH values and concentration of reac- tion materials on properties of nanophosphor were also investigated to obtain the controllable size, morphology and high luminescence efficiency. Morphology, crystalline structure, and optical properties were characterized by field emission scanning electron microscopy （FE-SEM）, X-ray diffraction （XRD） and fluorescence spectroscopy, respectively. The results showed that YVOa：Eu^3＋ nanophosphors were obtained by using diethyleneglycol （DEG） as soft template, with pH values in the range of 4 to 12, upon microwave irradiation from 300 to 900 W, at temperature of 80 ℃. The high fluorescent YVOa：Eu^3＋ nanocrystals obtained with size from 15 nm down to 8 nm are more effective to develop an ultrahigh sensitive fluorescent label for biomolecule, cell and tissue.

关键词： microwave synthesis method DEG soft template YVO4:Eu^3+ nanophosphor luminescence rare earths

Recent advances on small-molecule fluorophores with emission beyond 1000 nm for better molecular imaging in vivo

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Chinese Chemical letters 2019年第10期30卷 1731-1737页

作者： le.tu Yuling Xu Qingying Ouyang Xiangyang Li Yao Sun College of Chemistry China University of PetroleumQingdao 266555China International Joint Research Center for Intelligent Biosensor Technology and Health Key Laboratory of Pesticides and Chemical BiologyMinistry of EducationCollege of ChemistryCentral China Normal UniversityWuhan 430079China State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering Key Laboratory of Green Pesticide and Agricultural BioengineeringMinistry of EducationGuizhou UniversityGuiyang 550025China

In the second near-infrared channel(NIR-II, 1000–1700 nm), organic and inorganic fluorophores are designed with superior chemical/optical properties to provide real-time information with deeper penetration depth and higher resolution owing to the innate lower light scattering and absorption of the NIR-II imaging than conventional optical imaging. Among them, the small-molecule based fluorophores have been highlighted due to their desirable biocompatibility and favorable pharmacokinetics. In this review, we introduced the latest research progress of the rational design of small-molecule NIR-II fluorophores and their impressively biological applications including the NIR-II signal imaging,multimodal imaging and theranostic.

关键词： Small-molecule fluorophores The second near-infrared channel Benzo-bisthiadiazole Biomedical imaging

Finite-Time Consensus of a leader-Following Multi-Agent Network with Non-Identical Nonlinear Dynamics and Time-Varying Topologies

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Wuhan University Journal of Natural Sciences 2016年第5期21卷 438-444页

作者： YU le.tu Lilan HUANG Yifan Hubei Province Key Laboratory of Systems Science in Metallurgical Process Wuhan University of Science and Technology

In this paper, the finite-time consensus of a leader-following multi-agent network with non-identical nonlinear dynamics and time-varying topologies is investigated. All the agents, especially the leaders, have non-identical and nonlinear dynamics. According to the algebraic graph theory, Lyapunov stability theory and Kronecker product, a control strategy strategy is established to guarantee the finite-time consensus of multi-agent network with multiple leaders. Furthermore, several numerical simulations illustrate the effectiveness and feasibility of the proposed method.

关键词： finite-time consensus leader-following multi-agent network algebraic graph theory Lyapunov stability theory Kronecker product

Co-luminescence properties of terbium ions–benzoic acid–phen complexes doped with europium ions

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Rare Metals 2013年第6期32卷 599-604页

作者： Jing Zhang Li-Xi Wang le Zhang Yan Chen Qi-tu Zhang College of Materials Science and Engineering Nanjing University of Technology

Series of complexes Eux Tb1-x(BA)3phen(0.01 B x B 0.50)were synthesized by co-precipitation method,BA was used as the carboxylic acid ligand and 1,10-phenanthroline was used as the electrically neutral *** samples were characterized by means of X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),thermal gravimetric analyses and differential scanning calorimetry(TG–DSC),ultraviolet and visible spectrophotometer absorption spectra,and photoluminescence spectra to study the structure,the energy absorption,the thermal,and luminescent properties of the rare earth *** results show that the series rare earth organic complexes are well crystallized and show high thermal *** luminescent intensity of europium ion in the complexes increases as terbium ion transfers the absorbed energy to europium ion in the *** emission of terbium ion at 545 nm is not quenched by europium ion but increases with the content of europium ion *** the x value is 0.01,the fluorescence intensity reaches the maximum as well as the emission intensity of terbium ions at 545 nm and europium ions at614 nm are almost *** realizes the co-luminescence phenomenon of terbium ion and europium *** series rare earth organic complexes with different colors can be obtained by adjusting the ratio of terbium ion and europium ion.

关键词： Complexes Photoluminescence Rare earth Luminescent intensity Co-luminescence

Synchronization-Based Topology Identification of Uncertain Stochastic Delay Complex Networks

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Wuhan University Journal of Natural Sciences 2013年第4期18卷 337-342页

作者： LIU Hongfang tu Lilan YU le Hubei Province Key Laboratory of Systems Science in Metallurgical Process Wuhan University of Science and Technology

In this paper, topology identification of general weighted complex network with time-varying delay and stochastic perturbation,which is a zero-mean real scalar Wiener process, is investigated. Based on the adaptive-feedback control method, the stochastic Lyapunov stability theory and the ito formula, some synchronous criteria are established, which guarantee the asymptotical mean square synchronization of the drive network and the response network with stochastic disturbances, as well as identify the topological structure of the uncertain general drive complex network. Finally, numerical simulations are presented to verify the correctness and effectiveness of the proposed scheme.

关键词： topology identification time-varying coupling delay stochastic perturbation synchronization complex networks

基于光谱分析的鞣花酸和尿石素A~D与HSA相互作用机理研究

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光谱学与光谱分析 2025年第1期45卷 282-290页

作者：谢星程鑫鹏张露罗晶王乐怀林文静卢菲艳涂宗财江西师范大学健康学院食品营养与健康系江西南昌330022 南昌大学食品科学与资源挖掘全国重点实验室江西南昌330047

采用光谱分析结合分子模拟技术探究了鞣花酸(EA)及其代谢产物尿石素A~D(UA~D)与人血清白蛋白(HSA)的相互作用机理,有助于解析其药理毒性和药效。研究结果表明EA和UA~D能与HSA以1∶1的摩尔比例结合并通过静态方式猝灭HSA的荧光。UA和UC与... 详细信息

采用光谱分析结合分子模拟技术探究了鞣花酸(EA)及其代谢产物尿石素A~D(UA~D)与人血清白蛋白(HSA)的相互作用机理,有助于解析其药理毒性和药效。研究结果表明EA和UA~D能与HSA以1∶1的摩尔比例结合并通过静态方式猝灭HSA的荧光。UA和UC与HSA结合是氢键和范德华力驱动的放热过程,而EA和UD与HSA结合疏水相互作用驱动的吸热过程。三维荧光图谱分析表明UC~D和EA与UA~B分别增加了HSA色氨酸和酪氨酸微环境的亲水性和疏水性。分子模拟分析结果表明,EA和UA~D与HSA的活性氨基酸残基Lys436、Asp187、Lys432、Arg485、leu430、leu4、Ile388、Tyr411等形成氢键,与氨基酸残基Ala191、Val456、Lys199和Trp214之间存在疏水相互作用,证明其主要通过氢键和范德华力与HSA结合,屏蔽HSA的糖基化位点,抑制其糖基化。可为EA和UA~D作为糖基化抑制剂用于治疗糖尿病并发症奠定理论基础。

关键词：人血清白蛋白糖基化相互作用机理光谱分析鞣花单宁及其代谢产物