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mainchain conformation ordering self-assembly tailored room temperature phosphorescence emission

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Science China Chemistry 2025年第01期 329-336页

作者： Yuzhu Li Yumeng Gao Feng Tian Yu Wang Yuan Yao Shaoliang Lin Xiang ma Binbin Xu Shanghai Key Laboratory of Advanced Polymeric materials Key Laboratory for Ultrafine Materials of Ministry of Education School of Materials Science and Engineering East China University of Science and Technology Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of Sciences Key Laboratory for Advance materials and Feringa Noble Prize Scientist Joint Research Centre Frontiers Science for Materiobiology and Dynamic Chemistry School of Chemistry and Molecular Engineering East China University of Science & Technology

Developing organic room-temperature phosphorescence （RTP） materials with a wide range of tunable-emission is significant in expanding the applications of RTP ***,we rationally designed amphiphilic alternating copolymers poly(1,2-bis（4-alkoxyphenyl）ethane-1,2-dione-alt-（ethylene glycol）x)(P（Bz-alt-EGx）) that combined the advantage of alternating benzil and EGxskeleton,and tunable mainchain *** a mainchain conformation ordering assembly （COA） process,P（Bz-alt-EGx） self-assembled into well-defined platelets,and such assemblies emitted blue RTP at ca.425 nm due to the ordered folded-chain conformation and confined *** contrast,traditional self-assembly （ta） of P（Bz-alt-EGx） obtained less ordered aggregates,such as asymmetric worms,vesicles,and rod-like *** resultant less ordered aggregates exhibited yellow-green RTP at ca.550 *** wide-tuning RTP emission in solution （between blue and yellow-green,over125 nm） is realized using the P（Bz-alt-EGx） alternating copolymers under the treatment of different self-assembly *** study uncovers a new strategy to tailor the RTP emission through different self-assembly pathways and holds great promise for the fabrication of advanced optical materials.

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Fabrication of monodispersed B,N co-doped hierarchical porous carbon nanocages through confined etching to boost electrocatalytic oxygen reduction

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Nano Research 2023年第1期16卷 290-298页

作者： Xuefei Wang Chao Han Haitao Li Panpan Su Na ta Yanfu ma Zhenguo Huang Jian Liu School of Civil&Environmental Engineering University of Technology SydneySydneyNSW2007Australia State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China DICP-Surrey Joint Centre for Future materials University of Surrey GuildfordSurreyGU27XHUK

Dual heteroatom-doped carbons have attracted widespread research attention as catalysts in the field of energy storage and conversion due to their unique electronic structures and chemical *** particular,boron and nitrogen co-doped carbon(B,N@C)has shown great potential for photo/electrocatalytic ***,more needs to be done for rational designing and regulating the structure of these materials to improve their catalytic ***,monodispersed hierarchical porous B,N@C nanocages were fabricated by pyrolyzing zeolite imidazole framework(ZIF)which was treated with ammonia borane or boric acid via an integrated double-solvent impregnation and nanocofined-etching *** treated ZIF-8 provided an essential structural template to achieve B,N co-doped hierarchical structures with micro/meso/macro multimodal pore size *** resultant B,N@C nanocages displayed high catalytic activities for electrochemical oxygen reduction reaction(ORR)in alkaline media,outperforming most carbon-based catalysts,particularly from the perspective of the half-wave *** high catalytic performance is due to the enhanced activity by the coexistence of B and N and the mass transfer promoted by the unique hierarchical porous structure.

关键词： heteroatom doping hierarchical porous carbon host-guest chemistry confined etching electrocatalysis mass transfer

Highly dispersed NiMo@rGO nanocomposite catalysts fabricated by a two-step hydrothermal method for hydrogen evolution

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International Journal of Minerals,Metallurgy and materials 2023年第12期30卷 2432-2440页

作者： Duanhao Cao Xiaofeng ma Yipeng Zhang La ta Yakun Yang Chao Xu Feng Ye Jianguo Liu School of Energy Power and Mechanical Engineering North China Electric Power UniversityBeijing 102206China

Exploring and designing a high-performance non-noble metal catalyst for hydrogen evolution reaction(HER)are crucial for the large-scale application of H2 by water ***,novel catalysts with NiMo nanoparticles decorated on reduced graphene oxide(NiMo@r GO)synthesized by a two-step hydrothermal method were *** characterization results showed that the prepared NiMo@r GO-1 had an irregular lamellar structure,and the NiMo nanoparticles were uniformly dispersed on the ***@rGO-1 exhibited outstanding HER performance in an alkaline environment and required only 93 and 180 mV overpotential for HER in 1.0 M KOH solution to obtain current densities of-10 and-50 ma·cm^(-2),*** tests showed that NiMo@rGO-1 had a certain operating stability for32 *** the same condition,the performance of NiMo@rGO-1 can be comparable with that of commercial Pt/C catalysts at high current *** synergistic effect between NiMo particles and lamellate graphene can remarkably promote charge transfer in electrocatalytic *** a result,NiMo@rGO-1 presented the advantages of high intrinsic activity,large specific surface area,and small electrical *** lamellar graphene played a role in dispersion to prevent the aggregation of *** prepared NiMo@rGO-1 can be used in anion exchange membrane water electrolysis to produce *** study provides a simple preparation method for efficient and low-cost water electrolysis to produce hydrogen in the future.

关键词： hydrogen evolution reaction NiMo nanocomposite reduced graphene oxide synergistic effect

Seasonal Responses of Net Primary Productivity of Vegetation to Phenological Dynamics in the Loess Plateau, China

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Chinese Geographical Science 2022年第2期32卷 340-357页

作者： HAN Hongzhu BAI Jianjun ma Gao YAN Jianwu WANG Xiaohui ta Zhijie WANG Pengtao School of Tourism&Research Institute of Human Geography Xi'an International Studies UniversityXi'an 710128China School of Geography and Tourism Shaanxi Normal UniversityXi'an 710119China China Academy of Space Technology-Xi'an Xi'an 710000China School of Humanities and Social Sciences Xi'an University of Posts and TelecommunicationsXi'an 710121China

With global warming, the great changes in the patterns of plant growth have occurred. The conditions in early spring and late autumn have changed the process of vegetation photosynthesis, which are expected to have a significant impact on net primary productivity(NPP) and affect the global carbon cycle. Currently, the seasonal response characteristics of NPP to phenological changes in dryland ecosystems are still not well defined. This article calibrated and analyzed the normalized difference vegetation index(NDVI)time series of Advanced Very-High-Resolution Radiometer(AVHRR) data from 1982 to 2015 in the Loess Plateau, China. The spatial and temporal distributions of vegetation phenology and NPP in the Loess Plateau under semihumid and semiarid conditions were investigated. The seasonal variation in the NPP response to vegetation phenology under the climate change was also analyzed. The results showed that, different from the northern forest, there was distinct spatial heterogeneity in the effect of climate change on the dynamic change in vegetation growth in the Loess Plateau: 1) an advance of the start of the growing season(SOS) and a delay of the end of the growing season(EOS) significantly increased the NPP in spring and autumn, respectively, in the humid southeast;2) in the arid northwest, the NPP did not significantly increase in spring and autumn but significantly decreased in summer.

关键词： climate change normalized difference vegetation index phenology net primary productivity Loess Plateau,China

Effect of quantum therapy on pork quality

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2011年第11期12卷 892-899页

作者： martin BODNáR Jozef NAGY Peter POPELKA Beáta KORéNEKOVá Ján maANGA Alena NAGYOVá Private Veterinary Clinique Kremnická 9040 11 Kosicethe Slovak Republic Department of Food Hygiene and Technology University of Veterinary Medicine and Pharmacy in KosiceKomenského 73041 81 Kosicethe Slovak Republic Department of Environment Veterinary Legislation and EconomicsInstitute of Forensic and Public Veterinary MedicineUniversity of Veterinary Medicine and Pharmacy in KosiceKomenského 73041 81 Kosicethe Slovak Republic

In this study the impact of quantum therapy on meat quality of slaughtered pigs was *** this purpose the pigs were treated with different doses of magnet-infrared-laser(MIL) *** were divided into four groups according to radiation doses(4096,512,and 64 Hz,and control without application),which were applied in the lumbar area of musculus longissimus dorsi(loin) at various time intervals prior to the slaughter(14 d,24 h,and 1 h).Animals were slaughtered and the meat quality was evaluated by determining of pH value(1,3,and 24 h post slaughter),drip loss,colour,and lactic acid and phosphoric acid *** therapy can be used in various fields of veterinary medicine as are surgery and orthopaedics,internal medicine,dentistry,pulmonology,gastroenterology,gynaecology,urology,nephrology,and *** results achieved showed that MIL radiation used in a short period before slaughter(1 h) can cause a change in the meat quality,as reflected by the non-standard development of pH values,increases in drip loss,and changes of meat colour.

关键词： Quantum therapy Meat quality Colour Drip loss Lactic acid pH

Insights into gastric neuroendocrine tumors burden

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Chinese Journal of Cancer Research 2017年第2期29卷 137-143页

作者： taíssa maíra Thomaz Araújo Williams Fernandes Barra André Salim Khayat Paulo Pimentel de Assumpcao Oncology Research Center Federal University of paráPara 66073-005Brazil

Type 1 gastric neuroendocrine tumors （gNETs） are usually small lesions, restricted to mucosal and sub-mucosal layers of corpus and fundus, with low aggressive behavior, for the majority of cases. Nevertheless, some cases present aggressive behavior. The increasing incidence of gNETs brings together a new relevant problem： how to identify potentially aggressive type I gNETs. The challenging problem seems to be finding out signs or features able to predict potentially aggressive cases, allowing a tailored approach, since the involved societies dedicated to provide guidelines for management of these neoplasms apparently failed in producing staging systems able to accurately predict prognosis of these tumors. Additionally, it is also important to try to find out explanations for increasing incidence, as well as to identify potential targets aiming to reach better control of this neoplasia. Here, we discuss potential pathways implicated in aggressive behavior, as well as new strategies to improve clinical management of these tumors.

关键词： gNETs gastrin receptor epidemiology

Phase thermal stability and mechanical properties analyses of(Cr,Fe,V)–(ta,W)multiple-based elemental system using a compositional gradient film

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International Journal of Minerals,Metallurgy and materials 2020年第10期27卷 1379-1387页

作者： Qiu-wei Xing Jiang ma Yong Zhang Beijing Advanced Innovation Center of materials Genome Engineering State Key Laboratory of Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijing 100083China Guangdong Provincial Key Laboratory of Micro/Nano Optomechatronics Engineering College of Mechatronics and Control EngineeringShenzhen UniversityShenzhen 518060China

High-entropy alloys(HEAs)generally possess complex component combinations and abnormal *** traditional methods of investigating these alloys are becoming increasingly inefficient because of the unpredictable phase transformation and the combination of many *** development of compositionally complex materials such as HEAs requires high-throughput experimental methods,which involves preparing many samples in a short *** we apply the high-throughput method to investigate the phase evolution and mechanical properties of novel HEA film with the compositional gradient of(Cr,Fe,V)-(ta,W).First,we deposited the compositional gradient film by ***,the mechanical properties and thermal stability of the(Cr0.33Fe0.33V0.33)x(ta0.5W0.5)100−x(x=13-82)multiplebased-elemental(MBE)alloys were *** the deposited wafer was annealed at 600℃for 0.5 h,the initial amorphous phase was transformed into a body-centered cubic(bcc)structure phase when x=*** were observed on the film surface when x was 72 and ***,the highest hardness of as-deposited films was found when x=18,and the maximum hardness of annealed films was found when x=33.

关键词： high-throughput fabrication hard coating thermal resistance mechanical property phase stability high-entropy alloys

NLO effects for Ω_(QQQ) baryons in QCD Sum Rules

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Chinese Physics C 2021年第9期45卷 44-54页

作者： Ren-Hua Wu Yu-Sheng Zuo Ce Meng Yan-Qing ma Kuang-ta Chao School of Physics and State Key Laboratory of Nuclear Physics and Technology Peking UniversityBeijing 100871China Center for High Energy Physics Peking UniversityBeijing 100871China Collaborative Innovation Center of Quantum matter Beijing 100871China

We study the triply heavy baryonsΩ_(QQQ)(Q=c,b)in the QCD sum rules by performing the first calculation of the next-to-leading order(NLO)contribution to the perturbative QCD part of the correlation *** with the leading order(LO)result,the NLO contribution is found to be very important to theΩ_(QQQ).This is because the NLO not only results in a large correction but also reduces the parameter dependence,making the Borel platform more distinct,especially for the Q_(bbb)in the MS scheme,where the platform appears only at NLO but not at ***,owing to the inclusion of the NLO contribution,the renormalization schemes(MS and On-Shell)dependence and the scale dependence are significantly ***,after including the NLO contribution to the perturbative part in the QCD sum rules,the masses are estimated to be 4.53_)0.11)^(+0.26) GeV forΩ_(ccc) and14.27_(-0.32)^(+0.33) GeV forΩ_(bbb),where the results are obtained atμ=M_(B) with errors including those from the variation of the renormalization scaleμin the range(0.8-1.2)M_(B).A careful study of theμdependence in a wider range is further performed,which shows that the LO results are very sensitive to the choice ofμwhereas the NLO results are considerably *** addition to theμ=M_(B) result,a more stable value,(4.75-4.80)GeV,for theΩ_(ccc) mass is found in the range ofμ=(1.2-2.0)M_(B),which should be viewed as a more relevant prediction in our NLO approach because of μ dependence.

关键词： baryon heavy quark QCD sum rules NLO correction

Impact of chosen force fields and applied load on thin film lubrication

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Friction 2021年第5期9卷 1259-1274页

作者： Thi D.ta Hien D.ta Kiet A.TIEU Bach H.TRAN School of Mechanical MaterialsMechatronicsand Biomedical EngineeringUniversity of WollongongNSW 2522Australia Ho Chi Minh City University of Technology and Education Ho Chi Minh City 800010Vietnam

The rapid development of molecular dynamics(MD)simulations,as well as classical and reactive atomic potentials,has enabled tribologists to gain new insights into lubrication performance at the fundamental ***,the impact of adopted potentials on the rheological properties and tribological performance of hydrocarbons has not been researched *** extensive study analyzed the effects of surface structure,applied load,and force field(FF)on the thin film lubrication of *** lubricant film became more solid‐like as the applied load *** particular,with increasing applied load,there was an increase in the velocity slip,shear viscosity,and *** degree of ordering structure also changed with the applied load but rather *** was also significantly dependent on the surface *** chosen FFs significantly influenced the lubrication performance,rheological properties,and molecular *** adaptive intermolecular reactive empirical bond order(AIREBO)potential resulted in more significant liquid‐like behaviors,and the smallest velocity slip,degree of ordering structure,and shear stress were compared using the optimized potential for liquid simulations of united atoms(OPLS‐UAs),condensed‐phase optimized molecular potential for atomic simulation studies(COMPASS),and ***,classical potentials,such as OPLS‐UA and COMPASS,exhibit more solid‐like behavior than reactive potentials ***,owing to the solid‐like behavior,the lubricant temperatures obtained from OPLS‐UA and COMPASS were much lower than those obtained from AIREBO and *** increase in shear stress,as well as the decrease in velocity slip with an increase in the surface potential parameterζ,remained conserved for all chosen FFs,thus indicating that the proposed surface potential parameterζfor the COMPASS FF can be verified for a wide range of atomic models.

关键词： molecular dynamics simulation force fields applied load tribofilm hydrocarbon