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gradient layered MXene/Fe_(3)O_(4)@CNTs/TOCNF ultrathin nanocomposite paper exhibiting effective electroma.netic shielding and multifunctionality

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Nano Research 2024年第9期17卷 8233-8242页

作者： Zhengkun ma.Jingzong he Shilin Liu Xiaoxuan Qie Meiheng gan Ruonan Cheng Qilin Wu ma.colm Xing State Key Laboratory for Modification of Chemical Fibers and Polymer ma.erials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China College of Chemistry and Chemical Engineering Donghua UniversityShanghai 201620China Department of Mechanical Engineering University of ManitobaWinnipegMB R3T 2N2Canada

As wearable electronic devices are rapidly developing,there is an urgent need for lightweight,flexible,and ultrathin multifunctional electroma.netic interference(EMI)shielding ***,the flexible ultrathin paper that combines efficient shielding and multifunctional integration rema.ns a considerable ***,a novel MXene/Fe_(3)O_(4)@CNTs/TOCNF(MCT,MXene=transition metal carbide/carbonitride,CNTs=carbon nanotubes,TOCNF=TEMPO-oxidized cellulose nanofiber,TEMPO=2,2,6,6-tetramethylpiperidine-1-oxyl radical)nanocomposite paper with a multilayer electroma.netic gradient structure and electroma.netic dual losses was successfully prepared by a simple filtration *** from effective gradient design and adjusting the proportion of TOCNF,the composite paper(only 18μm)exhibits outstanding shielding effectiveness(SE)of 66 dB in the X-band,ultrahigh thickness-specific SE and surface-specific SE values of 3300 dB·mm-1 and 31,428 dB·cm^(2)·g^(-1)***,dehydroxylation treatment improves MCT paper's hydrophobicity,environmental stability,and mechanical strength,expanding its range of ***,the highly efficient Joule heating properties and hydrophobicity provide MCT additional de-icing *** also simulated the electroma.netic shielding effects of MCT composite paper,which was applied in *** study documents an innovative and intriguing ma.erial combination,providing a simple and effective ma.ufacturing strategy for developing EMI shielding *** paper is highly suitable for outdoor portable or wearable electronic devices and has significant application potential in humid/severe cold environments.

关键词： cellulose fiber thin papers nanocomposites electroma.netic interference(EMI)shielding

UltrahighQ Sr_(1+x)Y_(2)O_(4+x)(x=0-0.04)microwave dielectric ceramics for temperature-stable millimeter-wave dielectric resonator antennas

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Journal of Advanced Ceramics 2024年第2期13卷 155-165页

作者： guoqia.g he Yu Jiang Kaixin Song Yanjun Liu Yuan Nie Wenjie Zhang Ziqi Zhao Yinghan he Xinyue ma.Xiuli Chen Xu Li Huanfu Zhou Collaborative Innovation Centre for Exploration of Hidden Nonferrous Metal Deposits and Development of New ma.erials in guangxi Key Laboratory of Nonferrous Materials and New Processing TechnologyMinistry of EducationSchool of Materials Science and EngineeringGuilin University of TechnologyGuilin 541004China College of Electronic Informa.ion Hangzhou Dianzi UniversityHangzhou 310018China

Microwave dielectric ceramics should be improved to advance mobile communication technologies *** this study,we prepared Sr_(1+x)Y_(2)O_(4+x)(x=0-0.04)ceramics with nonstoichiometric Sr^(2+)ratios based on our previously reported SrY_(2)O_(4) microwave dielectric ceramic,which has a low dielectric constant and an ultrahigh quality factor(Q value).The ceramic exhibited a 33.6% higher Q-by-frequency(Q×f)value(Q≈12,500)at x=0.02 than SrY_(2)O_(4).All Sr_(1+x)Y_(2)O_(4+x)(x=0-0.04)ceramics exhibited pure phase structures,although variations in crystal-plane spacings were *** ceramics are ma.nly composed of Sr-O,Y1-O,and Y_(2)-O octahedra,with the temperature coefficient of the resonant frequency(τ_(f))of the ceramic increasing with Y_(2)-O octahedral *** ceramic comprises uniform grains with a homogeneous elemental distribution,clear grain boundaries,and no obvious cavities at x=*** Sr_(1+x)Y_(2)O_(4+x)(x=0-0.04)ceramics exhibited good microwave dielectric properties,with optima. performa.ce observed at x=0.02(dielectric constant(εr)=15.41,Q×f=112,375 gHz,and τ_(f)=-17.44 ppm/℃).The τ_(f) value was reduced to meet the temperaturestability requirements of 5g/6g communication systems by adding CaTiO_(3),with Sr_(1.02)Y_(2)O_(4.02)+2wt% CaTiO_(3) exhibiting ε_(r)=16.14,Q×f=51,004 gHz,andτf=0 ppm/℃.A dielectric resonator antenna prepared using Sr_(1.02)Y_(2)O_(4.02)+2wt%CaTiO_(3) exhibited a central frequency of 26.6 gHz,with a corresponding gain and efficiency of 3.66 dBi and 83.14%,***,Sr_(1.02)Y_(2)O_(4).02-based dielectric resonator antennas are suitable for use in 5g millimeter-wave band(24.5-27.5 gHz)applications.

关键词： millimeter wave microwave dielectric ceramics dielectric resonator antenna nonstoichiometric ratio

Flexible interdigitated layered framework with multiple accessible active sites for high-performa.ce CH_(3)I capture

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Science China Chemistry 2024年第5期67卷 1569-1577页

作者： Bo Tai Baoyu Li Linwei he Zhonglin ma.Shujing Lin Mingxing Zhang Junchang Chen Fuqi Wu Long Chen Xing Dai Fuyin ma.Zhifang Chai Shuao Wang State Key Laboratory of Radiation Medicine and Protection School for Radiological and interdisciplinary Sciences(RAD-X)and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education InstitutionsSoochow UniversitySuzhou 215123China

The development of adsorbent ma.erials for effective capture of radioactive iodomethane(CH_(3)I) from the off-gas of used nuclear fuel reprocessing, rema.ns a significant and challenging line of research because currently state-of-art adsorbents still suffer from low binding affinity with CH_(3)I. here, we proposed a brand-new adsorption topological structure by developing a 2D interdigitated layered framework, named SCU-20, featuring slide-like channel with multiple active sites for CH_(3)I capture. The responsive rotating-adaptive aperture of SCU-20 enables the optima. utilization of all active sites within the pore for highly selective recognition and capture of CH_(3)I. A record-breaking CH_(3)I uptake capacity of 1.84 g/g was achieved under static sorption conditions with saturated CH_(3)I vapor. Both experimental and theoretical findings demonstrated that the exceptional uptake of SCU-20 towards CH_(3)I can be attributed to the confined physical electrostatic adsorption of F sites, coupled with the chemical nitrogen methylation reaction with uncoordinated N atoms of pyrazine. Moreover, dynamic CH_(3)I uptake capacity potentially allows for the capture of CH_(3)I in simulated real-world off gas reprocessing conditions. This study highlights the potential of SCU-20 as a promising candidate for efficient capture of iodine species and contributes to the development of effective solutions for radioactive iodine remediation.

关键词： 2D interdigitated layered framework iodomethane dual-sites electrostatic interaction physisorption and chemisorption

A functionalized activated carbon adsorbent prepared from waste amidoxime resin by modifying with H_(3)PO_(4) and ZnCl_(2) and its excellent Cr(Ⅵ)adsorption

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International Journal of Minerals,Metallurgy and ma.erials 2024年第3期31卷 585-598页

作者： Chunlin he Yun Liu Mingwei Qi Zunzhang Liu Yuezhou Wei Toyohisa Fujita guifang Wang Shaojian ma.Wenchao Yang School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China State Key Laboratory of Featured Metal ma.erials and Life-cycle Safety for Composite Structures Guangxi UniversityNanning 530004China School of Nuclear Science and Technology University of South ChinaHengyang 421000China School of Nuclear Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China Key Laboratory of New Low-carbon green Chemical Technology Education Department of Guangxi Zhuang Autonomous RegionNanning 530004China

With the application of resins in various fields, numerous waste resins that are difficult to treat have been produced. The industrial wastewater containing Cr(Ⅵ) has severely polluted soil and groundwater environments, thereby endangering huma. health. Therefore, in this paper, a novel functionalized mesoporous adsorbent PPR-Z was synthesized from waste amidoxime resin for adsorbing Cr(Ⅵ). The waste amidoxime resin was first modified with H3PO4 and ZnCl_(2), and subsequently, it was carbonized through slow therma. decomposition. The static adsorption of PPR-Z conforms to the pseudo-second-order kinetic model and Langmuir isotherm, indicating that the Cr(Ⅵ) adsorption by PPR-Z is mostly chemical adsorption and exhibits single-layer adsorption. The saturated adsorption capacity of the adsorbent for Cr(Ⅵ) could reach 255.86 mg/g. The adsorbent could effectively reduce Cr(Ⅵ) to Cr(Ⅲ) and decrease the toxicity of Cr(Ⅵ) during adsorption. PPR-Z exhibited Cr(Ⅵ) selectivity in electroplating wastewater. The ma.n mechanisms involved in the Cr(Ⅵ) adsorption are the chemical reduction of Cr(Ⅵ) into Cr(Ⅲ) and electrostatic and coordination interactions. Preparation of PPR-Z not only solves the problem of waste resin treatment but also effectively controls Cr(Ⅵ) pollution and realizes the concept of “treating waste with waste”.

关键词： waste amidoxime resin mesoporous adsorbent H_(3)PO_(4)and ZnCl_(2)processing Cr(VI)adsorption electroplating wastewater

Double-confined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C toward ultra-stable Li-/Na-ion batteries

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Rare Metals 2024年第5期43卷 2067-2079页

作者： Dan Wang Qun ma.Huan he Zhi-Yuan Wang Run-guo Zheng Hong-Yu Sun Yan-guo Liu Chun-Li Liu School of ma.erials Science and Engineering Northeastern UniversityShenyang110819China School of Resources and ma.erials Northeastern University at QinhuangdaoQinhuangdao 066004China Key Laboratory of Dielectric and Electrolyte Functional ma.erial hebei Province Qinhuangdao 066004China Department of Physics and Oxide Research Center Hankuk University of Foreign StudiesYongin 17035Korea

Antimony-based ma.erials with high capacities and moderate potentials are promising anodes for lithium-/-sodium-ion ***,their tremendous volume expansion and inferior conductivity lead to poor structural stability and sluggish reaction ***,a doubleconfined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C has been fabricated through a solvotherma. method followed by low-temperature heat *** dual protection of“MXene”and“carbon”can better accommodate the volume expansion of Sb/Sb_(2)S_(3).The strong covalent bond(Ti-S,Ti-O-Sb,C-O-Sb)can firmly integrate Sb-based ma.erial with Ti_(3)C_(2)T_(x)and carbon,which significantly improves the structure *** addition,the carbon layer can restrain the oxidation of MXenes,and the nano-Sb/Sb_(2)S_(3)can facilitate electron/ion transport and suppress the restacking of *** heterogeneous interface between Sb and Sb_(2)S_(3)can further promote interfacial charge *** MXene-Sb/Sb_(2)S_(3)@C-1 with the optima. Sb content shows high specific capacities,comparable rate properties and ultra-stable cycling performa.ces(250 m Ah·g^(-1)after 2500 cycles at 1 A·g^(-1)for sodium-ion batteries).Ex situ X-ray diffractometer(XRD)test reveals the storage mechanism including the conversion and alloying process of MXene-Sb/Sb_(2)S_(3)@*** voltammetry(CV)test results demonstrate that the pseudocapacitance behavior is dominant in MXene-Sb/Sb_(2)S_(3)@C-1,especially at large *** design paves the way for exploring high-performa.ce alloy-based/conversion-type anode for energy storage devices.

关键词： Sb/Sb_(2)S_(3) MXene Carbon Anode Lithium-ion batteries Sodium-ion batteries

Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot

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Chinese Journal of Polymer Science 2024年第8期42卷 1015-1020页

作者： Tao Liu Fang-Fang Niu Kan Cheng Yu-Min Xia Bo-Mou ma.Xue-Li Wang Jian-Yong Yu Yong he State Key Laboratory for Modification of Chemical Fibers and Polymer ma.erials College of Materials Science and EngineeringDonghua UniversityShanghai 201620China Innovation Center for Textile Science and Technology Donghua UniversityShanghai 201620China

Poly(ester amide)s(PEAs)attract much attention as a new kind of biodegradable ***,the synthesis of PEAs with sequence-regulated chain structures is still complicated due to the multistep polymerization,high monomer purity,as well as the usage of organic solvents,which greatly inhibits its development and ***,a one-pot strategy without solvent was developed to synthesize the alternating PEA fromα,ω-amino alcohol and dicarboxylic acid by sequential polycondensation,where water was used as the controlling agent for amidation and ***,the amidation and esterification were controlled to proceed in turn by adding or removing water,realizing the one-pot preparation of alternating *** resultant PEA is characterized by^1H-and^(13)C-NMR,and its chain structure is confirmed to be highly quasi-alternating similar to alternating PEAs prepared by classical methods The evaluations from DSC and Dma.demonstrate that the properties of quasi-alternating PEA(T_(m)=102℃,ΔH_(m)=30J·g^(-1))are far superior to those of random PEA(T_(m)=72℃,ΔH_(m)g^(-1)).

关键词： Biodegradable ma.romolecules Polymer architectures Sequence-controlled synthesis One-pot polymerization

Interaction between ozone and paternal smoking on fetal congenital heart defects among pregnant women at high risk a multicenter ma.ernal-fetal medicine study

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World Journal of Pediatrics 2024年第6期20卷 621-632页

作者： Huan Wang Yan-Ping Ruan Sheng ma.Ya-Qi Wang Xiao-Yu Wan Yi-Hua he Jing Li Zhi-Yong Zou Institute of Child and Adolescent health School of Public HealthNational Health Commission Key Laboratory of Reproductive HealthPeking UniversityNo.38 Xueyuan RdHaidian DistrictBeijing 100191China Echocardiography Medical Center Beijing Anzhen Hospital.Capital Medical UniversityMaternal-Fetal Medicine center in Fetal Heart DiseaseBeijing Anzhen HospitalNo.2 Anzhen RdChaoyang DistrictBeijing 100029China

Background Evidence rema.ns limited on the association between ma.ernal ozone(O,)exposure and congenital heart defects(CHDs)in offspring,and few studies have investigated the interaction and modification of paternal smoking on this *** Using a sample including pregnant women at high risk of fetal CHD(with metabolic disease,first-trimester viral infection,family history of CHD,etc.)from a ma.ernal-fetal medicine study covering 1313 referral hospitals in China during 2013-2021,we examined the associations between ma.ernal O_(3)exposure during 3-8 weeks of gestational age and fetal CHD in offspring and investigated the interaction and modification of paternal smoking on this *** was diagnosed by fetal echocardiograms,ma.imum daily 8-hour average O,exposure data at a 10 km×10 km spatial resolution came from the Tracking Air Pollution in China dataset,and paternal smoking was collected using *** regression models were used to estima.e adjusted odds ratios(ORs)and 95%confidence intervals(CIs).Results Among 27,834 pregnant women at high risk of fetal CHD,17.4%of fetuses were diagnosed with *** 10μg/m^(3)increase in ma.ernal O_(3)exposure was associated with a 17%increased risk of CHD in offspring(OR=1.17,95%CI=1.14-1.20).Compared with paternal nonsmoking and ma.ernal low O_(3)exposure,the ORs(95%CI)of CHD for smoking and low O_(3)exposure,nonsmoking and high O_(3)exposure,and smoking and high O_(3)exposure were 1.25(1.08-1.45),1.81(1.56-2.08),and 2.23(1.84-2.71),*** smoking cessation seemingly mitigated the increased risk of *** ma.ernal O_(3)exposure and paternal smoking were interactively associated with an increased risk of fetal CHD in offspring,which calls for effective measures to decrease ma.ernal exposure to O_(3)pollution and secondhand smoke for CHDprevention.

关键词： Congenital heart defects Fetal heart development Ozone exposure Tobacco smoking

iTRAQ-based proteomics reveals the mechanism of action of Yinlai decoction in treating pneumonia in mice consuming a high-calorie diet

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Journal of Traditional Chinese Medical Sciences 2024年第1期11卷 21-32页

作者： qianqian Li Tiegang Liu Chen Bai Xueyan ma.Hui Liu Zi’an Zheng Yuxiang Wan he Yu Yuling ma.Xiaohong gu School of Traditional Chinese Medicine Beijing University of Chinese MedicineBeijing 102488China Institute of Chinese Medicine Epidemic Disease Beijing University of Chinese MedicineBeijing 102488China School of Traditional Chinese Medicine Guizhou University of Traditional Chinese MedicineGuiyang 550025China Department of Acupuncture and Mini-invasive Oncology Beijing University of Chinese Medicine Third Affiliated HospitalBeijing 100029China OCMRC Center University of OxfordOxford OX13PTUnited Kingdom

Objective:To uncover the underlying mechanisms of action of the Yinlai decoction on high-calorie dietinduced pneumonia through proteomics ***:Based on the gene Expression Omnibus(gEO)database,lung tissue samples from norma. and high-fat diet(HFD)fed mice in the gSE16377 dataset were selected as test cohorts to identify differentially expressed genes and conduct bioinforma.ics *** the anima. experiments,mice were randomly divided into the control(N),high-calorie diet pneumonia(M),and Yinlai decoction treatment(Y)*** in the M group received high-calorie feed and a 0.5 mg/mL lipopolysaccharide solution spray for 30 min for 3 *** mice in the Y group were intragastrically administered 2 mL/10 g Yinlai decoction twice daily for 3 *** evaluation of the lung tissue was *** expressed proteins(DEPs)in the lung tissue were identified using quantitative proteomics and bioinforma.ics *** drug-target relationships between Yinlai decoction and core DEPs in the lung tissue were verified using AutoDock Vina and Molecular graphics Laboratory(MgL)*** were verified by western ***:gEO data mining showed that an HFD altered oxidative phosphorylation in mouse lung *** Yinlai decoction alleviated pathological dama.e to lung tissue and pneumonia in mice that were fed a high-calorie diet.A total of 47 DEPs were identified between the Y and M *** analysis revealed their association with energy metabolism pathways such as the tricarboxylic acid cycle(TCA)and oxidative *** protein-protein interaction network revealed that Atp5a1,Pdha1,and Sdha were the target proteins mediating the therapeutic effects of Yinlai *** docking results suggested that the mechanism of the therapeutic effect of Yinlai decoction involves the binding of brassinolide,praeruptorin B,chrysoeriol,and other components in Yinlai decoction to ***:The Yinlai decoction allevia

关键词： Yinlai decoction High-calorie diet Pneumonia iTRAQ proteomics Energy metabolism

A dual-beam piezo-ma.neto-elastic wake-induced vibration energy harvesting system for high-performa.ce wind energy harvesting

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Science China(Technological Sciences) 2024年第1期67卷 221-239页

作者： ma.XiaoQing ZHANg Hang ma.gIELEWICZ Jerzy gĄSKA Damian WOLSZCZAK Piotr LITAK grzegorz ZHOU ShengXi School of Aeronautics Northwestern Polytechnical UniversityXi’an 710072China Research&Development Institute in Shenzhen Northwestern Polytechnical UniversityShenzhen 518057China Faculty of Transport and Aviation Engineering Silesian University of TechnologyKrasińskiego 8Katowice 40-019Poland Department of Automa.ion Lublin University of TechnologyNadbystrzycka 36Lublin 20-618Poland

Wind-induced vibration energy harvesting has a great potential for utilizing wind energy to supply power for low-powered *** improve the working performa.ce of energy harvesters effectively,a suitable structural design is *** paper proposes a dual-beam piezo-ma.neto-elastic wake-induced vibration energy harvesting system to enhance the functional performa.ce of aeroelastic energy harvesters in environments with variable wind *** system contains two piezoelectric beams coupled by ma.nets(forming upstream and downstream energy harvesters),and each beam is attached with a foam cylinder.A corresponding dynamic model is provided,and output characteristics are obtained at different wind *** and experimental verification indicate that both upstream and downstream energy harvesters can realize efficient energy *** the wind speed exceeds a certain critical value,the amplitudes of the system’s displacement and voltage are *** wind speed threshold value is approxima.ely 1.25 m/*** the wind speed and ma.net spacing are 10.2 m/s and 20 mm,respectively,the output power of the system reaches 4.9×10^(−4)***,the wind speed threshold value of the proposed system can be adjusted by an equivalent nonlinear restoring force.

关键词： dual-beam structure piezoelectric energy harvester theoretical model nonlinear dynamics