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Thermally activated delayed fluorescence enhanced by macrocyclization

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Science China Chemistry 2025年

作者： Shuo Li Chenghao zhu Lijun mao Xin Zhang Zecong Ye Chunju Li Da ma School of Pharmaceutical and Chemical Engineering & Institute for Advanced Studies Taizhou University School of Chemical Engineering and Light Industry Guangdong University of Technology Tianjin Key Laboratory of Structure and Performance for Functional Molecules Tianjin Normal University

Thermally activated delayed fluorescence (TADF) depends on reverse intersystem crossing (RISC) from the lowest triplet to the singlet excited state. Here, a macrocyclization strategy is developed to achieve TADF emission by promoting RISC. 5-(9Hcarbazol-9-yl) isophthalonitrile, a fluorescent molecule, is coupled with 1,4-dimethoxybenzene by methylene bridges to form a macrocycle with TADF emission. Experimental results and theoretical calculation indicate that the macrocyclization strategy contributes to RISC promotion and suppression of nonradiative decay, resulting in effective TADF emission transformed from prompt fluorescence. Three TADF luminophores are cyclized with the same strategy, and an enhanced TADF emission of up to3.8 folds is observed. The marriage of macrocycle chemistry and luminescent materials will provide new guidelines for designing efficient TADF materials.

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水耕时间对低丘水田土壤发育的影响

土壤通报 2022年第2期53卷 253-261页

作者：麻万诸章明奎丁志峰杨琼瑶朱康莹浙江省农业科学院数字农业研究所浙江杭州310021 浙江大学环境与资源学院浙江杭州310058

【目的】了解水耕时间对亚热带低丘水田土壤性态的影响,对水耕土壤进行正确分类。【方法】在浙江省金衢盆地内选择坡麓和岗地二种地貌单元,观测不同水耕时间的第四纪红土发育水田土壤的剖面形态特征,分层采集土样分析土壤理化性状。【... 详细信息

【目的】了解水耕时间对亚热带低丘水田土壤性态的影响,对水耕土壤进行正确分类。【方法】在浙江省金衢盆地内选择坡麓和岗地二种地貌单元,观测不同水耕时间的第四纪红土发育水田土壤的剖面形态特征,分层采集土样分析土壤理化性状。【结果】随着水耕时间的增加,土壤颜色由红转黄,色调由2.5YR向7.5YR或10YR演变;表层土壤黏粒含量逐渐下降,有机质与全磷及有效磷积累,pH、阳离子交换量和活性铁逐渐增加,土壤游离氧化铁逐渐下移淀积;水耕时间对土壤性状的影响由表层向心土层发展。调查表明,由于水分条件的差异,水耕时间对坡麓地带水田土壤性状的影响大于岗地水田。【结论】由第四纪红土旱地改为水田,形成典型水耕人为土约15 a,形成铁聚水耕人为土约150 a以上,水耕时间低于150 a主要形成简育水耕人为土;随着水稻种植时间的增加,活性有机质占有机质的比例随有机质积累同步增加,水稻土心土层具有较强的固碳潜力。

关键词：第四纪红土发生学性状水耕时间水耕人为土土壤类型演变固碳

CNKSR2 interactome analysis indicates its association with the centrosome/microtubule system

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Neural Regeneration Research 2025年第8期20卷 2420-2432页

作者： Lin Yin Yalan Xu Jie Mu Yu Leng Lei ma Yu Zheng Ruizhi Li Yin wang Peifeng Li Hai zhu Dong wang Jing Li Institute for Translational Medicine The Affiliated Hospital of Qingdao UniversityMedical CollegeQingdao UniversityQingdaoShandong ProvinceChina School of Basic Medicine Qingdao UniversityQingdaoShandong ProvinceChina College of Life Sciences and School of PharmacyMedical CollegeQingdao UniversityQingdaoShandong ProvinceChina Department of Urology Qingdao Municipal Hospital Affiliated to Qingdao UniversityQingdaoShandong ProvinceChina

The protein connector enhancer of kinase suppressor of Ras 2(CNKSR2),present in both the postsynaptic density and cytoplasm of neurons,is a scaffolding protein with several protein-binding *** of the CNKSR2 gene have been implicated in neurodevelopmental disorders,particularly intellectual disability,although the precise mechanism involved has not yet been fully *** has demonstrated that CNKSR2 plays a role in facilitating the localization of postsynaptic density protein complexes to the membrane,thereby influencing synaptic signaling and the morphogenesis of dendritic ***,the function of CNKSR2 in the cytoplasm remains to be *** this study,we used immunoprecipitation and high-resolution liquid chromatography-mass spectrometry to identify the interactors of *** a combination of bioinformatic analysis and cytological experiments,we found that the CNKSR2 interactors were significantly enriched in the proteome of the *** also showed that CNKSR2 interacted with the microtubule protein DYNC1H1 and with the centrosome marker *** colocalization analysis confirmed the centrosomal localization of *** we downregulated CNKSR2 expression in mouse neuroblastoma cells(Neuro 2A),we observed significant changes in the expression of numerous centrosomal *** manipulation also affected centrosome-related functions,including cell size and shape,cell proliferation,and ***,we found that CNKSR2 interactors were highly enriched in de novo variants associated with intellectual disability and autism spectrum *** findings establish a connection between CNKSR2 and the centrosome,and offer new insights into the underlying mechanisms of neurodevelopmental disorders.

关键词： autism spectrum disorder centrosome CNKSR2 intellectual disability interactome mass spectrometry microtubule neurodevelopmental disease protein complexes protein-protein interactions

Steel surface defect detection based on lightweight YOLOv7

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Optoelectronics Letters 2025年

作者： Shi Tao Wu Rongxin zhu Wenxu ma Qingliang School of Electrical Engineering and Automation， Tianjin University of Technology North China University of Science and Technology， College of Electrical Engineering Guangzhou Institute of Measurement and Testing Technology

Aiming at the problems of low detection efficiency and difficult positioning of traditional steel surface defect detection methods， a lightweight steel surface defect detection model based on YOLOv7 is proposed. First， a CSS Block module is proposed， which uses more lightweight operations to obtain redundant information in the feature map， reduces the amount of computation， and effectively improves the detection speed. Secondly， the improved SPPCSPC structure is adopted to ensure that the model can also pay attention to the defect location information while predicting the defect category information， obtain richer defect features. In addition， the convolution operation in the original model is simplified， which significantly reduces the size of the model and helps to improve the detection speed. Finally， using EIOU Loss to focus on high-quality Anchors， speed up convergence and improve positioning accuracy. Experiments were carried out on the NEU-DET steel surface defect dataset. Compared with the original YOLOv7 model， the number of parameters of this model was reduced by 40%， the FPS reached 112， and the average accuracy reached 79.1%.， the detection accuracy and speed have been improved， which can meet the needs of steel surface defect detection.

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Late Paleozoic to early Mesozoic volcanic-sedimentary history of the southeastern margin of the Central Asian Orogenic Belt: Timing of uplift of the Inner Mongolia paleo-uplift

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Science China Earth Sciences 2025年第1期68卷 297-309页

作者： Wenxing HAO Jin-Hui YANG Guang zhu State Key Laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences School of Resource and Environmental Engineering Hefei University of Technology

The Kulun region is located in the eastern Bainaimiao arc belt on the southeastern margin of the Central Asian Orogenic Belt(CAOB), adjacent to the North China Craton(NCC) to the south. This region records the closure of the PaleoAsian Ocean during the Paleozoic to early Mesozoic and is key to study the tectonic evolution of the northern margin of the *** conducted zircon U-Pb geochronology and Hf isotope analysis of volcanic-sedimentary and intrusive rocks in the Kulun region. The volcanic-sedimentary rocks were previously assigned an early Carboniferous age, but include volcanic rocks with ages of 267–266 ma and sedimentary rocks with youngest detrital zircon age peaks of 265–244 ma, which were intruded by a granite with an age of 242 ma. This indicates that these rocks are actually middle Permian to Middle Triassic in age(267–242ma) and correspond to the Qingfengshan and Liujiagou formations. Moreover, two volcanic rock samples have high εHf(t) values(+1.6 to +16.1) and relatively young two-stage Hf model ages(1095–327 ma), indicating their sources associated with the CAOB. The age spectra and Hf isotopic characteristics of detrital zircons from the sedimentary rocks suggest that, during the middle Permian to Middle Triassic, the sedimentary provenance in the Kulun region was mainly the CAOB. However, by the Early Jurassic, the provenance changed to the NCC(i.e., the Inner Mongolia Paleo-uplift, IMPU). This result, combined with the development of a series of conglomerates on the northern margin of the NCC in the Late Triassic(i.e., Xingshikou, Xiaoyingzi,and Xiaohekou formations), indicates the Kulun region experienced an abrupt change in paleogeography during the Late Triassic, with the IMPU undergoing significant uplift and thus becoming the main sediment source in the Kulun region. Based on the Late Triassic alkaline igneous belt(235–215 ma) in the IMPU, we speculate that this uplift was caused by detachment of the southward-subducting Paleo-Asian oceanic

关键词： Central Asian Orogenic Belt the North China Craton Zircon geochronology Hf isotopes Inner Mongolia Paleo-uplift

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重金属与土壤环境质量及食物安全问题研究

中国生态农业学报 2007年第2期15卷 197-200页

作者：吕晓男孟赐福麻万诸浙江省农业科学院环境资源与土壤肥料研究所杭州310021

As、Cd、Hg、Pb和Se是对食物链造成污染的最重要元素。简述了土壤环境质量的内涵,讨论了重金属污染的现状、特性、来源以及重金属与食物安全的关系,并提出治理重金属污染的途径与方法。

关键词：重金属土壤环境质量食物安全

闽浙两省水耕人为土的优势类型及其分布特点研究

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土壤通报 2016年第5期47卷 1025-1028页

作者：陈小梅姚玉才麻万诸章明奎浙江大学环境与资源学院浙江杭州310058 浙江省农业科学院数字农业研究所浙江杭州310021

调查采样分析了福建和浙江两省92个典型水耕人为土剖面,探讨了两省水耕人为土的优势类型及其分布规律。结果表明,铁聚水耕人为土和简育水耕人为土是主要类型,潜育水耕人为土和铁渗水耕人为土分布相对较少。调查共检出9个水耕人为土亚类... 详细信息

调查采样分析了福建和浙江两省92个典型水耕人为土剖面,探讨了两省水耕人为土的优势类型及其分布规律。结果表明,铁聚水耕人为土和简育水耕人为土是主要类型,潜育水耕人为土和铁渗水耕人为土分布相对较少。调查共检出9个水耕人为土亚类,主要属于"普通"、"铁聚"、"漂白"和"底潜"类别的亚类。潜育水耕人为土主要分布在山垅、水网平原和河谷平原;铁渗水耕人为土集中分布在河谷平原和丘陵山地;铁聚水耕人为土主要分布在河谷平原和丘陵山地;简育水耕人为土在丘陵山地分布较多,在水网平原、滨海平原和河谷平原也均有分布。各类水耕人为土的"漂白"亚类则主要分布在丘陵坡地或河谷与丘陵的过渡区域。

关键词：水耕人为土优势类别分布特点诊断层诊断特性

maintaining moderate levels of hypochlorous acid promotes neural stem cell proliferation and differentiation in the recovery phase of stroke

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Neural Regeneration Research 2025年第3期20卷 845-857页

作者： Lin-Yan Huang Yi-De Zhang Jie Chen Hai-Di Fan wan wang Bin wang Ju-Yun ma Peng-Peng Li Hai-Wei Pu Xin-Yian Guo Jian-Gang Shen Su-Hua Qi School of Medical Technology Xuzhou Key Laboratory of Laboratory DiagnosticsXuzhou Medical UniversityXuzhouJiangsu ProvinceChina School of Pharmacy Xuzhou Medical UniversityXuzhouJiangsu ProvinceChina Department of Laboratory Medicine Branch Hospital of Huai’an First People’s HospitalHuai’anJiangsu ProvinceChina Department of Laboratory Medicine the Affiliated Hospital of Xuzhou Medical UniversityXuzhouJiangsu ProvinceChina School of Chinese Medicine The University of Hong KongHong Kong Special Administrative RegionChina

It has been shown clinically that continuous removal of ischemia/reperfusion-induced reactive oxygen species is not conducive to the recovery of late ***,previous studies have shown that excessive increases in hypochlorous acid after stroke can cause severe damage to brain *** previous studies have found that a small amount of hypochlorous acid still exists in the later stage of stroke,but its specific role and mechanism are currently *** simulate stroke in vivo,a middle cerebral artery occlusion rat model was established,with an oxygen-glucose deprivation/reoxygenation model established in vitro to mimic *** found that in the early stage(within 24 hours)of ischemic stroke,neutrophils produced a large amount of hypochlorous acid,while in the recovery phase(10 days after stroke),microglia were activated and produced a small amount of hypochlorous ***,in acute stroke in rats,hypochlorous acid production was prevented using a hypochlorous acid scavenger,taurine,or myeloperoxidase inhibitor,4-aminobenzoic acid *** results showed that high levels of hypochlorous acid(200μM)induced neuronal apoptosis after oxygen/glucose deprivation/***,in the recovery phase of the middle cerebral artery occlusion model,a moderate level of hypochlorous acid promoted the proliferation and differentiation of neural stem cells into neurons and *** suggests that hypochlorous acid plays different roles at different phases of cerebral ischemia/reperfusion *** levels of hypochlorous acid(5 and 100μM)promoted nuclear translocation ofβ-*** transfection of single-site mutation plasmids,we found that hypochlorous acid induced chlorination of theβ-catenin tyrosine 30 residue,which promoted nuclear ***,our study indicates that maintaining low levels of hypochlorous acid plays a key role in the recovery of neurological function.

关键词： cell differentiation cerebral ischemia/reperfusion injury chlorination hypochlorous acid microglia neural stem cell neurogenesis nuclear translocation stroke β-catenin

Staged dendrite suppression for high safe and stable lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第1期100卷 674-683页

作者： Jun Jiang Zhenjie Lu Yanwen Ding Shujun Liu Zhijie Qi Tian Tang Yunfan Zhang Zhiyuan ma Jingwen Sun Liang Xue Wenyao Zhang Pan Xiong Xin wang Junwu zhu Yongsheng Fu Key Laboratory for Soft Chemistry and Functional materials of Ministry of Education Nanjing University of Science and Technology Jiangsu Pylon Battery Co.Ltd

The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur ***,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene （PP） *** uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition *** importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance（145.88 MPa） of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium *** Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 ma cm-2with a polarization voltage of only 29.3 ***,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity *** improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.

关键词： Ductility