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magnetron sputtered nickel oxide with suppressed interfacial defect states for efficient inverted perovskite solar cells

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Journal of Energy Chemistry 2025年第1期100卷 348-355页

作者： Guoqiang ma Qin Tan Zhaoning Li Jingwei Xiu Jiafeng Wang Tianle Cheng dong he Qiang Sun Xuhang ma Francesco Lamberti Zhubing he Department of materials Science and Engineering Institute of Innovative Materials (I2M) Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG)Southern University of Science and Technology (SUSTech) Core Research Facilities Southern University of Science and Technology Department of Chemical Sciences Department of Industrial Engineering University of Padova

Widely used spin-coated nickle oxide （NiOx） based perovskite solar cells often suffer from severe interfacial reactions between the NiOxand adjacent perovskite layers due to surface defect states,which inherently impair device performance in a long-term view,even with surface molecule *** this study,we developed high-quality magnetron-sputtered NiOxthin films through detailed process optimization,and compared systematically sputtered and spin-coated NiOxthin film surfaces from materials to *** sputtered NiOxfilms exhibit improved crystallinity,smoother surfaces,and significantly reduced Ni3+or Ni vacancies compared to their spin-coated ***,the interface between the perovskite and sputtered NiOxfilm shows a substantially reduced density of defect *** solar cells （PSCs） fabricated with our optimally sputtered NiOxfilms achieved a high power conversion efficiency （PCE） of up to 19.93%and demonstrated enhanced stability,maintaining 86.2% efficiency during 500 h of maximum power point tracking under one standard sun ***,with the surface modification using (4-(2,7-dibromo-9,9-dimethylacridin-10（9H）-yl)butyl)p hosphonic acid （DmacPA）,the device PCE was further promoted to 23.07%,which is the highest value reported for sputtered NiOxbased PSCs so far.

关键词： Nickle oxide magnetron sputter Defect Stability Perovskite solar cell

Interaction of major facilitator superfamily domain containing 2A with the blood-brain barrier

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Neural Regeneration Research 2025年第8期20卷 2133-2152页

作者： Yilun ma Taiwei dong Fei Luan Juanjuan Yang Feng Miao Peifeng Wei College of Pharmacy and First Clinical Medical College Shaanxi University of Chinese MedicineXianyangShaanxi ProvinceChina National Drug Clinical Trial Agency The Second Affiliated Hospital of Shaanxi University of Chinese Medicine/Xixian New District Central HospitalXi′anShaanxi ProvinceChina

The functional and structural integrity of the blood-brain barrier is crucial in maintaining homeostasis in the brain microenvironment;however,the molecular mechanisms underlying the formation and function of the blood-brain barrier remain poorly *** major facilitator superfamily domain containing 2A has been identified as a key regulator of blood-brain barrier *** plays a critical role in promoting and maintaining the formation and functional stability of the blood-brain barrier,in addition to the transport of lipids,such as docosahexaenoic acid,across the blood-brain ***,an increasing number of studies have suggested that major facilitator superfamily domain containing 2A is involved in the molecular mechanisms of blood-brain barrier dysfunction in a variety of neurological diseases;however,little is known regarding the mechanisms by which major facilitator superfamily domain containing 2A affects the blood-brain *** paper provides a comprehensive and systematic review of the close relationship between major facilitator superfamily domain containing 2A proteins and the blood-brain barrier,including their basic structures and functions,cross-linking between major facilitator superfamily domain containing 2A and the blood-brain barrier,and the in-depth studies on lipid transport and the regulation of blood-brain barrier *** comprehensive systematic review contributes to an in-depth understanding of the important role of major facilitator superfamily domain containing 2A proteins in maintaining the structure and function of the blood-brain barrier and the research progress to *** will not only help to elucidate the pathogenesis of neurological diseases,improve the accuracy of laboratory diagnosis,and optimize clinical treatment strategies,but it may also play an important role in prognostic *** addition,the effects of major facilitator superfamily domain containing 2A on blood-brain barrier lea

关键词： blood-brain barrier(BBB) caveolin-1 central nervous system docosahexaenoic acid endothelial cells lysophosphatidylcholine major facilitator superfamily domain containing 2A(MFSD2A) transcytosis

Small extracellular vesicles derived from human induced pluripotent stem cell-differentiated neural progenitor cells mitigate retinal ganglion cell degeneration in a mouse model of optic nerve injury

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Neural Regeneration Research 2025年第2期20卷 587-597页

作者： Tong Li Hui-Min Xing Hai-dong Qian Qiao Gao Sheng-Lan Xu Hua ma Zai-Long Chi State Key Laboratory of Ophthalmology Optometry and Visual ScienceEye HospitalWenzhou Medical UniversityWenzhouZhejiang ProvinceChina National Clinical Research Center for Ocular Diseases Eye HospitalWenzhou Medical UniversityWenzhouZhejiang ProvinceChina

Several studies have found that transplantation of neural progenitor cells(NPCs)promotes the survival of injured ***,a poor integration rate and high risk of tumorigenicity after cell transplantation limits their clinical *** extracellular vesicles(sEVs)contain bioactive molecules for neuronal protection and *** studies have shown that stem/progenitor cell-derived sEVs can promote neuronal survival and recovery of neurological function in neurodegenerative eye diseases and other eye *** this study,we intravitreally transplanted sEVs derived from human induced pluripotent stem cells(hiPSCs)and hiPSCs-differentiated NPCs(hiPSC-NPC)in a mouse model of optic nerve *** results show that these intravitreally injected sEVs were ingested by retinal cells,especially those localized in the ganglion cell *** with hiPSC-NPC-derived sEVs mitigated optic nerve crush-induced retinal ganglion cell degeneration,and regulated the retinal microenvironment by inhibiting excessive activation of *** analysis further revealed that hiPSC-NPC derived sEVs transported neuroprotective and anti-inflammatory miRNA cargos to target cells,which had protective effects on RGCs after optic nerve *** findings suggest that sEVs derived from hiPSC-NPC are a promising cell-free therapeutic strategy for optic neuropathy.

关键词： exosome miRNA neural progenitor cell neurodegeneration neuroinflammation neuroprotection optic nerve crush optic neuropathy retinal ganglion cell small extracellular vesicles

Enhanced solid-electrolyte interface efficiency for practically viable hydrogen-air fuel cell systems

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Journal of Energy Chemistry 2025年第1期100卷 356-368页

作者： Venkitesan Sakthivel dong Jin Yoo Graduate School Department of Energy Storage/Conversion Engineering (BK21 FOUR) Hydrogen and Fuel Cell Research Center Jeonbuk National University Jeonju Department of Life Science Jeonbuk National University

Proton exchange membrane fuel cells （PEMFCs） provide an appealing sustainable energy system,with the solid-electrolyte membrane playing a crucial role in its overall ***,sulfonated poly（1,4-phenylene ether-ether sulfone）(SPEES),an aromatic hydrocarbon polymer,has garnered considerable attention as an alternative to Nafion ***,the long-term durability and stability of SPEES present a significant *** this context,we introduce a potential solution in the form of an additive,specifically a core–shell-based amine-functionalized iron titanate （A–Fe2TiO5）,which holds promise for improving the lifetime,proton conductivity,and power density of SPEES in *** modified SPEES/A–Fe2TiO5composite membranes exhibited notable characteristics,including high water uptake,enhanced thermomechanical stability,and oxidative ***,the SPEES membrane loaded with 1.2 wt%of A–Fe2TiO5demonstrates a maximum proton conductivity of 155 mS cm-1,a twofold increase compared to the SPEES membrane,at 80°C under 100%relative humidity （RH）.Furthermore,the 1.2 wt%of A–Fe2TiO5/SPEES composite membranes exhibited a maximum power density of 397.37 mW cm-2and a current density of 1148 ma cm-2at 60°C under 100%RH,with an opencircuit voltage decay of 0.05 m V/h during 103 h of continuous *** study offers significant insights into the development and understanding of innovative SPEES nanocomposite membranes for PEMFC applications.

关键词： Acid-base Hybrid membrane Proton conductivity Polymer electrolyte fuel cell Single-cell performance

Near-wall behaviors of oblique-shock-wave/turbulent-boundary-layer interactions

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Applied mathematics and Mechanics(English Edition) 2017年第10期38卷 1357-1376页

作者： mingsheng YE Ming dong Department of Mechanics Tianjin University Tianjin Key Laboratory of Modern Engineering Mechanics

A direct numerical simulation （DNS） on an oblique shock wave with an incident angle of 33.2° impinging on a mach 2.25 supersonic turbulent boundary layer is performed. The numerical results are confirmed to be of high accuracy by comparison with the reference data. Particular efforts have been made on the investigation of the near-wall behaviors in the interaction region, where the pressure gradient is so significant that a certain separation zone emerges. It is found that, the traditional linear and loga- rithmic laws, which describe the mean-velocity profiles in the viscous and meso sublayers, respectively, cease to be valid in the neighborhood of the interaction region, and two new laws of the wall are proposed by elevating the pressure gradient to the leading order. The new laws are inspired by the analysis on the incompressible separation flows, while the compressibility is additionally taken into account. It is verified by the DNS results that the new laws are adequate to reproduce the mean-velocity profiles both inside and outside the interaction region. Moreover, the normalization adopted in the new laws is able to regularize the Reynolds stress into an almost universal distribution even with a salient adverse pressure gradient （APG）.

关键词： shock wave turbulent boundary layer direct numerical simulation (DNS),adverse pressure gradient (APG) separation

CNKSR2 interactome analysis indicates its association with the centrosome/microtubule system

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Neural Regeneration Research 2025年第8期20卷 2420-2432页

作者： Lin Yin Yalan Xu Jie Mu Yu Leng Lei ma Yu Zheng Ruizhi Li Yin Wang Peifeng Li Hai Zhu dong Wang Jing Li Institute for Translational Medicine The Affiliated Hospital of Qingdao UniversityMedical CollegeQingdao UniversityQingdaoShandong ProvinceChina School of Basic Medicine Qingdao UniversityQingdaoShandong ProvinceChina College of Life Sciences and School of PharmacyMedical CollegeQingdao UniversityQingdaoShandong ProvinceChina Department of Urology Qingdao Municipal Hospital Affiliated to Qingdao UniversityQingdaoShandong ProvinceChina

The protein connector enhancer of kinase suppressor of Ras 2(CNKSR2),present in both the postsynaptic density and cytoplasm of neurons,is a scaffolding protein with several protein-binding *** of the CNKSR2 gene have been implicated in neurodevelopmental disorders,particularly intellectual disability,although the precise mechanism involved has not yet been fully *** has demonstrated that CNKSR2 plays a role in facilitating the localization of postsynaptic density protein complexes to the membrane,thereby influencing synaptic signaling and the morphogenesis of dendritic ***,the function of CNKSR2 in the cytoplasm remains to be *** this study,we used immunoprecipitation and high-resolution liquid chromatography-mass spectrometry to identify the interactors of *** a combination of bioinformatic analysis and cytological experiments,we found that the CNKSR2 interactors were significantly enriched in the proteome of the *** also showed that CNKSR2 interacted with the microtubule protein DYNC1H1 and with the centrosome marker *** colocalization analysis confirmed the centrosomal localization of *** we downregulated CNKSR2 expression in mouse neuroblastoma cells(Neuro 2A),we observed significant changes in the expression of numerous centrosomal *** manipulation also affected centrosome-related functions,including cell size and shape,cell proliferation,and ***,we found that CNKSR2 interactors were highly enriched in de novo variants associated with intellectual disability and autism spectrum *** findings establish a connection between CNKSR2 and the centrosome,and offer new insights into the underlying mechanisms of neurodevelopmental disorders.

关键词： autism spectrum disorder centrosome CNKSR2 intellectual disability interactome mass spectrometry microtubule neurodevelopmental disease protein complexes protein-protein interactions

基于离散元法的水泥稳定碎石微裂细观机理研究

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土木与环境工程学报（中英文） 2025年第1期47卷 196-204页

作者：刘子龙马士宾贺苗梁栋牛宗岳河北工业大学土木与交通学院天津300401

为探究水泥稳定碎石微裂细观演化机理,构建了细观非均质水泥稳定碎石数值模型,结合室内无侧限抗压强度试验和单轴压缩数值试验反演出模型细观参数,引入微裂隙网络研究不同裂隙参数对微裂程度的影响,分析不同裂隙数目下系统能量演化规律... 详细信息

为探究水泥稳定碎石微裂细观演化机理,构建了细观非均质水泥稳定碎石数值模型,结合室内无侧限抗压强度试验和单轴压缩数值试验反演出模型细观参数,引入微裂隙网络研究不同裂隙参数对微裂程度的影响,分析不同裂隙数目下系统能量演化规律。结果表明:数值模拟与室内试验结果基本吻合,构建的水泥稳定碎石离散元模型可较为准确地表征材料细观破坏特征;微裂损伤是二次振动加载后裂隙宽度增大和裂隙数目增多共同作用的结果,裂隙密度对水泥稳定碎石微裂程度起决定性作用;裂隙密度增加,材料储存弹性应变能的能力减弱,峰值点水泥稳定碎石材料的输入总能量降低。验证了早期微裂对于降低收缩应力的积极作用,揭示了水泥稳定碎石材料微裂力学特征和细观机理。

关键词：水泥稳定碎石无侧限抗压强度离散元法微裂技术细观机理

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Iteration convergence condition modeling for single spaceborne SAR image direct positioning

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Geo-Spatial Information Science 2016年第4期19卷 278-284页

作者： Yuting dong Lu Zhang mingsheng Liao State Key Laboratory of Information Engineering in Surveying Mapping and Remote Sensing(LIESMARS)Wuhan UniversityWuhanChina Collaborative Innovation Center for Geospatial Technology Wuhan UniversityWuhanChina

Single SAR image direct positioning is to determine the ground coordinate for each pixel in the SAR image assisted with a reference *** this procedure,an iterative procedure is essentially needed to solve the uncertainty in elevation of each pixel in the SAR ***,such an iterative procedure may suffer from the problem of divergence in shaded and serious layover *** investigate this problem,we performed a theoretical analysis on the convergence conditions that has not been intensively studied till *** Range-Doppler(RD)model was simplified and then the general surface is degenerated into a planar *** deduction was then carried out to derive the convergence conditions and the impact factors for the convergence speed were *** theoretical findings were validated by experiments for both simulated and real scenarios.

关键词： Direct positioning RD model SAR iteration convergence condition

Optimizing and extending ion dielectric polarizability database for microwave frequencies using machine learning methods

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npj Computational materials 2023年第1期9卷 977-986页

作者： Jincheng Qin Zhifu Liu mingsheng ma Yongxiang Li CAS Key Laboratory of Inorganic Functional materials and Devices Shanghai Institute of CeramicsChinese Academy of Sciences201899 ShanghaiChina Center of materials Sciences and Optoelectronics Engineering University of Chinese Academy of Sciences100049 BeijingChina

Permittivity at microwave frequencies determines the practical applications of microwave dielectric *** accuracy and universality of the permittivity prediction by Clausius–Mossotti equation depends on the dielectric polarizability(αD)*** most influentialαD database put forward by Shannon is facing three challenges in the 5 G era:(1)Few data,(2)Simplistic relation and(3)Low frequency(kHz–MHz)***,we optimized and extended the Shannon’s database for microwave frequencies by the four-stage multiple linear regression and support vector machine *** comparison with the conventional database,the optimized and extended databases achieved higher accuracy and expanded the amount of data from 60 to more than ***,we analyzed the relationships betweenαD and ion characteristics,including ionic radius(IR),atomic number(N),valence state(V)and coordination number(CN).We found that the positive cubic law of“αD~IR3”discussed in Shannon’s work was valid for the IR changed by the N,but invalid for the change caused by the CN.

关键词： database microwave dielectric