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Novel synthesis of stabilized Bi1-x-yGdxDyyO1.5 solid electrolytes with enhanced conductivity for intermediate temperature solid oxide fuel cells（SOFCs）

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Journal of Rare Earths 2024年第10期42卷 1903-1911页

作者： Ahmed H.Ibrahim Yehia m.Abbas H.A.Ayoub marwa H.ali mustafa Aldoori materials Science Laboratory Physics DepartmentFaculty of ScienceSuez Canal University ministry of Higher Education and Scientific Research Aliraqia University

Herein,we report the synthesis of a Dy-Gd co-doped cubic phase-stabilized Bi2O3solid electrolyte system via solid-state processing under atmospheric *** with Dy3+and Gd3+has been observed to significantly enhance the densification process during sintering for stabilization purposes,thereby improving the electrical properties of δ-Bi2O3-type *** synthesized ceramics were characterized using X-ray diffraction（XRD）,field emission scanning electron microscopy-energy dispersive X-ray spectroscopy（FESEm-EDX）,thermal gravimetry/differential thermal analysis（TG/DTA）,and the four-point probe technique（4PPT）.XRD analysis reveals that the samples Bi1-x-yGdxDyyO1.5（y=0.05/x=0.05,0.10,0,15,and 0.20,and x=0.05/y=0.10,0.15,and 0.20） exhibit a stable face-centered cubic δ-phase and a mixed-phase crystallographic *** XRD analysis of the stabilized δ-phase suggests that the prepared oxides show a face-centered cubic（FCC） structure with a space group of *** micrographs reveal that the composition Bi0.90Gd0.05Dy0.05O1.5has no significant ***,an evident increase in the pore formation is observed as the amount of Gd2O3increases until it reaches 20%.This finding suggests that dense pellets are formed during the sintering process at 900-1000℃.The DTA analyses were performed to verify the phase stability,which agrees with the XRD *** electrochemical performance of the synthesized Dy-Gd co-doped Bi2O3solid electrolyte system was evaluated and analyzed in detail by using the electrochemical impedance spectroscopy（EIS） technique,Based on EIS and conductivity measurements,Bi0.75Gd0.20Dy0.05O1.5exhibits the lowest activation energy of 0.519 eV and the highest conductivity value of 0.398 S/cm at 627℃compared to the other samples;this composition can be used as a solid electrolyte for intermediatetemperature solid oxide fuel cells（SOFCs）.

关键词： Electrochemical impedance spectroscopy (EIS) Fast Fourier transform (FFT) Rare earths Rietveld Solid oxide fuel cells (SOFCs) Solid-state processing

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Web GIS-Based Temporal Analysis of Climatic Factors Impacting Heat Stroke in Karachi

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Journal of Geographic Information System 2024年第1期16卷 61-69页

作者： ali Atif mahnoor Rehman muhammad Butt syed mahmood Shahid Ghazi Rashid mehmood Department of management Victoria University Sydney Australia Department of Geography Government College University Lahore Pakistan Department of Space Science University of the Punjab Lahore Pakistan Centre of Geographic Information System University of The Punjab Lahore Pakistan

This study focuses on the impact of climate change, specifically the increasing threat of heatwaves, in Pakistan, with a particular emphasis on the city of Karachi. The Pakistan meteorological Department (PmD) analysed a century of climatic data to reveal warming trends, attributing them to human-induced factors. The vulnerability of Pakistan to climate change is highlighted, given its warm climate and location in a region where temperature increases are expected to surpass global averages. The study examines the past three decades, noting a significant rise in the frequency of hot days, especially in Karachi, where heatwaves have become more prevalent. The aims and objectives of the study involve identifying temporal changes in temperature, rainfall, humidity, and wind speed from 1984 to 2014 in Karachi. The literature review emphasizes the health implications of heatwaves, citing increased mortality during such events globally. The study incorporates a comprehensive temporal analysis, addressing gaps in previous research by considering multiple climate indicators responsible for heatwaves. The methodology involves statistical analyses, including linear regression and Pearson correlation, applied to temperature data and urbanization parameters. Results indicate an increasing trend in heat index temperature, with heatwave vulnerability peaking in the last three decades. Heat Index Temperature Anomalies show a clear surge, emphasizing the need for new indices to control critical heat stress conditions. The study concludes that tropical climate variability, particularly heat index, is linked to extreme hot days, urging measures to reduce population vulnerability. The findings underscore the importance of policy strategies, such as integrated coastal zone management, to mitigate the adverse health effects of heatwaves in Karachi’s vulnerable population.

关键词： IPCC Heat Wave Heat Index PmD

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Existence results and behavior analysis for nonlinear age-dependent population dynamics problems with conformable fractional operator

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International Journal of Biomathematics 2024年第5期17卷 229-256页

作者： Hiba El Asraoui m'hamed El Omari ali El mfadel Khalid Hilal Laboratory of Applied mathematics Scientific Computing Sultan moulay Slimane University BP 523 Beni MellalMorocco

In this paper,we investigate the existence of solutions and analyze the large-time behavior for Gurtin-maccamy population model involving conformable fractional *** a preliminary step,we construct a generic structure of the solution associated with our proposed model by utilizing some basic properties and tools of conformable fractional *** establish the existence of a unique solution of the given model with the given initial *** last,by using the upper and lower solutions for the characteristic equation,we define the upper and lower boundaries for the obtained solution and describe the large-time behavior of the total population.

关键词： Age-dependent population conformable fractional operator upper and lower boundary of the solution dynamics of populations

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Cooperative THz communication for UAVs in 6G and beyond

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Green Energy and Intelligent Transportation 2024年第1期3卷 25-31页

作者： Nazifa mustari muhammet ali Karabulut A.F.m.Shahen Shah Ufuk Tureli Department of Electronics and Communication Engineering Yildiz Technical UniversityTurkey Department of Electrical Electronics Engineering Faculty of Engineering and ArchitectureKafkas UniversityKarsTurkey

One of the key components of any smart city is considered to be its intelligent transportation systems(ITSs).Unmanned aerial vehicles(UAVs)are envisioned in several ITS application fields because of their autonomous operation,mobility,communication/processing capabilities,and other *** this paper,cooperative terahertz(THz)communication is proposed for flying ad hoc networks(FANETs),which is a particular kind of network made up of a collection of small UAVs linked in an ad hoc fashion and working together to accomplish high-level *** frequency spectrum for wireless communication has been expanding continuously in order to meet the demand for *** the forthcoming 6G and beyond,communications in the THz range will be vital,similar to how mmWave-band communications are currently influencing the 5G of wireless mobile *** finite state machine(FSm)of the proposed cooperative communication system for THz band is presented.A markov chain model-based analytical study is carried out,which derives relationships among ***,numerical results are provided to support the analytical study.

关键词： Cooperative mAC THz UAVs 6G

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A multi-mechanistic approach to the oil recovery study of a family of amphiphilic polysaccharides

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Petroleum Research 2024年第2期9卷 238-249页

作者： Funsho Afolabi syed mmahmood Lunech mario Nur Asyraf md Akhir Bennett Tackie-Otoo Hamid Sharifigaliuk Center of Research in Enhanced Oil Recovery Universiti Teknologi PETRONASSeri IskandarMalaysia Center for Subsurface Imaging Universiti Teknologi PETRONASSeri IskandarMalaysia Research Institute of Petroleum Industry(RIPI) TehranIran

Chemical enhanced oil recovery(cEOR)remains one of the most potent tertiary recovery ***,it is expensive and rarely environmentally ***-based amphiphilic polymers have been suggested as an alternative to eradicating the challenges of conventional cEOR because of cost-effectiveness,and ***,few in-depth studies exist in the literature to investigate the prospects of these materials.A new family of amphiphilic polysaccharides was synthesized by hydrophobic modification of cellulose sulphate,and the EOR functionalities were *** novel biopolymers exhibited the ability to alter rock wetting *** terms of recovery,one of the variants of the synthesized bio amphiphilic polymer(D-I)was able to reduce residual oil saturation to 12%at harsh conditions of 60,000 ppm salinity at 75℃.micromodel visual analysis revealed that the performance of the novel materials was due to the combination of mobility control,IFT lowering and emulsification,wettability alteration,and *** a performance commensurate to that of a commercial hydrophobically modified polymer,it can be said that the novel amphiphilic polysaccharides can stand as a viable cEOR agent for oilfield applications.

关键词： Bio-based polymers Amphiphilic polysaccharides EOR Cellulose sulphate Environmental sustainability

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Effects of family non-universal Z′model in angular observables of B→(ρ,a_(1))µ^(+)µ^(−)decays

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Chinese Physics C 2024年第10期48卷 86-113页

作者： Nimra Farooq marwah Zaki m.ali Paracha Faisal munir Bhutta Department of Physics School of Natural SciencesNational University of Sciences and TechnologyH-12Islamabad44000Pakistan

We present the angular distribution of the four-fold B→ρ(→ππ)µ^(+)µ^(−) and B→a_(1)(→ρ_(Ⅱ).⊥π)µ^(+)µ^(−) decays in the Standard model and family non-universal Z'*** the quark level,these decays are govered by the b→dµ^(+)µ^(−) *** with different angular observables,we provide predictions of differential branching ***,forward-backward asymmetry,and longitudinal polarization fractions of ρ and a_(1) *** analysis showsthat the signatures of the fimily non-universal Z’model are more distinct in the observables associated with the B→ρ(→ππ)µ^(+)µ^(−) decay than in those associated with the B→a_(1)(→ρ_(Ⅱ).⊥π)µ^(+)µ^(−) *** measurements ofthe predicted angular observables,both at current and fiuture high energy colliders,will provide useful *** data required to clarify the structure of the family non-universal Z' model in |△b|=△d|=1 processes.

关键词： heavy quark physics B meson physics beyond the Standard model

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Unraveling fundamental properties of power system resilience curves using unsupervised machine learning

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Energy and AI 2024年第2期16卷 227-240页

作者： Bo Li ali mostafavi Urban Resilience.AI Lab Zachry Department of Civil and Environmental EngineeringTexas A&M University3136 TAMU College StationTX77843-3136USA

Power system is vital to modern societies,while it is susceptible to hazard ***,analyzing resilience characteristics of power system is *** standard model of infrastructure resilience,the resilience triangle,has been the primary way of characterizing and quantifying resilience in infrastructure systems for more than two ***,the theoretical model provides a one-size-fits-all framework for all infrastructure systems and specifies general characteristics of resilience curves(e.g.,residual performance and duration of recovery).Little empirical work has been done to delineate infrastructure resilience curve archetypes and their fundamental properties based on observational *** of the existing studies examine the characteristics of infrastructure resilience curves based on analytical models constructed upon simulated system *** is a dire dearth of empirical studies in the field,which hindered our ability to fully understand and predict resilience characteristics in infrastructure *** address this gap,this study examined more than two hundred power-grid resilience curves related to power outages in three major extreme weather events in the United *** the use of unsupervised machine learning,we examined different curve archetypes,as well as the fundamental properties of each resilience curve *** results show two primary archetypes for power grid resilience curves,triangular curves,and trapezoidal *** curves characterize resilience behavior based on three fundamental properties:*** functionality threshold,*** functionality recovery rate,and *** pivot *** archetypes explain resilience curves based on *** of sustained function loss and *** recovery *** longer the duration of sustained function loss,the slower the constant rate of *** findings of this study provide novel perspectives enabling better understanding and predicti

关键词： Power system Infrastructure resilience Unsupervised learning Time-series clustering Resilience curve

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Inclusion of CoTiO_(3) to ameliorate the re/dehydrogenation properties of the mg–Na–Al system

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Journal of magnesium and Alloys 2024年第3期12卷 1215-1226页

作者： N.A.ali N.Y.Yusnizam N.A.Sazelee Sami-ullah Rather Haizhen Liu m.Ismail Energy Storage Research Group Faculty of Ocean Engineering TechnologyUniversiti Malaysia Terengganu21030 Kuala NerusTerengganuMalaysia Department of Chemical and materials Engineering King Abdulaziz UniversityP.O.Box80204Jeddah 21589Saudi Arabia Guangxi Novel Battery materials Research Center of Engineering Technology School of Physical Science and TechnologyGuangxi UniversityNanning 530004China State Key Laboratory of Featured metal materials and Life-Cycle Safety for Composite Structures Nanning 530004China

For the first time,the mgH_(2)–NaAlH_(4)(ratio 4:1)destabilized system with CoTiO_(3) addition has been *** CoTiO_(3)-doped mgH_(2)–NaAlH_(4) sample begins to dehydrogenate at 130℃,which is declined by 40℃ compared to the undoped mgH_(2)–NaAlH_(4).moreover,the de/rehydrogenation kinetics characteristics of the CoTiO_(3)-doped mgH_(2)–NaAlH_(4) were greatly *** the inclusion of CoTiO_(3),the mgH_(2)–NaAlH_(4) composite absorbed 5.2 wt.%H_(2),higher than undoped mgH_(2)–NaAlH_(4).In the context of dehydrogenation,the CoTiO_(3)-doped mgH_(2)–NaAlH_(4) sample desorbed 2.6 wt.%H_(2),almost doubled compared to the amount of hydrogen desorbed from the undoped mgH_(2)–NaAlH_(4) *** activation energy obtained by the Kissinger analysis for mgH_(2) decomposition was significantly lower by 35.9 kJ/mol than the undoped mgH_(2)–NaAlH_(4) *** reaction mechanism demonstrated that new phases of mgCo and AlTi_(3) were generated in situ during the heating process and are likely to play a substantial catalytic function and be useful in ameliorating the de/rehydrogenation properties of the destabilized mgH_(2)–NaAlH_(4) system with the inclusion of CoTiO_(3).

关键词： Destabilize system magnesium hydride Sodium alanate Hydrogen storage Additive.

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Convective drying of wood chips:Accelerating coupled DEm-CFD simulations with parametrized reduced single particle models

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Particuology 2024年第1期84卷 158-167页

作者： Lucas Reineking Jonas Fischer ali mjalled Enric Illana Siegmar Wirtz Viktor Scherer martin monnigmann Automatic Control and System Theory Ruhr-Universität-BochumUniversitätstraße 150Bochum44801Germany Energy Plant Technology Ruhr-Universität-BochumUniversitätstraße 150Bochum44801Germany

The simulation of industry-scale reactive bulks is challenging due to the complex interaction between fluid and *** particles in the bulk and their interaction with the fluid flow can be described by combined Discrete Element method-Computational Fluid Dynamics(DEm-CFD)***,the computational cost of the Finite Volume(FV)methods deployed in these models can become prohibi-tively expensive,especially for high inner-particle *** particle Reduced models(Rms)can be used to achieve both fast and accurate descriptions of the processes in each *** an example of bulk systems comprising heat and mass transfer,we compared FV and Rm simulations for the drying of wood chips in a bulk reactor.A manifold-based nonlinear interpolation was applied to resolve changing boundary conditions for the *** simulations showed that Rms provide accurate values for the thermodynamic state variables of the ***,the time required for the bulk simulation was reduced by 67%with the *** is evident that simulations with high inner-particle resolution can be accelerated by Rms if manifold-based nonlinear interpolation is used to address changing boundary conditions.

关键词： Reduced model Reactive bulk Discrete element method manifold-based interpolation Drying of porous mediaDEm-CFD

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NeuroPNm:model reduction of pore network models using neural networks

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Particuology 2024年第3期86卷 239-251页

作者： Robert Jendersie ali mjalled Xiang Lu Lucas Reineking Abdolreza Kharaghani martin monnigmann Christian Lessig Otto-von-Guericke-Universitat magdeburg Universitatsplatz 2Magdeburg39106Germany Ruhr-Universitat-Bochum Universitatstraβe 150Bochum44801Germany

Reacting particle systems play an important role in many industrial applications,for example biomass drying or the manufacturing of *** numerical modeling and simulation of such systems is therefore of great importance for an efficient,reliable,and environmentally sustainable operation of the *** complex thermodynamical,chemical,and flow processes that take place in the particles are a particular challenge in a ***,typically a large number of particles is involved,rendering an explicit treatment of individual ones impossible in a reactor-level *** approach for overcoming this challenge is to compute effective,physical parameters from single-particle,high-resolution *** can be combined with model reduction methods if the dynamical behaviour of particles must be *** network models with their unrivaled resolution have thereby been used successfully as high-resolution models,for instance to obtain the macroscopic diffusion coeffcient of *** parameter identification and model reduction have recently gained new impetus by the dramatic progress made in machine learning in the last *** report results on the use of neural networks for parameter identification and model reduction based on three-dimensional pore network models(PNm).We believe that our results provide a powerful complement to existing methodologies for reactor-level simulations with many thermally-thick particles.

关键词： Porenetwork models Neural networks Parameter estimation Reduced order model

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