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Rare earth-doped mixed Ni-Cu-Zn ferrites as an effective photocatalytic agent for active degradation of Rhodamine B dye

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Journal of Rare Earths 2024年第3期42卷 488-496,I0003页

作者： swapnil A.Jadhav sandeep B.somvanshi sudarshan s.Gawali Kranti Zakde K.m.Jadhav Department of Physics Dr.Babasaheb Ambedkar Marathwada UniversityAurangabad431004MaharashtraIndia school of materials Engineering Purdue UniversityWest Lafayette 47906USA University Department of Basic and Applied sciences MGM UniversityAurangabad431003MaharashtraIndia

In this study, a series of Gd^(3+)-doped mixed Ni-Cu-Zn ferrites with composition of Zn_(0.5)Ni_(0.3)Cu_(0.2)Fe_(2-x)Gd_(x)O_(4)(x = 0, 0.025, 0.05, 0.075, 0.1) was prepared using self-ignition sol-gel method. The prepared nanoparticles with an average size ranging from 22 to 26 nm show a single-phase cubic structure belonging to the spinel matrix. A rise in the Gd^(3+)concentration leads to an increase in crystallite size and lattice parameter. In Fourier transform infrared spectra, two main absorption bands belonging to the spinel structure are observed. The high-frequency bands(v_(1)) represent the tetrahedral complex, while the lowfrequency bands(v_(2)) signify the octahedral complex. The optical bandgap of the nanoferrites is found within the range of 2.91 to 2.41 eV, depending on their size. The magnetic characteristics of the material,such as saturation magnetization and coercivity are significantly altered with the concentration of Gd^(3+)in the solution. Using Rhodamine B(RhB) as a model organic pollutant, an in-depth investigation of the photocatalytic activity of the compounds was carried out. The present outcomes show that adding an adequate amount of Gd^(3+)significantly enhances the number of hydroxyl radicals produced by the ferrite,in turn, increasing the photocatalytic activity of the material. mechanism elucidated by scavenger studies reveals that ·OH and holes are the primary reactive radicals responsible for the degradation *** photocatalysts show an insignificant performance loss in five consecutive cycles. Thus, it is concluded that these photocatalysts are highly suitable for the remediation of dye-contaminated wastewater.

关键词： Gd^(3+)substitution spinel ferrite structural properties magnetic properties Photocatalysis Rare earths

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Hybrid-Vlasov simulation of soft X-ray emissions at the Earth’s dayside magnetospheric boundaries

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Earth and Planetary Physics 2024年第1期8卷 70-88页

作者： m.Grandin H.K.Connor s.Hoilijoki m.Battarbee Y.Pfau-Kempf U.Ganse K.Papadakis m.Palmroth Department of Physics University of HelsinkiHelsinkiFinland NAsA Goddard space Flight Center GreenbeltMD20771USA space and Earth Observation Centre Finnish Meteorological InstituteHelsinkiFinland

solar wind charge exchange produces emissions in the soft X-ray energy range which can enable the study of near-Earth space regions such as the magnetopause,the magnetosheath and the polar cusps by remote sensing *** solar wind magnetosphere Ionosphere Link Explorer(smILE)and Lunar Environment heliospheric X-ray Imager(LEXI)missions aim to obtain soft Xray images of near-Earth space thanks to their soft X-ray Imager(sXI)*** earlier modeling works have already simulated soft X-ray images as might be obtained by smILE sXI during its mission,the numerical models used so far are all based on the magnetohydrodynamics description of the space *** investigate the possible signatures of ion-kinetic-scale processes in soft Xray images,we use for the first time a global hybrid-Vlasov simulation of the geospace from the Vlasiator *** simulation is driven by fast and tenuous solar wind conditions and purely southward interplanetary magnetic *** first produce global X-ray images of the dayside near-Earth space by placing a virtual imaging satellite at two different locations,providing meridional and equatorial *** then analyze regional features present in the images and show that they correspond to signatures in soft X-ray emissions of mirrormode wave structures in the magnetosheath and flux transfer events(FTEs)at the *** results suggest that,although the time scales associated with the motion of those transient phenomena will likely be significantly smaller than the integration time of the smILE and LEXI imagers,mirror-mode structures and FTEs can cumulatively produce detectable signatures in the soft X-ray *** instance,a local increase by 30%in the proton density at the dayside magnetopause resulting from the transit of multiple FTEs leads to a 12%enhancement in the line-of-sight-and time-integrated soft X-ray emissivity originating from this ***,a proton density increase by 14%in the magnetosheath

关键词： magnetosphere magnetosheath numerical simulation smILE LEXI soft X-ray emissions hybrid-Vlasov model polar cusp flux transfer events mirror-mode waves

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Effect of solidification cooling rate on microstructure and tribology characteristics of Zn-4si alloy

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International Journal of minerals,metallurgy and materials 2024年第2期31卷 362-373页

作者： F.Akbari m.Golkaram s.Beyrami G.shirazi K.mantashloo R.Taghiabadi m.saghafi Yazdi I.Ansarian Department of metallurgy and material science Imam Khomeini International University(IKIU)Qazvin ***Iran

The main objective of this work was to modify the microstructure and enhance the tribological properties of a new Zn-4si al-loy through a high solidification cooling rate(sCR).According to the results,by increasing the sCR from 2.0 to 59.5℃/s the average size of primary si particles and that of the grains reduced from 76.1 and 3780μm to less than about 14.6 and 460μm,***-ing the sCR also enhanced the microstructural homogeneity,decreased the porosity content(by 50%),and increased the matrix hardness(by 36%).These microstructural changes enhanced the tribological *** instance,under the applied pressure of 0.5 mPa,an in-crease in the sCR from 2.0 to 59.5℃/s decreased the wear rate and the average friction coefficient of the alloy by 57%and 23%,*** wear mechanism was also changed from the severe delamination,adhesion,and abrasion in the slowly-cooled alloy to the mild tribolayer delamination/abrasion in the high-cooling-rate-solidified sample.

关键词： zinc-silicon alloy primary silicon solidification cooling rate tribology sliding wear

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Kriging-boosted CR modeling for prompt infill drilling optimization

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Petroleum 2024年第1期10卷 39-48页

作者： Elizaveta s.Gladchenko Anna E.Gubanova Denis m.Orlov Dmitry A.Koroteev skolkovo Institute of science and Technology Russian Federation Digital Petroleum LLC Russian Federation

The capacitance-resistance model(CRm) has been a useful physics-based tool for obtaining production forecasts for decades. However, the model's limitations make it difficult to work with real field cases,where a lot of various events happen. such events often include new well commissioning(NWC). We introduce a workflow that combines CRm concepts and kriging into a single tool to handle these types of events during history matching. moreover, it can be used for selecting a new well placement during infill drilling. To make the workflow even more versatile, an improved version of CRm was used. It takes into account wells shut-ins and performed workovers by additional adjustment of the model coefficients. By preliminary re-weighing and interpolating these coefficients using kriging, the coefficients for potential wells can be determined. The approach was validated using both synthetic and real datasets, from which the cases of putting new wells into operation were selected. The workflow allows a fast assessment of future well performance with a minimal set of reservoir data. This way, a lot of well placement scenarios can be considered, and the best ones could be chosen for more detailed studies.

关键词： Capacitance-resistance model (CRm) Field development optimization Infill drilling Interwell connectivity Kriging New well commissioning (NWC)

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Bayesian and Non-Bayesian Analysis for the sine Generalized Linear Exponential model under Progressively Censored Data

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Computer modeling in Engineering & sciences 2024年第9期140卷 2795-2823页

作者： Naif Alotaibi A.s.Al-moisheer Ibrahim Elbatal mohammed Elgarhy Ehab m.Almetwally Department of mathematics and statistics Faculty of ScienceImam Mohammad Ibn Saud Islamic University(IMSIU)Riyadh11432Saudi Arabia Department of mathematics College of ScienceJouf UniversityP.O.Box 848Sakaka72351Saudi Arabia mathematics and Computer science Department Faculty of ScienceBeni-Suef UniversityBeni-Suef62521Egypt Department of Basic sciences Higher Institute of Administrative SciencesBelbeisEgypt Faculty of Business Administration Delta University for Science and TechnologyGamasa11152Egypt

This article introduces a novel variant of the generalized linear exponential(GLE)distribution,known as the sine generalized linear exponential(sGLE)*** sGLE distribution utilizes the sine transformation to enhance its *** updated distribution is very adaptable and may be efficiently used in the modeling of survival data and dependability *** suggested model incorporates a hazard rate function(HRF)that may display a rising,J-shaped,or bathtub form,depending on its unique *** model includes many well-known lifespan distributions as separate *** suggested model is accompanied with a range of statistical *** model parameters are examined using the techniques of maximum likelihood and Bayesian estimation using progressively censored *** order to evaluate the effectiveness of these techniques,we provide a set of simulated data for testing *** relevance of the newly presented model is shown via two real-world dataset applications,highlighting its superiority over other respected similar models.

关键词： sine G family generalized linear failure rate progressively censored data moments maximum likelihood estimation Bayesian estimation simulation

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复发性多形胶质母细胞瘤对贝伐单抗治疗反应的ADC直方图分析预测

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国际医学放射学杂志 2009年第5期32卷 488-489页

作者： W.B.Pope H.J.Kim J.Huo J.Alger m.s.brown D.Gjertson 郭雪梅 Department of Radiological sciences David Geffen School of Medicine at UCLA Medical Center

目的研究表观扩散系数（ADC）直方图分析是否能在贝伐单抗治疗前预测复发性多形胶质母细胞瘤（GBm）病人的无进展生存时间。材料与方法本研究经机构审核委员会批准。符合健康医疗保险要求并获取知情同意书。确诊为复发性GBm病人分为贝... 详细信息

目的研究表观扩散系数（ADC）直方图分析是否能在贝伐单抗治疗前预测复发性多形胶质母细胞瘤（GBm）病人的无进展生存时间。材料与方法本研究经机构审核委员会批准。符合健康医疗保险要求并获取知情同意书。确诊为复发性GBm病人分为贝伐单抗治疗组和对照组，每组各41例。

关键词：胶质母细胞瘤直方图分析贝伐单抗复发性治疗反应预测多形 ADO

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Ranking environmental and edaphic attributes driving soil microbial community structure and activity with special attention to spatial and temporal scales

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mLife 2024年第1期3卷 21-41页

作者： Vadakattu V.s.R.Gupta James m.Tiedje CsIRO Agriculture&Food UrrbraeSouth AustraliaAustralia Centre for microbial Ecology Michigan State UniversityEast LansingMichiganUSA

The incredibly complex soil microbial communities at small scales make their analysis and identification of reasons for the observed structures *** community structure is mainly a result of the inoculum(dispersal),the selective advantages of those organisms under the habitat-based environmental attributes,and the ability of those colonizers to sustain themselves over *** soil is protective,and its microbial inhabitants have long adapted to varied soil conditions,significant portions of the soil microbial community structure are likely ***,a substantial portion of the community will not correlate to often measured soil *** suggest that the drivers be ranked on the basis of their importance to the fundamental needs of the microbes:(i)those that supply energy,i.e.,organic carbon and electron acceptors;(i)environmental effectors or stressors,i.e.,pH,salt,drought,and toxic chemicals;(ii)macro-organism associations,i.e.,plants and their seasonality,animals and their fecal matter,and soil fauna;and(iv)nutrients,in order,N,P,and probably of lesser importance,other micronutrients,and *** relevance of drivers also varies with spatial and time scales,for example,aggregate to field to regional,and persistent to dynamic populations to transcripts,and with the extent of phylogenetic difference,hence phenotypic differences in organismal *** present a summary matrix to provide guidance on which drivers are important for particular studies,with special emphasis on a wide range of spatial and temporal scales,and illustrate this with genomic and population(rRNA gene)data from selected studies.

关键词： abundance community structure diversity functional microbiome microorganisms

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Effect of Ta_(2)O_(5)nanoparticles on bioactivity,composition,structure,in vitro and in vivo behavior of PEO coatings on mg-alloy

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Journal of magnesium and Alloys 2024年第6期12卷 2360-2379页

作者： D.V.mashtalyar I.m.Imshinetskiy V.V.Kashepa K.V.Nadaraia m.A.Piatkova A.I.Pleshkova K.A.Fomenko A.Yu.Ustinov s.L.sinebryukhov s.V.Gnedenkov Institute of Chemistry Far Eastern BranchRussian Academy of SciencesVladivostok690022Russia Far Eastern Federal University Vladivostok690950Russia Regional Clinical Dermatovenerological Dispensary Vladivostok690033Russia

The present study investigates the physical and chemical characteristics,behavior in vitro and in vivo,and biocompatibility of coatings containing Ta_(2)O_(5),which are obtained by plasma electrolytic oxidation(PEO)on mA8 magnesium *** obtained coatings demonstrate in vivo biocompatibility and in vitro *** to the base PEO coating,the layers containing Ta_(2)O_(5)facilitate the development of apatite in simulated body fluid,suggesting that the inclusion of nanoparticles improves bioactivity of the *** was found that incorporation of Ta_(2)O_(5)nanoparticles increases roughness and porosity of the formed layers by increasing particle concentration in electrolytes for the PEO process contributing to sufficient soft tissue ingrowth in *** on in vivo studies,these coatings also provide favorable tissue response and minimal inflammatory reaction in comparison with the bare magnesium alloy due to protection of living tissues from deleterious corrosion events of magnesium implant such as local alkalization and intense hydrogen *** results obtained in the present study concluded biocompatibility,tissue integration of the PEO coatings containing Ta_(2)O_(5)nanoparticles making them a promising protective layer for biodegradable magnesium implants.

关键词： Plasma electrolytic oxidation Bioactive coatings Tantalum pentoxide simulated body fluid(sBF) Apatite formation Histology

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Unraveling the nature of sensing in electrostatic mEms gas sensors

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microsystems & Nanoengineering 2024年第3期10卷 109-117页

作者： Yasser s.shama sasan Rahmanian Hamza mouharrar Rana Abdelrahman Alaaeldin Elhady Eihab m.Abdel-Rahman systems Design Engineering University of Waterloo200 University Ave WWaterloo N2L 3G1 ONCanada mechanical Engineering Benha Faculty of EngineeringBenha UniversityBenha 13511Egypt

This paper investigates the fundamental sensing mechanism of electrostatic mEms gas *** compares among the responsivities of a set of mEms isopropanol sensors before and after functionalization,and in the presence and absence of electrostatic fields when operated in static and dynamic detection *** the static mode,we found that the sensors do not exhibit a measurable change in displacement due to added *** the other hand,bare sensors showed a clear change in displacement in response to isopropanol *** the dynamic mode,functionalized sensors showed a measurable frequency shift due to the added mass of isopropanol *** the presence of strong electrostatic fields,the measured frequency shift was found to be threefold larger than that in their absence in response to the same concentration of isopropanol *** enhanced responsivity of dynamic detection allows the sensors to measure the vapor mass captured by the functional material,which is not the case for static *** detection of isopropanol by bare sensors in static mode shows that change in the medium permittivity is the primary sensing *** enhanced responsivity of dynamic mode sensors when operated in strong electrostatic fields shows that their sensing mechanism is a combination of a weaker added mass effect and a stronger permittivity *** findings show that electrostatic mEms gas sensors are independent of the direction of the gravitational field and are,thus,robust to changes in *** is erroneous to refer to them as‘gravimetric’sensors.

关键词： mechanism. electrostatic measurable

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Physical activity volume,frequency,and intensity:Associations with hypertension and obesity over 21 years in Australian women

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Journal of sport and Health science 2024年第5期13卷 631-641页

作者： Gregore I.mielke Ding Ding shelley E.Keating Bruno P.Nunes Ruth Brady Wendy J.brown school of Public Health The University of QueenslandBrisbaneQLD 4006Australia sydney school of Public Health Faculty of Medicine and HealthThe University of SydneySydneyNSW 2006Australia The Charles Perkins Centre The University of SydneySydneyNSW 2006Australia school of Human movement and Nutrition sciences The University of QueenslandBrisbaneQLD 4072Australia school of Nursing Federal University of PelotasPelotasRio Grande do Sul 96010-610Brazil Faculty of Health sciences and medicine Bond UniversityGold CoastQLD 4226Australia

Background:Optimal patterns of accrual of recommended levels of physical activity(PA)for prevention of hypertension and obesity are not *** overall aim of this study was to investigate whether different patterns of accumulation of PA are differentially associated with hypertension and obesity in Australian women over 21 ***,we investigated whether,for the same weekly volume of PA,the number of sessions(frequency)and vigorousness of PA(intensity)were associated with a reduction in the occurrence of hypertension and obesity in ***:Data from the 1973-1978 and 1946-1951 cohorts of the Australian Longitudinal study on Women's Health were analyzed(n=20,588;12%-16%with a Bachelor's or higher degree).self-reported PA,hypertension,height,and weight were collected using mail surveys every 3 years from 1998/2000 to 2019/*** Estimating Equation models with a 3-year lag model were used to investigate the association of PA volume(metabolic equivalent min/week)(none;33-499;500-999;≥1000,weekly frequency(none;1-2 times;3-4times;5-7 times;≥8 times),and the proportion of vigorous PA to total volume of PA(none;0%;1%-33%;34%-66%;67%-100%)with odds of hypertension and obesity from 2000 to ***:The cumulative incidence of hypertension was 6%in the 1973-1978 and 23%in the 1946-1951 cohort;27%of women in the 1973-1978;and 15%in the 1946-1951 cohort developed obesity over the ***,a higher volume of PA was associated with reduced odds of hypertension and *** the volume of PA was considered,the odds of hypertension did not vary according to the frequency or intensity of ***,increased proportion of vigorous PA to the total volume of PA was associated with a small additional reduction in the risk of obe ***:PA volume appears to be more important than the pattern of accumulation for the prevention of hypertension and *** more sessions,particularly of vigorous-intensity PA,may provide extr

关键词： Physical activity Frequency Intensity Incidences Epidemiology Women

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