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Low-temperature chlorination roasting technology for the simultaneous recovery of valuable metals from spent LiCoO_(2)cathode material

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International Journal of minerals,metallurgy and materials 2025年第1期32卷 80-91页

作者： Junjie shi Changle Hou Jingjing Dong Dong Chen Jianzhong Li Key Laboratory for Ecological metallurgy of multimetallic mineral(ministry of Education) Northeastern UniversityShenyang 110819China School of metallurgy Northeastern UniversityShenyang 110819China

With the continuous increase in the disposal volume of spent lithium-ion batteries(LIBs),properly recycling spent LIBs has become essential for the advancement of the circular *** study presents a systematic analysis of the chlorination roasting kinetics and proposes a new two-step chlorination roasting process that integrates thermodynamics for the recycling of LIB cathode *** activation energy for the chloride reaction was 88.41 kJ/mol according to thermogravimetric analysis–derivative thermogravimetry data obtained by using model-free,model-fitting,and Z(α)function(αis conversion rate).Results indicated that the reaction was dominated by the first-order(F1)model when the conversion rate was less than or equal to 0.5 and shifted to the second-order(F2)model when the conversion rate exceeded *** conditions were determined by thoroughly investigating the effects of roasting temperature,roasting time,and the mass ratio of NH_(4)Cl to LiCoO_(2).Under the optimal conditions,namely 400℃,20 min,and NH_(4)Cl/LiCoO_(2)mass ratio of 3:1,the leaching efficiency of Li and Co reached 99.43% and 99.05%,*** of the roasted products revealed that valuable metals in LiCoO_(2)transformed into CoCl_(2) and ***,the reaction mechanism was elucidated,providing insights for the establishment of a novel low-temperature chlorination roasting technology based on a crystal structure *** technology can guide the development of LIB recycling processes with low energy consumption,low secondary pollution,high recovery efficiency,and high added value.

关键词： spent lithium-ion battery thermodynamics chlorination roasting kinetics circular economy

The regulatory network and critical factors promoting programmed cell death during embryogenesis

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Journal of Integrative Plant Biology 2025年第1期67卷 55-70页

作者： An Luo Ce shi Pan Luo Zifu Zhao meng-Xiang Sun College of Life Sciences Yangtze UniversityJingzhou 434023China State Key Laboratory of Hybrid Rice College of Life SciencesWuhan UniversityWuhan 430072China

Programmed cell death(PCD)is essential for animal and plant ***,the knowledge of the mechanism regulating PCD in plants remains limited,largely due to technical ***,we determined that the protease NtCP14 could trigger PCD in the embryonic suspensor of tobacco(Nicotiana tabacum),providing a unique opportunity to overcome the limitations by creating synchronous two-celled proembryos with ongoing PCD for transcriptome analysis and regulatory factor ***,we performed comparative transcriptome analysis using isolated two-celled proembryos and explored the potential regulatory network underlying NtCP14-triggered *** phytohormones,calcium,microtubule organization,the immunity system,soluble N-ethylmaleimide-sensitive factor attachment protein receptor proteins,long non-coding RNAs and alternative splicing are addressed as critical factors involved in the early stage of suspensor *** thought to play crucial roles in suspensor PCD are ***,decreased antioxidant gene expression and increased reactive oxygen species(ROS)levels during suspensor PCD suggest a critical role for ROS signaling in the initiation of NtCP14-triggered ***,five genes in the regulatory network are recommended as immediate downstream elements of ***,our analysis outlines an overall molecular network underlying protease-triggered PCD and provides a reliable database and valuable clues for targeting elements immediately downstream of NtCP14 to overcome technical bottlenecks and gain deep insight into the molecular mechanism regulating plant PCD.

关键词： programmed cell death protease reactive oxygen species suspensor transcriptome

New Insights on Gamma-Ray Burst Radiation mechanisms from multiwavelength Observations

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Research in Astronomy and Astrophysics 2025年第2期25卷 3-12页

作者： Yu-Hua Yao Fang-Sheng min shi Chen Yi-Qing Guo College of Physics Chongqing University Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Wisconsin Ice Cube Particle Astrophysics Center University of Wisconsin–Madison University of Chinese Academy of Sciences School of Physics and Astronomy Yunnan University Tianfu Cosmic Ray Research Center

The study of high-energy gamma-ray emission from gamma-ray bursts(GRBs) involves complex synchrotron radiation and synchrotron self-Compton(SSC) scattering mechanisms with multiple parameters exhibiting a wide distribution. Recent advancements in GRB research, particularly the observation of very high energy(VHE,>100 Ge V) radiation, have ushered in a new era of multiwavelength exploration, offering fresh perspectives and limitations for understanding GRB radiation mechanisms. This study aimed to leverage VHE observations to refine constraints on synchrotron + SSC radiation from electrons accelerated by forward shocks. By analyzing two external environments—the uniform interstellar medium and stratified stellar wind medium, we conducted spectral and variability fitting for five specific bursts(GRB 180720B, GRB 190114C, GRB 190829A, GRB 201216C, and GRB 221009A) to identify the optimal parameters characterizing these events. A comparative analysis of model parameter distributions with and without VHE radiation observations reveals that the magnetic energy equipartition factor εBis more concentrated with VHE emissions. This suggests that VHE emissions may offer greater constraints on this microphysical parameter. Additionally, we found that the energy budget between VHE and ke V–me V γ-ray emissions under the SSC radiation exhibits an almost linear relationship, which may serve as a tool to differentiate radiation mechanisms. We anticipate future statistical analyses of additional VHE bursts to validate our findings.

关键词： (transients:) gamma-ray bursts gamma-rays: ISm radiation mechanisms: non-thermal

Insight into the bimetallic structure sensibility of catalytic nitrate reduction over Pd-Cu nanocrystals

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Journal of Environmental Sciences 2025年第3期149卷 221-233页

作者： Zhiqiang Zhang Wenhang Li Cailin Zheng Kunyu Chen Heliang Pang Wenxin shi Jinsuo Lu School of Environmental and municipal Engineering Xi’an University of Architecture and TechnologyXi’an 710055China Key Laboratory of Northwest Water Resources Environment and EcologyMinistry of EducationXian 710055China State Key Laboratory of Urban Water Resource and Environment Harbin Institute of TechnologyHarbin 150090China Construction engineering quality and safety supervision center station House and Urban Rural Development Department of AnkangAnkang 725000China College of Urban Construction and Environmental Engineering Chongqing UniversityChongqing 400044China

Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing ***,the structure of bimetallic has been much less investigated for catalyst ***,two main types of Pd-Cu bimetallic nanocrystal structures,heterostructure and intermetallic,were prepared and characterized using high-resolution transmission electron microscopy(HRTEm),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that two individual Pd and Cu nanocrystals with a mixed interface exist in the heterostructure nanocrystals,while Pd and Cu atoms are uniformly distributed across the intermetallic Pd-Cu *** catalytic nitrate reduction experiments were carried out in a semibatch reactor under constant hydrogen *** nitrate conversion rate of the heterostructure Pd-Cu nanocrystals supported onα-Al_(2)O_(3),γ-Al_(2)O_(3),SBA-15,and XC-72R exhibited 3.82-,6.76-,4.28-,2.44-fold enhancements relative to the intermetallic nanocrystals,and the nitrogen and nitrite were the main products for the heterostructure and intermetallic Pd-Cu nanocrystals,*** indicates that the catalytic nitrate reduction over Pd-Cu catalyst is sensitive to the bimetallic structures of the catalysts,and heterostructure bimetallic nanocrystals exhibit better catalytic performances on both the activity and selectivity,which may provide new insights into the design and optimization of catalysts to improve catalytic activity and selectivity for nitrate reduction in water.

关键词： Catalytic nitrate reduction Pd-Cu bimetallic catalyst Heterostructure Intermetallic Activity and selectivity

Efficient photocatalytic reduction of CO_(2)to formate by a molecular noble metal-free system

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Science China Chemistry 2025年第1期68卷 152-156页

作者： Lihua Zhang Lingjing Chen Huatian shi Yue Wei Gui Chen Tai-Chu Lau School of Environment and Civil Engineering Research Center for Eco-environmental EngineeringDongguan University of TechnologyDongguan 523808China Department of Chemistry and Institute of molecular Functional materials City University of Hong KongHong Kong 999077China

Reducing CO_(2)to carbon-neutral solar fuels can not only alleviate the energy demand but also mitigate the greenhouse *** present,developing an efficient non-noble metal photo/electrocatalytic system for converting CO_(2)to a specific product beyond CO is still a big ***,we report a new cobalt complex bearing 2,2′-bi-1,10-phenanthroline ligand that can photocatalytically reduce CO_(2)to formate(HCOO^(-)).Turnover number(TON)for HCOO^(-)up to 677 with 99%selectivity can be achieved using organic dyes purpurin as photosensitizer and 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole(BIH)as sacrificial reductant in a CO_(2)-saturated NmP/TEA(v/v,3:1)solution under visible light *** potential electrolysis at-1.41 V(***/Ag Cl)in the presence of 12 mm Et_(3)NHBF_(4)also produced HCOO^(-)with Faradaic efficiency of 39%.Spectroscopic and electrochemical studies suggest that a[CoI-H]species is the key intermediate for CO_(2)reduction.

关键词： photocatalysis noble metal-free CO_(2)reduction formate cobalt hydride

Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors

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Chinese Chemical Letters 2025年第1期36卷 561-567页

作者： Ting shi Ziyang Song Yaokang Lv Dazhang Zhu Ling miao Lihua Gan mingxian Liu Shanghai Key Lab of Chemical Assessment and Sustainability School of Chemical Science and EngineeringTongji UniversityShanghai 200092China College of Chemical Engineering Zhejiang University of TechnologyHangzhou 310014China

Customized design of well-defined cathode structures with abundant adsorption sites and rapid diffusion dynamics,holds great promise in filling capacity gap of carbonaceous cathodes towards high-performance Zn-ion hybrid supercapacitors(ZHC).Herein,we fabricate a series of dynamics-oriented hierarchical porous carbons derived from the unique organic-inorganic interpenetrating polymer *** interpenetrating polymer networks are obtained through physically knitting polyferric chloride(PFC)network into the highly crosslinked resorcinol-formaldehyde(RF)*** of covalent bonding,physical interpenetrating force in such RF-PFC networks efficiently relieves the RF skeleton shrinkage upon ***,the in-situ PFC network sacrifices as a structure-directing agent to suppress the macrophase separation,and correspondingly 3D hierarchical porous structure with plentiful ion-diffusion channels(pore volume of 1.35 cm^(3)/g)is generated in the representative HPC_(4) via nanospace occupation and swelling *** removal of Fe fillers leaves behind a large accessible specific surface area of 1550 m^(2)/g for enhanced Zn-ion *** used as the cathode for ZHC,HPC_(4) demonstrates a remarkable electrochemical performance with a specific capacity of 215.1 mAh/g at 0.5 A/g and a high Zn^(2+)ion diffusion coefficient of 11.1×10^(-18)cm^(2)/*** ZHC device yields 117.0 Wh/kg energy output at a power density of 272.1 W/kg,coupled with good cycle lifespan(100,000 cycles@10 A/g).This work inspires innovative insights to accelerate Zn diffusion dynamics by structure elaboration towards high-capacity cathode materials.

关键词： Carbonaceous cathode Interpenetrating polymer networks Zinc-ion hybrid supercapacitors Specific capacity Energy/power density

Structure-phase transformation of bismuth oxide to Ta-Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder heterojunctions for efficient photocatalytic removal of antibiotic

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Journal of Environmental Sciences 2025年第3期149卷 149-163页

作者： man Yang Zhenzhen shi Shaodong Sun Bian Yang Jie Cui Jianing Li Daqin Yun Nian Lei Engineering Research Center of Conducting materials and Composite Technology Ministry of EducationShaanxi Engineering Research Center of Metal-Based Heterogeneous Materials and Advanced Manufacturing TechnologyShaanxi Province Key Laboratory for Electrical Materials and Infiltration TechnologySchool of Materials Science and EngineeringXi’an University of TechnologyXi’an 710048China College of Energy Xiamen UniversityXiamen 361005China Beijing Key Laboratory of Ionic Liquids Clean Process Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Developing heterojunction photocatalyst with well-matched interfaces andmultiple charge transfer paths is vital to boost carrier separation efficiency for photocatalytic antibiotics removal,but still remains a great *** present work,a new strategy of chloride anion intercalation in Bi_(2)O_(3)via one-pot hydrothermal process is *** as-prepared Ta-BiOCl/Bi_(24)O_(31)Cl_(10)(TBB)heterojunctions are featured with Ta-Bi_(24)O_(31)Cl_(10)and Ta-BiOCl lined shoulder-by-shouleder via semi-coherent *** this TBB heterojunctions,the well-matched semi-coherent interfaces and shoulder-by-shoulder structures provide fast electron transfer andmultiple transfer paths,respectively,leading to enhanced visible light response and improved photogenerated charge ***,a type-II heterojunction for photocharge separation has been obtained,in which photogenerated electrons are drove from the CB(conduction band)of Ta-Bi_(24)O_(31)Cl_(10)to the both of bilateral empty CB of Ta-BiOCl and gathered on the CB of Ta-BiOCl,while the photogenerated holes are left on the VB(valence band)of Ta-Bi_(24)O_(31)Cl_(10),effectively hindering the recombination of photogenerated electron-hole ***,the separated electrons can effectively activate dissolved oxygen for the generation of reactive oxygen species(·O_(2)^(−)).Such TBB heterojunctions exhibit remarkably superior photocatalytic degradation activity for tetracycline hydrochloride(TCH)solution to Bi_(2)O_(3),Ta-BiOCl and Ta-Bi_(24)O_(31)Cl_(10).This work not only proposes a Ta-BiOCl/Bi_(24)O_(31)Cl_(10)shoulder-by-shoulder micro-ribbon architectures with semi-coherent interfaces and successive type-Ⅱheterojunction for highly efficient photocatalytic activity,but offers a new insight into the design of highly efficient heterojunction through phasestructure synergistic transformation strategy.

关键词： Heterojunction Bismuth oxide Charge separation/transfer Photocatalytic degradation Catalytic mechanism

Joint Retrieval of Pm_(2.5) Concentration and Aerosol Optical Depth over China Using multi-Task Learning on FY-4A AGRI

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Advances in Atmospheric Sciences 2025年第1期42卷 94-110页

作者： Bo LI Disong FU Ling YANG Xuehua FAN Dazhi YANG Hongrong shi Xiang’ao XIA Electronic Engineering College Chengdu University of Information TechnologyChengdu 610225China Tianjin meteorological Radar Research Trial Center Tianjin Meteorological BureauTianjin 300074China Key Laboratory of middle Atmosphere and Global Environment Observation Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China Research Centre on meteorological Observation Engineering Technology China Meteorological AdministrationBeijing 100081China Key Laboratory of Atmospheric Environment and Extreme meteorology Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China School of Electrical Engineering and Automation Harbin Institute of TechnologyHarbin 150001China University of Chinese Academy of Sciences Beijing 100049China

Aerosol optical depth(AOD)and fine particulate matter with a diameter of less than or equal to 2.5μm(Pm_(2.5))play crucial roles in air quality,human health,and climate ***,the complex correlation of AOD–Pm_(2.5)and the limitations of existing algorithms pose a significant challenge in realizing the accurate joint retrieval of these two parameters at the same *** this point,a multi-task learning(mTL)model,which enables the joint retrieval of Pm_(2.5)concentration and AOD,is proposed and applied on the top-of-the-atmosphere reflectance data gathered by the Fengyun-4A Advanced Geosynchronous Radiation Imager(FY-4A AGRI),and compared to that of two single-task learning models—namely,Random Forest(RF)and Deep Neural Network(DNN).Specifically,mTL achieves a coefficient of determination(R^(2))of 0.88 and a root-mean-square error(RmSE)of 0.10 in AOD *** comparison to RF,the R^(2)increases by 0.04,the RmSE decreases by 0.02,and the percentage of retrieval results falling within the expected error range(Within-EE)rises by 5.55%.The R^(2)and RmSE of Pm_(2.5)retrieval by mTL are 0.84 and 13.76μg m~(-3)*** with RF,the R^(2)increases by 0.06,the RmSE decreases by 4.55μg m~(-3),and the Within-EE increases by 7.28%.Additionally,compared to DNN,mTL shows an increase of 0.01 in R^(2)and a decrease of 0.02 in RmSE in AOD retrieval,with a corresponding increase of 2.89%in *** Pm_(2.5)retrieval,mTL exhibits an increase of 0.05 in R^(2),a decrease of 1.76μg m~(-3)in RmSE,and an increase of 6.83%in *** evaluation suggests that mTL is able to provide simultaneously improved AOD and Pm_(2.5)retrievals,demonstrating a significant advantage in efficiently capturing the spatial distribution of Pm_(2.5)concentration and AOD.

关键词： AOD Pm_(2.5) FY-4A multi-task learning joint retrieval

Tailor-made high elasticity and low-hysteresis hydrogels based on asymmetric H-bonding crosslinking for wearable applications

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Science China Chemistry 2025年第03期 1117-1125页

作者： Xiaofang shi Nan shi miaomiao Dang Chengyu Ji Yingjie Li Peiyi Wu Zhiguo Hu Collaborative Innovation Centre of Henan Province for Green manufacturing of Fine Chemicals Henan Engineering Laboratory of Chemical Pharmaceutical and Biomedical MaterialsSchool of Chemistry and Chemical EngineeringHenan Normal University State Key Laboratory for modification of Chemical Fibers and Polymer materials College of ChemistryChemical Engineering and Biotechnology & Center for Advanced Low-dimension MaterialsDonghua University

The conventional method of fabricating hydrogels constantly confronts the conflict between elasticity and toughness,limiting their repetitive *** the desired elasticity through a simple and low-cost approach is a significant challenge for hydrogels,particularly through rational molecular ***,low-hysteresis and high-toughness hydrogels are developed from the design of a new feature monomer,N-acryloylethylsemicarbazide(NACE).Based on a concept of “asymmetric Hbonding design”,the unique double and triple H-bonding of NACE can result in a novel asymmetric crosslinking polymer with alternating strong and weak H-bonding *** NACE is copolymerized with acrylamide(Am) to regulate the mechanical properties of hydrogel via H-bonding *** P(NACE-Am) ionic hydrogels are obtained simply and rapidly via one-step photopolymerization without a chemical cross-linking *** P(NACE-Am) hydrogels combine superb mechanical elasticity and toughness,and excellent ionic conductivity,showing great potential as durable ionic conductive devices for wearable utilization.

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