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Synthesis of spherical nano-ZSm-5 zeolite with intergranular mesoporous for alkylation of ethylbenzene with ethanol to produce m-diethylbenzene

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Chinese Journal of Chemical Engineering 2024年第3期67卷 298-309页

作者： Siyue Wang Jinhong li Qingxin Xu Shengjie Song Yu'ni Jiang lidong Chen Xin Shi Weiguo Cheng Faculty of Chemistry and Chemical Engineering Liaoning Normal UniversityDalian 110629China Beijing Key laboratory of Ionic liquids Clean Process Key Laboratory of Green Process and EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Catalytic synthesis of m-diethylbenzene(m-DEB)through alkylation of ethylbenzene(EB)may be a promising alternative route in comparison with traditional rectification of mixed DEB,for which the top priority is to develop efficient and stable heterogeneous ***,the spherical nano-ZSm-5 zeolite with abundant intergranular mesoporous is synthesized by the seed-mediated growth method for alkylation of EB with ethanol to produce *** results show that the spherical nano-ZSm-5 zeolite exhibits better stability and higher alkylation activity at a lower temperature than those of commercial micropore *** then,the spherical nano-ZSm-5 is further modified by la_(2)O_(3) through acid treatment followed by immersion *** acid treatment causes nano-ZSm-5 to exhibit the increased pore size but decreased the acid sites,and subsequent la_(2)O_(3) loading reintroduces the weak acid *** a result,the HNO_(3)-la_(2)O_(3)-modified catalyst exhibits a slight increase in EB conversion and DEB yield in comparison with unmodified one,and meanwhile,it still maintains high m-DEB *** catalyst after acid treatment achieves higher catalytic stability besides maintaining the high alkylation activity of EB with *** present study on the spherical nano-HZSm-5 zeolite and its modification catalyst with excellent alkylation ability provides new insights into the production of mDEB.

关键词： Zeolite modification Alkylation reaction m-diethylbenzene Catalyst Fixed-bed

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The 2023 m_(w)6.8 Adassil Earthquake(Chichaoua,morocco)on a steep reverse fault in the deep crust and its geodynamic implications

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Earth and Planetary Physics 2024年第3期8卷 522-534页

作者： Billel Touati WangWang Gu SiDao ni Risheng Chu minHan Sheng QingJie Xue Fouzi Bellalem Said maouche Habibi Yahyaoui School of Earth and Space Sciences University of Science and Technology of ChinaHefei 230026China State Key laboratory of Geodesy and Earth’s Dynamics Innovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhan 430077China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China Centre de Recherche en Astronomie Astrophysique et Géophysique(CRAAG)BP 63BouzaréahAlgiers 16340Algeria Geography and Territory Planning Natural Hazards and Territory Planning LaboratoryBatna 2 UniversityFesdisBatna 05000Algeria

The mw 6.8 Adassil earthquake that occurred in the High Atlas on September 8,2023,was a catastrophic event that provided a rare opportunity to study the mechanics of deep crustal *** research aimed to decipher the rupture characteristics of the Adassil earthquake by analyzing teleseismic waveform data in conjunction with interferometric synthetic aperture radar(InSAR)observations from both ascending and descending *** analysis revealed a reverse fault mechanism with a centroid depth of approximately 28 km,exceeding the typical range for crustal *** result suggests the presence of cooler temperatures in the lower crust,which facilitates the accumulation of tectonic *** earthquake exhibited a steep reverse mechanism,dipping at 70°,accompanied by minor strike-slip *** the geotectonic framework of the High Atlas,known for its volcanic legacy and resulting thermal irregularities,we investigated the potential contributions of these factors to the initiation of the Adassil *** seismicity within the lower crust,away from plate boundaries,calls for extensive research to elucidate its implications for regional seismic hazard *** findings highlight the critical importance of studying and preparing for significant seismic events in similar geological settings,which would provide valuable insights into regional seismic hazard assessments and geodynamic paradigms.

关键词： Adassil earthquake seismogenic fault source depth interferometric synthetic aperture radar(InSAR) seismic waveform joint inversion

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Two mADS-box proteins,AGl9 and AGl15,recruit the FIS-PRC2 complex to trigger the phase transition from endosperm proliferation to embryo development in Arabidopsis

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molecular Plant 2024年第7期17卷 1110-1128页

作者： Shen Zhang Devasantosh mohanty Adnan muzaffar min ni Department of Plant and microbial Biology University of Minnesota at Twin CitiesSaint PaulMinnesota MN 55108United States of AmericaUSA

Spatiotemporal regulation of gene expression by polycomb repressive complex 2(PRc2)is critical for animal and plant *** Arabidopsis fertilization independent seed(FIS)-PRC2 complex functions specifically during plant reproduction from gametogenesis to seed *** a double fertilization event,triploid endosperm proliferates early,followed by the growth of a diploid embryo,which replaces the endosperm in Arabidopsis and many *** genes critical for endosperm proliferation such as IKkU2 and mIni3 are activated after *** we report that two mADS-box AGAmOUS-lIKE(AGl)proteins associate with the key endosperm proliferation loci and recruit the FIS-PRC2 repressive complex at 4-5 days after pollination(DAP).Interestingly,AGl9 and AGl15 only accumulate toward the end of endosperm proliferation at 4-5 DAP and promote the deposition of H3K27me3 marks at key endosperm proliferation *** of AGl9 and AGl15 or overexpression of AGl9 or AGl15 significantly influence endosperm proliferation and ***-wide analysis with cleavage Under Targets and tagmentation(CUT&Tag)sequencing and RNA sequencing revealed the landscape of endosperm H3K27me3 marks and gene expression profiles in Col-0 and agl9 ***&Tag qPCR also demonstrated the occupancy of the two mADS-box proteins and FIS-PRC2 on a few representative target *** studies suggest that mADS-box proteins could potentially recruit PRc2 to regulate many other developmental processes in plants or even in fungi and animals.

关键词： AGl9 AGl15 embryo endosperm IKU2 mEDEA mIni3

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Theoretical modeling and Surface Roughness Prediction of microtextured Surfaces in Ultrasonic Vibration-Assisted milling

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Chinese Journal of mechanical Engineering 2024年第2期37卷 163-183页

作者： Chenbing ni Junjie Zhu Youqiang Wang Dejian liu Xuezhao Wang lida Zhu School of mechanical and Automotive Engineering Qingdao University of TechnologyQingdao 266525China School of mechanical Engineering and Automation Northeastern UniversityShenyang 110819China

Textured surfaces with certain micro/nano structures have been proven to possess some advanced functions,such as reducing friction,improving wear and increasing *** prediction of micro/nano surface textures is of great significance for the design,fabrication and application of functional textured *** this paper,based on the kinematic analysis of cutter teeth,the discretization of ultrasonic machining process,transformation method of coordinate systems and the cubic spline data interpolation,an integrated theoretical model was established to characterize the distribution and geometric features of micro textures on the surfaces machined by different types of ultrasonic vibration-assisted milling(UVAm).Based on the theoretical model,the effect of key process parameters(vibration directions,vibration dimensions,cutting parameters and vibration parameters)on tool trajectories and microtextured surface morphology in UVAm is ***,the effect of phase difference on the elliptical shape in 2D/3D ultrasonic elliptical vibration-assisted milling(UEVAm)was *** to conventional numerical models,the method of the cubic spline data interpolation is applied to the simulation of microtextured surface morphology in UVAm,which is more suitable for characterizing the morphological features of microtextured surfaces than traditional methods due to the presence of numerous micro *** prediction of surface roughness indicates that the magnitude of ultrasonic amplitude in z-direction should be strictly limited in 1D rotary UVAm,2D and 3D UEVAm due to the unfavorable effect of axial ultrasonic vibration on the surface *** study can provide theoretical guidance for the design and fabrication of microtextured surfaces in UVAm.

关键词： Theoretical modeling microtextured surface Ultrasonic vibration-assisted milling Cubic spline interpolation Surface roughness

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Three-year field study on grass growth and soil hydrological properties in biochar-amended soil

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Journal of Rock mechanics and Geotechnical Engineering 2024年第7期16卷 2764-2774页

作者： Haowen Guo Charles Wang Wai Ng Junjun ni Qi Zhang Yuchen Wang Department of Civil and Environmental Engineering The Hong Kong University of Science and TechnologyHong KongChina School of Transportation Southeast UniversityNanjingChina

Field monitoring was conducted to investigate and quantify the long-term effects of peanut shell biochar on soil-grass interaction over three *** 10 m5 m grassed plots were constructed in completely decomposed granitic *** of them were amended,respectively,with 5%and 10%biochar contents(m3/m3)for grass growth,while the third was without biochar *** the threeyear monitoring,plant characteristics,saturated water permeability(ks)of grassed soil and soil suction were *** monitored results show that the grass leaf area index(lAI)and root length density(RlD)with biochar amendment were improved by 38%and 200%,*** the grassed plot without biochar,a threshold RlD existed with a value of 1.7 cm/cm3,beyond which ks raised *** threshold RlD increased by 52%when biochar content increased from 0%to 10%.This implies that biochar may restrict the increase in ks of grassed soil due to the rise in the threshold *** presence of biochar and grass can retain over 100%higher suction after heavy rainfalls,while 54%lower peak suction under evapotranspiration(ET)compared with the non-amended *** can alleviate the negative effects on hydraulic properties caused by plant growth and reduce ET-induced excessive water loss.A 5%peanut shell biochar content is recommended for the long-term management of vegetated earthen infrastructures.

关键词： Soil-grass interaction Biochar long-term Water infiltration Soil drying

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A statistical analysis of the Kappa-type energy spectrum distribution of radiation belt electrons observed by Van Allen Probes

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Earth and Planetary Physics 2024年第2期8卷 368-374页

作者： luHuai Jiao Xin ma YuanNong Zhang TaiFeng Jin Song Fu BinBin ni Department of Space Physics School of Electronic InformationWuhan UniversityWuhan 430072China

The energy spectrum of energetic electrons is a key factor representing the dynamic variations of Earth’s Van Allen radiation *** measurements have indicated that the commonly used maxwellian and Kappa distributions are inadequate for capturing the realistic spectral distributions of radiation belt *** we adopt the Kappa-type(KT)distribution as the fitting function and perform a statistical analysis to investigate the radiation belt electron flux spectra observed by the Van Allen *** calculating the optimal values of the key KT distribution parameters(i.e.,κandθ2)from the observed spectral shapes,we fit the radiation belt electron fluxes at different l-shells under different geomagnetic *** this manner,we obtain typical values of the KT distribution parameters,which are statistically feasible for modeling the radiation belt electron flux profiles during either geomagnetically quiet or active periods.A comparison of the KT distribution model results with those using the maxwellian or Kappa distribution reveals the advantage of the KT distribution for studying the overall properties of the radiation belt electron spectral distribution,which has important implications for deepening the current understanding of the radiation belt electron dynamics under evolving geomagnetic conditions.

关键词： radiation belt electron Kappa-type distribution fitting geomagnetic storm

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Aubry-mather theory for contact Hamiltonian systems III

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Science China mathematics 2024年

作者： Panrui ni lin Wang Shanghai Center for mathematical Sciences Fudan University School of mathematics and Statistics Beijing Institute of Technology

By exploiting the contact Hamiltonian dynamics(T*m × R, Φt) around the Aubry set of contact Hamiltonian systems, we provide a relation among the mather set, the Φt-recurrent set, the strongly static set,the Aubry set, the ma?ne′ set, and the Φt-non-wandering set. moreover, we consider the strongly static set, as a new flow-invariant set between the mather set and the Aubry set in the strictly increasing case. We show that this set plays an essential role in the representation of certain minimal forward weak Kolmogorov-Arnold-moser(KAm) solutions and the existence of transitive orbits around the Aubry set.

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multi-layer hierarchical cellulose nanofibers/carbon nanotubes/vinasse activated carbon composite materials for supercapacitors and electromagnetic interference shielding

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Nano Research 2024年第3期17卷 904-912页

作者： Tianxu Wang Chuanyin Xiong Yongkang Zhang Bo Wang Qing Xiong mengjie Zhao Yonghao ni College of Bioresources Chemical&materials Engineering Shaanxi University of Science and TechnologyXi’an 710021China Department of Chemical and biomedical Engineering The University of MaineOronoME 04469USA University of New Brunswick Limerick Pulp&Paper CtrFrederictonNB E3B 5A3Canada

Developing porous self-supporting electrodes with excellent conductivity,good mechanical properties,and high electrochemical activity is crucial for constructing electrode materials with lightweight,ultra-thin,flexible,and high capacitance *** this work,we prepared a cellulose nanofibers(CNFs)/carbon nanotubes(CNTs)/vinasse activated carbon(VAC)(CCV)composite material with a multi-layer hierarchical conductive structure through simple vacuum filtration and *** this composite material,the self-assembly of CNF provides the main skeleton structure of a multi-layer hierarchical *** provides a fast path for the rapid transfer of electrons and is beneficial for the loss of electromagnetic *** provides sufficient double layer *** synergistic effect of the above three endows CCV composite materials with excellent energy storage performance and electromagnetic interference(EmI)shielding *** addition,we endowed the CCV composite with a certain shape and performance by introducing a vitrimer polymer with a dynamic cross-linked network *** summary,thanks to the synergistic effect of various components in the multi-layer hierarchical structure,CCV composite materials exhibit excellent integration performance,especially stable energy storage performance and EmI shielding *** significant properties make CCV composite materials have great application prospects in the fields of energy storage and intelligent EmI shielding.

关键词： self-supporting electrodes multi-layer hierarchical structure supercapacitors electromagnetic interference shielding

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Random Terpolymer of Carbon Dioxide,Butadiene and Epoxides:Synthesis,Functionalization and Degradability

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Chinese Journal of Chemistry 2024年第14期42卷 1630-1636页

作者： Zi Wang Wuyi Zheng Sicong Yue Kaihao Chen Jun ling Xufeng ni mOE Key laboratory of macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhouZhejiang310058 China Westlake Electronics Group Co. Ltd.HangzhouZhejiang310012 China

The utilization of carbon dioxide(CO_(2))as a C1 feedstock is consistently attractive,especially in the preparation of sustainable polymeric *** this contribution,a terpolymer of CO_(2),1,3-butadiene(BD)and epoxide is synthesized by scandium triflate catalyzed cationic ring-opening copolymerization ofα-ethylidene-δ-vinyl-δ-valerolactone(EVl),an intermediate derived from CO_(2)and BD,with *** obtained terpolymer with a CO_(2)content of 22 mol%has a number-average molecular weight(m_(n))up to 7.8 kg/mol and a dispersity(Đ)of *** reactivity ratios of EVl and cyclohexene oxide(CHO)are determined as 0.01 and 1.07,respectively,suggesting random characteristic of the *** preserved C=C double bonds from BD allow for the further modification of the terpolymer by photoinitiated *** yielded networks are fluorescent and *** method offers enhanced versatility to the synthesis and additional functionalization of CO_(2)-based polymers.

关键词： Ring-opening polymerization Copolymerization Carbon dioxide Butadiene Scandium triflate Fluorescence

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Supramolecular Polymerization of Hydrogen-Bonded Trimers in Bulk and Aqueous medium

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CCS Chemistry 2024年第6期6卷 1458-1465页

作者： Freek V.de Graaf Stef A.H.Jansen Sandra m.C.Schoenmakers Bas van Genabeek marle E.J.Vleugels bart W.l.van den Bersselaar E.W.meijer Ghislaine Vantomme Institute for Complex molecular Systems Laboratory of Macromolecular and Organic ChemistryEindhoven University of Technology5600 MBEindhoven School of Chemistry and RNA Institute University of New South WalesSydneyNew South Wales 2052

Synthetic molecules that form functional noncovalent assemblies in water have received much attention for their potential applications as *** this work,we introduce a novel water-compatible monomer based on the phthalhydrazide moiety that assembles into hydrogen-bonded trimeric *** bulk,the material exhibits a cylindrical nanostructure in the liquid-crystalline phase at elevated temperatures,morphologically distinct from the crystalline lamellar *** water,these molecules effectively form cylinders in a one-dimensional fashion,yielding fibrous *** formation of these supramolecular polymers follows a cooperative mechanism,as evidenced by denaturation *** trimerized pattern represents a new category of aqueous su pramolecular polymers with future prospects for functional complex molecular systems.

关键词： noncovalent chemistry supramolecular polymers hydrogen bonding cooperativity nanostructure

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