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Effects of seepage pressure on the mechanical behaviors and microstructure of sandstone

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2033-2051页

作者： Xuewei liu Juxiang Chen Bin liu Sai Wang Quansheng liu jin luo State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China Faculty of Engineering China University of GeosciencesWuhan430074China Key Laboratory of Safety for Geotechnical and Structural Engineering of Hubei Province School of Civil EngineeringWuhan UniversityWuhan430072China

Surrounding rocks of underground engineering are subjected to long-term seepage pressure,which can deteriorate the mechanical properties and cause serious *** order to understand the impact of seepage pressure on the mechanical property of sandstone,uniaxial compression tests,P-wave velocity measurements,and nuclear magnetic resonance(NMR)tests were conducted on saturated sandstone samples with varied seepage pressures(i.e.0 MPa,3 MPa,4 MPa,5 MPa,6 MPa,7 MPa).The results demonstrate that the mechanical parameters(uniaxial compressive strength,peak strain,elastic modulus,and brittleness index),total energy,elastic strain energy,as well as elastic strain energy ratio,decrease with increasing seepage pressure,while the dissipation energy and dissipation energy ratio ***,as seepage pressure increases,the micro-pores gradually transform into meso-pores and *** increases the cumulative porosity of sandstone and decreases P-wave *** numerical results indicate that as seepage pressure rises,the number of tensile cracks increases progressively,the angle range of microcracks is basically from 50-120to 80-100,and as a result,the failure mode transforms to the tensile-shear mixed failure ***,the effects of seepage pressure on mechanical properties were *** results show that decrease in the effective stress and cohesion under the action of seepage pressure could lead to deterioration of strength behaviors of sandstone.

关键词： Rock mechanics Mechanical property Seepage pressure Numerical simulation Microcracks

Control of Secondary Phases by Solution Treatment in a N-Alloyed High-Mn Cryogenic Steel

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Acta Metallurgica Sinica(English Letters) 2018年第10期31卷 1059-1072页

作者： Xiao-Jiang Wang Xin-Jun Sun Cheng Song Shuai Tong luo-jin liu Huan Chen Wei Han Feng Pan Department of Materials Science and Engineering Tsinghua University Department of Structural Steels Central Iron and Steel Research Institute

The secondary phases of the steels have significant effects on the microstructure and mechanical properties, making controlling these secondary phases important. The control of MnS inclusions and A1N precipitates in a N-alloyed high-Mn twin-induced plastic cryogenic steel via solution treatment was investigated with several different techniques including microstructural characterization, 298 K tensile testing, and 77 K impact testing. The solutionizing temperature （ST） increased from 1323 to 1573 K, where the elongated MnS inclusions and large-sized AlN precipitates became spheroidized and dissolved. The aspect ratio of the MnS inclusions decreased as the ST increased and the number density increased. The impact toughness of the steels showed anisotropy and low impact energy values, due to the elongated MnS inclusions and large-sized AIN precipitates. The anisotropy was eliminated by spheroidizing the MnS inclusions. The impact energy was improved by dissolving the large-sized AlN precipitates during the solution treatment. The austenite grain size increased when the dissolution of the AlN precipitate increased, but the effect of the grain size on the yield strength, toughness, and the strength--ductility balance was weak.

关键词： Cryogenic Solutionizing temperature Low-temperature toughness Spheroidize Dissolution

Interface Design Strategy for GNS/AZ91 Composites with Semi-Coherent Structure

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Acta Metallurgica Sinica(English Letters) 2024年第3期37卷 467-483页

作者： jing-Peng Xiong Yi-Qi Zeng jin-Long liu Wei-Cheng Wang Lan luo Yong liu Key Laboratory of Lightweight and High Strength Structural Materials of Jiangxi Province School of Advanced ManufacturingNanchang UniversityNanchang 330031China School of Physics and Materials Science Nanchang UniversityNanchang 330031China

The interfacial structure plays an important role in the mechanical properties of magnesium matrix composite(MMCs)reinforced with graphene nanosheet(GNS)due to their poor wettability with the Mg *** interface design strategy was proposed to form the semi-coherent interfacial structure with superior bonding *** lattice mismatch and interfacial bonding strength between Mg/rare earth oxide/carbon were utilized as key characteristics to evaluate the interfacial *** oxide(La2O3)was selected as the intermediate candidate due to its low lattice mismatch and high interfacial bonding *** identify the interfacial structure of Mg/La2O3/graphene,first-principles calculations were conducted to calculate the ideal work of separation and electronic structure of the *** demonstrated the presence of strong ionic and covalent interactions at the interface,which theoretically verified the strong interfacial bonding strength among Mg/La2O3/graphene *** experimentally validate the interface strength,MMCs with the interface structure of Mg/La2O3/GNS were *** formation of in-situ La2O3 led to the successful attainment of semi-coherent structures between Mg/La2O3 and La2O3/GNS,resulting in high strength and good ductility of the ***,this work proposes a new approach to interface design in MMCs with an enhancement of mechanical properties.

关键词： Interface design strategy Magnesium matrix composite Graphene nanosheets Semi-coherent interface Mechanical properties

Structural Control of the Getang Carlin-Type Gold Deposit in Southwest China

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Journal of Earth Science 2024年第2期35卷 536-552页

作者： Guoping Zeng Xinlu Hu Diwei luo Jianzhong liu Shuzhen Yao Yongjie jin Wuhan Center China Geological SurveyWuhan430205China Central South China Innovation Center for Geosciences Wuhan430205China Faculty of Earth Resources China University of GeosciencesWuhan430074China Geological Party 105 Guizhou Bureau of Geology and Mineral Exploration&DevelopmentGuiyang550018China

The Getang is a representative Carlin-type gold deposit in Southwest *** has a proven reserve of about 30 tonnes at an average grade of 5.1 g/t *** orebodies occur as strat-abound lenses,and are structurally controlled by shallow NWW-and NE-trending fold-fault systems and the unconformity between the Upper and Middle *** this study,the regional-and deposit-scale structural investigations,joints and finite strain measurements,and stress and dynamic analysis were conducted with an aim to reveal the structural process of the Getang gold deposit and clarify the relationship between the gold mineralization and *** phases of deformation were identified in the deposit:(1)paleokarst was generated by a crustal uplift when the Youjiang Basin experienced extension at the end of the Middle Permian,laying the foundation for the unconformity;(2)the NW-trending structures were formed under a NNE-SSW compression during the Indochina-South China collision(Indosinian orogeny)in Triassic;(3)the NE-trending structures were generated or reactivated under a NW-SE-oriented compression during the Yanshanian intracontinental *** unconformity recorded two episodes of tectonic evolution in the NNE-SSW and NW-SE *** analyses and geochronology data suggest that the Getang gold deposit was formed as a result of tectonic transition from compression to extension during the Yanshanian intracontinental orogeny.

关键词： Carlin-type gold deposit structural features finite strain Getang Southwest China economy geology geochemistry

Enhancing blocking temperature using inverse hydrogen bonds for non-radical bridged dimeric Dy(Ⅲ)single-molecule magnets

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Science China Chemistry 2024年第10期67卷 3328-3338页

作者： Peng-Bo jin Qian-Cheng luo Ye-Ye liu Yan-Zhen Zheng Frontier Institute of Science and Technology State Key Laboratory of Electrical Insulation and Power EquipmentMOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed MatterXi’an Key Laboratory of Electronic Devices and Material Chemistry and School of ChemistryXi’an Jiaotong UniversityXi’an 710054China

Single-molecule magnets(SMMs)are a kind of nanosized magnetic materials that are capable of storing massive bytes of *** coupling the spin centers in a proper manner is a usual approach to promote the working temperature(or blocking temperature)for *** delocalized radicals have been widely employed to accomplish this ***,we show a new manner by using weak but multiple B–H^(δ-)···Dy^(3+)inverse hydrogen bonding(IHB)interactions to control the magnetic couplings in a series of dimeric dysprosiacaborane *** approach leads to a record high T_(B)^(100s)of 10 K among non-radical bridged dimeric SMMs,which is mainly ascribed to strong ferromagnetic coupling(4.38 cm^(-1))and the proper alignment of the magnetic principle axes of the adjacent dysprosium(Ⅲ)*** verifying by theoretical calculations,these results demonstrate that IHB interactions can be used to construct strong axial ferromagnetic coupling and enhancing magnetic blocking temperature for SMMs.

关键词： single-molecule magnets carborane dysprosium ferromagnetic coupling inverse hydrogen bond

Targeting the Warburg effect:A revisited perspective from molecular mechanisms to traditional and innovative therapeutic strategies in cancer

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Acta Pharmaceutica Sinica B 2024年第3期14卷 953-1008页

作者： Minru Liao Dahong Yao Lifeng Wu Chaodan luo Zhiwen Wang jin Zhang Bo liu Department of Biotherapy Cancer Center and State Key Laboratory of BiotherapyWest China HospitalSichuan UniversityChengdu 610041China School of Pharmaceutical Sciences Shenzhen Technology UniversityShenzhen 518118China School of Pharmacy Shenzhen University Medical SchoolShenzhen UniversityShenzhen 518055China Department of Psychology University of Southern CaliforniaLos AngelesCA 90089USA

Cancer reprogramming is an important facilitator of cancer development and survival,with tumor cells exhibiting a preference for aerobic glycolysis beyond oxidative phosphorylation,even under sufficient oxygen supply *** metabolic alteration,known as the Warburg effect,serves as a significant indicator of malignant tumor *** Warburg effect primarily impacts cancer occurrence by influencing the aerobic glycolysis pathway in cancer *** enzymes involved in this process include glucose transporters(GLUTs),HKs,PFKs,LDHs,and ***,the expression of transcriptional regulatory factors and proteins,such as FOXM1,p53,NF-κB,HIF1a,and c-Myc,can also influence cancer ***,lncRNAs,miRNAs,and circular RNAs play a vital role in directly regulating the Warburg ***,gene mutations,tumor microenvironment remodeling,and immune system interactions are closely associated with the Warburg ***,the development of drugs targeting the Warburg effect has exhibited promising potential in tumor *** comprehensive review presents novel directions and approaches for the early diagnosis and treatment of cancer patients by conducting in-depth research and summarizing the bright prospects of targeting the Warburg effect in cancer.

关键词： Warburg effect Cancer Regulatory factor LncRNAs miRNAs Traditional Chinese medicine Small-molecule drug Drug resistance

Biological Interaction and Imaging of Ultrasmall Gold Nanoparticles

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Nano-Micro Letters 2024年第3期16卷 69-98页

作者： Dongmiao Sang Xiaoxi luo jinbin liu Key Laboratory of Functional Molecular Engineering of Guangdong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640People’s Republic of China

Ultrasmall gold nanoparticles(AuNPs)typically includes atomically precise gold nanoclusters(AuNCs)and AuNPs with a core size below 3 *** as a bridge between small molecules and traditional inorganic nanoparticles,the ultrasmall AuNPs show the unique advantages of both small molecules(e.g.,rapid distribution,renal clearance,low non-specific organ accumulation)and nanoparticles(e.g.,long blood circulation and enhanced permeability and retention effect).The emergence of ultrasmall AuNPs creates significant opportunities to address many challenges in the health field including disease diagnosis,monitoring and *** the nano–bio interaction dictates the overall biological applications of the ultrasmall AuNPs,this review elucidates the recent advances in the biological interactions and imaging of ultrasmall *** begin with the introduction of the factors that influence the cellular interactions of ultrasmall *** then discuss the organ interactions,especially focus on the interactions of the liver and *** further present the recent advances in the tumor interactions of ultrasmall *** addition,the imaging performance of the ultrasmall AuNPs is summarized and ***,we summarize this review and provide some perspective on the future research direction of the ultrasmall AuNPs,aiming to accelerate their clinical translation.

关键词： Ultrasmall gold nanoparticle Cellular interaction Organ interaction Tumor interaction Bioimaging

Microbes in mass extinction: an accomplice or a savior?

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National Science Review 2024年第1期11卷 12-15页

作者： Genming luo Deng liu Hao Yang State Key Laboratory of Geobiology and Environmental Geology China University of Geosciences (Wuhan)

Microbes include various types of organisms that are invisible to the naked eye,e.g. bacteria, archaea and microeukaryotes. Although the precise number remains largely unknown, microbes are recognized as the unseen majority of our biosphere [1]. As a group of organisms classified by body size, microbes cover a considerable spectrum of metabolisms,

关键词： AFTERMATH

Effect of Al_(2)O_(3)fiber on twin intersections-induced dynamic recrystallization in fine-grained TiAl matrix composite

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Journal of Materials Science & Technology 2024年第5期172卷 1-14页

作者： Yaofeng luo Yan Wang Li Wang Bin liu Yong liu State Key Laboratory of Powder Metallurgy Central South UniversityChangsha 410083China

Dynamic recrystallization(DRX)is of great significance for the thermomechanical processing and microstructural regulation of TiAl ***,the underlying DRX mechanism remains poorly *** this study,an Avrami kinetics model for DRX was established,which was capable of predicting the DRX fraction *** addition,the effect of Al_(2)O_(3)short fiber on the DRX mechanisms of TiAl matrix composite during the isothermal compression was investigated for the first *** re-sults showed that other than inhibiting DRX by particles in the TiAl matrix composites,the addition of Al_(2)O_(3)short fiber accelerated a novel DRX process,which was induced by twinning and twin intersec-tions(TDRX).Thus,this composite exhibited a higher DRX rate than that of the as-cast TiAl monolithic *** origin of the twin intersection and TDRX for the composite was *** stress concentration near the Al_(2)O_(3)fiber was above the critical shear stress for twinning and thus was favorable for the formation of twinning and twin *** high stored strain energy at the regions of twins and twin intersections provided the driving force for *** accelerated the grain refinement in the TiAl matrix near the Al_(2)O_(3)*** present findings would provide a new perspective on DRX mechanisms,and provide the scientific guidance for optimizing the microstructures of TiAl matrix composites.

关键词： TiAl matrix composite Al_(2)O_(3)fiber Twin intersection Dynamic recrystallization