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Rare earth metal as a dopant element:Cerium ion as an articulator in hexavalent chromium removal by magnetic iron oxides

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Journal of Rare Earths 2023年第10期41卷 1616-1626,I0006页

作者： Pricila Maria Batista Chagas Maísa M.M.Lima Aline Aparecida Caetano lucas bragança carvalho Nayra Maria de Abreu Piva Maria Eduarda Resende Luiz Iara do Rosário Guimarães Laboratory of Environmental Catalysis and New Materials Department of ChemistryFederal University of LavrasCEP 37200-900LavrasMGBrazil Department of Viticulture&Enology University of CaliforniaDavisCA95616USA Institute of Science and Technology São Paulo State University18087-180SorocabaBrazil

This study highlights introducing the rare earth metal cerium(Ce(Ⅳ))into the structure of magnetite(Fe_(3)O_(4))to achieve enhanced adsorptive properties for the removal of chromium(Cr(VI))from an aqueous *** ratios of Ce(Ⅳ)were introduced into the iron oxide matrix,termed FeCe-5,FeCe-10,and *** numerical values correspond to the nominal content of the dopant element added to the synthesis *** solid materials were characterized for morphology and chemical structure,and N_(2)physical adsorption/desorption measurements were *** solid materials doped with Ce(IV)have a high surface area compared to Fe_(3)O_(4),and the solid material with the highest content of the dopant ion(Ce(IV))has a 4-fold greater surface *** increase in the dopant content in the iron oxide structure leads to a total chromium removal of 93.3%.Isotherms studies on the solid materials show that chromium adsorption follows the Langmuir *** adsorption capacity to Fe_(3)O_(4)is 12.59 mg/g and FeCe-10 is 22.49 mg/g at 35℃.By fitting the kinetic and isothermal models,it is found that for the Fe_(3)O_(4)and FeCe-10 materials Cr(VI)removal occurs in very different ways,attributed to the different surface areas and compositions of the oxide,with the formation of the goethite(α-FeOOH)*** FeCe-10reuse process was performed and the removal capacity the Cr(VI)is reduced after the first *** result is attributed to a strong and irreversible adsorption of Cr(VI)on the FeCe-10.

关键词： Bimetallic oxides Fe-Ce interaction Oxygen vacancies Adsorption Cr(Ⅵ) Rare earths

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Parasite Fauna of Lutjanus synagris Commercialized in the Fish Market from bragança-PA,Brazil

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Journal of Zoological Research 2019年第3期1卷 1-4页

作者： Natalino da Costa Sousa Daiana Silva dos Santos Silmara Rosa Silva Alexandre Vaz da Silva Jucimauro de Araújo P.Junior João Vitor Antunes Miranda Pedro Rodrigo Nery de Souza Matheus carvalho de Melo Fagner de Melo Xavier Wellington Lima da Silva Junior Fabricio Ramos Menezes Márcia Valeria Silva do Couto Federal University of Pará(UFPA) Campus BragançaAlameda Leandro RibeiroBragança68600-000PABrazil Federal University of Pará(UFPA) Campus Tucuruí-ParáBrazil Federal University of Sergipe(UFS) Departamento de Pesca e Aquicultura.Aracaju-SergipeBrazil Instituto Federal do Pará(IFPA) Campus de Cametá-ParáBrazil

Studies about the parasite fauna of marine fish highlights as an important problem for public health with zoonotic parasites or affecting the fish ***,this study evaluated the parasite fauna of Lutjanus synagris commercialized in the fish market from braganç*** laboratory,58 fish were measured,weighted and conducted to parasitological analysis to determine parasitological indexes and relative *** parasite was fixed and identified until to the lowest taxonomic *** the parasitological analysis,it found Cymothoidae,Digenea,Cucullanus *** Procamallanus(Spirocamallanus)sp.,with total prevalence 67.24%.Digenea showed the highest prevalence and mean intensity *** nematode,Cucullanus *** the greater prevalence and relative dominance,while Procamallanus(Spirocamallanus)*** the greater mean intensity and *** showed the lowest prevalence and mean intensity *** conclusion,the parasite fauna of *** has been noted with low diversity,reporting the nematode occurrence Procamallanus(Spirocamallanus).

关键词： Cymothoidae Parasite Marine fish

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