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Mercury Levels Assessment in the Population of Aby and Frambo Villages in the Vinicity of Aby Lagoon in Côte d’Ivoire (West Africa)

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Journal of Water Resource and Protection 2024年第3期16卷 219-232页

作者： Stéphane Jean Claon Serge kouakou Kouassi Nina Laurette Ahouéfa Laurent Kipré Seri Arsène M’bassidjé Seka Joseph Allico Djaman luc kouakou kouadio Analytical Sciences and Public Health Department University of Félix Houphou&eumlt-Boigny Abidjan C&ocircte d'Ivoire Water Quality Control and Analysis Laboratory (LACQUE) Office National de l’Eau Potable (ONEP) Abidjan C&ocircte d’Ivoire Biology and Health Laboratory University of Félix Houphou&eumlt-Boigny Abidjan C&ocircte d’Ivoire Laboratory of Nutrition and Food Safety Department of Science and Food Technology Nangui Abrogoua University Abidjan C&ocircte d'Ivoire Department of Medical and Fundamental Biochemistry Institut Pasteur of C&ocircte d'Ivoire Abidjan C&ocircte d’Ivoire Laboratory of Environmental Sciences (LSE) University of Nangui Abrogoua Abidjan C&ocircte d’Ivoire

The Minamata Convention in the aim to protect human life and the environment, seeks to reduce mercury (Hg) by monitoring it concentrations in the environment. Artisanal and Small-scale Gold Mining (ASGM) has been identified as the most important anthropogenic source of human exposure to Hg. In this context, the main goal of this study was to assess the level of mercury in hair of two (2) populations living along two lagoons respectively Aby and Tendo, in Ivory Coast. To reach this goal, hair samples of 138 residents were collected and analyzed by using Cold Vapor Atomic Fluorescence Spectrophotometry (CV-AFS) technique for mercury concentration. Results showed that for the entire population the Hg mean was 2.34 μg/g. Also, they were ranged between 0.15 to 8.53 μg/g and presented substantial differences amongst the villages. In Aby village, we observed the highest Hg concentrations (Mean = 2.62 μg/g). Our findings showed that almost the entire sample group (82%) exceed the USEPA recommended limit, furthermore 56% of them exceed the normal level of WHO and 2% of the respondent has the unhealthy levels of mercury (≥6 μg Hg/g) of hair by WHO standards. Gender differences in hair mercury varies greatly among reports. Lower levels in women’s hair compared to men were reported in the both village. Considering age, the lowest concentrations were observed with children. However, when we take in account the age groups, data suggested that the most exposed sub-population of [18-29] years old is from Aby village in opposite at Frambo village, the same case those who were ≥ 40 years old. It’s convenient to note that, the proportion of Mercury levels would not to be neglected among studied population especially with the resident from Aby village. So, some measures need to be taken at the political level to control mercury contamination.

关键词： Mercury Hair ASGM Population Exposure Côte d’Ivoire

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Assessment of Selenium Contamination in Sediments of the Aby and Tendo Lagoons in Côte d’Ivoire

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International Journal of Geosciences 2024年第4期15卷 334-349页

作者： Stéphane Jean Claon kouakou Serge Kouassi Kossonou Roland N’Guettia M’bassidjé Arsène Seka Guei Jokebed Dakouo Allico Joseph Djaman kouakou luc kouadio Analytical Sciences and Public Health Department University of F&#233lix Houphou&#235t-Boigny Abidjan C&#244te d&#8217Ivoire Water Quality Control and Analysis Laboratory (LACQUE) Office National de l&#8217Eau Potable (ONEP) Abidjan C&#244te d&#8217Ivoire Biology and Health Laboratory University of F&#233lix Houphou&#235t-Boigny Abidjan C&#244te d&#8217Ivoire Laboratory of Environmental Sciences (LSE) University of Nangui Abrogoua Abidjan C&#244te d&#8217Ivoire Department of Medical and Fundamental Biochemistry Institut Pasteur of C&#244te d&#8217Ivoire Abidjan C&#244te d&#8217Ivoire

Selenium is a trace element that can have both beneficial and harmful effects on aquatic life. The Aby Lagoon is a coastal environment in Côte d’Ivoire that receives selenium inputs from various natural and anthropogenic sources. The aim of this study was to assess the levels of selenium in the sediments of the Aby Lagoon and its tributaries, the Tanoe River and the Tendo Lagoon, and to examine the spatial and seasonal variations of selenium concentrations. Sediment samples were collected from different sites and seasons, and selenium concentrations were measured by atomic fluorescence spectrometry. The results showed that the average concentration of selenium in the sediments of the Aby Lagoon was 0.82 mg/kg, indicating moderate contamination. The concentration of selenium varied between sites and seasons, with higher values in the channel of the Tendo Lagoon and during the dry season. The study highlighted the complexity of selenium dynamics in aquatic ecosystems, and the need to take into account seasonal and spatial variability as well as interactions between environmental factors. The study also suggested potential ecotoxicological risks for some sensitive organisms in certain areas of the lagoon. This study contributes to the knowledge of the dynamics of selenium in lagoon ecosystems and to the assessment of the environmental risks associated with its presence.

关键词： Tropical Estuarine Selenium Sediments Aby Lagoon Seasonal Distribution

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Exposure of Mercury from Gold Ming Area: A Case Study in Tendo and Aby Lagoon in Côte d’Ivoire

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Journal of Environmental Protection 2022年第9期13卷 613-627页

作者： Stéphane Jean Claon Serge kouakou Kouassi Séka Arsène M’bassidje Laurent Kipré Séri luc kouakou kouadio Joseph Allico Djaman Public Health and Hydrology Laboratory Félix Houphou&euml t-Boigny University Abidjan C&ocirc te d’Ivoire Water Quality Control and Analysis Laboratory National Drinking Water Office Abidjan C&ocirc te d’Ivoire Biology and Health Laboratory Félix Houphou&euml t-Boigny University Abidjan C&ocirc te d’Ivoire Environmental Sciences Laboratory Nanguy Abrogoua University Abidjan C&ocirc te d’Ivoire Department of Medical and Fundamental Biochemistry Institut Pasteur of C&ocirc te d’Ivoire Abidjan C&ocirc te d’Ivoire

Lagoons of West African countries are seriously threatened by rapid artisanal and small-scale gold mining (ASGM) that exposes lagoons to mercury pollution. In this study, the mercury level in the sediments of the Tendo and Aby lagoons in Côte d’Ivoire had been evaluated. A total of 87 samples from 25 stations located on Tendo and Aby lagoons were analyzed by atomic fluorescence spectrometry. The mean Hg concentrations obtained in the sediments of Tendo and Aby lagoons were 0.89 ± 0.26 mg⋅kg-1 and 0.70 ± 0.18 mg⋅kg-1, respectively. Hg concentrations evaluated in the bays of Tendo and Aby during the dry season were 1.38 ± 0.45 mg⋅kg-1 and 1.07 ± 0.31 mg⋅kg-1, respectively. The minimum and maximum total Hg concentrations in the sediments from 25 stations were 0.04 and 3.56 mg⋅kg-1, respectively. Mercury contamination in lagoons during ASGM poses risks of pollution for the lagoon ecosystem and also poses health risks for the population living near these lagoons.

关键词： ASGM Mercury Sediments Côte d’Ivoire Pollution

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Occurrence of Enterobacter sakazakii(Cronobacter)and Other Enterobacteriaceae in Commercial Powdered Infant Formula in Abidjan,Ivory Coast

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Food and Nutrition Sciences 2012年第6期3卷 822-826页

作者： kouadio Yao Nanga Yessé Zinzendorf Guichard Bohoua Kra Athanase Kouassi Amian Koua luc kouakou kouadio Patrice Kouamé Guillaume Yao Loukou Department of Sciences and Food Technology University of Abobo-AdjaméAbidjanCote d’Ivoire Department of Microbiology National Laboratory of Public HealthAbidjanCote d’Ivoire Department of Bacteriology and Virology University of CocodyAbidjanCote d’Ivoire Deprtment of Hydrology and Public Health University of CocodyAbidjanCôte d’Ivoire Laboratory of Biology National Institut of Public HealthAbidjanCote d’Ivoire

To determine the occurrence of Enterobacter sakazakii and other Enerobateriaceae in commercial powdered infant formula (PIF), 185 packages of PIF from different manufacturers, supermarkets and drug-stores in Abidjan were analyzed. Ten g of sample was homogenized in 90 ml of buffered peptone water (PBW, Biorad, Paris) for further studies. Enterobacteriaceae (coliforms) were enumerated according to French Association of Standardization methods. E. sakazakii was detected according to Kandhai’s method. Bacteria were identified using API20 system. Thirty-eight samples (20.5%) were positive for Enterobacteriaceae. Twenty-four samples (13%) yielded Enterobacter sakazakii. Other Enterobacteriaceae isolated included Pantoea spp. 21 (11.5%), Klebsiella pneumoniae subsp. Pneumonia 8 (4.3%), Citrobacter diversus 1 (0.5%), Citrobacter freundii 1 (0.5%), Enterobacter cloacae 1 (0.5%), Salmonella reading 1 (0.5%), Serratia ficara 1 (0.5%) Serratia odorifera 1 (0.5%). This study is the first report to describe the contamination of PIF from Abidjan with E. sakazakii and several other Enterobacteriaceae that could be opportunistic pathogens. Therefore, well-controlled studies need to be conducted to assess the extent of risk associated with contaminated PIF for infants in Abidjan.

关键词： Enterobacteriaceae Enterobacter sakazakii Powedered Infant Formulat

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Detection of Burned Areas through Spectral Indices Analysis of Sentinel-2A Satellite Images in the Abokouamékro Wildlife Reserve (Central, Côte D’Ivoire)

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Open Journal of Applied Sciences 2024年第1期14卷 205-222页

作者： Bob kouakou kouadio Sié Ouattara Alain Clément Jean-Marc Gala Bi Zaouri Jean-luc kouadio Kouassi Jean-luc Edouard kouakou N’guessan Laboratoire des Sciences et Technologies de la Communication et de l’Information (LSTCI) Institut National Polytechnique Houphou&#235t Boigny (INP-HB) Yamoussoukro C&#244te d’Ivoire Laboratoire des Sciences Agronomiques et Génie Rural Institut National Polytechnique Houphou&#235t Boigny (INPHB) Yamoussoukro C&#244te d’Ivoire Ecole de Géomatique et du Territoire (EGT) Abidjan C&#244te d’Ivoire LARIS SFR MATHSTIC Université d’Angers Angers France Centre Universitaire de Recherche et d’application en Télédétection (CURAT) UFR des Sciences de la Terre et des Ressources Minières Abidjan C&#244te d’Ivoire Laboratoire de Botanique UFR Biosciences Université Félix Houphou&#235t Boigny Abidjan C&#244te d’Ivoire

In Côte d’Ivoire, the recurring and unregulated use of bushfires, which cause ecological damage, presents a pressing concern for the custodians of protected areas. This study aims to enhance our comprehension of the dynamics of burnt areas within the Abokouamékro Wildlife Reserve (AWR) by employing the analysis of spectral indices derived from satellite imagery. The research methodology began with the calculation of mean indices and their corresponding spectral sub-indices, including NDVI, SAVI, NDWI, NDMI, BAI, NBR, TCW, TCG, and TCB, utilizing data from the Sentinel-2A satellite image dated January 17, 2022. Subsequently, a fuzzy classification model was applied to these various indices and sub-indices, guided by the degree of membership α, with the goal of effectively distinguishing between burned and unburned areas. Following the classification, the accuracies of the classified indices and sub-indices were validated using the coordinates of 100 data points collected within the AWR through GPS technology. The results revealed that the overall accuracy of all indices and sub-indices declines as the degree of membership α decreases from 1 to 0. Among the mean spectral indices, NDVI-mean, SAVI-mean, NDMI-mean exhibited the highest overall accuracies, achieving 97%, 95%, and 90%, respectively. These results closely mirrored those obtained by sub-indices using band 8 (NDVI-B8, SAVI-B8, and NDMI-B8), which yield respective overall accuracies of 93%, 92%, and 89%. At a degree of membership α = 1, the estimated burned areas for the most effective indices encompassed 2144.38 hectares for NDVI-mean, 1932.14 hectares for mean SAVI-mean, and 4947.13 hectares for mean NDMI-mean. A prospective approach involving the amalgamation of these three indices could have the potential to yield improved outcomes. This study could be a substantial contribution to the discrimination of bushfires in Côte d’Ivoire.

关键词： Spectral Indices Wildfire Burned Areas Abokouamékro Wildlife Reserve Côte D’Ivoire

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Assessment of Nitrates and Nitrites in Borehole Water from the Southern and the Northern Region of Côte d’Ivoire (West Africa)

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Open Journal of Modern Hydrology 2024年第2期14卷 87-105页

作者： Jean Stéphane Claon Kouassi kouakou Serge Sérikipré Laurent Seka M’Bassidjé Arsène N’Guettia Kossonou Roland Traoré Aïcha Djamanallico Joseph kouadio kouakou luc Analytical Sciences and Public Health Department University of Félix Houphou&#235t-Boigny Abidjan C&#244te d’Ivoire Water Quality Control and Analysis Laboratory (LACQUE) Office National de l’Eau Potable (ONEP) Abidjan C&#244te d’Ivoire Biology and Health Laboratory University of Félix Houphou&#235t-Boigny Abidjan C&#244te d’Ivoire Department of Medical and Fundamental Biochemistry Institut Pasteur of C&#244te d’Ivoire Abidjan C&#244te d’Ivoire Laboratory of Environmental Sciences (LSE) University of Nangui Abrogoua Abidjan C&#244te d’Ivoire

This study aimed to evaluate the quality of water from village boreholes by measuring physicochemical parameters such as nitrates, nitrites, and total organic carbon (TOC). Forty-five (45) village pumps from the Southern (Basse Côte) and the Northern (Korhogo) region of Cte d’Ivoire (west Africa) were sampled. Physicochemical parameters such as temperature, pH, conductivity at 25˚C, and turbidity were determined in situ, while nitrite and nitrate were analyzed according to ISO 10304-1 (2007) standard and total organic carbon (TOC) by NF EN 1484 (1997) standard. The results showed that the borehole waters of the Basse Côte and Korhogo analyzed are acidic, with an average temperature of 27.51˚C ± 0.16˚C and 29.95˚C ± 0.51˚C respectively for the Basse Côte and Korhogo regions. The borehole waters of the Basse Côtedo not contain nitrites, while those of Korhogo have average nitrite contents of 0.32 mg/l. The average nitrate rate in the waters of the Basse Côte and Korhogo are 12.08 ± 2.11 mg/l and 11.03 ± 3.18 mg/l respectively. The average TOC concentration of the waters of the Basse Côte is 1.28 ± 0.32 mg/l and that of Korhogo is 0.56 ± 0.09 mg/L. The study showed that the borehole waters of the Basse Côte and Korhogo have average temperatures between 27.4˚C and 29.95˚C with a slightly acidic pH value and acceptable salinity. The TOC concentrations obtained at the different sampling points were all below the French standard (2 mg/L) except for certains pumps of the Basse Côte. The water samples from the Basse Côte were devoid of nitrite. On the other hand, those from Korhogo revealed the presence of nitrite. Also, the borehole waters of the regions of the Basse Côte and Korhogo contain relatively high nitrate contents, presumably due to anthropometric activity. Overall, our study on the quality of drinking water showed that the waters analyzed are in compliance with international standards and safe for consumption.

关键词： Drinking Water pH Turbidity TOC Nitrates Nitrites Health Effect

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Petrographic, Geochemical and Metallogenical Context of the Geological Formations of the Goumere Region (North-East of Cote D’Ivoire): Implication to the Knowledge of Gold Mineralization

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International Journal of Geosciences 2024年第2期15卷 180-203页

作者： Fossou Jean-luc Hervé kouadio Alain Nicaise Kouamelan Topka Kakeu Lionel Boya Roger Nicaise Kanga Laboratory of Geology Mineral and Energy Resources (LGRME) Faculty of Earth Science and Mineral Resources Félix Houphou&#235t Boigny University Abidjan C&#244te d’Ivoire

The Gouméré region is located in the North-East of Côte d’Ivoire and is located in the South-West of the Bui furrow. In order to highlight the geology of the area studied, 14 samples were taken for studies using petrographic, geochemical and metallogenic methods. The study of macroscopic and microscopic petrography made it possible to highlight two major lithological units: 1) a volcano-plutonic unit, formed of gabbros, basalt, volcaniclastics and rhyodacite;2) a sedimentary unit (microconglomerate). From a geochemical point of view, the results obtained indicate that the plutonites are gabbro and gabbro diorite while the volcanics have compositions of basaltic andesites, rhyolite and dacites. The sediments have a litharenitic to sublitharenitic character. The metallogenic study made it possible to highlight hydrothermal alterations and metalliferous paragenesis on the formations studied. Hydrothermal alteration is characterized by the presence of carbonation, silicification, sericitization, sulfidation and to a lesser degree chloritization. Metalliferous paragenesis consists of pyrite, chalcopyrite, hematite and magnetite.

关键词： Petrography Geochemistry Metallogeny Gouméré Côte d’Ivoire

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Screening for Hepatitis B and C in Occupational Settings: Cross-Sectional Study about 4268 Corporates Agents in Cote d’Ivoire

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Open Journal of Gastroenterology 2017年第3期7卷 89-95页

作者： Constant Assi Amadou Ouattara Siaka Kone Dramane Soro Emile Allah-kouadio Claude Ghislain kouakou Nigué luc Benoit-Mathieu Camara Marie-Jeanne Lohoues-Kouacou Teaching Hospital Center of Cocody Abidjan Cote d’Ivoire

Aim: To screen hepatitis B and C in occupational setting. Methods: Cross-sectional study multicenter in 16 enterprises (one occupational exposure;5602 agents). Screening was preceded by information, sensibilisation and informed consenting physician labor, labor union and agents. Hepatitis B surface antigen (HBsAg) and antibodies anti-hepatitis C (Elisa, third generation) were tested in all. For those with HBsAg positive, this test was completed by IgM and IgG, anti HBc, HBeAg, antibodies anti HBe, transaminases and HBB DNA;for those with positive anti-VHC antibodies, test was completed by transaminases and VHC’s RNA. Results: Rate of participation was 76.2% (4268/5602 labors). HBsAg or hepatitis C antibodies were positives in 425 (9.9%) of cases (HBsAg positive: 8.48%;Hepatitis C Antibodies positives: 1.50%;both: 0.05%). In HBsAg positive, viral replication and cytolysis were seen respectively in 2.5 % and 18.2%. According with transaminases, serologic markers and viral load, immunotolerance, inactive and immuno active phase were suspected in 0.56%, 80.9% and 1.6% of cases. In hepatitis C antibodies positives persons, any had viral replication but cytolysis was observed in 33.3% (n = 21). HBsAg was significantively (p < 0.00001) higher in exposed occupational enterprise versus non-occupational setting (14.4% vs 7.8%). They were no differences (p = 0.71) about hepatitis C antibodies in the two setting (1.8% vs 1.7%). Conclusion: Prevalence of HBsAg and hepatitis C antibodies was high in occupational setting in hepatitis endemic country. It’s important to screen all of person in these setting with no consideration with blood exposed or not exposed enterprise.

关键词： Hepatitis B and C Screening Occupational Setting Blood Exposed Enterprise

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Structural Control of Auriferous Mineralization in the Birimian: Case of the Agbahou Deposit in the Region of Divo, Côte d’Ivoire

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International Journal of Geosciences 2017年第2期8卷 189-204页

作者： N’Guessan Nestor Houssou Marc Ephrem Allialy Fossou Jean-luc Hervé kouadio Allou Gnanzou Geology of Basement and Metallogeny Laboratory (GBML) Training and Research Unit of Earth Sciences and Mining Re-sources University of Felix HOUPHOUET-BOIGNY Abidjan-Cocody Cote d’Ivoire

Located in the southwestern of the Oume-Fettekro greenstone belt, the Agbahou gold deposit is controlled by structural factors. Geophysics, teledetection and core data suggest the presence of NE and NW faults. However, the NE-faults define two major shear zones (ATZ: Agbahou Tectonic Zone and WTZ: West Tectonic Zone) that control the Agbahou gold mineralization. These first order structures are subparallel to the regional tectonic grain mostly north-east oriented. They seem to respectively develop on the both arms (eastern and western) of an anticline moderately plunging ~25° towards northeast. Each shear-zone contains several second-order shear-zones or lenses of variable direction and of 50° - 80° dip. NW-faults however correspond to strike-slip faults and their development should be related to transcurrent tectonics. They acted as control channels on the distribution of gold mineralizations. The ductile-brittle character of shear-zones favored the ascent of hydrothermal fluids and the formation of multiple auriferous quartz veins: veins Type IIa and veins Type IIb relating respectively to the shear-veins and extensional veins. However, Agbahou also shows the existence of a disseminated sulphides-bearing mineralization within host-rocks. At Agbahou, the precipitation of gold probably occurred in a post to late ductile-brittle deformation period.

关键词： Gold-Bearing Mineralization Structural Control Birimian Agbahou Ivory Coast

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Geochemistry of Mafic Rocks from the Birimian Basement of Doropo (Northeast of Côte d’Ivoire): Petrogenetic and Geodynamic Implications

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Open Journal of Geology 2022年第6期12卷 504-520页

作者： Wilfried Digbeu Alain Nicaise Kouamelan Asinne Tshibubudze Ziandjêdé Hervé Siagne Fossou Jean-luc Hervé kouadio Laboratoire de Géologie Ressources Minérales et Energétiques Université Félix Houphou&#235 t-Boigny Abidjan-Cocody C&#244 te d’Ivoire Council for Geosciences Pretoria South Africa

The northeastern region of Côte d’Ivoire is characterised by a granitic basement mainly composed of biotite granite rocks. According to mapping work in the Gbabédjou and Doropo areas, these Birimian granitoids are cut by gabbro dykes and amphibolite enclaves, which are the subject of this study. In order to better understand the role and the implication of mafic rocks in the Doropo basement emplacement, a multidisciplinary methodology integrating microscopic observations and geochemical analyses of major and trace elements was carried out on 4 samples considered representative of the outcrops studied. Green hornblende, clinopyroxene, and accessory sphene minerals are found in mafic mineral phases, according to petrographic research. Whole-rock analyses reveal that mafic samples with TiO2 contents 1.1 ratios giving them an orogenic granite nature (I-type). Their REE patterns are moderately fractionated (La/Sm)N = 2.66 - 6.13 and (La/Yb)N = 11.17 - 43.70) with a very negative Eu anomaly (Eu/Eu* = 0.75 - 0.97). The multi-element diagrams are characterized by negative Nb-Ta anomalies and geotectonic studies have identified them as volcanic arc formations. All these characteristics allowed us to distinguish the Doropo mafic rocks as formations originating from the juvenile continental crust, emplaced under the Archean tectonics model with significant crustal contamination in the source. Magma driven by mantle diapir has been injected at the base of the continental crust and the heat induces the partial melting of the overlying crust giving rise to mixed liquids. This magma now enriched in LILE was immediately drained to the upper crust to form the mafic rocks from the studied area.

关键词： Doropo Mafic Intrusive Birimian Crustal Contamination

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