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Precision tuning of highly efficient Pt-based ternary alloys on nitrogen-doped multi-wall carbon nanotubes for methanol oxidation reaction

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Journal of Energy Chemistry 2024年第1期88卷 242-251,I0006页

作者： Xingqun Zheng Zhengcheng Wang Qian Zhou Qingmei Wang Wei He shun lu College of Safety Engineering Chongqing University of Science&TechnologyChongqing 401331China College of Chemistry and Chemical Engineering Chongqing UniversityChongqing 400044China School of Chemistry and Chemical Engineering Guizhou UniversityGuizhou 550025GuiyangChina Department of Chemistry University of Rhode IslandKingston 02881Rhode IslandUnited States Chongqing Institute of Green and Intelligent Technology Chinese Academy of SciencesChongqing 400714China

The electrochemical methanol oxidation is a crucial reaction in the conversion of renewable *** enable the widespread adoption of direct methanol fuel cells(DMFCs),it is essential to create and engineer catalysts that are both highly effective and robust for conducting the methanol oxidation reaction(MOR).In this work,trimetallic PtCoRu electrocatalysts on nitrogen-doped carbon and multi-wall carbon nanotubes(PtCoRu@NC/MWCNTs)were prepared through a two-pot synthetic *** acceleration of CO oxidation to CO_(2) and the blocking of CO reduction on adjacent Pt active sites were attributed to the crucial role played by cobalt atoms in the as-prepared *** precise control of Co atoms loading was achieved through precursor *** physicochemical techniques were employed to analyze the morphology,element composition,and electronic state of the *** investigations and theoretical calculations confirmed that the Pt_(1)Co_(3)Ru_(1)@NC/MWCNTs exhibit excellent electrocatalytic performance and durability for the process of *** enhanced MOR activity can be attributed to the synergistic effect between the multiple elements resulting from precisely controlled Co loading content on surface of the electrocatalyst,which facilitates efficient charge *** interaction between the multiple components also modifies the electronic structures of active sites,thereby promoting the conversion of intermediates and accelerating the MOR ***,achieving precise control over Co loading in PtCoRu@NC/MWCNTs would enable the development of high-performance catalysts for DMFCs.

关键词： Ternary alloys Electrocatalysts Methanol oxidation reaction Electron transfer Theoretical calculations

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Efficient electroreduction of nitrate via enriched active phases on copper-cobalt oxides

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Chinese Chemical Letters 2024年第4期35卷 204-209页

作者： Ling Fang Sha Wang shun lu Fengjun Yin Yujie Dai Lin Chang Hong Liu Chongqing Institute of Green and Intelligent Technology Chinese Academy of SciencesChongqing 400714China University of Chinese Academy of Sciences Beijing 100049China

Electrochemical conversion of nitrate(NO_(3)~-) to ammonia(NH_(3)) can target two birds with one stone well, in NO_(3)^(-)-containing sewage remediation and sustainable NH_(3) production. However, single metalbased catalysts are difficult to drive high-efficient NO_(3)~- removal due to the multi-electron transfer ***, we present a tandem catalyst with simple structure, Cu-Co binary metal oxides(Cu-Co-O), by engineering intermediate phases as catalytic active species for NO_(3)~- conversion. Electrochemical evaluation,X-ray photoelectron spectroscopy, and in situ Raman spectra together suggest that the newly-generated Cu-based phases was prone to NO_(3)~- to NO_(2)~- conversion, then NO_(2)~- was reduced to NH_(3) on Co-based species. At an applied potential of -1.1 V vs. saturated calomel electrode, the Cu-Co-O catalyst achieved NO_(3)~- -N removal of 90% and NH_(3) faradaic efficiency of 81% for 120 min in 100 m L of 50 mg/L NO_(3)~- -N,consuming only 0.69 k Wh/mol in a two-electrode system. This study provides a facile and efficient engineering strategy for developing high-performance catalysts for electrocatalytic nitrate conversion.

关键词： NO_(3)^(-)-containing sewage remediation Electrocatalytic reduction Copper-cobalt oxides Tandem reactivity Enriched active phases

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One-step hydrothermal synthesis of few-layered metallic phase MoS2 for high-performance supercapacitors

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Progress in Natural Science:Materials International 2024年第2期34卷 429-436页

作者： Jing Xu Xulong Yuan Yujie Zhao Shaoqi Rui Qingling Jia Han Li shun lu Bing Li Yongxing Zhang Xuebin Zhu Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation Anhui Province Key Laboratory of Intelligent Computing and Applications Anhui Province Industrial Generic Technology Research Center for Alumics Materials Huaibei Normal University Chongqing Institute of Green and Intelligent Technology Chinese Academy of Sciences Key Laboratory of Materials Physics Institute of Solid State Physics HFIPS Chinese Academy of Sciences

In recent years,molybdenum disulfide（MoS2） has gained significant attention in the scientific *** MoS2demonstrates unique properties and potential ***,the synthesis of few-layered and high-purity 1T-MoS2is still a *** this study,we successfully employed a hydrothermal method to synthesize few-layered and high-purity *** purity of the material is controlled by a combination of sodium borohydride and ***,the few-layered 1T-MoS2exhibits exceptional performance as a supercapacitor,including the high specific capacitance(250.3 F g-1at a current density of 1 A g-1) and excellent long-trem cycling stability（90.7 % after 5000 cycles）.Meanwhile,the asymmetric device assembled by 6-FL-1TMoS2and active carbon on carbon cloths exhibits excellent flexibility and high energy and power density(23.1μWh cm-2at 600 μW cm-2,55 μWh cm-2at 12000 μW cm-2).This work provides valuable insights into the synthesis of few-layered and high-purity 1T-MoS2,opening up new avenues for further research and applications.

关键词： 1T-MoS2 Few-layered High-purity One-pot hydrothermal method Supercapacitor

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IMpower210:A phase Ⅲ study of second-line atezolizumab vs. docetaxel in East Asian patients with non-small cell lung cancer

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Chinese Journal of Cancer Research 2024年第2期36卷 103-113页

作者： Yi-Long Wu shun lu Gongyan Chen Jianxing He Jifeng Feng Yiping Zhang Liyan Jiang Hongming Pan Jianhua Chang Jian Fang Amy Cai Lilian Bu Jane Shi Jinjing Xia Guangdong lung Cancer Institute Guangdong Provincial Key Laboratory of Translational Medicine in Lung CancerGuangdong Provincial People's Hospital&Guangdong Academy of Medical SciencesSouthern Medical UniversityGuangzhou 510080China Shanghai lung Cancer Center Shanghai Chest HospitalSchool of MedicineShanghai Jiao Tong UniversityShanghai 200025China Department of Respiration Harbin Cancer HospitalHarbin Medical UniversityHarbin 150081China Department of Thoracic Oncology and Surgery the First Affliated Hospital of Guangzhou Medical UniversityGuangzhou 510120China Department of Medical Oncology Jiangsu Cancer HospitalNanjing 210009China Department of Medical Oncology Zhejiang Cancer HospitalHangzhou 330022China Department of Pulmonary Medicine Shanghai Chest HospitalShanghai Jiao Tong UniversityShanghai 200030China Department of Medical Oncology Sir Run Run Shaw HospitalZhejiang University School of MedicineHangzhou 310016China Department of Medical Oncology Shenzhen HospitalCancer Hospital of Chinese Academy of Medical SciencesShenzhen 518116China Department of Thoracic Oncology Beijing Cancer HospitalBeijing 100142China Product Development Shanghai Roche Pharmaceutical LtdShanghai 201203China

Objective: IMpower210(NCT02813785) explored the efficacy and safety of single-agent atezolizumab *** as second-line treatment for advanced non-small cell lung cancer(NSCLC) in East Asian ***: Key eligibility criteria for this phase Ⅲ, open-label, randomized study included age ≥18 years;histologically documented advanced NSCLC per the Union for International Cancer Control/American Joint Committee on Cancer staging system(7th edition);Eastern Cooperative Oncology Group performance status of 0 or 1;and disease progression following platinum-based chemotherapy for advanced or metastatic NSCLC. Patients were randomized 2:1 to receive either atezolizumab(1,200 mg) or docetaxel(75 mg/m^(2)). The primary study endpoint was overall survival(OS) in the intention-to-treat(ITT) population with wild-type epidermal growth factor receptor expression(ITT EGFR-WT) and in the overall ITT ***: Median OS in the ITT EGFR-WT population(n=467) was 12.3 [95% confidence interval(95% CI),10.3-13.8] months in the atezolizumab arm(n=312) and 9.9(95% CI, 7.8-13.9) months in the docetaxel arm[n=155;stratified hazard ratio(HR), 0.82;95% CI, 0.66-1.03]. Median OS in the overall ITT population was 12.5(95% CI, 10.8-13.8) months with atezolizumab treatment and 11.1(95% CI, 8.4-14.2) months(n=377) with docetaxel treatment(n=188;stratified HR, 0.87;95% CI, 0.71-1.08). Grade 3/4 treatment-related adverse events(TRAEs) occurred in 18.4% of patients in the atezolizumab arm and 50.0% of patients in the docetaxel ***: IMpower210 did not meet its primary efficacy endpoint of OS in the ITT EGFR-WT or overall ITT populations. Atezolizumab was comparatively more tolerable than docetaxel, with a lower incidence of grade3/4 TRAEs.

关键词： Atezolizumab East Asia non-small cell lung cancer programmed death-ligand 1 inhibitors monoclonal antibody

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导电酞菁基金属有机框架的高效电催化研究（英文）

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化学进展 2024年第3期36卷 285-296页

作者：陆顺刘元刘鸿中国科学院重庆绿色智能技术研究院

在满足日益增长的可持续能源和环境保护需求下，开发用于多种电化学场景的新型催化剂发挥着重要作用。导电酞菁基金属有机框架（MOFs）是一类新型的层叠多孔MOFs，具有面内扩展π共轭结构，可以通过促进传质和电子/电荷转移来增强电催... 详细信息

在满足日益增长的可持续能源和环境保护需求下，开发用于多种电化学场景的新型催化剂发挥着重要作用。导电酞菁基金属有机框架（MOFs）是一类新型的层叠多孔MOFs，具有面内扩展π共轭结构，可以通过促进传质和电子/电荷转移来增强电催化活性。导电酞菁基MOFs具有优异的导电性，使其在如水、氧、二氧化碳和氮还原等各种电催化反应中非常有前景。导电酞菁基MOFs在电化学能量转换和环境研究中表现出良好的活性。本文主要关注导电酞菁基MOFs，而非其他类型的导电MOFs，并全面概述其导电机理和主要的电催化反应，还将讨论在电催化中使用导电酞菁基MOFs作为非均相催化剂的最新进展。此外，本文将探讨与导电酞菁基MOFs在电催化中的应用的挑战和展望。

关键词：导电金属有机框架酞菁基金属有机骨架共轭结构电催化

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SHR-A1811 (antibody-drug conjugate) in advanced HER2-mutant non-small cell lung cancer: a multicenter, open-label, phase 1/2 study

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SIGNAL TRANSDUCTION AND TARGETED THERAPY 2024年第1期9卷 1-10页

作者： Li, Ziming Song, Zhengbo Hong, Wei Yang, Nong Wang, Yongsheng Jian, Hong Liang, Zibin Hu, Sheng Peng, Min Yu, Yan Wang, Yan Jiao, Zicong Zhao, Kaijing Song, Ke Li, You Shi, Wei lu, shun Shanghai Jiao Tong Univ Shanghai Chest Hosp Shanghai Lung Canc Ctr Sch Med Shanghai 200030 Peoples R China Zhejiang Canc Hosp Phase Clin Trial Ward 1 Hangzhou 310000 Peoples R China Zhejiang Canc Hosp Dept Thorac Oncol Hangzhou 310000 Peoples R China Hunan Canc Hosp Dept Lung & Gastrointestinal Oncol Changsha 410031 Peoples R China Sichuan Univ West China Hosp Thorac Oncol Ward Canc Ctr Chengdu 610041 Peoples R China Sun Yat Sen Univ Affiliated Hosp 5 Dept Thorac Oncol Zhuhai 519000 Peoples R China Hubei Canc Hosp Dept Med Oncol Wuhan 430000 Peoples R China Wuhan Univ Dept Oncol Renmin Hosp Wuhan 430200 Peoples R China Harbin Med Univ Dept Thorac Med Canc Hosp Harbin 150081 Peoples R China Chinese Acad Med Sci Canc Hosp Dept Med Oncol Beijing 100021 Peoples R China Geneplus Beijing Co Ltd Beijing 102206 Peoples R China Jiangsu Hengrui Pharmaceut Co Ltd Shanghai 200120 Peoples R China

A dose-escalation and expansion, phase 1/2 study (***, NCT04818333) was conducted to assess the novel antibody-drug conjugate SHR-A1811 in pretreated HER2-altered advanced non-small cell lung cancer (NSCLC). Here, we report results from the phase 1 portion. Patients who had previously failed or were intolerant to platinum-based chemotherapy were enrolled and received SHR-A1811 intravenously at doses of 3.2 to 8.0 mg/kg every 3 weeks. Dose escalation followed a Bayesian logistic regression model that included overdose control, with subsequent selection of tolerable levels for dose expansion. Overall, 63 patients were enrolled, including 43 receiving a recommended dose for expansion of 4.8 mg/kg. All patients had HER2-mutant disease. Dose-limiting toxicity occurred in one patient in the 8.0 mg/kg dose cohort. Grade >= 3 treatment-related adverse events occurred in 29 (46.0%) patients. One patient in the 6.4 mg/kg cohort died due to interstitial lung disease. As of April 11, 2023, the 4.8 mg/kg cohort showed an objective response rate of 41.9% (95% CI 27.0-57.9), and a disease control rate of 95.3% (95% CI 84.2-99.4). The median duration of response was 13.7 months, with 13 of 18 responses ongoing. The median progression-free survival was 8.4 months (95% CI 7.1-15.0). SHR-A1811 demonstrated favourable safety and clinically meaningful efficacy in pretreated advanced HER2-mutant NSCLC.

关键词： FACTOR RECEPTOR 2 TRASTUZUMAB DERUXTECAN ADVANCED BREAST HER2 EXPRESSION EMTANSINE TUMORS

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基于创新性内侧壁成型工艺的多光学通道微型碱金属原子气室

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Engineering 2024年第4期35卷 46-55页

作者： Mingzhi Yu Yao Chen Yongliang Wang Xiangguang Han Guoxi luo Libo Zhao Yanbin Wang Yintao Ma shun lu Ping Yang Qijing Lin Kaifei Wang Zhuangde Jiang International Joint Laboratory for Micro/Nano Manufacturing and Measurement Technologies Xi’an Jiaotong UniversityXi’an 710049China School of Mechanical Engineering Xi’an Jiaotong UniversityXi’an 710049China Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing Yantai 265503China Moon Environment Technology Co. Ltd.Yantai 264000China Emergency Department The First Affiliated Hospital of Xi’an Jiaotong UniversityXi’an 710061China

Existing microfabricated atomic vapor cells have only one optical channel,which is insufficient for supporting the multiple orthogonal beams required by atomic *** this study,we present a novel wafer-level manufacturing process for fabricating multi-optical-channel atomic vapor cells and an innovative method for batch processing the inner sidewalls of millimeter glass holes to meet optical channel *** characterization and transmittance tests demonstrate that the processed inner sidewalls satisfy the criteria for an optical *** addition,the construction of an integrated processing platform enables multilayer non-isothermal anode bonding,the filling of inert gases,and the recovery and recycling of noble *** of the absorption spectra and free-induction decay signals of xenon-129(^(129)Xe)and xenon-131(^(131)Xe)under different pump-probe schemes demonstrate the suitability of our vapor cell for use in atomic devices including atomic gyroscopes,dual-beam atomic magnetometers,and other optical/atomic *** proposed micromolding technology has broad application prospects in the field of optical-device processing.

关键词： Microfabricated atomic vapor cells Inner-sidewall molding Multiple optical channels Quantum sensing

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二维材料用于电化学法制备过氧化氢的研究进展

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材料导报 2024年第11期38卷 21-33页

作者：盛雄李邦兴陆顺陆文强李晓锋康帅重庆理工大学理学院重庆400054 中国科学院重庆绿色智能技术研究院重庆400714 重庆市计量质量检测研究院重庆401123

用电化学的方法通过氧还原反应生产过氧化氢更为环保和有效,而实现这一途径的关键在于制备高活性、高选择性和高稳定性的电催化剂。贵金属催化剂是首选,其催化活性好且稳定性高。但是,贵金属成本高,不利于过氧化氢的规模化制备。因此,... 详细信息

用电化学的方法通过氧还原反应生产过氧化氢更为环保和有效,而实现这一途径的关键在于制备高活性、高选择性和高稳定性的电催化剂。贵金属催化剂是首选,其催化活性好且稳定性高。但是,贵金属成本高,不利于过氧化氢的规模化制备。因此,减少贵金属用量或者寻找低成本的可替代品一直是近年来的研究热点。很多非贵金属材料已被用作氧还原反应的电催化剂,其中部分材料和贵金属的催化性能相当,甚至更加优异。二维材料相比于本体材料更利于电子传递且更加容易进行化学修饰,二维材料的原子利用率高,可以给电化学反应提供较大的反应场所和更多的裸露活性位点。本文根据已报道的大量实验和理论计算研究,讨论了用二电子氧还原反应法制备过氧化氢的反应机理,然后列举了近年来石墨烯类催化材料、二维过渡金属硫族化合物、二维共价有机骨架和二维金属有机骨架、石墨相氮化碳、二维过渡金属碳/氮化物在电催化氧还原反应中的研究进展,重点分析了其电化学反应机理。最后,指出了二维材料在二电子氧还原反应中的研究挑战和趋势。

关键词：电催化氧还原反应过氧化氢二维材料

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基于行动导向教学模式的高职《财务管理》教学方法探究

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湖北开放职业学院学报 2024年第1期37卷 174-176页

作者：鲁务顺无锡商业职业技术学院江苏无锡214153

科技革命和数字经济对教育提出了新的要求,教学不但要秉承传统教育的知识传授,更需关注学生独立思考能力和创造能力的培养,养成使学生能够自主同时有能力开展智力活动的习惯。传统以教师为主导的教学模式更多关注学生知识的接收与掌握,... 详细信息

科技革命和数字经济对教育提出了新的要求,教学不但要秉承传统教育的知识传授,更需关注学生独立思考能力和创造能力的培养,养成使学生能够自主同时有能力开展智力活动的习惯。传统以教师为主导的教学模式更多关注学生知识的接收与掌握,忽略了发现和探索学习的重要性。基于行动导向的教学模式关注批判理解,强调学生学习内容与探究式学习方法的关联性,从而把握事物的实质,深入理解核心概念和原理,提升自我学习、自我探究的学习能力。

关键词：行动导向财务管理教学方法

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银行业规模分布与流动性创造效率

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经济体制改革 2024年第2期 157-166页

作者：高远东陆子顺孙成己西南大学经济管理学院重庆400715 中国政法大学商学院

基于中国银行业规模分布的特征事实,考察银行业规模分布对流动性创造效率的潜在影响,研究发现:中国银行业规模分布表现出幂律分布特征,且时间上呈现先集中化后多元化的趋势,空间上中小银行的分布趋于多元化,较大规模的银行趋于集中;多... 详细信息

基于中国银行业规模分布的特征事实,考察银行业规模分布对流动性创造效率的潜在影响,研究发现:中国银行业规模分布表现出幂律分布特征,且时间上呈现先集中化后多元化的趋势,空间上中小银行的分布趋于多元化,较大规模的银行趋于集中;多元化的银行业规模分布提升了流动性创造效率;进一步分析表明,相较于较大规模的银行,中小银行规模分布趋于多元化对于提升流动性创造效率更为显著。据此,应完善银行业准入政策,继续引导银行业的规模多元化发展,更好地服务实体经济;中小银行应深入挖掘其规模与区位优势,强化市场竞争力,与大型商业银行共同构建细分工、广覆盖的多元化银行业规模分布体系;相关部门应关注银行业规模分布情况,积极探索适应不同地区与经济发展变化的最优金融结构。

关键词：银行规模银行业结构流动性创造

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