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Chemical Research in Chinese Universities 2025年第1期41卷 21-32页

作者： PEI Hanwen ZHANG Jun sun Zhaoyan State Key Laboratory of Polymer Physics and Chemistry&Key Laboratory of Polymer Science and Technology Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun130022P.R.China School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei230026P.R.China

Molecular dynamics simulations are conducted to investigate the deposition patterns of cyclic diblock copolymer solution nanodroplets on solid surfaces(walls).The primary focus is how initial polymer concentration,chain length,and solvent-wall interaction affect these *** patterns are categorized into phase diagrams,mainly composed of multihollow,coffee-ring,and multilayer *** also study the deposition of polymer blocks with different adsorption behavior by adjusting the interaction strength between the polymer block and the wall[ε_(A(B)W)],including weakly adsorbable(ε_(A(B)W)=0.6),moderately adsorbable(ε_(A(B)W)=1.0),and strongly adsorbable(εA(B)W=1.2)polymer *** study identifies the key factors influencing the droplet’s deposition structure and elucidates the mechanisms behind pattern *** findings contribute to the design of deposition patterns for cyclic diblock copolymer solution nanodroplets,enhancing applications related to droplet evaporation.

关键词： Cyclic diblock copolymer Nanodroplet Evaporation Deposition pattern Chain length and concentration

Unraveling the complex interactions between plasmonic Ag nanoparticles and biomolecules for enhancing molecular chirality

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Science China Chemistry 2025年第2期68卷 543-551页

作者： Chen Wang Yunlong Tao Qingqing Cheng Dandan Lu Chuang Liu Guizeng Yang Xuehao sun Lichao sun Qingfeng Zhang College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power SourcesWuhan UniversityWuhan 430072China Suzhou Institute of Wuhan University Suzhou 215123China

Plasmonic nanostructures have been widely employed to enhance the chiral light-matter interactions for chirality sensing owing to their intriguing optical ***,a quantitative understanding of the correlation between enhanced molecular chirality and plasmonic properties in plasmonic nanoparticle-molecule complexes remains a challenge yet to be *** we demonstrate the complex interactions between Ag nanoparticles and biomolecules that generate distinct plasmonic circular dichroism signals ranging from UV to visible *** deliberately changing the surface coverage of chiral molecules,the geometry of Ag nanoparticles,and the aggregation states of the complexes,three distinct underlying mechanisms were found to be intertwined and hybridized for enhancing circular dichroism *** further employed the chiral plasmonic nanoparticle-molecule complexes to quantify the enantiomeric purity of cysteine and explore their possible applications in other chiral *** insights gained from this work shed light on the underlying mechanisms dictating the enhanced circular dichroism signals of chiral plasmonic nanoparticle-molecule complexes.

关键词： chiral plasmonics plasmonic circular dichroism nanoparticle-molecule complexes Ag nanoparticles chirality sensing

MetaCoorNet: an improved generated residual network for grasping pose estimation

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Science China(Information Sciences) 2025年第03期68卷 242-257页

作者： Hejia GAO Chuanfeng HE Junjie ZHAO Changyin sun School of Artificial Intelligence Anhui University Engineering Research Center of Autonomous Unmanned System Technology Ministry of Education Anhui Provincial Key Laboratory of Security Artificial Intelligence Anhui University School of Automation Southeast University

Robotic grasping presents significant challenges due to variations in object properties, environmental complexities,and the demand for real-time operation. This study proposes the MetaCoorNet(MCN), which is a novel deep learning architecture specifically designed to address these challenges in robotic grasping pose estimation. By combining spatial and channel operators, the MetaCoor block is utilized to extract features efficiently. This architecture enhances feature selectivity by embedding location information into channel attention using a positional embedding technique within the coordinate attention mechanism. Consequently, the proposed MCN can focus on pertinent grasp-related regions. Furthermore, convolutional fusion blocks seamlessly integrate spatial and channel features, resulting in enhanced feature resolution and representation *** innovative design enables the proposed MCN to achieve state-of-the-art performance on the Cornell and Jacquard datasets,attaining accuracies of 98% and 91.2%, respectively. The effectiveness and robustness of MCN are further validated through real-world experiments conducted using a seven-degree-of-freedom Kinova manipulator.

关键词： generative ResNet meta light block coordinate attention feature resolution robot grasping

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Output Consensus of Heterogeneous Linear MASs via Adaptive Event-Triggered Feedback Combination Control

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 285-287页

作者： Shuo Yuan Chengpu Yu Jian sun the School of Automation Beijing Institute of Technology the Beijing Institute of Technology Chongqing Innovation Center

Dear Editor,This letter studies output consensus problem of heterogeneous linear multiagent systems over directed graphs. A novel adaptive dynamic event-triggered controller is presented based only on the feedback combination of the agent's own state and neighbors' output,which can achieve exponential output consensus through intermittent communication. The controller is obtained by solving two linear matrix equations, and Zeno behavior is excluded.

关键词： Directed graphs

An Unprecedented Efficiency with Approaching 21%Enabled by Additive‑Assisted Layer‑by‑Layer Processing in Organic Solar Cells

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Nano-Micro Letters 2025年第2期17卷 372-375页

作者： Shuai Xu Youdi Zhang Yanna sun Pei Cheng Zhaoyang Yao Ning Li long Ye Lijian Zuo Ke Gao Key Laboratory of Advanced Green Functional Materials College of ChemistryChangchun Normal UniversityChangchun 130032People’s Republic of China Shandong Provincial Key Laboratory for Science of Material Creation and Energy Conversion School of Chemistry and Chemical EngineeringShandong UniversityQingdao 266237People’s Republic of China College of Polymer Science and Engineering Sichuan UniversityChengdu 610065People’s Republic of China State Key Laboratory and Institute of Elemento‑Organic Chemistry Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071People’s Republic of China Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and Devices South China University of TechnologyGuangzhou 510640People’s Republic of China Tianjin Key Laboratory of Molecular Optoelectronic Sciences School of Materials Science and EngineeringTianjin UniversityTianjin 300350People’s Republic of China State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China

Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer *** optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture *** approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs.

关键词： Organic solar cells Additive-assisted layer-by-layer processing Three-dimensional fibril morphology Bulk p-i-n structure Optical management

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新能源车企创新与消费者购买的行为差异研究——基于政府补贴有效性视角

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工业技术经济 2025年第2期44卷 15-24页

作者：李娜孙龙上海财经大学经济学院上海200433 复旦大学管理学院上海200433

本文基于契约理论的视角,将补贴视为政府为企业与消费者提供的“契约”,构建政府补贴与车企和消费者的演化博弈模型,探讨补贴退坡的现实下新能源汽车产业的发展道路。研究发现,政府与企业、政府与消费者各存在两种演化稳定策略:(1)政府... 详细信息

本文基于契约理论的视角,将补贴视为政府为企业与消费者提供的“契约”,构建政府补贴与车企和消费者的演化博弈模型,探讨补贴退坡的现实下新能源汽车产业的发展道路。研究发现,政府与企业、政府与消费者各存在两种演化稳定策略:(1)政府没有对企业创新进行补贴激励时,企业选择传统方式生产;(2)政府对企业进行补贴时,企业选择科技创新;(3)政府没有对消费者购买进行补贴激励时,消费者选择新能源汽车;(4)政府对消费者进行补贴时,消费者购买传统汽车。其中“政府对企业进行补贴且企业选择科技创新”“政府没有补贴而消费者选择新能源汽车”两个稳定策略更能实现社会福利最大化,据此提出政策建议。

关键词：契约理论政府补贴新能源汽车演化博弈消费者购买企业创新行为差异委托-代理理论

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Improved reference-frame-independent quantum key distribution with intensity fluctuations

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Chinese Physics B 2025年第2期34卷 48-52页

作者： Zi-Qi Chen Hao-Bing sun Ming-Shuo sun Qin Wang Institute of Quantum Information and Technology Nanjing University of Posts and TelecommunicationsNanjing 210003China Broadband Wireless Communication and Sensor Network Technology Key Laboratory of Ministry of EducationNanjing University of Posts and TelecommunicationsNanjing 210003China

Reference-frame-independent quantum key distribution(RFI-QKD) can avoid real-time calibration operation of reference frames and improve the efficiency of the communication process. However, due to imperfections of optical devices,there will inevitably exist intensity fluctuations in the source side of the QKD system, which will affect the final secure key rate. To reduce the influence of intensity fluctuations, an improved 3-intensity RFI-QKD scheme is proposed in this *** considering statistical fluctuations and implementing global parameter optimization, we conduct corresponding simulation analysis. The results show that our present work can present both higher key rate and a farther transmission distance than the standard method.

关键词： quantum key distribution intensity fluctuations decoy-state method

Zooplankton community composition in summers of 2021and 2022 in the northern East China Sea and Yellow Sea,and their linkage with abiotic and biotic factors

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Journal of Oceanology and Limnology 2025年第1期43卷 159-176页

作者： Dongjie GUO Fang ZHANG Shuangyan ZHANG Song sun CAS Key Laboratory of Marine Ecology and Environmental Sciences Institute of OceanologyChinese Academy of SciencesQingdao 266071China College of Marine Science University of Chinese Academy of SciencesQingdao 266071China Jiaozhou Bay National Marine Ecosystem Research Station Institute of OceanologyChinese Academy of SciencesQingdao 266071China

The northern East China Sea and Yellow Sea are highly dynamic marginal seas,serving as important fishing grounds and primary areas for *** zooplankton community structure,including abundance,biovolume,and normalized biovolume size spectra(NBSS)within this ecosystem in summers 2021 and 2022 was assessed through ZooScan digital imaging *** abundances of zooplankton in summers 2021 and 2022 were 3364.22±2190.53 and 4435.52±2520.06 inds./m^(3),respectively,whereas the corresponding biovolumes were 649.10±519.63 and 1064.86±1254.87 mm^(3)/m^(3),*** copepods as the dominant zooplankton functional group in terms of abundance in both years,while chaetognath and medusae were the dominant groups in terms of *** dominance of medusae and chaetognath in terms of biovolume,along with the flatter slopes of NBSS compared to a stable community,indicated that more energy accumulated in gelatinous organisms within the study *** were significant positive relationships between temperature and tunicates or medusae,with a significantly higher population size observed in summer 2022 than in *** lower abundance and biovolume of zooplankton,mainly of small copepods,in summer 2021 may be related to the larger population size of the large jellyfish and the proliferation of green *** investigation provided basic data and fundamental insights for achieving a comprehensive understanding of zooplankton community structure and their long-term dynamics.

关键词： zooplankton community spatial distribution global warming Nemopilema nomurai Ulva prolifera

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A Mn-porphyrinic metal–organic framework immobilizing glucose oxidase for combined photodynamic/chemodynamic/starvation therapy

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Tungsten 2025年第1期7卷 183-194页

作者： Xin-Ran sun Hao-Ming Yuan Guo-Da Zhang Chao Wang Shu-Juan sun Peng-Fei Shi Shandong Provincial Key Laboratory of Detection Technology for Tumor Markers School of Chemistry and Chemical Engineering Linyi University

The combination of photodynamic therapy（PDT） and chemodynamic therapy（CDT） in tumor treatment has attracted considerable ***,tumor hypoxia and glutathione（GSH） overproduction in the tumor tissue restricted the progress of their ***,a Mn-porphyrinic metal-organic framework（Mn-TCPP） was constructed by the one-pot method and further used for immobilizing glucose oxidase（GOx） to obtain GOx@*** would rapidly exhaust endogenous glucose into hydrogen peroxide（H2O2） and gluconic acid,thus shutting off the energy supply of tumor cells for starvation ***-TCPP catalyzed H2O2to produce oxygen,regulating the hypoxic tumor microenvironment and in turn improving1O2generation under laser ***,Mn-TCPP can reduce reactive oxygen species consumption owing to the redox reaction between Mn3+and GSH,thus greatly enhancing ***,benefiting from GOx-mediated starvation therapy,Mn2+produced by Mn3+reduction can react with sufficient intracellular H2O2to generate ·OH with high cytotoxicity through a Fenton-like *** treatment by GOx@Mn-TCPP under laser irradiation in vitro,the cell viability of 4T1 and A549 tumor cells reached to 20%,reflecting GOx@Mn-TCPP could give full play to the advantages of PDT/CDT/starvation *** results in vivo demonstrated that GOx@Mn-TCPP mediated synergistic cascade therapy could significantly inhibit tumor growth and improve the therapeutic effect.

关键词： Chemodynamic therapy Immobilizing enzyme Metal–organic frameworks Photodynamic therapy Starvation therapy

Recycling Fe and improving organic pollutant removal via in situ forming magnetic core-shell Fe_(3)O_(4)@CaFe-LDH in Fe(Ⅱ)-catalyzed oxidative wastewater treatment

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Journal of Environmental Sciences 2025年第1期147卷 523-537页

作者： Ting He Jie sun Liangwei Deng Jialin Ming Changwei Hu Key Laboratory of Green Chemistry and Technology Ministry of EducationCollege of ChemistrySichuan UniversityChengdu 610064China Biogas Institute of Ministry of Agriculture and Rural Affairs Chengdu 610041China Inner Mongolia Key Laboratory of Fine Organic Synthesis Inner Mongolia UniversityHohhot 010021China

Due to its high efficiency,Fe(Ⅱ)-based catalytic oxidation has been one of the most popular types of technology for treating growing organic pollutants.A lot of chemical Fe sludge alongwith various refractory pollutantswas concomitantly produced,whichmay cause secondary environmental problemswithout proper *** here innovatively proposed an effective method of achieving zero Fe sludge,reusing Fe resources(Fe recovery=100%)and advancing organics removal(final TOC removal>70%)simultaneously,based on the in situ formation of magnetic Ca-Fe layered double hydroxide(Fe_(3)O_(4)@CaFe-LDH)***(Ca^(2+)and Fe^(3+))concentration(≥30 mmol/L)and their molar ratio(Ca:Fe≥1.75)were crucial to the success of the *** nano Fe_(3)O_(4)was designed to be involved in the Fe(Ⅱ)-catalytic wastewater treatment process,and was modified by oxidation intermediates/products(especially those with COO-structure),which promoted the co-precipitation of Ca^(2+)(originated from Ca(OH)_(2)added after oxidation process)and byproduced Fe^(3+)cations on its surface to in situ generate core-shell Fe_(3)O_(4)@*** oxidation products were further removed during Fe_(3)O_(4)@CaFe-LDH material formation via intercalation and *** applicable to many kinds of organicwastewater,such as bisphenol A,methyl orange,humics,and biogas *** prepared magnetic and hierarchical CaFe-LDH nanocomposite material showed comparable application performance to the recently reported *** work provides a new strategy for efficiently enhancing the efficiency and economy of Fe(Ⅱ)-catalyzed oxidative wastewater treatment by producing high value-added LDHs materials.

关键词： CaFe layered double hydroxide Fe(Ⅱ)-catalytic oxidation Fe recycling Magnetic nanomaterial in situ formation Fe_(3)O_(4)modification