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Through-polymer,via technology-enabled,flexible,lightweight,and integrated devices for implantable neural probes

Microsystems & Nanoengineering 2024年第2期10卷 279-291页

作者： Cunkai zhou Ye Tian Gen Li Yifei Ye Lusha Gao Jiazhi Li Ziwei Liu Haoyang Su Yunxiao Lu Meng Li Zhitao zhou Xiaoling Wei Lunming Qin Tiger H.Tao liuyang Sun College of Electronics and Information Engineering Shanghai University of Electric PowerShanghaiChina 2020 X-Lab Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghaiChina School of Graduate Study University of Chinese Academy of SciencesBeijingChina State Key Laboratory of Transducer Technology Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghaiChina Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijingChina School of Physical Science and Technology ShanghaiTech UniversityShanghaiChina Center for Excellence in Brain Science and Intelligence Technology Chinese Academy of SciencesShanghaiChina Neuroxess Co. Ltd.(Jiangxi)NanchangJiangxiChina Guangdong Institute of Intelligence Science and Technology HengqinZhuhaiGuangdongChina Tianqiao and Chrissy Chen Institute for Translational Research ShanghaiChina

In implantable electrophysiological recording systems,the headstage typically comprises neural probes that interface with brain tissue and integrated circuit chips for signal processing.While advancements in MEMS and CMOS technology have significantly improved these components,their interconnection still relies on conventional printed circuit boards and sophisticated adapters.This conventional approach adds considerable weight and volume to the package,especially for high channel count systems.To address this issue,we developed a through-polymer via(TPV)method inspired by the through-silicon via(TSV)technique in advanced three-dimensional packaging.This innovation enables the vertical integration of flexible probes,amplifier chips,and PCBs,realizing a flexible,lightweight,and integrated device(FLID).The total weight of the FLIDis only 25%that of its conventional counterparts relying on adapters,which significantly increased the activity levels of animals wearing the FLIDs to nearly match the levels of control animals without implants.Furthermore,by incorporating a platinum-iridium alloy as the top layer material for electrical contact,the FLID realizes exceptional electrical performance,enabling in vivo measurements of both local field potentials and individual neuron action potentials.These findings showcase the potential of FLIDs in scaling up implantable neural recording systems and mark a significant advancement in the field of neurotechnology.

关键词： alloy neural recording

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Yolk-shell FeSe_(2)@CoSe_(2)/FeSe_(2) heterojunction as anode materials for sodium-ion batteries with high rate capability and stability

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Journal of Materials Science & Technology 2024年第5期172卷 185-195页

作者： liuyang Zhang Bicheng Zhu Difa Xu Zibao Qian Ping Xie Tao Liu Jiaguo Yu Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430078China Hunan Key Laboratory of Applied Environmental Photocatalysis Changsha UniversityChangsha 410022China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Sodium-ion batteries are promising candidates for large-scale grid storage systems and other applications.Their foremost advantage derives from superior environmental credentials,enhanced safety as well as lower raw material costs than lithium-ion batteries.It is still challenging to explore desirable anode material.In this study,FeSe_(2)@CoSe_(2)/FeSe_(2),with a yolk-shell structure was prepared by ion exchange and selenisation.The FeSe_(2)@CoSe_(2)/FeSe_(2)prepared as anode material for sodiumion batteries exhibits excellent rate capability due to the synergistic effect of bimetallic selenides and the interfacial effect of the heterostructure.Moreover,it delivers high performance(510 mAh g^(-1)at 0.2 A g^(-1)),superior rate capa-bility(90%retention at 5 A g^(-1)),and good long-time cycling stability(78%capacity retention after 1800 cycles at a high current density of 2 A g^(-1)).The optimized sodiumion full cell with FeSe_(2)@CoSe_(2)/FeSe_(2)as the anode and Na 3 V 2(PO 4)3 as the cathode still demonstrates excellent performance.Namely,a ca-pacity of 272 mAh g^(-1)(at 1 A g^(-1))within the operating voltage from 1 to 3.8 V can be obtained.This work illustrates the potential of bimetallic selenides with heterostructures for performance enhancement of sodium-ion batteries.

关键词： Cobalt-iron selenide Heterojunctions Sodium storage Anode material Full battery

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Ecological Networks of Allometric Growth,Feeding Behavior and Gut Microbiota in Chinese Alligator Hatchlings

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Asian Herpetological Research 2024年第2期15卷 104-114页

作者： Ke SUN Wengang LI Guangwei FAN liuyang YANG Huabin ZHANG Yilin SHU Yongkang zhou Genjun TU Song ZHANG Pingsi YI Maliha AYUB Xiaobing WU Tao PAN College of Life Sciences Anhui Normal UniversityWuhu 241000AnhuiChina The Anhui Provincial Key Laboratory of Biodiversity Conservation and Ecological Security in the Yangtze River Basin Wuhu 241000AnhuiChina School of Wetland Yancheng Teachers UniversityYancheng 224007JiangsuChina National Long-term Scientific Research Base for Chinese Alligator Artificial Breeding and Protection in Anhui Anhui Research Center for Chinese Alligator ReproductionXuancheng 242034AnhuiChina

Chinese alligator hatchlings in captivity are fragile and have a high mortality rate within first year.The body mass gain of reptile animals is closely related to their feeding behavior and gut microbiota.This study analyzed the intrinsic factors influencing the allometric growth of Chinese alligator hatchlings based on their body mass gain,feeding behavior,and gut microbiota.This information would enhance the health management of Chinese alligator hatchlings.There was a significant correlation between the total distance moved,the average number of conspecifics nearby,and body mass gain.Chinese alligator hatchlings with a greater growth rate showed greater activity and more independent behavior during feeding than those with a lower growth rate.Moreover,after feeding started,some functions of the gut microbiota showed significant relationships with growth rate and feeding activity.Chinese alligator hatchlings with a greater growth rate showed greater levels of heme biosynthesis than those with a lower growth rate,and feeding activity was inhibited by long-chain fatty acid biosynthesis.These results elucidate the relationships between health,feeding behavior,and the gut microbiota of Chinese alligator hatchlings.Understanding the intrinsic factors of their health and feeding behavior can improve the health management of Chinese alligator hatchlings in captivity for conservation.

关键词： allometric growth behavior Chinese alligator hatchlings gut microbiota

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Analysis of mesoscopic mechanical dynamic characteristics of ballast bed with under sleeper pads

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Railway Engineering Science 2024年第1期32卷 107-123页

作者： Xiong Yang liuyang Yu Xuejun Wang Zhigang Xu Yu Deng Houxu Li Faculty of Mechanical and Electrical Engineering Kunming University of Science and TechnologyKunmingChina Yunnan Provincial Key Laboratory of Advanced Equipment Intelligent Manufacturing Technology KunmingChina

The meso-dynamical behaviour of a high-speed rail ballast bed with under sleeper pads(USPs)was studied.The geometrically irregular refined discrete element model of the ballast particles was constructed using 3D scanning techniques,and the 3D dynamic model of the rail-sleeper-ballast bed was constructed using the coupled discrete element method-multiflexible-body dynamics(DEM-MFBD)approach.We analyse the meso-mechanical dynamics of the ballast bed with USPs under dynamic load on a train and verify the correctness of the model in laboratory tests.It is shown that the deformation of the USPs increases the contact area between the sleeper and the ballast particles,and subsequently the number of contacts between them.As the depth of the granular ballast bed increases,the contact area becomes larger,and the contact force between the ballast particles gradually decreases.Under the action of the elastic USPs,the contact forces between ballast particles are reduced and the overall vibration level of the ballast bed can be reduced.The settlement of the granular ballast bed occurs mainly at the shallow position of the sleeper bottom,and the installation of the elastic USPs can be effective in reducing the stress on the ballast particles and the settlement of the ballast bed.

关键词： Under sleeper pads Ballast bed Discrete element method Mesoscopic mechanical dynamic characteristics

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Optimizing side chains on different nitrogen aromatic rings achieving 17% efficiency for organic photovoltaics

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Journal of Energy Chemistry 2022年第2期31卷 173-178页

作者： Zhe Li Can Zhu Jun Yuan liuyang zhou Wei Liu Xinxin Xia c Juan Hong Honggang Chen Qingya Wei Xinhui Lu Yongfang Li Yingping Zou College of Chemistry and Chemical Engineering Central South UniversityChangsha 410000HunanChina CAS Key Laboratory of Organic Solids Institute of Chemistry Chinese Academy of SciencesBeijing 100000China Department of Physics The Chinese University of Hong KongHong Kong 999077China

Balancing charge generation and low energy loss(E_(loss)), especially in the wide spectral absorption region is critical to obtain high-performance organic photovoltaics(OPVs). Therefore, Y11-M and Y11-EB are designed and synthesized through modifying alkyl chains on different nitrogen aromatic rings of the reported non-fullerene acceptor Y11. Although all the molecules have almost similar low band-gap(around 1.30 e V), Y11-M and Y11-EB exhibit wider absorption in 410–870 nm region. Eventually, the conventional devices based on Y11-M and Y11-EB possess more efficient charge generation with low Eloss(around 0.44 e V). In addition, outstanding efficiencies of 16.64% and 17.15% with the fill factor of 76.15% and 74.73% are obtained in PM6:Y11-M and PM6:Y11-EB-based devices, both higher than Y11:PM6. The results highlight the importance of rational alkyl chains optimization, and a good structureproperty relationship is established as well.

关键词： Fused-ring benzotriazole Side chains modification Low band-gap acceptors High-efficiency organic photovoltaics

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制约“们”字用法的语法规则和语用原则

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汉语学报 2024年第2期 49-58页

作者：樊留洋澳门大学人文学院中国语言文学系中国澳门999078

现代汉语中“们”的用法和功能一直是汉语数范畴研究中的热点问题。学界多有讨论,却一直悬而未决。我们认为只有准确地把问题归档至它们应在的位置,才能为从根本上解决这些问题创造条件。本文提出“们”的用法是刚性的语法规则和柔性的... 详细信息

现代汉语中“们”的用法和功能一直是汉语数范畴研究中的热点问题。学界多有讨论,却一直悬而未决。我们认为只有准确地把问题归档至它们应在的位置,才能为从根本上解决这些问题创造条件。本文提出“们”的用法是刚性的语法规则和柔性的语用原则共同作用的结果。前者决定了必用或者必不用“们”的语法条件,而后者则定义了可用可不用时使用“们”的语用环境。原本可不用却使用“们”主要是受语用因素的驱动,目的在于凸显和强化名词性成分的复数义。这种刚柔并济的处理方案不仅可以消除有关此问题的讨论中经常不得不使用“倾向”等等模棱两可的不理想概括方式,为相关的语言现象提供更加彻底的分析实践和更为深刻的理论解释,同时也为语言现象的全面解释提供了可行的分析框架。

关键词： “们” 使用条件语法规则语用原则语缀

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The potential mechanism and clinical application value of remote ischemic conditioning in stroke

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Neural Regeneration Research 2025年第6期 1613-1627页

作者： Yajun Zhu Xiaoguo Li Xingwei Lei liuyang Tang Daochen Wen Bo Zeng Xiaofeng Zhang Zichao Huang Zongduo Guo The First Affiliated Hospital of Chongqing Medical University

Some studies have confirmed the neuroprotective effect of remote ischemic conditioning against stroke. Although numerous animal researches have shown that the neuroprotective effect of remote ischemic conditioning may be related to neuroinflammation, cellular immunity, apoptosis, and autophagy, the exact underlying molecular mechanisms are unclear. This review summarizes the current status of different types of remote ischemic conditioning methods in animal and clinical studies and analyzes their commonalities and differences in neuroprotective mechanisms and signaling pathways. Remote ischemic conditioning has emerged as a potential therapeutic approach for improving stroke-induced brain injury owing to its simplicity, non-invasiveness, safety, and patient tolerability. Different forms of remote ischemic conditioning exhibit distinct intervention patterns, timing, and application range. Mechanistically, remote ischemic conditioning can exert neuroprotective effects by activating the Notch1/phosphatidylinositol 3-kinase/Akt signaling pathway, improving cerebral perfusion, suppressing neuroinflammation, inhibiting cell apoptosis, activating autophagy, and promoting neural regeneration. While remote ischemic conditioning has shown potential in improving stroke outcomes, its full clinical translation has not yet been achieved.

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A new non-fullerene acceptor based on the heptacyclic benzotriazole unit for efficient organic solar cells

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Journal of Energy Chemistry 2020年第3期29卷 169-173页

作者： Mei Luo liuyang zhou Jun Yuan Can Zhu Fangfang Cai Jiefeng Hai Yingping Zou College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083HunanChina Guangxi Key Laboratory of Electrochemical and Magneto-Chemical Functional Materials College of Chemistry and BioengineeringGuilin University of TechnologyGuilin 541004GuangxiChina

Non-fullerene acceptors(NFAs)become an interesting family of organic photovoltaic materials,and have attracted considerable interest for their great potential in manufacturing large-area flexible solar panels by low cost coating methods[1–5].Recently,our group proposed in the first time an A-DA’D-A molecular strategy and synthesized a new class of non-fullerene acceptor Y6 with a record efficiency above 15%with single junction organic solar cells(OSCs)[6].To further improve the photovoltaic performance of OSCs,many effective strategies have been successfully explored,such as side-chain engineering and extension of fused core and terminal group engineering[7–12].As well-known,PCE of devices is determined by the open circuit voltage(Voc),short-circuit current density(Jsc)and fill factor(FF)[13].Among them,Voc is associated with low-lying highest occupied molecular orbital(HOMO)of donor and lowest unoccupied molecular orbital(LUMO)of acceptor of the active layer[14–16].Side-chain engineering is an effective strategy for manipulating energy levels and improving photovoltaic performance of devices[17–19].For example,introducing the alkyl/alkoxy chains can effectively tune the HOMO/LUMO energy levels[20–22].Tang et al.have reported a novel non-fullerene acceptor ITC6-IC.ITC6-IC has relatively high LUMO level and high Voc than those of ITIC due to the introduction of weak electrondonating hexyl group on thiophene[23].

关键词： Near-infrared electron acceptor Y9 Ladder-type heptacyclic fused ring Non-fullerene electron acceptors High-performance OSCs

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Non-equivalent D-A copolymerization strategy towards highly efficient polymer donor for polymer solar cells

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Science China Chemistry 2021年第6期64卷 1031-1038页

作者： Ziya Shang liuyang zhou Chenkai Sun Lei Meng Wenbin Lai Jinyuan Zhang Wenchao Huang Yongfang Li Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China School of Chemical Science University of Chinese Academy of SciencesBeijing 100049China College of Chemistry Green Catalysis CenterZhengzhou UniversityZhengzhou 455001China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528216China Laboratory of Advanced Optoelectronic Materials College of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China

D-A copolymerization is a broadly utilized molecular design strategy to construct high efficiency photovoltaic materials for polymer solar cells(PSCs),and all the D-A copolymer donors reported till now are the alternate D-A copolymers with equal D-and A-units.Here,we first propose a non-equivalent D-A copolymerization strategy with unequal D-and A-units,and develop three novel non-equivalent D-A copolymer donors(PM6-D1,PM6-D2 and PM6-D3 with D/A unit ratio of 1.1:0.9,1.2:0.8 and1.3:0.7,respectively)by inserting more D units into the alternate D-A copolymer PM6 backbone to finely tune the physicochemical and photovoltaic properties of the polymers.The three non-equivalent D-A copolymers show the down-shifted highest occupied molecular orbital(HOMO)energy levels,higher hole mobility,higher degree of molecular self-assembly and higher molecular crystallinity with the increase of D-unit ratio in comparison with the alternate D-A copolymer PM6.As a result,all the three non-equivalent D-A copolymer-based PSCs with Y6 as acceptor achieve improved power conversion efficiency(PCE)with higher V_(oc),larger J_(sc)and higher FF simultaneously.Particularly,the PM6-D1:Y6 based PSC achieved a high PCE of17.71%,which is significantly higher than that(15.82%)of the PM6:Y6 based PSC and is one of the highest performances in the binary PSCs.

关键词： polymer solar cells conjugated polymer donor materials donor-acceptor copolymers non-equivalent D-A copolymerization

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数据驱动的学校周边道路拥堵识别

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江苏大学学报（自然科学版） 2024年第2期45卷 141-146页

作者：景鹏顾倩杜刘洋江苏大学汽车与交通工程学院江苏镇江212013

为定量分析多个中小学周边道路拥堵情况,针对性地改善学校周边拥堵状况,对比通学时期与非通学时期的交通拥堵数据.建立学校周边道路拥堵指标,通过拥堵评价函数,分析各道路受周边学校出行影响的程度,识别重点拥堵道路.提出了一种基于地... 详细信息

为定量分析多个中小学周边道路拥堵情况,针对性地改善学校周边拥堵状况,对比通学时期与非通学时期的交通拥堵数据.建立学校周边道路拥堵指标,通过拥堵评价函数,分析各道路受周边学校出行影响的程度,识别重点拥堵道路.提出了一种基于地图开放平台获取交通大数据的算法,对南京主城区79所中小学周边道路进行实例分析,给出了各道路受学校出行影响的拥堵值.结果表明:在通学期间交通整体拥堵程度高于非通学时期,通学时期平均拥堵指数为1.973,非通学时期平均拥堵指数为1.664,通学时期比非通学时期平均拥堵指数提高了18.57%.

关键词：学校道路拥堵指数大数据拥堵识别地图平台

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