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Journal of Environmental Sciences 2024年第2期136卷 390-399页

作者： Aihua Cheng Yi He xiaohe liu Chi He Department of Environmental Engineering College of Geology and EnvironmentXi’an University of Science and TechnologyXi’an 710054China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China National Engineering Laboratory for VOCs Pollution Control Material and Technology University of Chinese Academy of SciencesBeijing 101408China

Achieving an efficient and stable heterogeneous Fenton reaction over a wide pH range is of great significance for wastewater ***,a pollen-derived biochar catalyst with a unique honeycomb-like structure,coupled with the dispersion of magnetic Fe_(3)O_(4)/FeS(Fe/S)nanoparticles,was synthesized by simple impregnation precursor,followed by *** prepared Fe/S-biochar catalyst demonstrated outstanding phenol degradation efficiency across a wide pH range,with 98%of which eliminated even under neutral conditions(pH 7.0).The high catalytic activity was due to the multilevel porous structure of pollenderived biochar provided enough active sites and allowed for better electron transfer,then increases oxidation ability to promote the ***,the acid microenvironment formed by SO_(4)^(2-)group from Fe/S composite extended the pH range for Fenton reaction,and S^(2-)facilitated the conversion of≡Fe^(3+)to≡Fe^(2+),resulting in remarkable degradation ***,biochar can effectively promote cycling stability by limiting Fe *** work may provide a general strategy for designing 3D framework biochar-based Fe/S catalysts with excellent performance for heterogeneous Fenton reactions.

关键词： Biomass Biochar Fenton reaction Fe_(3)O_(4)/FeS(Fe/S) Phenol degradation

Boosting charge transfer via interface charge reconstruction between amorphous NiFe-LDH and crystalline NiCo_(2)O_(4)for efficient alkaline water/seawater oxidation

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Nano Research 2024年第6期17卷 4856-4863页

作者： Zhonghang Xing Yi Zhao Yunhai Wang xiaohe liu Zhiqiang Guo Qingyun Chen International Research Center for Renewable Energy and State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Department of Environmental Science and Engineering Xi’an Jiaotong UniversityXi’an 710049China China School of Geology and Environment Xi’an University of Science and TechnologyXi’an 710049China Changqing Engineering Design Co. Ltd.Xi’an 710018China

Electrocatalysts with optimal efficiency and durability for the oxygen evolution reaction(OER)are becoming increasingly important as the demand for alkaline water/seawater electrolysis technology ***,a novel rose-shaped NiFe-layered double hydroxide(LDH)/NiCo_(2)O_(4)composed of amorphous wrinkled NiFe-LDH and highly crystalline NiCo_(2)O_(4)was synthesized with rich *** unsaturated metal sites are generated due to significant charge reconstruction at the heterointerface between the crystalline and amorphous *** metal sites could trigger and provide more active *** density functional theory(DFT)reveals that a new charge transfer channel(Co-Fe)was formed at the heterointerface between NiFe-LDH as electron acceptor and NiCo_(2)O_(4)as electron *** new charge transfer channel boosts interfacial charge transfer and enhances catalytic *** NiFe-LDH/NiCo_(2)O_(4)/nickel foam(NF)drives current densities of 10 and 100 mA·cm−2 with overpotentials of 193 and 236 mV,*** composite electrode demonstrates a fast turnover frequency(0.0143 s−1)at 1.45 V ***(RHE=reversible hydrogen electrode),which is 5.5 times greater than pure NiCo_(2)O_(4),suggesting its superior intrinsic ***,NiFe-LDH/NiCo_(2)O_(4)/NF electrode exhibited negligible degradation after 150 h of uninterrupted running in alkaline seawater *** study introduces a method for preparing high-efficiency electrocatalysts utilized in alkaline water/seawater electrolysis.

关键词： NiFe-layered double hydroxide(LDH)/NiCo_(2)O_(4)/nickel foam(NF) heterogeneous interfaces charge reconstruction water/seawater electrolysis

Recent advances in multifunctional metal-organic frameworks for lithium metal batteries

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Science China Chemistry 2024年第3期67卷 759-773页

作者： Jiaqi Li Zheng Weng Zuosu Qin Ying Zhang Ning Zhang xiaohe liu Chuankun Jia Gen Chen Jiang Zhou School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South University Zhongyuan Critical Metals Laboratory Zhengzhou University College of Materials Science and Engineering Changsha University of Science&Technology

In view of novel materials in the field of lithium metal batteries(LMBs), metal-organic frameworks(MOFs) have attracted extensive research interest owing to their controllable pore size, unsaturated metal sites and multifunctional organic groups. A variety of MOFs have been elaborately calculated and synthesized to be applied as separator coating, electrolyte modulators and solid-state electrolyte fillers in LMBs. In this mini-review, we summarize the mechanism of MOFs to limit the migration of anions, improve the Li-ion transference number and prolong the lifespan of LMBs. Suitable pore structure of MOFs can physically restrict the movement of Li^(+). Unsaturated metal sites can adsorb anions by electrostatic interaction. In addition,multifunctional organic functional groups that limit the migration of anions are discussed. Finally, the key challenges and perspectives in the development direction of MOFs-based separators and electrolytes are further elaborated.

关键词： metal-organic frameworks lithium metal battery separator electrolyte

岛状多年冻土区高速铁路路基热状态及工程措施效果分析

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铁道学报 2024年第3期46卷 145-154页

作者：刘晓贺蔡德钩闫宏业张先军王斌刘浩中国铁道科学研究院研究生部北京100081 中国铁道科学研究院集团有限公司铁道建筑研究所北京100081 中国国家铁路集团有限公司工程管理中心北京100844 黑龙江铁路发展集团有限公司黑龙江哈尔滨150000

为揭示岛状多年冻土区高速铁路路基热状态,提出合理有效的制冷结构,在新建哈尔滨至伊春高速铁路某车站试验段开展现场监测,获得岛状多年冻土的地温数据;基于实测地温数据,采用冻土水热耦合理论,对将在试验段实施的两侧双排普通热棒路基... 详细信息

为揭示岛状多年冻土区高速铁路路基热状态,提出合理有效的制冷结构,在新建哈尔滨至伊春高速铁路某车站试验段开展现场监测,获得岛状多年冻土的地温数据;基于实测地温数据,采用冻土水热耦合理论,对将在试验段实施的两侧双排普通热棒路基、两侧双排+中心单排全季热棒路基、两侧单排+基底横向通铺全季热棒路基3种制冷路基结构进行数值模拟,对比了3种制冷路基结构的地温分布特征及对下伏岛状多年冻土的降温效果。研究结果表明:铁力地区年均气温和降水呈增大趋势,天然场地岛状多年冻土地温在-0.3℃左右,属于高温极不稳定多年冻土。3种制冷路基结构中,两侧单排+基底横向通铺全季热棒对岛状多年冻土保护及降温效果最优,两侧双排普通热棒最差。普通热棒路基的多年冻土上限呈“两侧凸,中间凹”形态,抬升不明显;全季热棒路基的多年冻土上限呈“上凸缓斜平顶”形态,抬升显著。研究成果可对多年冻土区高速铁路路基建设和结构优化提供技术支撑。

关键词：寒区铁路路基岛状多年冻土普通热棒全季热棒冻土上限

气候变化影响下多年冻土区铁路路基热稳定性分析

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中国铁道科学 2024年第5期45卷 1-12页

作者：闫宏业蔡德钩答治华张先军刘有乾米维军刘晓贺中国铁道科学研究院研究生部北京100081 中国铁道科学研究院集团有限公司铁道建筑研究所北京100081 中国国家铁路集团有限公司科技和信息化部北京100844 中国国家铁路集团有限公司工程管理中心北京100844 中国铁路青藏集团有限公司青海西宁810000 中铁西北科学研究院有限公司特殊土治理科创中心甘肃兰州730000

全球气候变暖加剧了青藏高原气候暖湿化,威胁着高原铁路路基及下伏多年冻土的热稳定性,但以往研究缺乏综合考虑铁路沿线气候、多年冻土及路基稳定性的系统分析。针对这一研究的不足,基于铁路沿线气象和多年冻土路基地温监测数据,分析铁... 详细信息

全球气候变暖加剧了青藏高原气候暖湿化,威胁着高原铁路路基及下伏多年冻土的热稳定性,但以往研究缺乏综合考虑铁路沿线气候、多年冻土及路基稳定性的系统分析。针对这一研究的不足,基于铁路沿线气象和多年冻土路基地温监测数据,分析铁路沿线多年冻土区气温降水、天然场地年平均地温与天然上限、路基人为上限及路基左右路肩沉降变化,揭示气候暖湿化背景下铁路多年冻土路基热稳定性变化,为多年冻土区铁路建设和维护提供参考。结果表明:近20年来,铁路沿线年均气温和年均降水量的平均值分别增加了1.2℃和80mm;相较于2007年,2020年铁路沿线天然场地多年冻土年均地温平均升高0.1℃,多年冻土天然上限平均下降0.58 m,路基人为上限平均抬升2.34 m,路基左路肩平均沉降大于右路肩,存在阴阳坡效应。整体而言,铁路多年冻土路基状态稳定,运行状态良好,建设运营期间采取的一系列工程措施有效,但面向未来气候加剧变化趋势,应提前谋划多年冻土保护新技术。

关键词：高原铁路气候变化多年冻土冻土上限阴阳坡效应地温监测

Optimal set integer programming algorithm for multiple maneuvering targets tracking in clutter

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Journal of Systems Engineering and Electronics 2013年第4期24卷 555-563页

作者： Xiaoyan Fu Yingmin Jia xiaohe liu School of Mathematics and System Science Beihang University College of Information Engineering Capital Normal University Department of Systems and Control Beijing Information Science and Technology University

The aim of this paper is to solve the problems of multitarget tracking in clutter. Firstly, the data association of measurement-to-target is formulated as an integer programming problem. Through using the linear programming （LP） based branchand-bound method and adjusting the constraint conditions, an optimal set integer programming （OSIP） algorithm is then proposed for tracking multiple non-maneuvering targets in clutter. For the case of maneuvering targets, this paper introduces the OSIP algorithm into the filtering step of the interacting multiple model （IMM） algorithm resulting in the IMM based on OSIP algorithm. Extensive Monte Carlo simulations show that the presented algorithms can obtain superior estimations even in the case of high density noises.

关键词： data association target tracking integer programming clutter.

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多年冻土区铁路桥梁桩基础竖向承载特性分析

中国铁道科学 2024年第5期45卷 77-89页

作者：张熙胤刘宁宁蔡德钩闫宏业刘晓贺王万平兰州交通大学土木工程学院甘肃兰州730070 中国铁道科学研究院集团有限公司铁道建筑研究所北京100089

为研究多年冻土区铁路桥梁桩基础在竖向荷载作用下的承载性能及荷载传递机理,以多年冻土区广泛存在的高桩承台基础为研究对象,通过室内缩尺模型试验结合有限元方法分析桩基础几何尺寸和多年冻土温度对桩基础竖向承载性能的影响。结果表... 详细信息

为研究多年冻土区铁路桥梁桩基础在竖向荷载作用下的承载性能及荷载传递机理,以多年冻土区广泛存在的高桩承台基础为研究对象,通过室内缩尺模型试验结合有限元方法分析桩基础几何尺寸和多年冻土温度对桩基础竖向承载性能的影响。结果表明:增加桩长能减小桩基础的沉降量并提高桩基础的极限承载力,桩长从1.5 m增至3.0 m过程中,每增加0.5 m,桩基础极限承载力分别增加41%,23%和15%,且能够减小桩基础端承力及其占比,但对桩基础的轴力、桩身应力和侧摩阻力的分布规律影响较小;多年冻土的存在对桩基础承载性能的提升更为显著,其中侧摩阻力发挥重要作用,且多年冻土的温度越低,其提升效果越明显,在多年冻土层温度为-5和-9℃时,桩基础的极限承载力分别为125.9和199.5 kN,相较于融土条件分别提升了2.98和5.31倍;桩基础在多年冻土层中的最大侧摩阻力分别约为300和500 kPa,是上部融土层的2.1和3.5倍;在上部融土层和多年冻土层的交界处桩身轴力、侧摩阻力、土体应力均发生明显变化。

关键词：桩基础多年冻土承载特性缩尺模型室内试验有限元分析

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三功能共晶溶剂添加剂用于高性能锂金属电池

Science Bulletin 2024年第11期69卷 1686-1696页

作者：方文强温祖鑫王锋霖陈龙张颖张宁刘小鹤陈根 School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan ProvinceCentral South UniversityChangsha 410083China Zhongyuan Critical Metals Laboratory School of Chemical EngineeringZhengzhou UniversityZhengzhou 450001China

Rational carbonate electrolyte chemistry is critical for the development of high-voltage lithium metal batteries(LMBs).However,the implementation of traditional carbonate electrolyte is greatly hindered by the generation of an unstable electrode interphase and corrosive by-product(HF).Herein,we propose a triple-function eutectic solvent additive of N-methylacetamide(NmAc)with LiNO_(3) to enhance the stability and compatibility of carbonate ***,the addition of NmAc significantly improves the solubility of LiNO_(3) in carbonate electrolyte by forming an eutectic pair,which regulates the Li~+solvation structure and leads to dense and homogenous Li ***,the hydrolysis of acidic PF_5 is effectively alleviated due to the strong complexation of NmAc with PF_5,thus reducing the generation of corrosive *** addition,the optimized cathode electrolyte interphase layer decreases the structural degradation and transition metal ***,Li||LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM622)cells with the designed electrolyte deliver superior long-term cycle reversibility and excellent rate *** study unveils the rationale for incorporating eutectic solvent additives within carbonate electrolytes,which significantly contribute to the advancement of their practical application for high-voltage LMBs.

关键词： Eutectic solvent additive Solvation structure Interfacial chemistry PF_5 capturer Lithium metal battery

β-cyclodextrin as Lithium-ion Diffusion Channel with Enhanced Kinetics for Stable Silicon Anode

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Energy & Environmental Materials 2021年第1期4卷 72-80页

作者： Pengcheng Li Gen Chen Ning Zhang Renzhi Ma xiaohe liu State Key Laboratory of Powder Metallurgy and School of Materials Science and Engineering Central South UniversityChangsha Hunan 410083China International Center for Materials Nanoarchitectonics(MANA) National Institute for Materials Science(NIMS)Namiki 1-1Tsukuba Ibaraki 305-0044Japan School of Chemical Engineering and Energy Zhengzhou UniversityChangsha Hunan 410083China

Silicon(Si)is regarded as a promising anode material for next-generation lithium-ion batteries due to its ultrahigh theoretical ***,the drastic volume change and the continuous solid electrolyte interphase(SEI)formation during the lithiation/delithiation process seriously hinder its practical application as commercial ***,macrocyclic betacyclodextrin(β-CD)has been designed as the diffusion channel for lithium ions at the molecular *** diameter of molecular channel is approximately comparable with the solvated lithium ions,which enables the transport of lithium ions and prevents the penetration of solvent ***,the addition ofβ-CD changes the formation behavior of SEI layer and stabilizes the Si *** enhanced electrochemical performances in terms of fast kinetics and improved stability have been *** Si anode with the particularly selected lithium-ion diffusion channel and stabilized SEI layer exhibits a high reversible capability of 2562 m Ah g-1 after 50 cycles at the current density of 500 m A g-1,1944 m Ah g-1 after 200 cycles at the current density of 1 A g-1,and high rate *** novel strategy of molecular channel for lithium-ion diffusion offers new insights into the design of alloy-typed anode electrodes with high capacity for lithium-ion batteries.

关键词： lithium-ion batteries lithium-ion diffusion channel Silicon solid electrolyte interphase β-cyclodextrin

Advanced silicon nanostructures derived from natural silicate minerals for energy storage and conversion

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Green Energy & Environment 2022年第2期7卷 205-220页

作者： Hao Wan Wei Ma Kechao Zhou Yijun Cao xiaohe liu Renzhi Ma School of Chemical Engineering Zhengzhou UniversityZhengzhou450001China State Key Laboratory of Powder Metallurgy Central South UniversityChangsha410083China International Center for Materials Nanoarchitectonics(WPI-MANA) National Institute for Materials Science(NIMS)Namiki 1-1TsukubaIbaraki305-0044Japan

To effectively alleviate the ever-increasing energy crisis and environmental issues,clean and sustainable energy-related materials as well as the corresponding storage/conversion devices are in urgent ***(Si) with the second most elemental abundance on the crust in the form of silicate or silica(SiO_(2)) minerals,is an advanced emerging material showing high performance in energy-related fields(***,photocatalytic hydrogen evolution).For the improved performance in industry-scale applications,Si materials with delicate nanostructures and ideal compositions in a massive production are highly *** account of the reserve,low cost and diverse micro-nanostructures,silicate minerals are proposed as promising raw *** the article,crystal structures and the reduction approaches for silicate minerals,as well as recent progress on the as-reduced Si products for clean energy storage/conversion,are presented ***,some cutting-edge fields involving Si materials are discussed,which may offer deep insights into the rational design of advanced Si nanostructures for extended energy-related fields.

关键词： minerals massive silicate