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Polyimide covalent organic frameworks as efficient solid-state Li^(+) electrolytes

Science China Chemistry 2024年第5期67卷 1647-1652页

作者： Xu liu Shi Wang Siqi liu Chengfang liu Xiangchun Li Jian Wu Dazhi Li Shihao Xu Chongyang liu Wen-Yong Lai State Key Laboratory of Organic Electronics and Information Displays(SKLOEID) Institute of Advanced Materials(IAM)School of Chemistry and Life SciencesNanjing University of Posts&TelecommunicationsNanjing 210023China

Covalent organic frameworks(COFs) are attractive porous crystalline materials with extremely high stability, easy functionalization, and open channels, which are expected to be unique ion conductors/transporters in lithium ion batteries(LIBs). Despite recent advances, low ion conductivity and low transference number, resulting in low charging/discharging rate, low energy density, and short battery life, are the main issues that limit their direct application as solid electrolytes in LIBs. Here, we designed and synthesized a novel polyimide COF, namely, TAPA-PDI-COF, with abundant C=O groups, which has been successfully employed as high-performance solid electrolytes by doping TAPA-PDI-COF and succinonitrile(SN). Both the well-defined nanochannels of COFs and SN confined in the well-aligned channels restricted the free migration of anions, while C=O on COFs and CN groups of SN enhanced Li^(+) transport, thus achieving a high ion conductivity of 0.102 m S cm^(-1)at 80 °C and a high lithium-ion transference number of 0.855 at room temperature. According to density functional theory(DFT)calculations, Li-ion migration mainly adopted in-plane transport rather than the axial pathway, which may be due to the shorter hopping distances in the planar pathway. The results suggest an effective strategy for the design and development of all-solidstate ionic conductors for achieving high-performance LIBs.

关键词： lithium ion batteries(LIBs) covalent organic frameworks(COFs) solid-state ion conductors solid-state electrolytes ion conductivity

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Evolution of molecular structure of TATB under shock loading from transient Raman spectroscopic technique

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Defence Technology（防务技术） 2024年第3期33卷 613-620页

作者： Hongliang Kang Xue Yang Wenshuo Yuan Lei Yang Xinghan Li Fusheng liu Zhengtang liu Qijun liu Bond and Band Engineering Group School of Physical Science and TechnologySouthwest Jiaotong UniversityChengdu 610031China State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi'an 710072China

By combination of the transient Raman spectroscopic measurement and the density functional theoretical calculations,the structural evolution and stability of TATB under shock compression was *** to the improvement in synchronization control between two-stage light gas gun and the transient Raman spectra acquisition,as well as the sample preparation,the Raman peak of the N-O mode of TATB was firstly observed under shock pressure up to 13.6 GPa,noticeably higher than the upper limit of 8.5 GPa reported in available *** taking into account of the continuous shift of the main peak and other observed Raman peaks,we did not distinguish any structural transition or any new ***,both the present Raman spectra and the time-resolved radiation of TATB during shock loading showed that TATB exhibits higher chemical stability than previous *** reveal the detailed structural response and evolution of TATB under compression,the density functional theoretical calculations were conducted,and it was found that the pressure make N-O bond lengths shorter,nitro bond angles larger,and intermolecular and intra-molecular hydrogen bond interactions *** observed red shift of Raman peak was ascribed to the abnormal enhancement of H-bound effect on the scissor vibration mode of the nitro group.

关键词： TATB Raman spectra Structural evolution Shock loading

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59Co核磁共振效应的观测

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兰州大学学报 1984年第1期 14-18页

作者：杨金发刘肃广东省梅州磁性材料厂

本文描述了一个测量59Co核磁共振效应的波谱仪装置的工作原理和电路,其工作频率120—240MH2,灵敏度优于5μv可用它在77°k或室温、零场或有外加直流磁场的情况下分析Co及含Co磁性物质的超精细相互作用。

关键词：射频脉冲频带 SE 装置磁性物质电磁脉冲频程自旋回波核磁共振效应 Co

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Effects of seepage pressure on the mechanical behaviors and microstructure of sandstone

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2033-2051页

作者： Xuewei liu Juxiang Chen Bin liu Sai Wang Quansheng liu Jin Luo State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China Faculty of Engineering China University of GeosciencesWuhan430074China Key Laboratory of Safety for Geotechnical and Structural Engineering of Hubei Province School of Civil EngineeringWuhan UniversityWuhan430072China

Surrounding rocks of underground engineering are subjected to long-term seepage pressure,which can deteriorate the mechanical properties and cause serious *** order to understand the impact of seepage pressure on the mechanical property of sandstone,uniaxial compression tests,P-wave velocity measurements,and nuclear magnetic resonance(NMR)tests were conducted on saturated sandstone samples with varied seepage pressures(i.e.0 MPa,3 MPa,4 MPa,5 MPa,6 MPa,7 MPa).The results demonstrate that the mechanical parameters(uniaxial compressive strength,peak strain,elastic modulus,and brittleness index),total energy,elastic strain energy,as well as elastic strain energy ratio,decrease with increasing seepage pressure,while the dissipation energy and dissipation energy ratio ***,as seepage pressure increases,the micro-pores gradually transform into meso-pores and *** increases the cumulative porosity of sandstone and decreases P-wave *** numerical results indicate that as seepage pressure rises,the number of tensile cracks increases progressively,the angle range of microcracks is basically from 50-120to 80-100,and as a result,the failure mode transforms to the tensile-shear mixed failure ***,the effects of seepage pressure on mechanical properties were *** results show that decrease in the effective stress and cohesion under the action of seepage pressure could lead to deterioration of strength behaviors of sandstone.

关键词： Rock mechanics Mechanical property Seepage pressure Numerical simulation Microcracks

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On electro-acoustic characteristics of a marine broadband sparker for seismic exploration

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Journal of Oceanology and Limnology 2024年第3期42卷 760-771页

作者： Jing LI Kai liu Liancheng ZHANG Chenguang liu Yanliang PEI Baohua liu Key Laboratory of Marine Geology and Metallogency First Institute of OceanographyMinistry of Natural ResourcesQingdao 266061China Laboratory of Marine Geology Laoshan LaboratoryQingdao 266237China Key Laboratory of Fluid Transmission Technology of Zhejiang Province Zhejiang Sci-Tech UniversityHangzhou 310018China Key Laboratory of Submarine Acoustic Investigation and Application of Qingdao(Preparatory) Qingdao 266061China Key Laboratory of Deep Sea Mineral Resources Development Shandong(Preparatory)Qingdao 266061China

The construction of major marine infrastructure projects and the exploration and development of deep-sea mineral resources require fine imaging of seabed strata and *** highresolution marine seismic exploration based on a high broadband sparker source is an important approach to reveal seabed stratum and reservoir structure,and identify *** optimize the performance of sparker seismic source,we investigated the electro-acoustic characteristics of spark discharge under conditions of different charging voltages and electrode *** show that the sound source level increased with the increase of the charging voltage,whereas the main frequency decreased when the charging voltage *** addition,it was found that the charging capacitance had more obvious influence on the main frequency than the sound source level *** the load energy decreased with increasing electrode number,the sound source level still increased but the main frequency ***,the primary to bubble(P/B)ratio increased with the increase of the electrode *** gain a deeper insight into the electro-acoustic characteristics,we investigate the relationship between sound source level and power peak,from which a good correlation was observed.A more practical statistical analysis on the rise rate of current was processed,and a perfect logarithmic function was ***,we found that the main frequency was most possibly subjected to the electrical energy,especially the charging energy per *** results indicate that the charging energy per electrode less than 10 J could increase the main frequency to above 300 *** last,the main frequency could be reduced to 20 Hz when the charging energy of a single-electrode discharge was enhanced to over 4 *** study shall be helpful in developing a sparker seismic source and improving the performance for marine engineering exploration and geohazard assessment.

关键词： high-resolution marine seismic exploration sparker seismic source sound source level main frequency electro-acoustic characteristics

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Performance of composite foundations with different load transfer platforms and substratum stiffness over silty clay

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Journal of Mountain Science 2024年第5期21卷 1761-1774页

作者： ZHANG Shuming liu Yan YUAN Shengyang liu Xianfeng JIANG Guanlu liu Junyan School of Civil Engineering and Architecture University of JinanJinan 250022China The Engineering Technology Research Center for Urban Underground Engineering Supporting and Risk Monitoring of Shandong Province Jinan 250022China School of Civil Engineering Southwest Jiaotong UniversityChengdu 610031China Key Laboratory of High-speed Railway Engineering Ministry of EducationSouthwest Jiaotong UniversityChengdu 610031China

The semi-rigid pile-supported composite foundation is widely used in highway projects due to its effectiveness in increasing the bearing capacity and stability of *** is crucial to understand the stress distribution across the embankment width and the behaviour of unreinforced ***,five centrifuge tests were conducted to examine the bearing and deformation behaviours of NPRS(Non-Connected Piled Raft Systems)and GRPS(GeosyntheticReinforced Pile-Supported systems)with varying substratum stiffness,then a comparative analysis was conducted on embankment settlement,pressures underneath the embankments,and axial forces along the *** results indicated that greater substratum stiffness correlates with reduced settlement and deformation at various *** occurring 5 meters from the embankment toe includes settlement in NPRS and upward movement in *** potential sliding surface is primarily located within the embankment in NPRS,whereas it may extend through both the embankment and foundation in *** pile-soil stress ratio and efficiency in NPRS are higher than in GRPS across the *** axial force borne by end-bearing piles is significantly greater than that by floating *** the buried depth increases,the axial force in GRPS initially rises then declines,whereas in NPRS,it remains relatively constant within a certain range before *** study aids in assessing the applicability of composite foundations in complex railway environments and provides a reference for procedural measures under similar conditions.

关键词： Centrifuge modelling Composite foundation Failure mode Load transfer platform Substratum Stiffness Silty clay

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以营卫理论指导儿童食物过敏的辨治

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中医杂志 2023年第1期64卷 32-36页

作者：周瑶秦雯李勇军刘璐佳王有鹏黑龙江中医药大学黑龙江省哈尔滨市150040 黑龙江中医药大学附属第二医院

基于肠黏膜屏障破坏在儿童食物过敏发病机制中的作用,从营卫理论出发,认为肠黏膜属于中医学“肠络”范畴,而肠络是儿童食物过敏的主要病位;提出卫气失常是儿童食物过敏发病的先决条件,营卫失和是儿童食物过敏的核心病机。治疗全程均应... 详细信息

基于肠黏膜屏障破坏在儿童食物过敏发病机制中的作用,从营卫理论出发,认为肠黏膜属于中医学“肠络”范畴,而肠络是儿童食物过敏的主要病位;提出卫气失常是儿童食物过敏发病的先决条件,营卫失和是儿童食物过敏的核心病机。治疗全程均应重视调和营卫、疏利三焦,常用温胆汤加减;起病初期可用风药宣通腠理,截断扭转营卫失和的病理进程,恢复营卫运行的正常状态;平素饮食应谨和五味,减少高糖饮食,增加新鲜苦味蔬菜和甘淡杂粮的摄入,以运脾化源。

关键词：食物过敏营卫理论儿童肠络肠黏膜屏障

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肺炎继发腹泻中西医诊疗进展

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辽宁中医药大学学报 2020年第3期22卷 195-199页

作者：刘鑫刘璐佳王有鹏黑龙江中医药大学黑龙江哈尔滨150040 黑龙江中医药大学附属第二医院黑龙江哈尔滨150001

肺炎继发腹泻是指感染肺炎的患儿在治疗过程中或是向愈后出现腹泻症状的疾病。临床发病率高,且严重影响儿童的生长发育。该病的发病机制尚不明确,可能与免疫功能、病原体毒素、低氧血症及治疗药物有关,现代医学对其治疗以微生态制剂和... 详细信息

肺炎继发腹泻是指感染肺炎的患儿在治疗过程中或是向愈后出现腹泻症状的疾病。临床发病率高,且严重影响儿童的生长发育。该病的发病机制尚不明确,可能与免疫功能、病原体毒素、低氧血症及治疗药物有关,现代医学对其治疗以微生态制剂和胃肠道黏膜保护剂为主。中医学主要从肺合大肠、邪克阳明及脾虚湿盛三个角度看待该病,以辨证论治为原则遣方用药。该文以近年来相关中西医学文献研究为基础,对肺炎继发腹泻的发病机制和治疗方法进行梳理,以期更好的指导临床实践工作。

关键词：儿童肺炎继发腹泻抗生素相关腹泻病因病机治疗方法

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Atomically precise Ru-O-Ru clusters for enhanced water dissociation in alkaline hydrogen evolution

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Nano Research 2024年第8期17卷 6993-7000页

作者： Dong liu Li Xu Sicheng Li Airong Xu Yuanhua Sun Tong liu Mengyuan liu Huijuan Wang Xiaokang liu Tao Yao Tao Ding Hefei National Research Center for Physical Sciences at the Microscale School of Nuclear Science and TechnologyKey Laboratory of Precision and Intelligent ChemistryNational Synchrotron Radiation LaboratoryUniversity of Science and Technology of ChinaHefei 230029China Experimental Center of Engineering and Materials Science University of Science and Technology of ChinaHefei 230026China

Atomic clusters typically exhibit distinctive electronic structures and physicochemical ***,as the size decreases,their ability to adsorb and dissociate water also diminishes,thereby affecting chemical reactions involving water *** the adsorption and dissociation capabilities of atomic clusters towards water molecules and elucidating the mechanisms underlying their performance enhancement have become important research ***,employing the carrier-anchored strategy,Ru-O-Ru atomic clusters were prepared and displayed excellent activity and durability in the hydrogen evolution ***,the Ru-O-Ru atomic clusters exhibited only 86 mV overpotential at 100 mA·cm−^(2) and superior membrane-electrode-assembly activity than commercial Ru/C *** radiation-based Fourier transform infrared spectroscopic measurements revealed that the modification of oxygen in Ru-O-Ru units promoted the reorientation of water molecules from a H-up orientation to H-down,therefore,enhanced the formation of strong hydrogen-bond network of interfacial water on the surface of Ru-O-Ru clusters,leading to enhanced adsorption and dissociation of water and accelerated Volmer *** findings provide a potential strategy and deep insights for the development of atomic clusters in electrocatalysts.

关键词： hydrogen evolution in-situ Fourier transform infrared(FTIR) Ru catalysts electrocatalysis atomic clusters

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Atomistic study on the microscopic mechanism of grain boundary embrittlement induced by small dense helium bubbles in iron

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Nuclear Science and Techniques 2024年第3期35卷 84-95页

作者： Lei Peng Yong-Jie Sun Jing-Yi Shi Yi-Fei liu Shang-Ming Chen liu-liu Li State Key Laboratory of Particle Detection and Electronics University of Science and Technology of ChinaHefei 230026China School of Nuclear Science and Technology University of Science and Technology of ChinaHefei 230027China Science and Technology on Reactor System Design Technology Laboratory Nuclear Power Institute of ChinaChengdu 610213China

The helium bubbles induced by 14 MeV neutron irradiation can cause intergranular fractures in reduced activation ferritic martensitic steel,which is a candidate structural material for fusion *** order to elucidate the susceptibility of different grain boundaries(GBs)to helium-induced embrittlement,the tensile fracture processes of 10 types of GBs with and without helium bubbles in body-centered cubic(bcc)iron at the relevant service temperature of 600 K were investigated via molecular dynamics *** results indicate that in the absence of helium bubbles,the GBs studied here can be classified into two distinct categories:brittle GBs and ductile *** atomic scale analysis shows that the plastic deformation of ductile GB at high temperatures originates from complex plastic deformation mechanisms,including the Bain/Burgers path phase transition and deformation twinning,in which the Bain path phase transition is the most dominant plastic deformation ***,the presence of helium bubbles severely inhibits the plastic deformation channels of the GBs,resulting in a significant decrease in elongation at *** bubble-decorated GBs,the ultimate tensile strength increases with the increase in the misorientation ***,the coherent twin boundary∑3{112}was found to maintain relatively high fracture strength and maximum failure strain under the influence of helium bubbles.

关键词： Helium bubble Grain boundary Embrittlement Reduced activation ferritic martensitic steel Molecular dynamics Bain path

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