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Thiazoloisoindigo-based Polymer Semiconductors: Synthesis,Structure-Property Relationship, Charge Carrier Polarity, and Field-Effect Transistor Performance

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Chinese Journal of Polymer Science 2024年第1期42卷 24-31,I0006页

作者： Bo-Wen Li Miao Xiong Mei-Hua liu Zhi-Gao Li Long Sang Zi-Han Xiong Biao Xiao Jian Pei Xiao-Bo Wan Key Laboratory of Optoelectronic Chemical Materials and Devices Ministry of EducationSchoolofOptoelectronic Materials&TechnologyJianghan UniversityWuhan430056China Bejing National Laboratoryfor Molecular Sciences the Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China

Developing new polymeric semiconductors with excellent device performance is essential for organic electronics. Herein, we synthesized two new thiazoloisoindigo(Tz II)-based polymers, namely, P(Tz II-d Th-d Th) and P(Tz II-d Th-d Tz), by copolymerizing thiophene-flanked Tz II with bithiophene and bithiazole, respectively. Owing to the more electron-deficient nature of bithiazole than bithiophene, P(Tz II-d Th-d Tz)possesses deeper LUMO/HOMO levels of-3.45/-5.47 e V than P(Tz II-d Th-d Th)(-3.34/-5.32 e V). The organic field-effect transistor(OFET) devices based on P(Tz II-d Th-d Th) exhibited p-type behaviors with an average hole mobility value as high as 1.43 cm^(2)·V^(-1)·s^(-1), while P(Tz II-d Th-d Tz)showed typical ambipolar characteristics with average hole and electron mobilities of 0.38 and 0.56 cm^(2)·V^(-1)·s^(-1). In addition, we compared the performances of both polymers with other Tz II-based polymers reported in our previous work, and showed that the charge carrier polarity can be manipulated by adjusting the number of the thiophene units between the acceptor unit. As the increase of the number of thiophene rings,charge carrier polarity shifts from electron-dominated ambipolar transport to hole-dominated ambipolar transport and then to unipolar hole transport in OFETs, which provides an effective molecular design strategy for further optimization of polymer OFET performance.

关键词： Field-effect transistor Charge carrier polarity Thiazoloisoindigo

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Application status and prospect of ionic liquids in oilfield chemistry

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Petroleum 2024年第1期10卷 11-18页

作者： Jinsheng Sun Zhuoyang Xiu Li Li Kaihe Lv Xianfa Zhang Zonglun Wang Zhiwen Dai Zhe Xu Ning Huang Jingping liu School of Petroleum Engineering China University of Petroleum (East China) CNPC Engineering Technology R&D Company Limited Oil & Gas Technology Research Institute of Changqing Oilfield Company

The ionic liquid, as a new treatment agent, has been increasingly applied in oil fields due to its strong temperature resistance, good solubility and high surface activity. In this paper, we systematically discuss the action mechanism and application effect of ionic liquids in oilfield chemistry. Ionic liquids can inhibit shale hydration expansion and reduce fluid loss through adsorption and intercalation, inhibit the formation of natural gas hydrate through imidazole five-membered ring structure as a space barrier, reduce viscosity of heavy oil by breaking chemical bonds of heavy oil macromolecules and charge transfer,improve oil displacement efficiency by forming ions pairs with carboxyl groups in crude oil, demulsify by forming channels between dispersed water droplets, acidify the formation by reacting with water to produce acid, interacts with organic material through weak hydrogen bonds and extracts it from oilfield wastewater, desulphurize by inserting sulfide molecules into the “stack” structure and form liquid inclusion complex, inhibit corrosion by forming a protective film on the metal surface. Based on the above aspects, the development direction of ionic liquids is proposed. The application of ionic liquids in oilfield chemistry is still in its infancy. It is urgent to fully explore the application performance of ionic liquids in oilfield chemistry, which also provides theoretical and technical supports for efficient reservoir development.

关键词： Ionic liquids Oilfield chemistry Shale inhibitor Drilling fluid

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火星水冰分布特征和研究进展

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地球科学 2024年第6期49卷 2253-2276页

作者：刘正豪刘洋刘佳牛胜利邹永廖中国科学院国家空间科学中心空间天气学国家重点实验室北京100190 中国科学院大学北京100049 中国科学院比较行星学卓越创新中心安徽合肥230026

火星作为太阳系中与地球相似的一颗行星,它曾经存在活跃的水活动历史,现今火星稀薄的大气和寒冷干旱的气候使得液态水很难存在于火星表面,火星上水大多以冰的形式在南北两极和中纬度区域分布并形成沉积地貌类型.随着国内外深空探测任务... 详细信息

火星作为太阳系中与地球相似的一颗行星,它曾经存在活跃的水活动历史,现今火星稀薄的大气和寒冷干旱的气候使得液态水很难存在于火星表面,火星上水大多以冰的形式在南北两极和中纬度区域分布并形成沉积地貌类型.随着国内外深空探测任务的逐年增多,火星上的水冰环境与宜居性越来越受到关注,以极区冰盖、中纬度冰川作用地貌和浅地表水冰升华地貌为重点,对它们的形貌特征、分布情况、成因机制以及与气候的耦合关系进行介绍和剖析.火星中纬度地区水冰地貌的分布与自转轴倾角有关,当火星处于高倾角时,极区水冰会向中纬度表面转移,此时火星转变为寒冷的冰期,中纬度水冰环境区域增加;反之,则极区冰盖区域增加.因此,火星自转轴倾角的周期性改变引起气候的改变,从而导致形成了水冰在火星表面不断重新分布的过程,主要表现为从极区到中高纬度区域水冰阶段性的富集.通过对火星水冰分布特征的总结,加深了对火星水冰环境的认识,同时结合火星水冰的研究现状提出了展望.火星水冰地貌与火星宜居环境以及生命赋存形式息息相关,对火星水冰的研究可以帮助我们深入了解火星的气候演化历史、宜居环境情况等以及为未来的火星探测任务提供支撑.

关键词：火星水冰冰盖冰川地貌特征气候演化行星地质

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Metal-Free Photocatalytic[4+2]Annulation of Acrylamides with 2-Benzyl-2-bromocarbonyls to Assemble Tetralin-1-carboxamides

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Chinese Journal of Chemistry 2024年第2期42卷 157-163页

作者： Weicai Li Lu Tan Yijun Chen Rui liu Zhongyu Qi Shixuan Yuan Zhanwen Huang Siping Wei Xi Du Dong Yi Nuclear Medicine and Molecular Imaging Key Laboratory of Sichuan Province School of PharmacySouthwest Medical UniversityLuzhouSichuan 646000China Department of Chemistry School of Basic Medical ScienceSouthwest Medical UniversityLuzhouSichuan 646000China Department of Pharmacy Affiliated HospitalSouthwest Medical UniversityLuzhouSichuan 646000China

Tetralin-1-carboxamides are frequently incorporated in myriad medicinally important ***,their existing synthetic routes not only suffer from some drawbacks such as tedious procedures,harsh reaction conditions,narrow substrate scope,low yields,and environmental problems,but are also based upon the elaboration of uneasily available non-linear tetralin ***,we describe a metal-and additive-free visible light-induced[4+2]annulation of two simple linear starting materials,namely acrylamides and 2-benzyl-2-bromocarbonyls,through a cascade C(sp^(3))-Br/C(sp^(2))-H bond cleavage,double C-C bond formation,and aromatization *** developed protocol provides a convenient,efficient,and green approach to a variety of tetralin-1-carboxamide derivatives with good functional group ***,the resulting products could also undergo the Licl-mediated mono-decarboxylative cyclization process to further furnish the architecturally novel bridged polycyclic imides with excellentcis-diastereoselectivities.

关键词： Annulation Metal-free Photoredox catalysis Tetralin-1-carboxamide Cyclic imides Synthetic methods C-C coupling Radical reactions Reaction mechanisms

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基于数字孪生的建筑工程交付模型建立及应用研究

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建筑结构学报 2024年第4期45卷 97-106页

作者：刘占省刘俊杰及炜煜刘亮北京工业大学城市建设学部北京100124 北京工业大学城市与工程安全减灾教育部重点实验室北京100124

建筑生命周期数据包含建筑项目立项、设计、施工、运维等过程的有价值信息,是重要的数据资产。目前建筑业尚未有统一的数字化交付标准,建筑工程交付数据同时存在完整性不足、利用率低等问题。为了更好地利用建筑信息,并用于工程交付,综... 详细信息

建筑生命周期数据包含建筑项目立项、设计、施工、运维等过程的有价值信息,是重要的数据资产。目前建筑业尚未有统一的数字化交付标准,建筑工程交付数据同时存在完整性不足、利用率低等问题。为了更好地利用建筑信息,并用于工程交付,综合分析了目前数字化交付中的难点问题,总结了建筑项目各阶段所产生的数据特点以及交付对象,定义了需要交付的数据要素,在此基础上建立了建筑工程数字化交付模型。该模型以数字孪生框架为驱动,在数据模型构建过程中,引入了时空演化规律和虚实交互机制,以及对多维多尺度的建筑数据集成方式。基于交付模型开发了数字化交付平台,以实际工程案例为依托,以平台为载体,实现了交付模型的运行以及在工程中的功能应用。结果表明:数字化交付模型能较好地完成建筑数据从采集到传输到最后利用过程,简化相关方的交付步骤,保证了交付数据的完整性、及时性与真实性,对交付的数据能通过平台为参与方共享利用,提升数据利用率。

关键词：建筑工程竣工交付数字孪生数据管理交付模型

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Restoring cellular calcium homeostasis to rescue ER stress by 1,2-bis(2-aminophenoxy)ethane-N,N,N’,N’-tetraacetic acid acetoxymethyl ester-loaded lipid-mPLGA hybrid-nanoparticles for acute kidney injury therapy

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Chinese Chemical Letters 2024年第3期35卷 337-345页

作者： Jingwen Zhang Jiahui Yan Yanan Wang Hong liu Xueping Sun Yuchao Gu Liangmin Yu Changcheng Li Jun Wu Zhiyu He Frontiers Science Center for Deep Ocean Multispheres and Earth System and Key Laboratory of Marine Chemistry Theory and TechnologyMinistry of EducationOcean University of ChinaQingdao 266100China College of Chemistry and Chemical Engineering Ocean University of ChinaQingdao 266100China School of Medicine and Pharmacy Ocean University of ChinaQingdao 266003China Sanya Oceanographic Institution Ocean University of ChinaQingdao 572024China Bioscience and Biomedical Engineering Thrust The Hong Kong University of Science and Technology(Guangzhou)NanshaGuangzhou 511400China Division of Life Science The Hong Kong University of Science and TechnologyHong Kong 999077China

Early pathogenesis of ischemia-reperfusion(I/R)-induced acute kidney injury(AKI)is dominated by intracellular calcium overload,which induces oxidative stress,intracellular energy metabolism disorder,inflammatory activation,and a series of pathologic cascaded reactions that are closely intertwined with self-amplifying and interactive feedback loops,ultimately resulting in cell damage and kidney ***,most nanomedicines originate from the perspective of antioxidant stress,which can only quench existing reactive oxide species(ROS)but cannot prevent the continuous production of ROS,resulting in insufficient *** a safe and promising drug,BAPTA-AM is hydrolyzed into BAPTA by intracellular esterase upon entering cells,which can rapidly chelate with overloaded Ca^(2+),restoring intracellular calcium homeostasis,thus inhibiting ROS regeneration at the ***,we designed a KTP-targeting peptide-modified yolk-shell structure of liposome–poly(ethylene glycol)methyl ether-block-poly(L-lactide-co-glycolic)(mPLGA)hybrid nanoparticles(<100 nm),with the characteristics of high encapsulation rate,high colloid stability,facile modification,and prolonged blood circulation *** the BA/mPLGA@Lipo-KTP was targeted to the site of kidney injury,the cholesteryl hemisuccinate(CHEMS)in the phospholipid bilayer,as an acidic cholesterol ester,was protonated in the simulated inflammatory slightly acidic environment(pH 6.5),causing the liposomes to rupture and release the BA/mPLGA nanoparticles,which were then depolymerized by intracellular *** BAPTA-AM was diffused and hydrolyzed to produce BAPTA,which can rapidly cut off the malignant loop of calcium overload/ROS generation at its source,blocking the endoplasmic reticulum(ER)apoptosis pathway(ATF4–CHOP–Bax/Bcl-2,Casp-12–Casp-3)and the inflammatory pathway(TNF-α–NF-κB–IL-6 axes),thus alleviating pathological changes in kidney tissue,thereby inhibiting the expression of renal tubular marker kidney injury mole

关键词： BAPTA-AM Calcium overload Acid-responsive AKI ER stress

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A dicistrovirus increases pupal mortality in Spodoptera frugiperda by suppressing protease activity and inhibiting larval diet consumption

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Journal of Integrative Agriculture 2024年第8期23卷 2723-2734页

作者： Meixue Sun Tong Li Yingjie liu Kenneth Wilson Xingyu Chen Robert I.Graham Xianming Yang Guangwei Ren Pengjun Xu Key Laboratory of Tobacco Pest Monitoring&Integrated Management Tobacco Research InstituteChinese Academy of Agricultural SciencesQingdao 266101China Institute of Plant Protection Henan Academy of Agricultural SciencesZhengzhou 450000China Staff Development Institute of China National Tobacco Corporation Zhengzhou 450000China Lancaster Environment Centre Lancaster UniversityLancaster LA14YWUK Department of Rural Land Use Scotland’s Rural CollegeCraibstone CampusAberdeen AB01ABUK State Key Laboratory for Biology of Plant Diseases and Insect Pests Institute of Plant ProtectionChinese Academy of Agricultural SciencesBeijing 100193China

Understanding interactions between viruses and their hosts is conducive to enabling better application of viruses as biocontrol *** viruses carried by parasitic wasps enhance the parasitic efficiency of wasp-larvae by protecting them against the immune system of their Lepidopteran ***,the relationship between prey pests and viruses found in predatory natural enemies remains ***,we report the interaction between Arma chinensis virus-1(AcV-1),originally isolated from a predatory natural enemy,Arma chinensis(Hemiptera:Pentatomidae),and one of its prey species,Spodoptera frugiperda(Lepidoptera:Noctuidae).The results showed that the AcV-1 virus appeared harmful to the novel host *** by inhibiting larval diet consumption and increasing pupal ***,sequencing data indicated that the virus altered the gene expression profiles of *** analysis showed that the proteasome and phagosome pathways related to protein degradation and immune response were significantly *** the expression levels of digestive enzyme genes did not change significantly,the total protease activity of AcV-1 virus-positive individuals was significantly decreased,suggesting that the virus inhibited diet consumption of *** via the down-regulation of digestive enzyme *** results indicate that a virus initially isolated in a predatory natural enemy can decrease the fitness of its prey *** virus was found to impact the host proteasome and phagosome pathways related to protein degradation and immunity,providing a potential mechanism to enhance controlling efficiency.

关键词： Arma chinensis virus-1 diet consumption fitness transcriptome protease activity

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Effects and Causes of VR-Supported Interpreting Learning Environment on the Interpretation Classroom Anxiety of Student Interpreter

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Open Journal of Applied Sciences 2024年第2期14卷 398-410页

作者： Ruizhe Zhang Jinyu liu College of Foreign Languages Inner Mongolia University Hohhot China

Interpreting activity is considered a high-anxiety activity due to its immediacy, multitasking, complexity of cognitive processing, and uncertainty of cognitive processing. Research has shown that interpreting anxiety, as the biggest emotional obstacle in the interpreting process, is the main emotional factor that leads to individual differences in interpreting. Students often claim to have fear or anxiety behaviors in interpreting exams, interpreting competitions, and interpreting classes. However, the research on interpreting teaching attaches importance to the cultivation of language knowledge, cultural knowledge, and interpreting skills, and does not pay enough attention to emotional factors such as motivation and anxiety in interpreting learning, which makes it difficult for the cultivated interpreters to meet the requirements of professional practice. In recent years, virtual reality technology (VR) has been gradually applied in the field of foreign language and interpreting teaching for creating a real, interactive and experiential language learning environment. Situated Learning Theory stresses that the fundamental mechanism for learning to take place is for individuals to participate in the real context in which knowledge is generated, and to realize the construction of knowledge through the interaction with the community of practice and the environment. Virtual reality technology can satisfy the needs of language learners for real contexts by providing learners with immersive, imaginative and interactive scenario simulations, and has a certain positive effect on alleviating learning anxiety. Therefore, relying on the virtual simulation course “United Nations Kubuqi International Desert Ecological Science and Technology Innovation International Volunteer Language Service Practical Training System”, this paper adopts a combination of quantitative and qualitative analyses to investigate the interpretation anxiety level of the interpreter trainees and the fact

关键词： Interpreter Anxiety Virtual Reality Situated Cognition and Learning

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Surgically treating a rare and asymptomatic intraductal papillary neoplasm of the bile duct:A case report

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World Journal of Clinical Cases 2024年第2期12卷 367-373页

作者： Shen-Zhen Zhu Zhao-Feng Gao Xiao-Rong liu Xiao-Guang Wang Fei Chen Department of General Surgery Jiaxing Second HospitalJiaxing 314000Zhejiang ProvinceChina Department of Hepatobiliary Surgery Jiaxing Second HospitalJiaxing 314000Zhejiang ProvinceChina

BACKGROUND Intraductal papillary neoplasms of the bile duct(IPNBs)are rare and characterized by papillary growth within the bile duct *** is similar to obstructive biliary *** this report,we present an unexpected case of asymptomatic IPNB and consolidate our findings with the relevant literature to augment our understanding of this *** relevant literature contributes to a more comprehensive understanding of the *** SUMMARY A 66-year-old Chinese male patient was admitted to our hospital for surgical intervention after gallstones were discovered during a routine physical *** imaging revealed a lesion on the left side of the liver,which raised the suspicion of IPNB.A laparoscopic left hemihepatectomy was performed,and subsequent histopathological examination confirmed the diagnosis of *** the 3-mo postoperative follow-up,the patient reported good recovery and no *** can manifest both latently and *** surgical resection is the most effective treatment for *** Hepatic and biliary masses,should be considered to diagnose *** surgery and vigilant follow-up are crucial in determining prognosis.

关键词： Intraductal papillary neoplasm of the bile duct Tumor Surgical treatment Prognosis Case report

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建筑蓄热原理及其设计参数

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科学通报 2024年第11期69卷 1475-1490页

作者：刘衍毕冰藤乔宇豪杨柳刘加平绿色建筑全国重点实验室西安710055 西安建筑科技大学建筑学院西安710055 西安建筑科技大学交叉创新研究院西安710055

建筑蓄热是解决建筑热流作用不稳定的核心,通过建筑设计的方式,将建筑部件的“削峰填谷”效应与其他因素耦合,使建筑对热流的调控作用最大化,实现对室内热环境的优化.本文对建筑蓄热相关概念做了辨析,将“建筑蓄热”与“围护结构蓄热”... 详细信息

建筑蓄热是解决建筑热流作用不稳定的核心,通过建筑设计的方式,将建筑部件的“削峰填谷”效应与其他因素耦合,使建筑对热流的调控作用最大化,实现对室内热环境的优化.本文对建筑蓄热相关概念做了辨析,将“建筑蓄热”与“围护结构蓄热”,“保温”与“隔热”,“热惰性”、“热质量”以及“热惰性指标”等相似概念进行区分,总结了建筑蓄热的作用原理和基础模型,揭示了各向异性太阳辐射多过程传输与转化形成的“双高波谷温度波”效应,和部件蓄热、自然通风与长波辐射降温多种热作用形成的“双低波峰温度波”效应,提出了能够表征建筑系统蓄热能力的指标参数.通过对蓄热问题历史发展背景的挖掘和对相关研究现状的梳理,总结了我国在建筑蓄热研究中存在的问题.建筑蓄热在不同气候条件下的应用潜力差异显著,将相关气候指标应用到建筑热工设计分区之中是当务之急;建筑热工设计过度追求构件高指标,实际则是建筑整体低性能,亟需构建以建筑蓄热为代表的热工设计综合指标体系;亟需加强建筑蓄热基础理论研究,强化建筑蓄热与建筑设计之间的联系.

关键词：建筑节能建筑蓄热建筑热工建筑热流围护结构

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