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Directional amine-based solvent extraction for simultaneous enhanced water recovery,salt separation and effective descaling from hypersaline brines

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Frontiers of Environmental Science & Engineering 2024年第3期18卷 83-92页

作者： Yuyao Zhang litao jia Jin Zhao Xuming Liu Shuyu Dong Chuanyang Liu Yuanyuan Cui Shougang Research Institute of Technology Beijing 100043China Research Center of Environmental Technology in Water Pollution Source Identification and Precise Supervision School of EnvironmentTsinghua UniversityBeijing 100084China

The feasibility of simultaneous water recovery,salt separation and effective descaling of hypersaline brine was investigated by diisopropylamine(DIPA)-based directional solvent extraction(DSE),using diluted/concentrated seawater with initial saline concentration range of 12–237 g/L at extraction temperatures of 5 and 15℃,*** water recovery shows an obvious boundary at saline concentration of 115 g/L under dual effect of specific water extraction efficiency and extraction *** Cl^(–) ion concentration in product water is in sharp contrast to the nearly complete removal of SO_(4)^(2–)and hardness ions,indicating that DIPA-based DSE process indeed achieved efficient separation and purification of Cl^(–) ion from hypersaline ***,the radical precipitation of Mg^(2+)and Ca^(2+)ions in form of Mg(OH)_(2)and CaCO_(3)demonstrates effective descaling potential,although it leads to more DIPA residues in dewatered raffinate than product ***,an exponential correlation between the Cl^(–) removal efficiency and specific water extraction efficiency further reveals the intrinsic relationship of water extraction process and transfer of Cl^(–) ion to the product ***,the study provides a novel approach for integrating the water recovery and separation of Cl^(–) ion from ultra-high-salinity brines with radical precipitation of Mg^(2+)and Ca^(2+) ions in one step.

关键词： Hypersaline brines Directional solvent extraction Salt separation Ca^(2+)and Mg^(2+)descaling

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固相外延生长法制备ZSM-5@Silicalite-1分子筛及其CO_(2)加氢耦合甲苯烷基化反应的影响

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燃料化学学报（中英文） 2024年第8期52卷 1115-1130页

作者：贾艺敏牛鹏宇贾丽涛林明桂郭荷芹肖勇侯博李德宝中国科学院山西煤炭化学研究所煤炭高效低碳利用全国重点实验室山西太原030001 中国科学院大学北京100049 中国科学院洁净能源创新研究院辽宁大连116023

本研究采用固相法在ZSM-5表面外延生长Silicalite-1,制备出ZSM-5@Silicalite-1分子筛。同时制备高活性氧化物ZnZrOx,并与ZSM-5@Silicalite-1物理混合组成ZnZrOx/ZSM-5@Silicalite-1双功能催化剂,研究了CO_(2)加氢耦合甲苯烷基化催化性能。相比于ZnZrOx/ZSM-5催化剂,分子筛改性后的双功能催化剂提高了对二甲苯(PX)选择性。研究了晶化条件(硅源、晶化过程、晶化次数)对ZSM-5外延生长Silicalite-1的影响,以及Silicalite-1钝化层厚度对CO_(2)加氢耦合甲苯烷基化反应性能的影响。在400℃、3 MPa反应条件下,ZZO/1:3.5Z5-Na-SiO_(2)催化剂的甲苯转化率为12.0%,二甲苯选择性为77.4%,在二甲苯中对二甲苯选择性为73.4%。通过SEM、XRD、N2吸附-脱附、XPS、NH3-TPD、Py-FTIR等表征,研究了分子筛的结构和酸性质。结果表明,通过固相外延生长,延长ZSM-5的孔道,增加间二甲苯(MX)、邻二甲苯(OX)的扩散阻力,同时钝化外表面的酸性,可以有效提高对二甲苯(PX)的选择性。固相外延生长法改性ZSM-5分子筛,摒弃了以往堵塞孔以缩小孔口改性分子筛的缺点,在保证催化剂活性的同时提高了产物选择性。

关键词： MFI型分子筛外延生长对二甲苯固相法 CO_(2)加氢耦合甲苯烷基化

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简易保鲜储藏设备质量评价研究——以北京市为例

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中国农机化学报 2024年第7期45卷 135-140,151页

作者：蒋晓禹振军盛顺卜小东贾利涛陈向东北京农业职业学院北京市102208 北京市农业机械试验鉴定推广站北京市100079

为实现简易保鲜储藏设备的推广应用,需要先确定简易保鲜储藏设备的质量评价方法。通过分析研究简易保鲜储藏设备质量调查评价方法并进行实际应用,对简易保鲜储藏设备的安全性、可靠性、适应性和售后服务状况等内容进行调查及评价,掌握... 详细信息

为实现简易保鲜储藏设备的推广应用,需要先确定简易保鲜储藏设备的质量评价方法。通过分析研究简易保鲜储藏设备质量调查评价方法并进行实际应用,对简易保鲜储藏设备的安全性、可靠性、适应性和售后服务状况等内容进行调查及评价,掌握在用保鲜储藏设备的整体质量水平。在分析研究简易保鲜储藏设备的组成结构、参数及功能原理、用途、设备实际运行使用过程中可能出现的状况及故障、用户使用设备的质量要求及服务感受的基础上,设置设备质量评价指标,每个指标赋予不同的权重系数。其中一级指标5个,分别是安全性、适用性、可靠性、物料使用负荷程度、售后服务;二级指标25个。一级指标中安全性25分、适用性20分、可靠性20分、物料使用负荷程度20分、售后服务15分。调查结果表明,简易保鲜储藏设备所有样本加权得分为83.10。3家公司的产品生产使用性能较好,达到产品设计标准。

关键词：北京市简易保鲜储藏设备质量评价权重系数

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Synthesis and characterization of the flower-like La_(x)Ce_(1-x)O_(1.5+δ) catalyst for low-temperature oxidative coupling of methane

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Journal of Energy Chemistry 2022年第4期31卷 342-353页

作者： Ru Feng Pengyu Niu Bo Hou Qiang Wang litao jia Minggui Lin Debao Li State Key Laboratory of Coal Conversion Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001ShanxiChina University of Chinese Academy of Sciences Beijing 100049China Dalian National Laboratory For Clean Energy Chinese Academy of SciencesDalian 116023LiaoningChina

Lanthanum-based oxides are promising candidates for low-temperature oxidative coupling of methane(OCM).To further lower the OCM reaction temperature,the Ce doped flower-like La_(2)O_(2)CO_(3)microsphere catalysts were synthesized,achieving a significantly low reaction temperature (375℃) while maintaining high C_(2) hydrocarbon selectivity (43.0%).Doping Ce into the lattice of La_(2)O_(2)CO_(3)created more surface oxygen vacancies and bulk lattice defects,which was in favor of the transformation and migration of oxygen species at 350–400℃.The designed H_(2) temperature-programmed reduction (H_(2)-TPR) experiments provided strong evidence that the low reaction temperature of La_(x)Ce_(1-x)O_(1.5+δ)can be attributed to the transformation and migration of oxygen species,which dynamically generated surface oxygen vacancies for continuous oxygen activation to selectively convert ***,designed temperatureprogrammed surface reaction (TPSR) clarified that two kinds of surface oxygen species in La_(x)Ce_(1-x)O_(1.5+δ)catalysts were concerned with catalytic performance,that is,the surface chemisorbed oxygen species for the activation of CH_(2)and the formation of CH_(2)·intermediates,surface La-Ce-O lattice oxygen species that caused the excessive oxidation of CH_(2)·***,the factors affecting the transformation and migration of oxygen species were explored.

关键词： Lanthanum-based oxides Oxygen vacancy Transformation and migration of oxygen species Oxidative coupling of methane(OCM)

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ZrO_(2)修饰对Co/SiC催化剂的费托合成性能影响

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燃料化学学报（中英文） 2024年第8期52卷 1088-1094页

作者：王民郭舒鹏许金山李留忠陈从标马中义贾丽涛侯博李德宝中国石油化工股份有限公司齐鲁分公司研究院山东淄博255400 中国科学院山西煤炭化学研究所山西太原030001

本研究采用ZrO_(2)对SiC表面进行改性,制得系列Co-ZrO_(2)/SiC催化剂,借助N2物理吸附、XRD、H2-TPR、XPS等表征手段对催化剂物化性质进行结构分析,并利用微型固定床反应器对催化剂的活性进行评价,研究ZrO_(2)改性SiC载体对钴基费托合成... 详细信息

本研究采用ZrO_(2)对SiC表面进行改性,制得系列Co-ZrO_(2)/SiC催化剂,借助N2物理吸附、XRD、H2-TPR、XPS等表征手段对催化剂物化性质进行结构分析,并利用微型固定床反应器对催化剂的活性进行评价,研究ZrO_(2)改性SiC载体对钴基费托合成催化剂的影响。研究结果表明,由于ZrO_(2)体相存在氧空穴等不同的活性位,H2在Co表面被活化后形成的部分H溢流到ZrO_(2)表面并储存到ZrO_(2)表面,而ZrO_(2)与Co之间存在相对较强的相互作用,使得Co周围的H浓度增加,进而Co/SiC催化剂的还原度显著增加。同时,ZrO_(2)与SiC表面的无定形相发生相互作用形成Zr−O−Si键。由于Si(1.90)的电负性高于Zr(1.33),部分电子可以通过Zr-O-Si结构从Zr转向Si,形成富电子的SiOxCy相和SiO_(2)相。从而降低了SiC表面无定形相的对Co物相吸电子能力,减弱了Co与SiC表面的无定形相的相互作用,进而提高了Co相的电子密度。采用ZrO_(2)对SiC进行修饰后,同时提高了Co/SiC催化剂中Co物相的电子密度和还原度,使得催化剂对长链烃的选择性显著提升。

关键词：钴基催化剂 SiC ZrO_(2) 费托合成

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Bioprinting and regeneration of auricular cartilage using a bioactive bioink based on microporous photocrosslinkable acellular cartilage matrix

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Bioactive Materials 2022年第10期7卷 66-81页

作者： litao jia Yujie Hua Jinshi Zeng Wenshuai Liu Di Wang Guangdong Zhou Xia Liu Haiyue jiang Research Center of Plastic Surgery Hospital Chinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing100144PR China Department of Plastic and Reconstructive Surgery Shanghai Ninth People’s HospitalShanghai Key Laboratory of Tissue EngineeringShanghai Jiao Tong University School of MedicineShanghai200011PR China Research Institute of Plastic Surgery Weifang Medical UniversityWeifang261042PR China

Tissue engineering provides a promising strategy for auricular *** the first international clinical breakthrough of tissue-engineered auricular reconstruction has been realized based on polymer scaffolds,this approach has not been recognized as a clinically available treatment because of its unsatisfactory clinical *** is mainly since reconstruction constructs easily cause inflammation and *** this study,we present a novel strategy for the development of biological auricle equivalents with precise shapes,low immunogenicity,and excellent mechanics using auricular chondrocytes and a bioactive bioink based on biomimetic microporous methacrylate-modified acellular cartilage matrix(ACMMA)with the assistance of gelatin methacrylate(GelMA),poly(ethylene oxide)(PEO),and polycaprolactone(PCL)by integrating multi-nozzle bioprinting *** ACMMA is used to emulate the intricacy of the cartilage-specific microenvironment for active cellular behavior,while GelMA,PEO,and PCL are used to balance printability and physical properties for precise structural stability,form the microporous structure for unhindered nutrient exchange,and provide mechanical support for higher shape fidelity,***,mature auricular cartilage-like tissues with high morphological fidelity,excellent elasticity,abundant cartilage lacunae,and cartilage-specific ECM deposition are successfully regenerated in vivo,which provides new opportunities and novel strategies for the fabrication and regeneration of patient-specific auricular cartilage.

关键词： 3D bioprinting Photocrosslinkable acellular cartilage matrix Bioactive bioink Microporous Auricular cartilage regeneration

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三维酰胺质子转移成像在原发性肝癌临床扫描可行性及图像质量评估中的初步研究

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磁共振成像 2024年第3期15卷 163-169页

作者：齐晓辉王琦沈智威段梦婷刘响潘江洋范雪丽贾丽涛王亚宁杜煜河北医科大学第四医院CT/MRI科石家庄050000 飞利浦(中国)投资有限公司北京100600

目的评估参数优化的三维酰胺质子转移加权(3 dimensions-amide proton transfer weighted,3D-APTw)成像在原发性肝癌扫描中的图像质量并分析其临床扫描的可行性。材料与方法前瞻性招募2020年10月至2022年2月临床怀疑原发性肝癌患者,共... 详细信息

目的评估参数优化的三维酰胺质子转移加权(3 dimensions-amide proton transfer weighted,3D-APTw)成像在原发性肝癌扫描中的图像质量并分析其临床扫描的可行性。材料与方法前瞻性招募2020年10月至2022年2月临床怀疑原发性肝癌患者,共109例。采用飞利浦3.0 T MRI设备进行扫描,分别采集T1WI、T2WI、弥散加权成像、酰胺质子转移加权(amide proton transfer weighted,APTw)及多期增强图像。机器自动生成经过B0校正的肝脏APTw图像。计算3D-APTw成像的扫描成功率及计算成功率。采用Kendall一致性系数对观察者内及观察者间主观评分进行一致性分析,对主观评分3分以上的病例测量3D-APTw图像的信噪比(signal-to-noise ratio,SNR)、肿瘤对比噪声比(contrast-to-noise ratio,CNR)、肿瘤及肝实质的APTw值并计算各参数值的变异系数,采用组内相关系数进行观察者内及观察者间可重复性测量的一致性分析。结果 109例患者中有11例患者3D-APTw图像中病变区域存在信号缺失,扫描成功率为89.91%(98/109),剩余98例患者中78例3D-APTw图像的主观评分为3分以上,计算成功率为71.56%(78/109)。观察者内及观察者间图像质量主观评分一致性分别为0.771和0.692,P<0.01。肿瘤组织APTw值观察者内及观察者间ICC分别为0.822和0.811,肝实质APTw值、SNR及CNR观察者ICC分别为0.675、0.634、0.666,肝实质APTw值、SNR及CNR观察者间ICC分别为0.614、0.290、0.560。肿瘤组织APTw值高于肝实质[(2.55±0.08)%vs.(1.45±0.07)%],两者间差异有统计学意义(P<0.001)。肿瘤组织和肝实质APTw值的变异系数分别为30.40%和44.40%。SNR和CNR为25.92±18.50和3.35±3.20。SNR变异系数为71.40%,CNR变异系数为90.00%。结论参数优化后的3D-APTw成像可以用于原发性肝癌的临床扫描,但容易受呼吸运动、胆囊或血管的影响而出现信号缺失或伪影,在参数设置及成像技术上仍有需要改进和提高的空间,以进一步优化其图像质量。

关键词：原发性肝癌诊断可行性图像质量三维酰胺质子转移成像磁共振成像

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高炉风口水腔结垢原因及防治措施

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冶金动力 2024年第3期 50-55页

作者：赵锦贾利涛张玉瑶董舒宇武建龙黄俊杰徐萌首钢集团有限公司技术研究院北京100043 绿色可循环钢铁流程北京市重点实验室北京100043 首钢京唐钢铁联合有限责任公司河北唐山063200

针对某钢铁厂高炉风口水腔结垢问题,对垢样进行X射线衍射(XRD)检测,检测结果显示垢样的主要成分为CaSO_(4)、CaSO_(4)·2H_(2)O和CaSO_(4)·0.5H_(2)O。分析高炉风口循环冷却水水质和原有阻垢剂性能,提出相应的改善措施,调控循环冷却水... 详细信息

针对某钢铁厂高炉风口水腔结垢问题,对垢样进行X射线衍射(XRD)检测,检测结果显示垢样的主要成分为CaSO_(4)、CaSO_(4)·2H_(2)O和CaSO_(4)·0.5H_(2)O。分析高炉风口循环冷却水水质和原有阻垢剂性能,提出相应的改善措施,调控循环冷却水硬度在400 mg/L以下,并在原阻垢剂中配加6 mg/L乙二胺四甲叉磷酸钠(EDTMPS),有效避免了风口水垢的形成,提高了高炉风口的寿命。

关键词：风口水垢阻垢剂硬度循环冷却水

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Experimental Analysis of Radial Centrifugal Pump Shutdown

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Fluid Dynamics & Materials Processing 2024年第4期20卷 725-737页

作者： Xiao Sun jiangbo Tong Yuliang Zhang Haibing Cai Wen Zhou Xiaoqi jia litao Ou School of Mechanical Engineering Hunan University of TechnologyZhuzhou412007China College of Mechanical Engineering Quzhou UniversityQuzhou324000China Zhejiang Testing&Inspection Institute for Mechanical and Electrical Products Quality Co. Ltd.Hangzhou310014China Quzhou Special Equipment Inspection Center Quzhou324000China The Zhejiang Provincial Key Lab of Fluid Transmission Technology Zhejiang Sci-Tech UniversityHangzhou310018China Zhuzhou Nanfang Valve Co. Ltd.Zhuzhou412000China

Centrifugal pumps are widely used in the metallurgy,coal,and building *** order to study the hydraulic characteristics of a closed impeller centrifugal pump during its shutdown in the so-called power frequency and frequency conversion modes,experiments were carried to determine the characteristic evolution of parameters such as speed,inlet and outlet pressure,head,flow rate and shaft power.A quasi-steady-state method was also used to further investigate these transient *** results show that,compared to the power frequency input,the performance parameter curves for the frequency conversion input are less volatile and *** characteristic time is longer and the response to shutdown is *** quasi-steady-state theoretical head-flow curves match the experimental head-flow curves more closely at low flow rates when the frequency conversion input is ***,in this case,the similarity law predicts the hydraulic performance more accurately.

关键词： Centrifugal pump power frequency frequency conversion shutdown external characteristic experimental study

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Bioresource Upgrade for Sustainable Energy,Environment,and Biomedicine

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Nano-Micro Letters 2023年第3期15卷 48-97页

作者： Fanghua Li Yiwei Li KSNovoselov Feng Liang jiashen Meng Shih‑Hsin Ho Tong Zhao Hui Zhou Awais Ahmad Yinlong Zhu Liangxing Hu Dongxiao Ji litao jia Rui Liu Seeram Ramakrishna Xingcai Zhang Center for Nanofibers and Nanotechnology National University of SingaporeSingapore 119260Singapore State Key Laboratory of Urban Water Resource and Environment Harbin Institute of TechnologyHarbin 150090People’s Republic of China School of Engineering Massachusetts Institute of TechnologyCambridgeMA 02139USA John A Paulson School of Engineering and Applied Sciences Harvard UniversityCambridgeMA 02138USA The Key Laboratory for Biomedical Photonics of MOE at Wuhan National Laboratory for Optoelectronics–Department of Biomedical Engineering College of Life Science and TechnologyHuazhong University of Science and TechnologyWuhanHubei 430074People’s Republic of China Centre for Advanced 2D Materials National University of SingaporeSingapore 117546Singapore School of Physics and Astronomy The University of ManchesterManchester M139PLUK Department of Anesthesia Critical Care and Pain MedicineMassachusetts General Hospital and Harvard Medical SchoolBostonMA 02114USA Department of Energy and Power Engineering Tsinghua UniversityBeijing 100084People’s Republic of China Departamento de Quimica Organica Universidad de CordobaEdificio Marie Curie(C‑3)Ctra Nnal IV‑AKm 39614014 CordobaSpain Department of Chemical Engineering Monash UniversityClaytonVIC 3800Australia School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore

We conceptualize bioresource upgrade for sustainable energy,environment,and biomedicine with a focus on circular economy,sustainability,and carbon neutrality using high availability and low utilization biomass(HALUB).We acme energy-efficient technologies for sustainable energy and material recovery and *** technologies of thermochemical conversion(TC),biochemical conversion(BC),electrochemical conversion(EC),and photochemical conversion(PTC)are summarized for *** biomass could contribute to a biofuel HHV of 35.72 MJ Kg^(-1)and total benefit of 749$/ton biomass via *** surface area of biochar reached 3000 m^(2)g^(-1)via pyrolytic carbonization of waste bean *** biomass can be effectively converted into bio-stimulants and biofertilizers via BC with a high conversion efficiency of more than 90%.Besides,lignocellulosic biomass can contribute to a current density of 672 mA m^(-2)via *** can be 100%selectively synthesized via electrocatalysis through EC and *** learning,techno-economic analysis,and life cycle analysis are essential to various upgrading approaches of *** biomaterials,sustainable living materials and technologies for biomedical and multifunctional applications like nano-catalysis,microfluidic and micro/nanomotors beyond are also *** techniques and systems for the complete conversion and utilization of HALUB for new energy and materials are further discussed.

关键词： High availability low utilization biomass(HALUB) Circular economy Machine learning Energy-efficient conversion Nano-catalysis

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