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Study of the reaction mechanism for preparing powdered activated coke with SO_(2)adsorption capability via one-step rapid activation method under flue gas atmosphere

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Chinese Journal of Chemical Engineering 2024年第1期65卷 158-168页

作者： Binxuan Zhou Jingcai Chang Jun Li Jinglan Hong Tao Wang liqiang Zhang Ping Zhou Chunyuan ma School of Environmental Science and Engineering Shandong UniversityQingdao 266237China School of Energy and Power Engineering Shandong UniversityJinan 250061China Weihai Research Institute of Industrial Technology of Shandong University Weihai 264209China

In this study,the impact of different reaction times on the preparation of powdered activated carbon(PAC)using a one-step rapid activation method under flue gas atmosphere is investigated,and the underlying reaction mechanism is summarized.Results indicate that the reaction process of this method can be divided into three stages:stage I is the rapid release of volatiles and the rapid consumption of O_(2),primarily occurring within a reaction time range of 0-0.5 s;stage II is mainly the continuous release and diffusion of volatiles,which is the carbonization and activation coupling reaction stage,and the carbonization process is the main in this stage.This stage mainly occurs at the reaction time range of 0.5 -2.0 s when SL-coal is used as material,and that is 0.5-3.0 s when JJ-coal is used as material;stage III is mainly the activation stage,during which activated components diffuse to both the surface and interior of particles.This stage mainly involves the reaction stage of CO_(2)and H2O(g)activation,and it mainly occurs at the reaction time range of 2.0-4.0 s when SL-coal is used as material,and that is 3.0-4.0 s when JJ-coal is used as material.Besides,the main function of the first two stages is to provide more diffusion channels and contact surfaces/activation sites for the diffusion and activation of the activated components in the third stage.mastering the reaction mechanism would serve as a crucial reference and foundation for designing the structure,size of the reactor,and optimal positioning of the activator nozzle in PAC preparation.

关键词： Reaction mechanism Powdered activated coke preparation SO_(2)adsorption One-step rapid activation Flue gas atmosphere

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Enhancing fly ash utilization in backfill materials treated with CO_(2)carbonation under ambient conditions

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International Journal of Mining Science and Technology 2023年第3期33卷 323-337页

作者： Ichhuy Ngo liqiang ma Jiangtao Zhai Yangyang Wang Key Laboratory of Deep Coal Resource Mining China University of Mining&TechnologyXuzhou 221116China

The environmental concerns resulting from coal-fired power generation that produces large amounts of CO_(2)and fly ash are of great interest.To mitigate,this study aims to develop a novel carbonated CO_(2)-fly ash-based backfill(CFBF)material under ambient conditions.The performance of CFBF was investigated for different fly ash-cement ratios and compared with non-CO_(2)reacted samples.The fresh CFBF slurry conformed to the Herschel-Bulkley model with shear thinning characteristics.After carbonation,the yield stress of the fresh slurry increased significantly by lowering fly ash ratio due to gel formation.The setting times were accelerated,resulting in approximately 40.6%of increased early strength.The final strength decreased when incorporating a lower fly ash ratio(50%and 60%),which was related to the existing heterogeneous pores caused by rapid fluid loss.The strength increased with fly ash content above 70%because additional C-S(A)-H and silica gels were characterized to precipitate on the grain surface,so the binding between particles increased.The C-S(A)-H gel was developed through the pozzolanic reaction,where CaCO_(3)was the prerequisite calcium source obtained in the CO_(2)-fly ash reaction.Furthermore,the maximum CO_(2)uptake efficiency was 1.39 mg-CO_(2)/g-CFBF.The CFBF material is feasible to co-dispose CO_(2)and fly ash in the mine goaf as negative carbon backfill materials,and simultaneously mitigates the strata movement and water lost in post-subsurface mining.

关键词： Fly ash utilization CO_(2)carbonation Ambient conditions Water conservative backfill mining Negative carbon backfill materials

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Petrogenesis, oxidation state and volatile content of Dongga tonalite in the Gangdese belt, Xizang: Implication for porphyry Cu mineralization

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Acta Geochimica 2024年第2期43卷 280-295页

作者： liqiang Zhang Xilian Chen Shaohao Zou Deru Xu Xuena Wang Hua Wang State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013China School of Earth Sciences East China University of TechnologyNanchang 330013China

The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 ma. It exhibits high whole-rock V/Sc values(8.76–14.6), relatively low apatite CeN/CeN*ratios(1.04–1.28), elevated zircon(Eu/Eu*)Nvalues(an average of 0.44), high Ce4+/Ce3+values(205–1896), and high ?FMQ values(1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios(20.3–58.9), and lower zircon Ti temperatures (502–740 ℃), reflecting a high magmatic water content. Estimation of magmatic sulfur content(0.002–0.024 wt%) based on apatite SO3contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the Neo-Tethys oceanic slab. When compared with Xietongmen orebearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineralization exploration.

关键词： Tonalite Zircon Apatite Mineralization potential Dongga area Gangdese belt

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In situ observation of the electrochemical behavior of Li–CO_(2)/O_(2)batteries in an environmental transmission electron microscope

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Carbon Energy 2024年第4期6卷 244-255页

作者： Peng Jia Yunna Guo Dongliang Chen Jingming Yao Xuedong Zhang Jianguo Lu Yuqing Qiao liqiang Zhang Hebei Key Laboratory of Applied Chemistry College of Environmental and Chemical EngineeringYanshan UniversityQinhuangdaoChina State Key Laboratory of Metastable materials Science and Technology Clean Nano Energy CenterYanshan UniversityQinhuangdaoChina State Key Laboratory of Silicon and Advanced Semiconductor materials School of Materials Science and EngineeringZhejiang UniversityHangzhouChina Key Laboratory of Low Dimensional materials and Application Technology of Ministry of Education School of Materials Science and EngineeringXiangtan UniversityXiangtanChina

Li–CO_(2)/O_(2)batteries,a promising energy storage technology,not only provide ultrahigh discharge capacity but also capture CO_(2)and turn it into renewable energy.Their electrochemical reaction pathways'ambiguity,however,creates a hurdle for their practical application.This study used copper selenide(CuSe)nanosheets as the air cathode medium in an environmental transmission electron microscope to in situ study Li–CO_(2)/O_(2)(mix CO_(2)as well as O_(2)at a volume ratio of 1:1)and Li–O_(2)batteries as well as Li–CO_(2)batteries.Primary discharge reactions take place successively in the Li–CO_(2)/O_(2)–CuSe nanobattery:(I)4Li^(+)+O_(2)+4e^(−)→2Li_(2)O;(II)Li_(2)O+CO_(2)→Li_(2)CO_(3).The charge reaction proceeded via(III)2Li_(2)CO_(3)→4Li^(+)+2CO_(2)+O_(2)+4e^(−).However,Li–O_(2)and Li–CO_(2)nanobatteries showed poor cycling stability,suggesting the difficulty in the direct decomposition of the discharge product.The fluctuations of the Li–CO_(2)/O_(2)battery's electrochemistry were also shown to depend heavily on O_(2).The CuSe‐based Li–CO_(2)/O_(2)battery showed exceptional electrochemical performance.The Li^–CO_(2)/O_(2)battery offered a discharge capacity apex of 15,492 mah g^(−1) and stable cycling 60 times at 100 ma g^(−1).Our research offers crucial insight into the electrochemical behavior of Li–CO_(2)/O_(2),Li–O_(2),and Li–CO_(2)nanobatteries,which may help the creation of high‐performance Li–CO_(2)/O_(2)batteries for energy storage applications.

关键词： CuSe nanosheets electrochemical reaction in situ environmental transmission electron microscopy Li-CO_(2)battery Li-CO_(2)/O_(2)battery Li-O_(2)battery

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Tuning electronic structure of RuO_(2)by single atom Zn and oxygen vacancies to boost oxygen evolution reaction in acidic medium

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Journal of Energy Chemistry 2024年第1期88卷 94-102,I0003页

作者： Qing Qin Tiantian Wang Zijian Li Guolin Zhang Haeseong Jang liqiang Hou Yu Wang Min Gyu Kim Shangguo Liu Xien Liu College of Chemical Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Department of Chemistry City University of Hong KongHong Kong 999077China Department of Advanced materials Engineering Chung-Ang UniversityAnseong-siGyeonggi-do 17546SeoulRepublic of Korea Beamline Research Division Pohang Accelerator Laboratory(PAL)Pohang 37673Gyeongsangbuk-doRepublic of Korea

The poor stability of RuO_(2)electrocatalysts has been the primary obstacles for their practical application in polymer electrolyte membrane electrolyzers.To dramatically enhance the durability of RuO_(2)to construct activity-stability trade-off model is full of significance but challenging.Herein,a single atom Zn stabilized RuO_(2)with enriched oxygen vacancies(SA Zn-RuO_(2))is developed as a promising alternative to iridium oxide for acidic oxygen evolution reaction(OER).Compared with commercial RuO_(2),the enhanced Ru–O bond strength of SA Zn-RuO_(2)by forming Zn-O-Ru local structure motif is favorable to stabilize surface Ru,while the electrons transferred from Zn single atoms to adjacent Ru atoms protects the Ru active sites from overoxidation.Simultaneously,the optimized surrounding electronic structure of Ru sites in SA ZnRuO_(2)decreases the adsorption energies of OER intermediates to reduce the reaction barrier.As a result,the representative SA Zn-RuO_(2)exhibits a low overpotential of 210 mV to achieve 10 ma cm^(-2)and a greatly enhanced durability than commercial RuO_(2).This work provides a promising dual-engineering strategy by coupling single atom doping and vacancy for the tradeoff of high activity and catalytic stability toward acidic OER.

关键词： Electrocatalyst Acidic oxygen evolution reaction Electronic structure engineering Durability Reaction barrier

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Low-temperature-pyrolysis preparation of nanostructured graphite towards rapid potassium storage with high initial Coulombic efficiency

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Nano Research 2024年第6期17卷 5138-5147页

作者： Jingke Ren Boyu Xing Wen Luo Binyang Luo Xinfei Wu Xin Yan Wencong Feng Feiyue Wang Chaojie Cheng liqiang mai State Key Laboratory of Advanced Technology for materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Physics School of ScienceWuhan University of TechnologyWuhan 430070China

Industrially prepared artificial graphite(AG)is attractive for potassium-ion batteries(PIBs),but its rate performance is poor and the production process is energy intensive,so developing an efficient strategy to produce novel graphite with low energy consumption and high performance is economically important.Herein,a nanostructured graphite composed of multi-walled carbon nanotubes(MWCNTs)and graphite shells was prepared by one-pot method through low-temperature pyrolysis of iron-based metal-organic framework(MOF)and carbon source.The high graphitization degree of nanostructured graphite makes the initial Coulombic efficiency(ICE)exceed 80%,and the three-dimensional(3D)conductive network ensures a specific capacity of 234 mah·g^(−1)after 1000 cycles at a high current density of 500 ma·g^(−1).In addition,the typical graphite potassium storage mechanism is also demonstrated by in situ X-ray diffraction(XRD)and in situ Raman spectroscopy,and its practicality is also proved by the voltage of the full cells.This work provides a feasible way to optimize the practical production process of AG and expand its application in energy storage.

关键词： graphite anode potassium-ion batteries high graphitization degree low-temperature pyrolysis initial Coulombic efficiency

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特厚煤层底板断层破坏与顶板垮断联动效应的CFDEM模拟研究

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煤炭学报 2024年第6期49卷 2615-2629页

作者：李浩唐世斌康志勤杨栋马立强太原理工大学原位改性采矿教育部重点实验室山西太原030000 大连理工大学土木工程学院岩石破裂与失稳研究所辽宁大连116024 中国矿业大学矿业工程学院江苏徐州211116

特厚煤层采场空间大、覆岩扰动范围广,顶板垮断产生的强扰动加卸荷载易导致底板断层破坏加剧。通过数值模拟研究特厚煤层底板断层突水与顶板垮断联动效应机理规律是开展水害防治的基础,关键在于掌握加卸载下岩体渐进破坏与裂隙流耦合特... 详细信息

特厚煤层采场空间大、覆岩扰动范围广,顶板垮断产生的强扰动加卸荷载易导致底板断层破坏加剧。通过数值模拟研究特厚煤层底板断层突水与顶板垮断联动效应机理规律是开展水害防治的基础,关键在于掌握加卸载下岩体渐进破坏与裂隙流耦合特征。构建加卸载下拉、剪损伤演化方程,结合有效偏/球应力为基本变量的屈服准则与塑性势函数,得到完整岩块的塑性损伤本构;建立拉/剪、混合型加卸载过程中塑性位移与强度劣化关系,以平方拉剪应力与B-K准则为初始、完全断裂准则,形成非贯通裂隙断裂本构;提出岩块分离、压缩、剪切判据,结合实验数据建立离散块体间挤压、剪切摩擦本构与剪胀方程。基于质量/动量守恒、状态方程,并结合流体体积与浸没边界方法,形成裂隙岩体气−水二相流模拟理论。由此形成CFDEM数值计算程序,并将加卸载下塑性损伤、断裂、挤压/摩擦、流体属性分别赋予实体单元(岩块)、黏聚力单元(非贯通裂隙)、接触对(贯通裂隙)、欧拉单元(水和气)。根据宁武煤田北部矿区工程地质条件,建立特厚煤层底板断层突水与顶板垮断联动效应数值计算模型。结果表明:①CFDEM耦合程序及相应的理论模型可数值实现特厚煤层覆岩及底板断层从(准)连续体到离散体转化,以及地下水在裂隙中运移;②模拟条件下特厚煤层含断层底板的采动裂隙包络线呈w形,最深处超过55 m位于断层及其上盘,最浅处23 m位于断层下盘,而无构造底板处的破坏深度为24~36 m,已导通奥灰含水层;③特厚煤层底板普遍出现二次破坏现象。表现为无构造底板在超前工作面处破坏深度为24.0~29.3 m,但在采空区内普遍增加至31.5~36.0 m;断层及其上盘在超前工作面处裂隙总开度为0.34~0.86 m,但在采空区内迅速增加至3.6 m,形成突水优势通道。④底板断层突水与顶板垮断联动效应的根源在于覆岩高位关键岩层垮断失稳、砌体梁下沉与二次断裂,并导致底板二次破坏,突水风险加剧。

关键词：特厚煤层底板断层突水顶底板联动效应 CFDEM程序微震实验

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Water-conserving mining influencing factors identification and weight determination in northwest China

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International Journal of Coal Science & Technology 2019年第1期6卷 95-101页

作者： Limin Fan liqiang ma Yihe Yu Shuokang Wang Yujun Xu Shaanxi Institute of Geo-Environment Monitoring Xi'an 710054China School of Energy Xi'an University of Science and TechnologyXi'an 710054 Shaanxi China School of Mines China University of Mining and TechnologyXuzhou 221116JiangsuChina

Water-conserving mining is an effective way to alleviate the contradiction between fragile ecological environment and high-intensity coal mining in the arid and semi-arid region of northwest China. It needs to consider the engineering and geological conditions, hydrogeological conditions and mining methods of coal seams. From the three aspects, this paper systematically analyzes the influencing factors and establishes an identification model with multi-level structures. The model includes three primary factors (including the engineering and geological conditions, hydrogeological conditions and mining methods), nine secondary factors (including overlying strata thickness, aquiclude, mining parameters and etc.), sixteen third-tier factors (including the faults, aquiclude thickness and effective mining height and etc.) and twelve fourth-tier factors (including the fault throw exp on ent, aquiclude permeability and coal pillar sizes and etc.). On the basis, the analytic hierarchy process is used to build the judgment matrix and obtain the weight of each influencing factor. The results indicate that the overlying strata thickness, aquiclude and effective mining height are the most import a nt factors among the primary factors of engineering and geological conditions, hydrogeological conditions and mining methods, respectively. The research results could provide theoretical references for the water-conserving mining of coal resources in northwest China.

关键词： Water-conserving mining In flue ncing factors Analytic hierarchy process Judgment matrix Weight

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高校基本职能赋能乡村全面振兴策略研究

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中国农机装备 2024年第6期 100-102页

作者：马利强内蒙古工业大学人文学院呼和浩特010080 内蒙古工业大学铸牢中华民族共同体意识研究基地呼和浩特010080

高校可立足五大基本职能,助力乡村全面振兴。具体体现在强化科教支撑,明晰培养规格,切实为乡村振兴提供人才支持;深化产学研融合,对接农村实际需要,为乡村振兴输出发展动能;践行高校社会服务功能,发挥乡村振兴智库作用,为乡村振兴把脉开... 详细信息

高校可立足五大基本职能,助力乡村全面振兴。具体体现在强化科教支撑,明晰培养规格,切实为乡村振兴提供人才支持;深化产学研融合,对接农村实际需要,为乡村振兴输出发展动能;践行高校社会服务功能,发挥乡村振兴智库作用,为乡村振兴把脉开方;坚定乡村文化自信,推动乡村文化传承创新,为乡村文化振兴塑形铸魂;发挥高校国际交流合作职能,为乡村拓展国际视野,链接国际资源。具体工作中,要进一步挖掘高校潜能、发挥高校优势,实现高校和乡村全面振兴的嵌合式成长。

关键词：高校职能赋能乡村振兴策略

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河下浅埋厚煤层采动覆岩裂隙-涌水量时空演化的FDEM-CFD耦合分析

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煤炭科学技术 2024年第6期52卷 176-184页

作者：杨泽斌李浩马立强麦龙泉太原理工大学原位改性采矿教育部重点实验室山西太原030024 中国矿业大学矿业工程学院江苏徐州211116

河下浅埋厚煤层采动覆岩裂隙分布与涌水量是工作面安全生产的决定性因素之一。数值模拟是二者重要预测方法,其合理性的关键在于建立岩体破坏-裂隙流体耦合理论及相应的模拟方法。以路家村矿15404工作面为研究背景,构建拉/剪应力下非贯... 详细信息

河下浅埋厚煤层采动覆岩裂隙分布与涌水量是工作面安全生产的决定性因素之一。数值模拟是二者重要预测方法,其合理性的关键在于建立岩体破坏-裂隙流体耦合理论及相应的模拟方法。以路家村矿15404工作面为研究背景,构建拉/剪应力下非贯通裂隙开裂、贯通裂隙的法向与切向本构关系,并基于二相流质量守恒、动量守恒与状态方程,结合增强的浸没边界算法识别流-固界面,通过流体体积法实现裂隙内流体自由面的追踪和重构。在此基础上形成FDEM-CFD河下采煤覆岩裂隙与涌水量预测数值模型耦合程序,通过相邻工作面地面钻孔冲洗液消耗量观测法验证导水裂隙带发育高度,以及采用大井法理论对涌水量结果进行对比。结果表明:采动岩体破坏-裂隙流体耦合理论及相应的FDEM-CFD程序,可数值实现河下浅埋厚煤层采动覆岩裂隙形成,以及裂隙内流体运移过程。当工作面推进至80~120 m时覆岩内形成贯通地表的导水裂隙。招山河水的主要下泄路径为工作面后方8~20 m位置处的导水裂隙,其斜向采空区、倾角65°~72°。模拟所得采空区涌水量为18.78 m^(3)/h,与大井法计算结果接近。上述成果在路家村矿区得到初步应用,为进一步开展河下浅埋厚煤层防治水工程提供理论支撑。

关键词：河下浅埋煤层覆岩裂隙涌水量本构模型 FDEM-CFD耦合

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