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π-conjugated chromophore functionalized high-nuclearity titanium-oxo clusters containing structural unit of anatase for photocatalytic selective oxidation of sulfides

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Rare Metals 2024年第4期43卷 1736-1746页

作者： ling-rong liao Dong-Chun Zheng Pin-Xi Ou Qi-Xin Zhao Wei-Min Xuan Qi Zheng State Key Laboratory for Modification of Chemical Fibers and Polymer Materials&College of Materials Science and Engineering Donghua UniversityShanghai201620China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials and College of Chemistry and Chemical Engineering Donghua UniversityShanghai 201620China

N-doping has significant influence in manipulating the properties of TiO_(2),and this has stimulated the development of N-donor-functionalized titanium-oxo clusters(TOCs)as molecular models to study the structure-property ***,the structural type and photoresponsive application are still limited for such TOCs,especially regarding the high-nuclearity TOCs that contain structure unit of TiO_(2)for ***,we showed the synthesis of a series of high-nuclearity TOCs 1-3 compounds usingπ-conjugated 1,10-phenanthroline(phen)as chromophore and N-donor functional *** 1 features cocrystal structure composed of one[Ti_(26)]~(2+)and half[Ti_(22)]~(2+),which renders it as the first cocrystallized TOC containing two positively charged species and phen-functionalized TOC showing the highest nuclearity up to 37 Ti *** adjusting the synthetic conditions,the individual{Ti_(22)}and{Ti_(26)}clusters can also be isolated as Compounds 2 and 3,*** core structure of{Ti_(22)}is mainly constructed from four lacunary{Ti_(4)}derived from pentagonal{Ti(Ti)_5}unit,while{Ti_(26)}is built from four complete{Ti(Ti)_5}***,a{Ti_8O_(14)}structure unit of anatase TiO_(2)can be identified in{Ti_(26)}.Based on the unique structural features and proper photophysical and photochemical properties of Compounds 1-3,they are applied for photocatalytic *** to the presence of anatase structure unit in{Ti_(26)}and the synergistic effect from{Ti_(22)}and{Ti_(26)},the catalytic performance presents in the order of Compound 1>Compound 3>Compound *** work provides excellent models to understand the structureproperty relationship from the perspective of cocrystallization and Ti-O binding model and will further promote the application of TOCs as functional catalysts for organic transformation.

关键词： Titanium-oxo cluster Molecular model of anatase TiO_(2) High nuclearity π-conjugated chromophore Photocatalytic sulfoxidation

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Phase-matching enhanced quantum phase and amplitude estimation of a two-level system in a squeezed reservoir

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Chinese Physics B 2025年第1期34卷 257-263页

作者： Yan-ling Li Cai-Hong liao Xing Xiao School of Information Engineering Jiangxi University of Science and TechnologyGanzhou 341000China College of Physics and Electronic Information Gannan Normal UniversityGanzhou 341000China

Squeezed reservoir engineering is a powerful technique in quantum information that combines the features of squeezing and reservoir engineering to create and stabilize non-classical quantum states. In this paper, we focus on the previously neglected aspect of the impact of the squeezing phase on the precision of quantum phase and amplitude estimation based on a simple model of a two-level system(TLS) interacting with a squeezed reservoir. We derive the optimal squeezed phase-matching conditions for phase φ and amplitude θ parameters, which are crucial for enhancing the precision of quantum parameter estimation. The robustness of the squeezing-enhanced quantum Fisher information against departures from these conditions is examined, demonstrating that minor deviations from phase-matching can still result in remarkable precision of estimation. Additionally, we provide a geometric interpretation of the squeezed phase-matching conditions from the classical motion of a TLS on the Bloch sphere. Our research contributes to a deeper understanding of the operational requirements for employing squeezed reservoir engineering to advance quantum parameter estimation.

关键词： quantum parameter estimation squeezed reservoir phase-matching conditions quantum Fisher information

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刚果桉人工林营养元素生物循环研究

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水土保持学报 2004年第6期18卷 45-48,62页

作者：钟继洪李淑仪蓝佩玲廖新荣廖观荣广东省生态环境与土壤研究所广东广州510650

对刚果12号桉无性系W5人工林营养元素积累、分布和生物循环进行了研究。结果表明,刚果桉W5不同组分的营养元素含量存在差异。树叶的主要营养元素N、P、K、Ca、Mg含量均较高,树皮的Ca、K含量较高,树干主要营养元素的含量均较低;刚果桉W5... 详细信息

对刚果12号桉无性系W5人工林营养元素积累、分布和生物循环进行了研究。结果表明,刚果桉W5不同组分的营养元素含量存在差异。树叶的主要营养元素N、P、K、Ca、Mg含量均较高,树皮的Ca、K含量较高,树干主要营养元素的含量均较低;刚果桉W5人工林主要营养元素年净积累量随林龄增长而增加,2年生的主要营养元素净积累量的增幅最大;刚果桉W5人工林的N、K或Ca的年吸收量与总存留量较高,Mg次之,P最小。植后第5年,Ca的吸收与存留增加明显;刚果桉W5人工林归还林地的主要营养元素比例很低,2～5年生林木以凋落物形式归还的营养元素在12%～15%,其中N、Mg的归还率在20%以上,Ca的在8%～14%,P的在6 5%～9%,K的不足5%。与热带半落叶季雨林比较,刚果桉W5人工林的养分循环率要小得多,说明这一人工林土壤养分趋向于减少。

关键词：刚果桉人工林营养元素生物循环

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Reaction Mechanisms of the Mg2+-dependent Enzyme Phosphoserine Phosphatase from Methanococcusj annaschii（MJPSP）:A Theoretical Study

Reaction Mechanisms of the Mg2+-dependent Enzyme Phosphoseri...

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第一届全国生物物理化学会议暨生物物理化学发展战略研讨会

作者： ling Yang,rong-Zhen liao,Jian-Guo Yu~*,Ruo-Zhuang Liu College of Chemistry,Beijing Normal University,Beijing 100875,P.R.China

＜正＞The reaction mechanism of the mononuclear magnesium enzyme Phosphoserine Phosphatase（PSP） was investigated using hybrid density functional *** catalyzes the hydrolysis of phospho-L-serine （PLS）（Scheme 1）.L...

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A six-variable quasi-3D isogeometric approach for free vibration of functionally graded graphene origami-enabled auxetic metamaterial plates submerged in a fluid medium

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 157-176页

作者： Wei CHEN Zhihong TANG Yufen liao Linxin PENG College of Civil Engineering University of South China College of Civil Engineering and Architecture Guangxi University Key Laboratory of Disaster Prevention and Structural Safety of Ministry of Education Guangxi University

This paper presents, for the first time, an effective numerical approach based on the isogeometric analysis(IGA) and the six-variable quasi-three dimensional(3D)higher-order shear deformation theory(HSDT) to study the free vibration characteristics of functionally-graded(FG) graphene origami(GOri)-enabled auxetic metamaterial(GOEAM) plates submerged in a fluid medium. The plate theory incorporates the thickness stretching and the effects of transverse shear deformation without using any shear correction factors. The velocity potential function and Bernoulli's equation are used to derive the hydrodynamic pressure acting on the plate surface. Both horizontally and vertically immersed plate configurations are considered here in the form of inertia *** plates are composed of multilayer GOEAMs, with the GOri content varying through the plate's thickness in a layer-wise manner. This design results in graded auxetic *** material properties are evaluated by mixing rules and a genetic programming(GP)-assisted micromechanical model. The governing equations of motion for the FG-GOEAM plates immersed in a fluid medium are derived by Hamilton's principle. After validating the convergence and accuracy of the present model, a comprehensive parametric study is carried out to examine the effects of the GOri content, GOri distribution pattern, GOri folding degree, fluid level, immersed depth, and geometric parameter on the natural frequencies of the FG-GOEAM plates. The results show that the natural frequencies for the four GOri distribution patterns increase with the increase in the layer number when the lay number is fewer than 10, and then stabilize after the layer number reaches ***, in general, the natural frequency of the FG-GOEAM plate in a vacuum or fluid increases when the GOri content increases, while decreases when the GOri folding degree increases. Some additional findings related to the numerical results are presented in the conclusions. It is belie

关键词： free vibration functionally-graded (FG) graphene origami (GOri)-enabled auxetic metamaterial (GOEAM) plate hydrodynamic pressure isogeometric analysis (IGA) O321 quasi-three dimensional (3D) higher-order shear deformation theory (HSDT)

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The potential of Ca isotopes to trace subducted marine carbonates in deep mantle

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Journal of Oceanology and Limnology 2025年第1期43卷 29-40页

作者： Hongli ZHU Renqiang liao Long DU Zhaofeng ZHANG Key Laboratory of Ocean Observation and Forecasting Center of Deep Sea ResearchInstitute of OceanographyChinese Academy of SciencesQingdao 266071China Laboratory for Marine Geology Qingdao Marine Science and Technology CenterQingdao 266237China College of Earth Science and Engineering Shandong University of Science and TechnologyQingdao 266590China Research Center for Planetary Science College of Earth SciencesChengdu University of TechnologyChengdu 610059China

Marine carbonates,the major carrier of carbon upon the upper crust,can be subducted into the Earth’s interior along with oceanic crust,and then returned to the surface through magmatism,which constitute the deep carbon *** process plays an important role in modulating the CO_(2) concentrations in the atmosphere over geologic time,and thus the forming of the habitable ***,identifying recycled marine carbonates in the mantle is critical to well understand the global deep carbon *** is one of the major constituent cations in marine carbonates and its isotopes may be a potential tracer for recycled marine carbonates in the *** further evaluate the capability and challenges of Ca isotopes as such a geochemical tracer,we reviewed the Ca isotopic compositions in important reservoirs and the behavior of Ca isotopes during high-temperature geological processes that are related to the deep carbon cycle,including plate subduction,mantle metasomatism,mantle partial melting,magma differentiation,*** studies show that carbonate-rich marine sediments have significantly lowerδ^(44/40) Ca than the Earth mantle,and metasomatism by such recycled materials can cause lighter Ca isotopic compositions in deep mantle-derived rocks than those of the depleted mantle and mid ocean ridge ***,the Ca isotopic fractionation during partial melting of mantle peridotites is small(~0.10‰)and the Ca isotopic fractionation during plate subduction and intermediate-mafic magma evolution is *** investigations suggest that Ca isotopes have great advances in tracing such recycled materials in the ***,other processes(such as the influence by partial melts of eclogites)may induce similar effects on mantle-derived rocks as subducted marine carbonates but still remains debated,and thus further investigations are strongly needed in the future.

关键词： Ca isotope marine carbonate mantle metasomatism partial melting fractional crystallization

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Synergistic BrΦnsted/Lewis acid catalyzed atroposelective synthesis of aryl-β-naphthol

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Chinese Chemical Letters 2025年第1期36卷 293-298页

作者： Jiajun Lu Zhehui liao Tongxiang Cao Shifa Zhu Key Laboratory of Functional Molecular Engineering of Guang-dong Province School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China School of Chemistry and Chemical Engineering Zhejiang Sci-Tech UniversityHangzhou 310018China State Key Laboratory of Elemento-Organic Chemistry Nankai UniversityTianjin 300071China

Axially chiral binaphthol have achieved great success in asymmetric *** toα-binaphthol,axially chiral aryl-β-naphthol are far less ***,we report a method of asymmetric catalysis to constructβ-naphthol with up to 99%yield,95.5:4.5 enantiomeric ratio,using alkynyl esters as precursors and chiral phosphonic acid(CPA)/Lewis acid as *** steps involve oxygen transfer and de novo arene formation to set up the chiral ***,this methodology provides a versatile platform for structurally divergent synthesis of atroposelectiveβ-naphthol analogs,which are widely found in bioactive molecules and asymmetric catalysts.

关键词： Synergistic catalysis Atropisomerism Aryl-β-naphthol Enantioselectivity Tandem reaction

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A fast amplitude preserving three-parameter 3D parabolic Radon transform and its application on multiple attenuation

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Petroleum Science 2025年第1期22卷 163-177页

作者： Ji-Tao Ma Kai-Ge Zhao Zhen liao College of Geophysics China University of Petroleum (Beijing) State Key Laboratory of Petroleum Resources and Engineering China University of Petroleum (Beijing) CNPC Key Laboratory of Geophysical Prospecting China University of Petroleum (Beijing)

Seismic wavefields propagate through three-dimensional(3D) space, and their precise characterization is crucial for understanding subsurface structures. Traditional 2D algorithms, due to their limitations, are insufficient to fully represent three-dimensional wavefields. The classic 3D Radon transform algorithm assumes that the wavefield's propagation characteristics are consistent in all directions, which often does not hold true in complex underground media. To address this issue, we present an improved 3D threeparameter Radon algorithm that considers the wavefield variation with azimuth and provides a more accurate wavefield description. However, introducing new parameters to describe the azimuthal variation also poses computational challenges. The new Radon transform operator involves five variables and cannot be simply decomposed into small matrices for efficient computation; instead, it requires large matrix multiplication and inversion operations, significantly increasing the computational load. To overcome this challenge, we have integrated the curvature and frequency parameters, simplifying all frequency operators to the same, thereby significantly improving computation efficiency. Furthermore,existing transform algorithms neglect the lateral variation of seismic amplitudes, leading to discrepancies between the estimated multiples and those in the data. To enhance the amplitude preservation of the algorithm, we employ orthogonal polynomial fitting to capture the amplitude spatial variation in 3D seismic data. Combining these improvements, we propose a fast, amplitude-preserving, 3D threeparameter Radon transform algorithm. This algorithm not only enhances computational efficiency while maintaining the original wavefield characteristics, but also improves the representation of seismic data by increasing amplitude fidelity. We validated the algorithm in multiple attenuation using both synthetic and real seismic data. The results demonstrate that the new algor

关键词： Three-parameter 3D Radon Orthogonal polynomial Amplitude-preserving Multiple attenuation

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Local Search-Based Anytime Algorithms for Continuous Distributed Constraint Optimization Problems

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 288-290页

作者： Xin liao Khoi Hoang Xin Luo the College of Computer and Information Science Southwest University the Department of Computer Science and Engineering Washington University in St.Louis IEEE

Dear Editor,The distributed constraint optimization problems(DCOPs) [1]-[3]provide an efficient model for solving the cooperative problems of multi-agent systems, which has been successfully applied to model the real-world problems like the distributed scheduling [4], sensor network management [5], [6], multi-robot coordination [7], and smart grid [8]. However, DCOPs were not well suited to solve the problems with continuous variables and constraint cost in functional form, such as the target tracking sensor orientation [9], the air and ground cooperative surveillance [10], and the sensor network coverage [11].

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Social function scores and influencing factors in patients with residual depressive symptoms

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World Journal of Psychiatry 2025年第1期15卷 117-127页

作者： Zong-ling liao Xiao-Li Pu Zhi-Yi Zheng Jie Luo Department 1 of Psychiatry Gele Mountain Hospital of Chongqing Mental Health CenterChongqing 400030China Department of Psychology Chongqing Jiangjin District Psychiatric HospitalChongqing 402260China Department of Psychiatry Chongqing Third Social Welfare InstituteChongqing 400036China Women and Children’s Mental Health Center Affiliated Hospital of Chongqing Population and Family Planning Research InstituteChongqing 400020China

BACKGROUND At present,the influencing factors of social function in patients with residual depressive symptoms are still *** depressive symptoms are highly harmful,leading to low mood in patients,affecting work and interpersonal communication,increasing the risk of recurrence,and adding to the burden on *** the influencing factors of their social function is of great *** To explore the social function score and its influencing factors in patients with residual depressive *** This observational study surveyed patients with residual depressive symptoms(case group)and healthy patients undergoing physical examinations(control group).Participants were admitted between January 2022 and December *** functioning was assessed using the Sheehan Disability Scale(SDS),and scores were compared between *** influencing SDS scores in patients with residual depressive symptoms were analyzed by applying multiple linear regression while using the receiver operating characteristic curve,and these RESULTS The SDS scores of the 158 patients with depressive symptoms were 11.48±*** with the control group,the SDS scores and all items in the case group were *** scores were higher in patients with relapse,discon-tinuous medication,drug therapy alone,severe somatic symptoms,obvious residual symptoms,and anxiety scores≥*** history,medication compliance,therapy method,and residual symptoms correlated positively with SDS scores(r=0.354,0.414,0.602,and 0.456,respectively).Independent influencing factors included disease history,medication compliance,therapy method,somatic symptoms,residual symptoms,and anxiety scores(P<0.05).The areas under the curve for predicting social functional impairment using these factors were 0.713,0.559,0.684,0.729,0.668,and 0.628,respectively,with sensitivities of 79.2%,61.8%,76.8%,81.7%,63.6%,and 65.5%and specificities of 83.3%,87.5%,82.6%,83.3%,86.7%,and 92.1%,respectively.C

关键词： Depressive Residual symptoms Social function Influence factors

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