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The component-activity interrelationship of cobalt-based bifunctional electrocatalysts for overall water splitting:Strategies and performance

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Journal of Energy Chemistry 2024年第4期91卷 453-474页

作者： Mingjie sun Riyue Ge Sean Li liming Dai Yiran Li Bin Liu Wenxian Li School of Materials Science and Engineering Shanghai UniversityShanghai 200444China Institute of Textiles and Clothing The Hong Kong Polytechnic UniversityHong Kong SAR 999077China School of Materials Science and Engineering University of New South WalesSydneyNew South Wales 2052Australia UNSW Materials&Manufacturing Futures Institute UNSW SydneyNew South Wales 2052Australia School of Chemical Engineering University of New South WalesSydneyNew South Wales 2052Australia

Cobalt-based electrocatalysts take advantage of potentially harmonizable microstructure and flexible coupling effects compared to commercial noble metal-based catalytic ***,conventional water electrolysis systems based on cobalt-based monofunctional hydrogen evolution reaction(HER)or oxygen evolution reaction(OER)catalysts have certain shortcomings in terms of resource utilization and *** contrast,cobalt-based bifunctional catalysts(CBCs)have attracted much attention in recent years for overall water splitting systems because of their practicality and reduced preparation cost of *** review aims to address the latest development in CBCs for total *** main modification strategies of CBCs are systematically classified in water electrolysis to provide an overview of how to regulate their morphology and electronic ***,the catalytic performance of CBCs in total-hydrolysis is summarized according to the types of cobalt-based phosphides,sulfides and oxides,and the mechanism of strengthened electrocatalytic ability is emphasized through combining experiments and theoretical *** efforts are finally suggested to focus on exploring the dynamic conversion of reaction intermediates and building near-industrial CBCs,designing advanced CBC materials through micro-modulation,and addressing commercial applications.

关键词： Cobalt Bifunctional electrocatalysis Water splitting Modification strategies Electrocatalytic performances

Computational fluid dynamics simulation and experimental study on mixing performance of a three-dimensional circular cyclone-type microreactor

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Chinese Chemical Letters 2024年第4期35卷 382-388页

作者： Shiyu Hou Maolin sun liming Cao Chaoming Liang Jiaxin Yang Xinggui Zhou Jinxing Ye Ruihua Cheng School of Chemical Engineering East China University of Science and TechnologyShanghai 200237China School of Biomedical and Pharmaceutical Sciences Guangdong University of TechnologyGuangzhou 510006China School of Pharmacy East China University of Science and TechnologyShanghai 200237China

Microchannels enable the fast and efficient mixing of multiphase *** this study, a millimeter-scale three-dimensional(3D) circular cyclone-type microreactor was designed for the *** flow characteristics and mixing intensity were simulated by computational fluid dynamics simulations at a flow rate range of 12–96 m L/min using a water/ethyl acetate *** the 3D variable-diameter structure,the microreactor induced paired opposite vortices and abruptly changed the local pressure to achieve a stable turbulent effect within the theoretical range of laminar *** injection simulations indicated that sufficient mixing units successfully promote fluid ***-coupling experiments showed a segregation index of X_S= 0.00,039 within a residence time of 9 *** experiments on the nbutanol/succinic acid/water system showed that the 3D circular cyclone-type microreactor achieved 100%extraction efficiency(E) in 4.25 s, and the overall volume mass transfer coefficient(K_La) reached 0.05–1.5s^(-1) in 12–96 m L/*** isolated yield of the phase transfer alkylation and oxidation reactions in the 3D circular cyclone-type microreactor achieved 99% within 36 s, which was superior to the coil microreactor and batch reactor.

关键词： Microfluidics Passive microreactor CFD simulation Extraction Liquid-liquid biphase reaction

Influence of nano-mechanical evolution of Ti_(3)AlC_(2) ceramic on the arc erosion resistance of Ag-based composite electrical contact material

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Journal of Advanced Ceramics 2024年第2期13卷 176-188页

作者： Xuelian Wu Chengzhe Wu Xinpeng Wei Wanjie sun Chengjian Ma Yundeng Zhang Gege Li liming Chen Dandan Wang Peigen Zhang Zhengming sun Jianxiang Ding School of Materials Science and Engineering Anhui University of TechnologyMa’anshan 243032China Analytical and Testing Center Yancheng Institute of TechnologyYancheng 224051China School of Materials Science and Engineering Changzhou UniversityChangzhou 213164China Jiangsu Key Laboratory of Advanced Metallic Materials School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China

Al-containing MAX phase ceramic has demonstrated great potential in the field of high-performance low-voltage electrical contact *** the anti-arc erosion mechanism of the MAX phase is crucial for further improving performance,but it is not *** this study,Ag/Ti_(3)AlC_(2) electrical contact material was synthesized by powder metallurgy and examined by nanoindentation techniques such as constant loading rate indentation,creep testing,and continuous stiffness *** results indicated a gradual degradation in the nano-mechanical properties of the Ti_(3)AlC_(2) reinforcing phase with increasing arc erosion times,although the rate of this degradation appeared to decelerate over arc erosion ***,continuous stiffness measurements highlighted the uneven mechanical properties within Ti_(3)AlC_(2),attributing this heterogeneity to the phase’s *** the early(1-100 times)and intermediate(100-1000 times)stages of arc erosion,the decline in the nano-mechanical properties of Ti_(3)AlC_(2) was primarily ascribed to the decomposition of Ti_(3)AlC_(2) and limited surface *** the later stage of arc erosion(1000-6200 times),the inner region of Ti_(3)AlC_(2) also sustained arc damage,but a thick oxide layer formed on its surface,enhancing the mechanical properties and overall arc erosion resistance of the Ag/Ti_(3)AlC_(2).

关键词： MAX phase nano-mechanical properties decomposition surface oxidation anti-arc erosion mechanism

An Opposition-Based Learning-Based Search Mechanism for Flying Foxes Optimization Algorithm

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Computers, Materials & Continua 2024年第6期79卷 5201-5223页

作者： Chen Zhang liming Liu Yufei Yang Yu sun Jiaxu Ning Yu Zhang Changsheng Zhang Ying Guo Software College Northeastern UniversityShenyang110169China School of Information Science and Engineering Shenyang Ligong UniversityShenyang110159China China Telecom Digital Intelligence Technology Co. Ltd.Beijing100035China College of Computer Science and Engineering Ningxia Institute of Science and TechnologyShizuishan753000China

The flying foxes optimization(FFO)algorithm,as a newly introduced metaheuristic algorithm,is inspired by the survival tactics of flying foxes in heat wave *** preferentially selects the best-performing *** tendency will cause the newly generated solution to remain closely tied to the candidate optimal in the search *** address this issue,the paper introduces an opposition-based learning-based search mechanism for FFO algorithm(IFFO).Firstly,this paper introduces niching techniques to improve the survival list method,which not only focuses on the adaptability of individuals but also considers the population’s crowding degree to enhance the global search ***,an initialization strategy of opposition-based learning is used to perturb the initial population and elevate its ***,to verify the superiority of the improved search mechanism,IFFO,FFO and the cutting-edge metaheuristic algorithms are compared and analyzed using a set of test *** results prove that compared with other algorithms,IFFO is characterized by its rapid convergence,precise results and robust stability.

关键词： Flying foxes optimization(FFO)algorithm opposition-based learning niching techniques swarm intelligence metaheuristics evolutionary algorithms

A sequential continuous flow synthesis and purification process of calcium dibutyryladenosine cyclophosphate

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Chinese Chemical Letters 2024年第2期35卷 402-406页

作者： liming Cao Maolin sun Chaoming Liang Lei Yang Yueyue Ma Ruihua Cheng Yanxiong Ke Wei Yu Jinxing Ye Engineering Research Center of Pharmaceutical Process Chemistry Ministry of EducationSchool of PharmacyEast China University of Science and TechnologyShanghai 200237China School of Biomedical and Pharmaceutical Sciences Guangdong University of TechnologyGuangzhou 510006China Shanghai No.1 Biochemical& Pharmaceutical Co. Ltd.Shanghai 200080China

Calcium dibutyryladenosine cyclophosphate is a widely used cardiovascular *** traditional batch synthesis process suffers from long reaction times,tedious operations,and unstable ***,a sequential continuous flow synthesis combined with a multistage in-line purification process of calcium dibutyryladenosine cyclophosphate was *** acylation reaction was completed in a continuous coil reactor at 160℃ in 20 *** the high toxic solvent pyridine was replaced by ***,the multistage in-line purification process was integrated into the homemade 3D circular cyclone-type micromixer *** with the membrane phase separators,the residence time of the purification step was 30 *** isolated yield of this sequential continuous process was 92%with 99%purity.

关键词： Flow chemistry Calcium dibutyryladenosine cyclophosphate Continuous flow synthesis In-line purification 3D circular cyclone-type micromixer chip

Engineering Cu_(2)O/Cu/N-C interface to induce directional migration of charge for driving photocatalytic homo-coupling of terminal alkynes

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Nano Research 2024年第8期17卷 6895-6902页

作者： Xiaoqin Yan Tianyi Xu Wenwen Zhan Yang Yang Yang Yu Jianjian Yi Xiaoxiao He Lei Yang Jianwei Zhao liming.sun Xiguang Han Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials Department of ChemistrySchool of Chemistry&Materials ScienceJiangsu Normal UniversityXuzhou 221116China State Key Laboratory of Precision Spectroscopy East China Normal UniversityShanghai 200241China College of Environmental Science and Engineering Yangzhou UniversityYangzhou 225009China Shenzhen HUASUAN Technology Co. LtdShenzhen 518055China

The efficient utilization of visible light catalysts for organic reactions necessitates not only the effective separation of photogenerated electrons and holes to participate in the reaction,but also their ability to form key intermediates with reactant *** present study successfully synthesized a crusiform-like mesoporous structure of nitrogen-doped carbon-coated Cu_(2)O/Cu(Cu_(2)O/Cu/N-C)with a Cu_(2)O/dual electron acceptor interface using etched HKUST-1 as the precursor.A series of theoretical and experimental studies have demonstrated that the Cu_(2)O/Cu/N-C interface in the photocatalytic homo-coupling of terminal alkynes not only effectively enhances the separation of photogenerated electron−hole pairs,but also facilitates the formation of the key intermediate[Cu_(2)O/Cu/N-C]-phenylacetylide and promotes the rearrangement of its internal *** a result,the homo-coupling reaction can be effectively *** primary reason for the functional role of Cu_(2)O/Cu/N-C interface lies in the downward bending of energy band from Cu_(2)O to N-doped C layers,induced by the different work functions of Cu_(2)O,Cu and N-doped C ***,Cu_(2)O/Cu/N-C photocatalysts demonstrate exceptional photocatalytic activity in the homo-coupling reaction of terminal alkynes under blue-light irradiation and air *** present study presents a novel research methodology for the development of highly efficient visible light catalysts to facilitate organic reactions in future applications.

关键词： photocatalysis homo-coupling of terminal alkynes directional migration of charges heterojunction interface Cu_(2)O carbon coated

Hydrogels for ameliorating osteoarthritis:Mechanical modulation,anti-inflammation,and regeneration

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BMEMat(BioMedical Engineering Materials) 2024年第2期2卷 34-60页

作者： Xuwei Jiang Yuxiang sun Yuanning Lyu Heemin Kang Jianyang Zhao Kunyu Zhang liming Bian School of Biomedical Sciences and Engineering South China University of TechnologyGuangzhou International CampusGuangzhouChina National Engineering Research Center for Tissue Restoration and Reconstruction South China University of TechnologyGuangzhouChina Guangdong Provincial Key Laboratory of Biomedical Engineering South China University of TechnologyGuangzhouChina Key Laboratory of Biomedical Materials and Engineering of the Ministry of Education South China University of TechnologyGuangzhouChina Department of Materials Science and Engineering Korea UniversitySeoulRepublic of Korea

Osteoarthritis(OA)is a chronic and degenerative disease with limited clinical options for effective ***,significant endeavors have been explored to reveal its pathogenesis and develop treatments against ***,designed with a striking resemblance to the extracellular matrix,offer a biomimetic interaction with biological tissues,presenting a promising avenue for OA *** a result,biocompatible hydrogels have been erected incorporating on-demand bioactivities to optimize the intra-articular microenvironment,thereby alleviating OA symptoms and fostering the eventual regeneration of articular *** review highlights the collaborative objectives underlying the establishment of this tissue microenvironment,encompassing mechanical modulation,anti-inflammation,and tissue regen***,we consolidate recent advances in hydrogel-based biomaterials,serving as the tissue engineering scaffolds to replicate the lubrication properties of natural joints or the bioactive agent-loaded vehicles to combat localized ***,hydrogels function as cell scaffolds to facilitate the maintenance of cellular homeostasis and contribute to the advancement of cartilage ***,this review outlines the prospective directions for hydrogel-mediated OA therapies.

关键词： cargo-delivery cellular induction hydrogels lubrication osteoarthritis

Efficient desorption and reuse of collector from the flotation concentrate:A case study of scheelite

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International Journal of Minerals,Metallurgy and Materials 2024年第11期31卷 2435-2444页

作者： liming Tao Jianjun Wang Dejin Liao Wenkai Jia Zihan Zhao Wenfang Che Zhongxu Qi Wei sun Zhiyong Gao School of Minerals Processing and Bioengineering Key Laboratory of Hunan Province for Clean and Efficient Utilization of Strategic Calcium-containing Mineral ResourcesEngineering Research Center of Ministry of Education for Carbon Emission Reduction in Metal Resource Exploitation and UtilizationCentral South UniversityChangsha 410083China State Key Laboratory of Mineral Processing BGRIMM Technology GroupBeijing 102628China Mining Technology Research Center China Tungsten and Hightech Materials Co.Ltd.Chenzhou 423000China Luoyang Luanchuan molybdenum Group Co. Ltd.Luoyang 471500China Changsha Institute of Mining Research Co. Ltd.Changsha 410012China

Flotation is the most common method to obtain concentrate through the selective adsorption of collectors on target minerals to make them hydrophobic and *** the hydrometallurgy of concentrate,collectors adsorbed on concentrate can damage ion-exchange resin and increase the chemical oxygen demand(COD)value of *** this work,we proposed a new scheme,i.e.,desorbing the collectors from concentrate in ore dressing plant and reusing them in flotation *** nitrate and benzohydroxamic acid(Pb-BHA)complex is a common collector in scheelite *** this study,different physical(stirring or ultrasonic waves)and chemical(strong acid or alkali environment)methods for facilitating the desorption of Pb-BHA collector from scheelite concentrate were ***-mineral desorption tests showed that under the condition of pulp pH 13 and ultrasonic treatment for 15 min,the highest desorption rates of Pb and BHA from the scheelite concentrate were 90.48%and 63.75%,***-of-mine ore flotation tests revealed that the reuse of desorbed Pb and BHA reduced the collector dosage by 30%for BHA and 25%for *** strong alkali environment broke the chemical bonds between Pb and *** cavitation effect of ultrasonic waves effectively reduced the interaction intensity between Pb-BHA collector and scheelite *** method combining ultrasonic waves and strong alkali environment can effectively desorb the collectors from concentrate and provide“clean”scheelite concentrate for metallurgic plants;the reuse of desorbed collector in flotation flowsheet can reduce reagent cost for ore dressing plants.

关键词： scheelite concentrate collector desorption reuse flotation

Multiscale confinement nitridation in molybdenum carbide for efficient hydrogen production

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Journal of Energy Chemistry 2024年第7期94卷 61-69页

作者： liming Dai Chenchen Fang Xiaoyuan Zhang Xuefeng Xu Xuanxuan Chen Xinyue Zong Xueming Hu Wenyao Zhang Liang Xue Pan Xiong Yongsheng Fu Jingwen sun Junwu Zhu Key Laboratory for Soft Chemistry and Functional Materials Ministry of EducationNanjing University of Science and TechnologyNanjing 210094JiangsuChina

The molybdenum carbide(Mo_(2)C)has been regarded as one of the most cost-efficient and stable electrocatalyst for the hydrogen evolution reaction(HER)by the virtue of its Pt-like electronic ***,the inherent limitation of high density of empty valence band significantly reduces its catalytic reactivity by reason of strong hydrogen desorption ***,we propose a multiscale confinement synthesis method to design the nitrogen-rich Mo_(2)C for modulating the band structure via decomposing the pre-coordination bonded polymer in a pressure-tight tube sealing ***-bonded c/N-Mo in the coordination precursor constructs a micro-confinement space,enabling the homogeneous nitrogenization in-situ happened during the formation of Mo_(2)***,the evolved gases from the precursor decomposition in tube sealing system establish a macro-confinement environment,preventing the lattice N escape and further endowing a continuous *** the multiscale confinement effects,the nitrogen-rich Mo2C displays as high as 25%N-Mo concentration in carbide lattice,leading to a satisfactory band ***,the constructed nitrogen-rich Mo_(2)C reveals an adorable catalytic activity for HER in both alkaline and acid *** is anticipated that the multiscale confinement synthesis strategy presents guideline for the rational design of electrocatalysts and beyond.

关键词： Molybdenum carbide Hydrogen evolution reaction Multiscale confinement synthesis Valence band modulation Nitrogen doping