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Organic Chemistry Frontiers 2022年第2期9卷 320-328页

作者： Zeyu Liu Zhen Liu Rui Gao Jie Su Yi Qiu liangbing gan Beijing National Laboratory for Molecular Sciences Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China

Open-cage fullerenes with carbonyl functional groups on the rim of the orifice are ideal precursors for the extension of fullerene π-systems.Unlike isopropylphenylaniline,which reacts selectively with the lactone moiety on the rim of the orifice,phenylenediamine reacts with the adjacent carbonyl and imino groups on a pentagon to form a quinoxaline moiety.Further dehydroxylative aromatization connects the fullerene cage π-system with the quinoxaline π-system.Both the NMR and UV-Vis spectra revealed an evident effect after the extension of the fullerene cage π-system.

关键词： moiety carbonyl react

Synthesis of Open-Cage Fullerene Derivatives Containing Multiple Hydroxyl and Amino Groups on the Rim of the Orifice

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Chinese Journal of Chemistry 2023年第12期41卷 1471-1477页

作者： Xueli Liu Rui Gao Zhen Liu Jialin Ming Yi Qiu Jie Su liangbing gan Department of Chemistry College of Chemistry and Chemical Engineering Inner Mongolia University Hohhot Inner Mongolia 010021 China Beijing National Laboratory for Molecular Sciences Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education College of Chemistry and Molecular Engineering Peking University Beijing 100871 China

Most of the known open-cage fullerene derivatives contain carbonyl and other relatively inert groups on the rim of the orifice.It is difficult to rationally design further reactions and attach other functional groups on to these open-cage derivatives.In the present work,two molecules of difunctional 1,4-benzenediamine have been incorporated into the rim of an open-cage C60 derivative through one amino group leaving the other amino group free for further functionalization.The difunctional 4-aminophenol reacted analogously to form an open-cage derivative with a free OH group each on the two phenyl rings.The amino and hydroxyl groups on the phenyl ring above the rim of the orifice showed similar reactivity as aniline and phenol.One of the carbonyl groups on the rim of the orifice could be selectively reduced by NaBH4 and P(OEt)3.The reduction reactions were reversible and the reduced products could be readily converted back to the carbonyl precursor.Thus,this redox process acts as a tool to fine tune the size of the orifice for host-guest studies.

关键词： Fullerene Open-cage Molecular container Carbonyl reduction Chan-Evans-Lam coupling

The Chemistry of Fullerene-Mixed Peroxides

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Chinese Journal of Chemistry 2018年第11期36卷 991-994页

作者： liangbing gan College of Chemistry and Molecular Engineering Peking University Bei- jing 200871 China

Peroxy radicals such as Bu t OO · add to fullerenes efficiently to form isomerically pure multiadducts, for example, C 60 (OOBu t ) 6 . The fullerene‐ mixed peroxides exhibit rich chemical reactivity. Further transformation of the peroxy groups has resulted in fullereneols, open‐cage fullerenes, aza‐ and oxafullerenes and/or fulleroids. Practical applications such as photoinitiator remain to be explored for these fullerene‐mixed peroxides.

关键词： peroxide fullerene heterofullerene open‐cage radical aromaticity

Aniline Induced Domino Ring Contraction Process on the Rim of an Open-Cage Fullerene with Carbonyl, Imino and lactone Moieties

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Chinese Journal of Chemistry 2014年第8期32卷 819-821页

作者： Shuming Liu liangbing gan Beijing National Laboratory for Molecular Sciences CAS Key Laboratory for Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100080China Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryShanghai 200032China Key Laboratory of Small Organic Molecule of Handan College of ChemistryChemical Engineering and MaterialsHandan CollegeHandanHebei 056005China

Functional groups on the rim of open-cage fullerenes usually exhibit different reactivity from those in classical organic molecules due to the unique spherical structure of fullerenes.The present work shows a sequence of lactone opening,imino hydrolysis,aminal formation and imine formation processes during the reaction of aniline with the open-cage compound 1 with functional groups including lactone on the rim of the orifice.Single crystal X-ray diffraction analysis confirmed the structure of the product.

关键词： fullerene open-cage fullerene ring contraction molecular container

A　Study　on　Yttrium　Containing　Fullerene　YC＿（82）　Using　Laser　Ablation　Mass　Spectroscopy

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Chinese Journal of Lasers 1996年第6期B5卷 556-560页

作者： DONG Guoxuan WANG Shiliang DAI Songtao LI Chunming CHEN Dieyan (Laser Single Atom Detection Laboratory, Department of Modern Applied Physics,Theghua University, Beijing 100084,China)LUO Chuping TAN Haisong gan liangbing HUANG Chunhui (State Key Labo Tsinghua Univ Beijing China

ＡＳｔｕｄｙｏｎＹｔｔｒｉｕｍＣｏｎｔａｉｎｉｎｇＦｕｌｌｅｒｅｎｅＹＣ＿（８２）ＵｓｉｎｇＬａｓｅｒＡｂｌａｔｉｏｎＭａｓｓＳｐｅｃｔｒｏｓｃｏｐｙ￥ＤＯＮＧＧｕｏｘｕａｎ；ＷＡＮＧＳｈｉｌｉａｎｇ；ＤＡＩＳｏｎｇ... 详细信息

ＡＳｔｕｄｙｏｎＹｔｔｒｉｕｍＣｏｎｔａｉｎｉｎｇＦｕｌｌｅｒｅｎｅＹＣ＿（８２）ＵｓｉｎｇＬａｓｅｒＡｂｌａｔｉｏｎＭａｓｓＳｐｅｃｔｒｏｓｃｏｐｙ￥ＤＯＮＧＧｕｏｘｕａｎ；ＷＡＮＧＳｈｉｌｉａｎｇ；ＤＡＩＳｏｎｇｔａｏ；ＬＩＣｈｕｎｍｉｎｇ；ＣＨ...

关键词： laser ablation time-of-flight mass sperereopy YC82 Yttrium Containing fullerenes

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蔓花生PEPC基因家族的生物信息学分析

热带亚热带植物学报 2018年第2期26卷 107-115页

作者：涂嘉琦甘璐冯兰兰袁良兵黎茵广东省热带亚热带植物资源重点实验室中山大学生命科学学院广州510275

为了解花生中磷酸烯醇式丙酮酸羧化酶(phosphoenolpyruvate carboxylase,PEPC)的功能,对二倍体祖先种野生蔓花生(Arachis duranensis)基因组数据库进行分析,发现存在9个Ad PEPC基因家族成员,这些基因的序列长度为3 584~12 956 bp,开放... 详细信息

为了解花生中磷酸烯醇式丙酮酸羧化酶(phosphoenolpyruvate carboxylase,PEPC)的功能,对二倍体祖先种野生蔓花生(Arachis duranensis)基因组数据库进行分析,发现存在9个Ad PEPC基因家族成员,这些基因的序列长度为3 584~12 956 bp,开放阅读框(ORF)长度为702~3 168 bp,分布在3、5、7、8、9、10号染色体上。蔓花生Ad PEPC家族蛋白的氨基酸序列中均含有HCO3-结合位点和PEP结合位点等保守结构域,根据序列特征可分为植物型、细菌型和序列较短的PEPC等3类,同类蛋白序列的同源性较高,基因结构中的内含子与外显子的数目也较相似。基因表达分析表明,多数成员在花或茎中的表达量较高,Ad PEPC1;2和Ad PEPC4;2在茎中的表达量最高,其他家族成员尤其是Ad PEPC2、Ad PEPC1;5和Ad PEPC1;3在花中的表达量明显高于其他组织,Ad PEPC1;5基因在叶中不表达。Ad PEPC3在根、茎、叶和花中均不表达,推测该基因为假基因。这为深入研究Ad PEPC家族基因的功能奠定了基础。

关键词：花生磷酸烯醇式丙酮酸羧化酶基因家族生物信息