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Morphology of Branch Chain in Copolymer Surfactants on Interface

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Chinese Chemical Letters 1996年第10期7卷 948-950页

作者： Jian XU liang he shi Mei Ling YE(Polymer Physics Laboratory,Institute of Chemistry, Academia Sinica, Beijing 100080) ACAD SINICA INST CHEMPOLYMER PHYS LABBEIJING 100080PEOPLES R CHINA

The conformation of amphiphilic branch chain in acrylamide-poly(oxyethylene alkyl ether) acrylate copolymers on interface was investigated by static laser light scattering amid X-ray photoelectron spectroscopy. The re...

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XPS Study on Water-Soluble Polymer Surfactant Film

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Chinese Chemical Letters 1997年第12期8卷 0-0页

作者： Jian XU liang he shi Mei Ling YE (Polymer Physics Laboratory, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080) Chinese Acad Sci Inst Chem Polymer Phys Lab Beijing 100080 Peoples R China

By means of changing the detection angle, the molecular conformation of a new type of polymer surfactant, acrylamide-poly(oxyethykene alkyl ether)acrylate-anionic monomer random copolymer, was studied by x-ray photoel... 详细信息

关键词： XPS Study on Water-Soluble Polymer Surfactant Film

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Construction of Phosphorus-Functionalized Multichannel Carbon Interlayers for Dendrite-Free Metallic Zn Anodes

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Energy & Environmental Materials 2024年第05期7卷 99-107页

作者： liang he Qingyin Zhang he Li shiping Liu Ting Cheng Ruoxuan Zhang Yujia Wang Peng Zhang Zhiqiang shi Tianjin Key Laboratory of Advanced Fibers and Energy Storage School of Materials Science and Engineering Tiangong University Cangzhou Institute of Tiangong University School of Chemical Engineering and Technology Tiangong University Tianjin Lishen Battery Joint-Stock CO. LTD

Zn metal anodes are usually subject to grave dendrite growth during platting/stripping, which dramatically curtails the lifespan of aqueous Zn-ion batteries and capacitors. To address above problems, in our work, a novel phosphorus-functionalized multichannel carbon interlayer was designed and covered on Zn anodes. The results demonstrated that the multichannel structure combined with the three-dimensional meshy skeleton can provide more sufficient space for Zn deposition, thereby effectively inhibiting the growth of zinc dendrites. Meanwhile, theoretical calculations also confirmed that the P–C and P=O functional groups from phosphorus-functionalized multichannel carbon interlayer have the decisive influence in reducing the zinc nucleation potential and depositing uniformly zinc. Concretely, the symmetrical battery assembled with phosphorus-functionalized multichannel carbon interlayer-covered Zn anodes possessed a long lifetime of 3300 h at2 mA cm-2with 1 mAh cm-2. Furthermore, the full cell with activated carbon cathodes exhibited a high specific capacity of 80.5 mAh g-1and outstanding cycling stability without capacity decay after 15 000 cycles at a high current density of 5 A g-1. The superior electrochemical performance exceeded that of most reported papers. Consequently, our synthesized zincophilic interlayer with the unique structure has superior prospects for application in stabilizing zinc anodes and prolonging the lifespan of batteries.

关键词： aqueous Zn-ion supercapacitors multichannel carbon fiber phosphorus functionalized Zn dendrite Zn metal anode

Effects of plug tray cell size on the growth of Atractylodes Chinensis (DC) Koidz seedlings

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International Journal of Agricultural and Biological Engineering 2024年第4期17卷 45-52页

作者： Kaixuan shi Juwen liang Fang Ji Dongxian he Key Laboratory of Agricultural Engineering in Structure and Environment of MARA College of Water Resources&Civil EngineeringChina Agricultural UniversityBeijing 100083China

Atractylodes Chinensis(DC)Koidz is a perennial herb often used as a prescription medicine for influenza,to invigorate the spleen and remove *** quality of the herb is determined by the quality of the *** traditional *** seedling production technique has nonuniform seedlings and low *** plug seedling technique was used to produce *** *** study was conducted to determine the growth characteristics of *** seedlings according to the cell size of plug trays and number of days after *** height,stem diameter,rhizome diameter,number of leaves,leaf area,and shoot dry and fresh weight of *** seedlings were significantly higher in the P32-D treatment than in the P72,P50,and P32 treatments,but not significantly different from the P28-D treatment 60 d after *** P28-D treatment resulted in a considerable drop in rhizome fresh weight and healthy seedling index,both of which are key indicators for assessing seedling *** the differences in Pn among treatments were not significantly different,Tr was considerably greater in *** seedlings treated with P32-D and P28-D than in the other three *** P32-D and P28-D treatments had considerably greater potential maximum photochemical efficiency of PSII,quantum yield of photosystem II,photochemical quenching and electron transport rate than the other three *** vitality of *** seedlings was significantly stronger in the P32-D treatment than in the other four treatments,and it was 1.9 times higher than in the P28-D *** soluble protein,soluble sugar,and starch contents of *** seedlings were highest in the P32-D treatment,but the differences among treatments were not ***,EUE,PY and EY were significantly higher in the P32-D treatment than in the other four treatments,being 1.3,1.3,1.4 and 1.4 times higher than in P28-D,*** the other hand,as for the change in the gro

关键词： Atractylodes Chinensis(DC)Koidz plug seedling plug tray cell size

Adhesive Contact of Elastic Solids with Self-Affine Fractal Rough Surfaces

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Acta Mechanica Solida Sinica 2024年第2期37卷 265-270页

作者： Xuan-Ming liang shi-Wen Chen Si-he Wang Zhen-Yuan Gong Jun Feng Gang-Feng Wang Department of Engineering Mechanics SVL and MMMLXi’an Jiaotong UniversityXi’an710049China OPPO Mobile Telecommunications Corporation Ltd. Dongguan523860China

The elastic adhesive contact of self-affine fractal rough surfaces against a rigid flat is simulated using the finite element method. An array of nonlinear springs, of which the force-separation law obeys the Lennard–Jones potential, is introduced to account for the interfacial adhesion. For fractal rough surfaces, the interfacial interaction is generally attractive for large mean gaps, but turns repulsive as the gap continuously shrinks. The interfacial interactions at the turning point corresponding to the spontaneous contact are shown for various surfaces. For relatively smooth surfaces, the probability density distributions of repulsion and attraction are nearly symmetric. However, for rougher surfaces, the simulation results suggest a uniform distribution for attraction but a monotonously decreasing distribution with a long tail for repulsion. The pull-off force rises with increasing ratio of the work of adhesion to the equilibrium distance, whereas decreases for solids with a higher elastic modulus and a larger surface roughness. The current study will be helpful for understanding the adhesion of various types of rough solids.

关键词： Fractal rough surfaces Adhesion Contact mechanics Lennard-Jones potential

Research on Credit Default Swaps Pricing Considering Moral Hazard Incentive under Reduce-Form Model

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Journal of Systems Science and Systems Engineering 2024年第3期33卷 311-329页

作者： liang Wu Kangjie he Zhe Guo School of Mathematical Science Henan Institute of Science and TechnologyXinxiang453003China Public Front Office Department Industrial and Commercial Bank of ChinaZhengzhou450000China

Equilibrium pricing of credit default swaps(CDS)promotes efficient identification of credit risk in the market,which in turn leads to efficient allocation of ***,even when CDS have been priced in equilibrium,i.e.,when premiums are equal to anticipated payments,the moral hazard incentives of CDS buyers increase with CDS ***,it becomes an interesting research direction to study the impact of moral hazard incentives on the trading mechanism or pricing of derivatives(CDS).Most of the existing literature on the impact of moral hazard incentives in CDS pricing on derivatives trading mechanisms takes a macro perspective and focuses on the agreement risk *** literature exploring the analysis of the impact of moral hazard on the probability of agreement default from a micro perspective is not yet *** this in mind,this paper focuses on the mechanisms by which“fraud”,an extreme manifestation of micro-moral hazard incentives,affects the probability of *** paper introduces for the first time the concept of“claiming fraud”by credit protection buyers,which is different from the macro perspective of moral hazard incentives,and thus defines a specific extreme form of moral hazard ***,to address the intrinsic feature of the lack of economic explanatory power of the reduce-form model,this paper introduces a moral hazard incentive factor into the reduce-form model,and proposes a moral hazard state variable as a function of the asset value of the reference entity,which gives the reduce-form model strong economic explanatory power,and the default predictability is reduced by the description of the reduce-form *** terms of the object of study,this paper considers the issue of moral hazard incentives in the presence of claiming fraud in two reference entities to further explore the impact of moral hazard incentives on default protection at the micro level in terms of cyclic ***,based on the

关键词： Financial engineering moral hazard incentive claiming fraud reduce-form model probability of default calculation CDS pricing

The chlorine evolution reaction promoted by organocatalysts with amide functional groups

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Science China Chemistry 2024年第3期67卷 749-750页

作者： Lan Zhao liang-Nian he State Key Laboratory and Institute of Elemento-Organic Chemistry College of ChemistryNankai UniversityTianjin 300071China

Since the nineteenth century, the chlor-alkali process entails the electrochemical oxidation of sodium chloride solutions to Cl_(2) by the chlorine evolution reaction(CER) and the simultaneous production of sodium hyd... 详细信息

关键词： chlorine hydroxide promoted

High-Order Two-Scale Asymptotic Paradigm for the Elastodynamic Homogenization of Periodic Composites

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Acta Mechanica Solida Sinica 2024年第1期37卷 124-138页

作者： Wei-Zhi Luo Mu he liang Xia Qi-Chang he State Key Laboratory of Intelligent Manufacturing Equipment and Technology Huazhong University of Science and TechnologyWuhan 430074China Laboratoire Modélisation et Simulation Multi-Echelle MSME UMR 8208 CNRSUniversite Gustave Eiffel77454 Marne-la-ValléeFrance

The classical two-scale asymptotic paradigm provides macroscopic and microscopic analyses for the elastodynamic homogenization of periodic composites based on the spatial or/and temporal variable,which offers an approximate framework for the asymptotic homogenization analysis of the motion ***,in this framework,the growing complexity of the homogenization formulation gradually becomes an obstacle as the asymptotic order *** such a context,a compact,fast,and accurate asymptotic paradigm is *** work reviews the high-order spatial two-scale asymptotic paradigm with the effective displacement field representation and optimizes the implementation by symmetrizing the tensor to be ***,the modified implementation gets rid of the excessive memory consumption required for computing the high-order tensor,which is demonstrated by representative one-and two-dimensional *** numerical results show that(1)the contrast of the material parameters between media in composites directly affects the convergence rate of the asymptotic results for the homogenization of periodic composites,(2)the convergence error of the asymptotic results mainly comes from the truncation error of the modified asymptotic homogenized motion equation,and(3)the excessive norm of the normalized wavenumber vector in the two-dimensional inclusion case may lead to a non-convergence of the asymptotic results.

关键词： Composites Homogenization Asymptotic analysis Dynamics Dispersion

Processing of a low-costγ-γ'NiPtAl coating with improved oxidation resistance

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Rare Metals 2024年第6期43卷 2832-2841页

作者： Yan Jiang liang-liang Wei Jian he Hong-Bo Guo School of Materials Science and Engineering Beihang UniversityBeijing 100191China Key Laboratory of High-Temperature Structural Materials and Protective Coatings Ministry of Industry and Information TechnologyBeihang UniversityBeijing 100191China

A novelγ-γ'(Ni solid solution—Ni_(3)Al)NiPtAl coating was produced on advanced single-crystal(SC)superalloy N5 by electroplating of a thin Pt coating with~3μm in thickness followed by heat treatment at 1000℃in *** comparison,a traditionalγ-γ'NiPtAl coating was also produced by electroplating of a thick Pt coating with~6μm in thickness followed by heat treatment at 1100℃in *** novel coating has a mass gain of~0.5 mg·cm^(-2)after 100 h 1-h cyclic oxidation at 1150℃,showing better oxidation resistance than the traditional *** oxide scale mostly consisting ofα-Al_(2)O_(3)grew on the novel coating because the element Cr from the SC alloy substrate contributes to the formation ofα-Al_(2)O_(3).Pt content in the novel coating has significant effect on the oxidation *** optimized Pt content in the coating is about 16 at%,which is helpful to reduce the diffusion of harmful elements from the substrate into the coating but also to reduce the cost of the coating.

关键词： γ-γ'NiPtAl coating Platinum Oxidation Al_(2)O_(3) Superalloy