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光驱动Rh/InGaN_(1-x)O_(x)纳米组装体甲烷干重整制合成气

Science Bulletin 2024年第10期69卷 1400-1409页

作者：李亦昕李景林俞天奇邱亮 Syed M.Najib Hasan 姚琳潘虎 Shamsul Arafin Sharif Md.Sadaf 朱磊周宝文 Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic FuelSchool of Mechanical EngineeringShanghai Jiao Tong UniversityShanghai 200240China China-UK Low Carbon College Shanghai Jiao Tong UniversityShanghai 201306China Centre Energie Matériaux et TélécommunicationsInstitut National de la Recherche Scientifique(INRS)-Universitédu QuébecVarennes J3X 1E4Canada Department of Electrical and Computer Engineering The Ohio State UniversityColumbusOH43210USA

Light-driven dry reforming of methane toward syngas presents a proper solution for alleviating climate change and for the sustainable supply of transportation fuels and ***,Rh/InGaN_(1-x)O_(x) nanowires supported by silicon wafer are explored as an ideal platform for loading Rh nanoparticles,thus assembling a new nanoarchitecture for this grand *** combination with the remarkable photothermal synergy,the O atoms in Rh/InGaN_(1-x)O_(x) can significantly lower the apparent activation energy of dry reforming of methane from 2.96 eV downward to 1.70 *** as-designed Rh/InGaN_(1-x)O_(x) NWs nanoarchitecture thus demonstrates a measurable syngas evolution rate of 180.9 mmol g_(cat)^(-1) h^(-1) with a marked selectivity of 96.3% under concentrated light illumination of 6 W cm^(-2).What is more,a high turnover number(TON)of 4182 mol syngas per mole Rh has been realized after six reuse cycles without obvious activity *** correlative 18O isotope labeling experiments,in-situ irradiated X-ray photoelectron spectroscopy(ISI-XPS)and in-situ diffuse reflectance Fourier transform infrared spectroscopy characterizations,as well as density functional theory calculations reveal that under light illumination,Rh/InGaN_(1-x)O_(x) NWs facilitate releasing^(*)CH_(3) and H^(+)from CH_(4) by holes,followed by H_(2) evolution from H^(+)reduction with ***,the O atoms in Rh/InGaN_(1-x)O_(x) can directly participate in CO generation by reacting with the ^(*)C species from CH_(4) dehydrogenation and contributes to the coke elimination,in concurrent formation of O *** resultant O vacancies are then replenished by CO_(2),showing an ideal chemical *** work presents a green strategy for syngas production via light-driven dry reforming of methane.

关键词： Dry reforming of methane Photo-thermal catalysis Rh/InGaN_(1-x)O_(x)nanowires

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草酸和抑制剂对氮肥在喀斯特土壤中迁移规律的影响

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西南农业学报 2024年第2期37卷 382-390页

作者：谢富金钟宁王家凤张嘉佳田嫄陶毅才周柳强蔡秋亮广西芒果生物学重点实验室广西百色533000 百色学院农业与食品工程学院广西百色533000 百色学院亚热带特色农业产业学院广西百色533000 闽南师范大学福建漳州363000 重庆三峡学院生物与食品工程学院重庆404100 广西农业科学院农业资源与环境研究所南宁530007

【目的】探究草酸、硝化抑制剂(DMPP)和脲酶抑制剂(NBPT)与氮肥配施后氮素在喀斯特土壤中的迁移规律,为喀斯特地区合理施用氮肥及提高肥料利用效率提供科学依据。【方法】采用室内土柱培养法,在土壤湿度为30%条件下,以草酸、DMPP和NBPT... 详细信息

【目的】探究草酸、硝化抑制剂(DMPP)和脲酶抑制剂(NBPT)与氮肥配施后氮素在喀斯特土壤中的迁移规律,为喀斯特地区合理施用氮肥及提高肥料利用效率提供科学依据。【方法】采用室内土柱培养法,在土壤湿度为30%条件下,以草酸、DMPP和NBPT与3种氮肥(硝酸钾、氯化铵和尿素)组合配施,培养15、30和90 d后,测定土柱中不同土层的可溶性无机氮含量及其百分率,探究氮肥配施草酸和2种抑制剂对喀斯特土壤中氮素迁移规律的影响。【结果】在15、30和90 d的培养时间下,与单施氮肥相比,氮肥配施草酸和抑制剂对氮素在喀斯特土壤中迁移具有明显影响。硝酸钾、氯化铵和尿素配施草酸后,土壤的可溶性无机氮含量增加,分别为0.516、3.266和0.958 mg/g,同时,3种氮肥在土壤中的可溶性无机氮百分率均升高(硝酸钾、氯化铵和尿素的可溶性无机氮百分率最高分别为16.68%、41.28%和11.02%)。氯化铵配施草酸+DMPP后,土壤的可溶性无机氮含量增加,其百分率提高,且在培养15 d时百分率最高,为45.48%;尿素配施草酸+DMPP后,在培养90 d时土壤的可溶性无机氮含量和百分率均最高,分别为0.935 mg/g和11.19%。【结论】在喀斯特地区土壤中,硝酸钾、氯化铵和尿素分别配施草酸均能提高土壤可溶性无机氮含量,促进氮素向深层次土壤迁移,氯化铵和尿素分别配施草酸+DMPP也可提高土壤可溶性无机氮含量,这些高效利用氮肥的施肥方式可在农业生产上参考应用。

关键词：氮肥喀斯特土壤迁移规律草酸抑制剂可溶性无机氮

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虾壳源多肽酶解条件的优化及其抗冻活性和作用机制的探究

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食品安全质量检测学报 2024年第3期15卷 59-68页

作者：刘铭利白顺杰邱亮涂子仪于巍廖涛武汉工程大学化学与环境工程学院武汉430073 湖北省农业科学院农产品加工与核农技术研究所/农业农村部农产品冷链物流技术重点实验室武汉430064 湖北省小龙虾产业技术研究院有限公司潜江433100

目的优化从虾壳中提取多肽的酶解条件,并探究虾壳多肽的抗冻活性及作用机制。方法以小龙虾虾壳为原料,使用复合酶酶解提取多肽。在单因素实验的基础上,通过正交实验得到虾壳最佳酶解条件。以面包酵母菌为抗冻测试对象测试其抗冻能力。... 详细信息

目的优化从虾壳中提取多肽的酶解条件,并探究虾壳多肽的抗冻活性及作用机制。方法以小龙虾虾壳为原料,使用复合酶酶解提取多肽。在单因素实验的基础上,通过正交实验得到虾壳最佳酶解条件。以面包酵母菌为抗冻测试对象测试其抗冻能力。采用液相色谱-串联质谱法(liquid chromatography-mass spectrometry,LC-MS/MS)对虾壳多肽的组成进行鉴定,基于多肽的理化性质和序列,结合抗冻预测平台筛选抗冻肽(antifreeze peptides,AFPs)。使用分子动力学模拟探究了AFPs的作用机制。结果在酶解温度40℃,底物质量浓度20mg/mL,加酶量12000U,酶比0.33的最佳酶解条件下,多肽提取率达到了70%以上。虾壳多肽中含有1004种肽段,能明显提升酵母菌存活率。从具有抗冻活性且置信度靠前的20条多肽中进一步筛选出了潜在的抗冻肽AFP1、AFP2。AFP2和冰面之间形成的氢键数量为14,部分水分子同时与2个氨基酸残基形成氢键,充当水桥稳定多肽的构象,AFP2与冰之间的结合能为-105.08 kcal/mol,冰结合模拟效果理想。结论AFPs与冰结合并抑制冰晶生长可能归因于带电荷的亲水性氨基酸残基与水分子形成的氢键、范德华力等分子间作用力,可开发为有益的冷冻保护剂,用于冷冻食品加工,具备良好的应用前景。

关键词：抗冻肽虾壳肽组学复合酶解冰晶生长抑制分子动力学模拟

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Failure transition of shear-to-dilation band of rock salt under triaxial stresses

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第1期16卷 56-64页

作者： Jianfeng Liu Xiaosong qiu Jianxiong Yang Chao liang Jingjing Dai Yu Bian State Key Laboratory of Hydraulics and Mountain River Engineering Sichuan UniversityChengdu610065China CNPC Key Laboratory of Oil and Gas Underground Storage Engineering Langfang065007China College of Water Resource and Hydropower Sichuan UniversityChengdu610065China

Great potential of underground gas/energy storage in salt caverns seems to be a promising solution to support renewable *** the underground storage method,the operating cycle unfortunately may reach up to daily or even hourly,which generates complicated pressures on the salt ***,the mechanical behavior of rock salt may change and present distinct failure characteristics under different stress states,which affects the performance of salt cavern during the time period of full *** reproduce a similar loading condition on the cavern surrounding rock mass,the cyclic triaxial loading/unloading tests are performed on the rock salt to explore the mechanical transition behavior and failure characteristics under different *** results show that the rock salt samples pre-sent a diffused shear failure band with significant bulges at certain locations in low confining pressure conditions(e.g.5 MPa,10 MPa and 15 MPa),which is closely related to crystal misorientation and grain boundary *** the elevated confinement(e.g.20 MPa,30 MPa and 40 MPa),the dilation band dominates the failure mechanism,where the large-size halite crystals are crushed to be smaller size and new pores are *** failure transition mechanism revealed in the paper provides additional insight into the mechanical performance of salt caverns influenced by complicated stress states.

关键词： Rock salt Cyclic mechanical loading Shear band Dilation band Underground gas storage(UGS)

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农业物联网技术在温室大棚生产中的应用进展

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浙江农业科学 2024年第1期65卷 242-248页

作者：葛礼姣程玉静仇亮王小秋翟彩娇丁晓卫江苏沿江地区农业科学研究所江苏南通226012 江苏超数信息科技有限公司江苏南通226004

农业物联网作为我国的战略性新兴产业,在加快我国传统农业向现代农业转变的进程中发挥重大作用。本文综述了农业物联网的概念、国内外应用概况、系统结构、在温室大棚中的关键技术及具体应用,并结合我国实际情况,对农业物联网技术在温... 详细信息

农业物联网作为我国的战略性新兴产业,在加快我国传统农业向现代农业转变的进程中发挥重大作用。本文综述了农业物联网的概念、国内外应用概况、系统结构、在温室大棚中的关键技术及具体应用,并结合我国实际情况,对农业物联网技术在温室大棚应用推广中存在的问题以及未来的建设方向进行了分析和展望,以期充分发挥农业物联网技术在温室大棚中的应用优势,为我国大范围推广应用提供参考依据。

关键词：农业物联网温室大棚应用

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Effects of Hydrogen Charging Time and Pressure on the Hydrogen Embrittlement Susceptibility of X52 Pipeline Steel Material

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Acta Metallurgica Sinica(English Letters) 2024年第2期37卷 293-307页

作者： Hong-Jiang Wan Xiao-Qi Wu Hong-liang Ming Jian-qiu Wang En-Hou Han School of Materials Science and Engineering University of Science and Technology of ChinaShenyang110016China CAS Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang110016China School of Materials Science and Engineering Northeastern UniversityShenyang110819China Institute of Corrosion Science and Technology Guangzhou510530China

The effects of hydrogen charging time and pressure on the hydrogen embrittlement(HE)susceptibility of X52 pipeline steel material are studied by slow strain rate tensile *** fracture morphologies of the specimens are observed by scanning electron *** HE susceptibility of the X52 pipeline steel material increases with an increase in both hydrogen charging time and hydrogen *** a charging time of 96 h,the HE susceptibility index reaches 45.86%,approximately 3.6 times that at a charging time of 0 ***,a charging pressure of 4 MPa results in a HE susceptibility index of 31.61%,approximately 2.5 times higher than that at a charging pressure of 0.3 MPa.

关键词： Hydrogen embrittlement X52 pipeline steel material Tubular specimen Hydrogen charging time Hydrogen charging pressure

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Scheme for Remote Implementation of Partially Unknown Quantum Operation of Two Qubits in Cavity QED

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Communications in Theoretical Physics 2008年第11期50卷 1233-1236页

作者： qiu liang WANG An-Min Quantum Theory Group Department of Modern Physics University of Science and Technology of China Hefei 230026China

By constructing the recovery operations of the protocol of remote implementation of partially unknownquantum operation of two qubits[An-Min Wang:***.A 74(2006)032317]with two-qubit Cnot gate and singlequbit logic gates,we present a scheme to implement it in cavity ***-lived Rydberg atoms are used as qubits,and the interaction between the atoms and the field of cavity is a nonresonant ***,we analyze the experimentalfeasibility of this scheme.

关键词：远程控制量子理论 QED腔逻辑学

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Yolk-shell FeCu/NC electrocatalyst boosting high-performance zinc-air battery

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Nano Research 2024年第9期17卷 7918-7925页

作者： Chen liang Tianyu Zhang Shilun Sun Aijuan Han Zenghui qiu Haijun Xu Junfeng Liu State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China College of Mathematics&Physics Beijing University of Chemical TechnologyBeijing 100029China Beijing Bioprocess Key Laboratory Beijing University of Chemical TechnologyBeijing 100029China

Iron-nitrogen-carbon single-atom catalysts(Fe-N-C SACs)are widely acknowledged for their effective oxygen reduction activity,however,their activity requires further ***,additional structural optimization is necessary to enhance mass transport and achieve higher power density in practical ***,using ZIF-8 as a template,we synthesized yolk-shell catalysts featuring complex sites of Fe single atoms and Cu nanoclusters(y-FeCu/NC)via partial etching and liquid-phase *** synthesized y-FeCu/NC catalyst exhibits high specific surface area and mesoporous *** with the advantages of highly active sites and yolk-shell structure,the y-FeCu/NC catalyst demonstrated outstanding catalytic performance in the oxygen reduction reaction,achieving a half-wave potential(E_(1/2))of 0.97 V in 0.1 M *** a practical energy device,Zn-air battery(ZAB)assembled with y-FeCu/NC catalyst achieved a remarkable power density of 356.3 mW·cm^(-2),representing an improvement of approximately 28.5%compared to its solid FeCu/NC ***,it showcased impressive stability,surpassing all control samples.

关键词： atomic Fe-N4 sites Cu nanoclusters yolk-shell structure oxygen reduction reaction zinc-air battery

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Colorectal Cancer Segmentation Algorithm Based on Deep Features from Enhanced CT Images

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Computers, Materials & Continua 2024年第8期80卷 2495-2510页

作者： Shi qiu Hongbing Lu Jun Shu Ting liang Tao Zhou School of Biomedical Engineering Fourth Military Medical UniversityXi’an710119China Department of Radiology Xijing HospitalFourth Military Medical UniversityXi’an710032China Department of Radiology The First Affiliated Hospital of Xi’an Jiaotong UniversityXi’an710061China School of Computer Science and Engineering North Minzu UniversityYinchuan750030China

Colorectal cancer,a malignant lesion of the intestines,significantly affects human health and life,emphasizing the necessity of early detection and *** segmentation of colorectal cancer regions directly impacts subsequent staging,treatment methods,and prognostic *** colonoscopy is an effective method for detecting colorectal cancer,its data collection approach can cause patient *** address this,current research utilizes Computed Tomography(CT)imaging;however,conventional CT images only capture transient states,lacking sufficient representational capability to precisely locate colorectal *** study utilizes enhanced CT images,constructing a deep feature network from the arterial,portal venous,and delay phases to simulate the physician’s diagnostic process and achieve accurate cancer *** innovations include:1)Utilizing portal venous phase CT images to introduce a context-aware multi-scale aggregation module for preliminary shape extraction of colorectal cancer.2)Building an image sequence based on arterial and delay phases,transforming the cancer segmentation issue into an anomaly detection problem,establishing a pixel-pairing strategy,and proposing a colorectal cancer segmentation algorithm using a Siamese *** with 84 clinical cases of colorectal cancer enhanced CT data demonstrated an Area Overlap Measure of 0.90,significantly better than Fully Convolutional Networks(FCNs)at *** research will explore the relationship between conventional and enhanced CT to further reduce segmentation time and improve accuracy.

关键词： Colorectal cancer enhanced CT multi-scale siamese network segmentation

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Dynamics of Nonclassical Correlation in Interacting Qubits under Correlated Dissipative Environments

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Chinese Physics Letters 2011年第11期28卷 20-23页

作者：仇亮 Department of Physics China University of Mining and TechnologyXuzhou 221008

The dynamical evolution of nonclassical correlation in interacting qubits is investigated under the correlated dissipative environments for two classes of initial *** the correlated decay rate equals the independent decay rate,there will be stationary nonclassical correlation between the qubits prepared initially in some separable *** the correlated decay rate is different from the independent decay rate,the nonclassical correlation between the qubits eventually decays to zero for a certain class of initial states.

关键词： states decay eventually

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