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Interface sites on vanadia-based catalysts are highly active for NO_(x) removal under realistic conditions

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Journal of Environmental Sciences 2024年第2期136卷 523-536页

作者： Zhihui Lv Guangzhi he Wenshuo zhang Jingjing Liu Zhihua lian Yang Yang Zidi Yan Guangyan Xu Wenpo Shan yunbo yu hong he State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China Center for Excellence in Regional Atmospheric Environment and Key Laboratory of Urban Pollutant Conversion Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou 341000China Ningbo Research Center for Urban Environment Chinese Academy of SciencesNingbo 315800China

TiO_(2)-supported V_(2)O_(5)catalysts are commonly used in NO_(x)reduction with ammonia due to their robust catalytic *** these catalysts,it is generally considered that the active species are mainly derived from the vanadia species rather than the intrinsic structure of V-O-Ti entities,namely the interface *** reveal the role of V-O-Ti entities in NH_(3)-SCR,herein,we prepared TiO_(2)/V_(2)O_(5)catalysts and demonstrated that V-O-Ti entities were more active for NO_(x)reduction under wet conditions than the V sites(V=O)working *** the V-O-Ti entities,kinetic measurements and first principles calculations revealed that NH_(3)activation exhibited a much lower energy barrier than that on V=O *** wet conditions,the V-O-Ti interface significantly inhibited the transformation of V=O to V-OH sites thus benefiting NH_(3)*** wet conditions,meanwhile,the migration of NH_(4)^(+)from Ti site neighboring the V-O-Ti interface to Ti site of the V-O-Ti interface was exothermic;thus,V-O-Ti entities together with neighboring Ti sites could serve as channels linking NH_(3)pool and active centers for activation of NH_(4)^(+).This finding reveals that the V-O-Ti interface sites on V-based catalysts play a crucial role in NO_(x)removal under realistic conditions,providing a new perspective on NH_(3)-SCR mechanism.

关键词： NO_(x)removal Vanadia-based catalysts V-O-Ti entities Interface sites Reaction mechanism

Values of macular ganglion cell-inner plexiform layer and 10-2 visual field measurements in detecting and evaluating glaucoma

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International Journal of Ophthalmology(English edition) 2024年第5期17卷 852-860页

作者： Hai-Jian Hu Ping Li Bin Tong yu-lian Pang hong-Dou Luo Fei-Fei Wang Chan Xiong yu-Lin yu Hai he Xu zhang Affiliated Eye Hospital of Nanchang University Jiangxi Research Institute of Ophthalmology and Visual ScienceJiangxi Clinical Research Center for Ophthalmic DiseaseJiangxi Branch of National Clinical Research Center for Ocular DiseasesNanchang 330006Jiangxi ProvinceChina Wuhan Children’s Hospital(Wuhan Maternal and Child healthcare Hospital) Tongji Medical CollegeHuazhong University of Science&TechnologyWuhan 430015Hubei ProvinceChina

AIM:To assess the performance of macular ganglion cell-inner plexiform layer thickness(mGCIPLT)and 10-2 visual field(VF)parameters in detecting early glaucoma and evaluating the severity of advanced ***:Totally 127 eyes from 89 participants(36 eyes of 19 healthy participants,45 eyes of 31 early glaucoma patients and 46 eyes of 39 advanced glaucoma patients)were *** relationships between the optical coherence tomography(OCT)-derived parameters and VF sensitivity were *** with early glaucoma were divided into eyes with or without central 10°of the VF damages(CVFDs),and the diagnostic performances of OCT-derived parameters were ***:In early glaucoma,the mGCIPLT was significantly correlated with 10-2 VF pattern standard deviation(PSD;with average mGCIPLT:β=-0.046,95%CI,-0.067 to-0.024,Phe mGCIPLT was related to the 24-2 VF mean deviation(MD;with average mGCIPLT:β=0.397,95%CI,0.199 to 0.595,Phe minimum and superotemporal mGCIPLT,the decrease of mGCIPLT in early glaucomatous eyes with CVFDs was more severe than that of early glaucomatous eyes without *** area under the curve(AUC)of the average mGCIPLT(AUC=0.949,95%CI,0.868 to 0.982)was greater than that of the average circumpapillary retinal nerve fiber layer thickness(cpRNFLT;AUC=0.827,95%CI,0.674 to 0.918)and rim area(AUC=0.799,95%CI,0.610 to 0.907)in early glaucomatous eyes with CVFDs versus normal ***:The 10-2 VF and mGCIPLT parameters are complementary to 24-2 VF,cpRNFLT and ONH parameters,especially in detecting early glaucoma with CVFDs and evaluating the severity of advanced glaucoma in group level.

关键词： 10-2 visual field ganglion cell-inner plexiform layer retinal nerve fiber layer thickness glaucoma

Genomic data and ecological niche modeling reveal an unusually slow rate of molecular evolution in the Cretaceous Eupteleaceae

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Science China(Life Sciences) 2024年第4期67卷 803-816页

作者： Kun-Li Xiang Sheng-Dan Wu lian lian Wen-Chuang he Dan Peng Huan-Wen Peng Xiao-Ni zhang hong-Lei Li Jia-yu Xue hong-Yan Shan Gui-Xia Xu Yang Liu Zhi-Qiang Wu Wei Wang State Key Laboratory of Plant Diversity and Specialty Crops Institute of BotanyChinese Academy of SciencesBeijing 100093China Shenzhen Branch Guangdong Laboratory of Lingnan Modern AgricultureKey Laboratory of Synthetic BiologyLaboratory of the Ministry of Agriculture and Rural AffairsAgricultural Genomics Institute at ShenzhenChinese Academy of Agricultural SciencesShenzhen 518120China China National Botanical Garden Beijing 100093China State Key Laboratory of Grassland Agro-Ecosystems and College of Ecology Lanzhou UniversityLanzhou 730000China University of Chinese Academy of Sciences Beijing 100049China College of Landscape Architecture and Life Science/Institute of Special Plants Chongqing University of Arts and SciencesChongqing 402160China College of Horticulture Academy for Advanced Interdisciplinary StudiesNanjing Agricultural UniversityNanjing 210095China Fairylake Botanical Garden Shenzhen&Chinese Academy of SciencesShenzhen 518004China

Living fossils are evidence of long-term sustained ecological ***,whether living fossils have little molecular changes remains poorly known,particularly in ***,we have introduced a novel method that integrates phylogenomic,comparative genomic,and ecological niche modeling analyses to investigate the rate of molecular evolution of Eupteleaceae,a Cretaceous relict angiosperm family endemic to East *** assembled a high-quality chromosome-level nuclear genome,and the chloroplast and mitochondrial genomes of a member of Eupteleaceae(Euptelea pleiosperma).Our results show that Eupteleaceae is most basal in Ranunculales,the earliest-diverging order in eudicots,and shares an ancient whole-genome duplication event with the other *** document that Eupteleaceae has the slowest rate of molecular changes in the observed *** unusually low rate of molecular evolution of Eupteleaceae across all three independent inherited genomes and genes within each of the three genomes is in association with its conserved genome architecture,ancestral woody habit,and conserved niche *** findings reveal the evolution and adaptation of living fossil plants through large-scale environmental change and also provide new insights into early eudicot diversification.

关键词： conservation genomics eudicots evolutionary rates niche conservatism phylogenomics

Glucose production from hydrolysis of cellulose over a novel silica catalyst under hydrothermal conditions

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Journal of Environmental Sciences 2012年第3期24卷 473-478页

作者： Huayu Wang changbin zhang hong he lian Wang State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

A novel silica catalyst was synthesized by evaporation-induced self-assembly （EISA） method and tested for the catalytic selective hydrolysis of cellulose to glucose. This silica catalyst exhibited a higher catalytic activity than other oxides prepared by the same method, such as ZrO2, TiO2, and Al2O3. Using silica as a catalyst, cellulose was selectively hydrolyzed into glucose with a glucose yield as high as 50% under hydrothermal conditions without hydrogen gas. The silica catalyst was characterized by Brunauer-Emmett-Teller （BET）, X-ray diffraction （XRD） and transmission electron microscopy （TEM）. The results of temperature-programmed desorption of ammonia （NH3-TPD） and textural properties indicated that the synergistic effect between strong acidity and a suitable pore diameter of the silica catalyst may be responsible for its high activity. In addition, the catalyst was recyclable and showed excellent stability during the recycle catalytic runs.

关键词： cellulose glucose silica catalyst hydrolysis hydrothermal biomass

Experimental and density functional theory study of the adsorption of N_2O on ion-exchanged ZSM-5: Part II. The adsorption of N_2O on main-group ion-exchanged ZSM-5

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Journal of Environmental Sciences 2011年第4期23卷 681-686页

作者： Bo zhang Yongan Lu hong he Jianguo Wang changbin zhang yunbo yu Li Xue Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China. College of Chemical Engineering and Materials Science Zhejiang University of Technology Hangzhou 310032 China

The adsorption and desorption of N 2 O on main-group ion-exchanged ZSM-5 was studied using temperature-programmed desorption （TPD） and density functional theory （DFT） calculations. TPD experiments were carried out to determine the desorbed temperature T max corresponding to the maximum mass intensity of N 2 O desorption peak and adsorption capacity of N 2 O on metal-ion-exchanged ZSM- 5s. The results indicated that T max followed a sequence of Ba 2＋ Ca 2＋ Cs ＋ K ＋ Na ＋ Mg 2＋ and the amount of adsorbed N 2 O on main-group metal cation followed a sequence of Ba 2＋ Mg 2＋ Ca 2＋ Na ＋ K ＋ Cs ＋ . The DFT calculations were performed to obtain the adsorption energy （E ads ）, which represents the strength of the interaction between metal cations and the N-end or O-end of N 2 O. The calculation results showed that the N-end of the N 2 O molecule was favorably adsorbed on ion-exchanged ZSM-5, except for Cs-ZSM-5. For alkali metal cations, the E ads of N 2 O on cations followed the order which was the same to that of T max ： Cs ＋ K ＋ Na ＋ . The calculated and experimental results consistently showed that the adsorption performances of alkaline-earth metal cations were better than those of alkali metal cations.

关键词： N 2 O adsorption ZSM-5 DFT ion-exchanged zeolites

Antimicrobial activity of silver loaded MnO_2 nanomaterials with different crystal phases against Escherichia coli

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Journal of Environmental Sciences 2016年第3期28卷 112-120页

作者： lian Wang hong he changbin zhang Li Sun Sijin Liu Shaoxin Wang State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of Sciences

Silver-loaded MnO_2 nanomaterials（Ag/MnO_2）,including Ag/α-MnO_2,Ag/β-MnO_2,Ag/γ-MnO_2and Ag/δ-MnO_2 nanorods,were prepared with hydrothermal and impregnation *** bactericidal activities of four types of Ag/MnO_2 nanomaterials against Escherichia coli were investigated and an inactivation mechanism involving Ag~＋ and reactive oxygen species（ROS）was also *** bactericidal activities of Ag/MnO_2 depended on the MnO_2 crystal *** these nanomaterials,Ag/β^-MnO_2 showed the highest bactericidal *** was a 6-log decrease in *** survival number after treatment with Ag/β^-MnO_2 for120 *** results of 5,5-dimethyl-l-pyrroline-N-oxide spin-trapping measurements by electron spin resonance indicate OH and O_2^- formation with addition of Ag/β-MnO_2,Ag/γ-MnO_2 or Ag/δ-MnO_*** strongest peak of OH appeared for Ag/β-MnO_2,while no OH or ·O_2^-signal was found over Ag/α-MnO_*** analysis of electron spin resonance（ESR） and Ag＋elution results,it could be deduced that the toxicity of Ag~＋ eluted from Ag/MnO_2 nanomaterials and ROS played the main roles during the bactericidal *** showed the highest dispersion on the surface of β-MnO_2,which promoted ROS formation and the increase of bactericidal *** results also indicated that Ag/MnO_2 induced the production of intracellular ROS and disruption of the cell wall and cell membrane.

关键词： Silver MnO_2 Bactericidal activity Escherichia coli ROS

Removal of bromate ion using powdered activated carbon

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Journal of Environmental Sciences 2010年第12期22卷 1846-1853页

作者： lian Wang Jie zhang Jingze Liu hong he Min Yang Jianwei yu Zichuan Ma Feng Jiang College of Life Science Hebei Normal University Shijiazhuang 050016 China Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China College of Chemistry & Material Science Hebei Normal University Shijiazhuang 050016 China Beijing YADU Indoor Environmental Protection Science and Technology Co. Ltd. Beijing 102206 China

Bromate ion （BrO3-） removal from drinking water by powdered activated carbons （PACs） in bath mode was evaluated under various operational conditions. Six kinds of PACs, including wood-based carbon, fruit-based carbon, coal-based carbon, and these three carbons thermally deoxidized in a nitrogen atmosphere, were selected to investigate their capacity on BrO3- removal. With the highest zeta potential value and being richly mesoporous, coal-based carbon had a high and an excellent BrO3- adsorption efficiency. The removal content of BrO3- by per gram of coal-based carbon was 0.45 mg within 5 hr in 100 μg/L bromate solution. The surface characteristics of PACs and bromide formation revealed that both physical and chemical PACs properties simultaneously affected the adsorptionreduction process. Under acidic conditions, PACs possessed high zeta value and adequate basic groups and exhibited neutral or positive charges, promoting BrO3- adsorption-reduction on the carbon surface. Interestingly, the PACs thermally deoxidized in N2 atmosphere optimized their properties, e.g. increasing their zeta values and decreasing the oxygen content which accelerated the BrO3- removal rate. The maximum adsorption capacity of fruit-based carbon was the highest among all tested carbons （99.6 mg/g）, possibly due to its highest pore volume. Remarkably, the thermal regeneration of PACs in N2 atmosphere could completely recover the adsorption capacity of PACs. The kinetic data obtained from carbons was analyzed using pseudo second-order and intraparticle diffusion models, with results showing that the intraparticle diffusion was the more applicable model to describe adsorption of BrO3- onto PACs.

关键词： bromate powdered activated carbons adsorption-reduction process adsorption capacity

亚热带同质园不同树种枝、叶氮磷含量及其重吸收特征

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长江流域资源与环境 2024年第5期33卷 993-1003页

作者：赖明玥何樟儒朱鹏杨玉莲李婧李济宏贾世冰李晗张丽谭波徐振锋游成铭长江上游林业生态工程四川省重点实验室长江上游森林资源保育与生态安全国家林业和草原局重点实验室华西雨屏区人工林生态系统研究长期科研基地都江堰灵岩山常绿阔叶林省级长期科研基地四川农业大学林学院四川成都611130 绵阳市安州区自然资源局四川绵阳622651 绵阳师范学院生态安全与保护四川省重点实验室四川绵阳621000

植物氮磷含量及其重吸收特征是揭示林木养分利用策略的有效途径。然而,目前关于不同树种枝、叶氮磷含量及其重吸收特征的研究结果尚不明确。为探究不同树种枝、叶氮磷化学计量及其重吸收效率的变化规律,以亚热带同质园中大叶樟(Cinnamom... 详细信息

植物氮磷含量及其重吸收特征是揭示林木养分利用策略的有效途径。然而,目前关于不同树种枝、叶氮磷含量及其重吸收特征的研究结果尚不明确。为探究不同树种枝、叶氮磷化学计量及其重吸收效率的变化规律,以亚热带同质园中大叶樟(Cinnamomum platyphyllum)、油樟(***)、香樟(***)、香椿(Toona sinensis)、红椿(***)、天竺桂(***)和桤木(Alnus cremastogyne)7种阔叶树种人工林为研究对象,采集其枝、叶(成熟、凋落)样品,测定氮、磷含量,计算重吸收效率。结果表明:(1)桤木成熟(6.35 g/kg)和凋落枝(5.38 g/kg)氮含量显著高于其他树种,但其磷含量则相反,而红椿、香椿、桤木成熟(20.02~23.21 g/kg;1.59~2.75 g/kg)和凋落叶(17.69~21.43 g/kg;1.12~1.95 g/kg)氮、磷含量整体高于其他树种。香樟、油樟成熟叶以及桤木凋落枝、叶氮磷比均显著高于其他树种,且树种枝叶氮磷比均<14,表明该区物种主要受到氮限制。(2)成熟叶氮磷元素的异速指数为0.744,符合氮磷计量关系的2/3法则,但成熟枝和凋落枝、叶则不符合。相较于成熟枝、叶,凋落枝、叶的氮元素变异性更大,但其磷元素则相反。(3)落叶树种桤木、红椿和香椿枝、叶氮重吸收效率均显著低于其他树种(香椿枝除外),但其枝、叶磷重吸收效率整体高于其他树种(桤木枝除外)。(4)叶片氮磷化学计量主要受林分特征和土壤理化性质的共同影响,而枝主要受土壤理化性质的影响。研究结果表明,相较于其他乡土树种,选择桤木和红椿等落叶树种作为人工混交林的改造树种,可能更有利于提升亚热带人工林的质量。

关键词：同质园人工林乡土树种氮磷化学计量养分重吸收效率

Molecular Design and Performance Studies of 4-(1,2,4-Triazole-5-yl)Furazan Derivatives as Promising Energetic Materials

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Chinese Journal of Structural Chemistry 2021年第7期40卷 942-948,841页

作者： ZENG lian JIANG yu-he WU Jin-Ting LI hong-Bo zhang Jian-Guo School of Materials Science and Engineering Southwest University of Science and TechnologyMianyang 621010China State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China

In this paper,eight 4-(1,2,4-triazole-5-yl)furazan(TZFZ)derivatives were designed,and the molecular configurations of TZFZ compounds were optimized by using the B3LYP/6-311+G****,the detonation performance,density,impact sensitivity,heat of formation and oxygen balance have been *** results clearly and intuitively illustrate that the introduction of-NO2 and coordination oxygen plays a pivotal role in increasing the density and heat of *** summary,the properties of these compounds are better than the traditional explosives RDX and TNT,especially the density and detonation *** evaluations showed that compounds B1(P=36.73 GPa;D=8.98 km·s^(-1),ρ=1.88 g·cm^(-3))and B7(P=38.51 GPa;D=9.17 km·s-1,ρ=1.90 g·cm^(-3))could be seen as promising candidates of energetic insensitive compounds with remarkable performance.

关键词： density functional theory 4-(1,2,4-triazole-5-yl)furazan derivatives performance prediction molecular design