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Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

Journal of Energy Chemistry 2025年第1期100卷 286-308页

作者： Yuhao peng Yuefeng Song Ihar Razanau Juanxiu Xiao Wei Xiao Di Hu Guoxiong Wang College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power Sources Wuhan University State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences Laboratory of Physical-Chemical Technologies SSPA Scientific and Practical Materials Research Centre of NAS of Belarus State Key Laboratory of Marine Resources Utilization in South chi.a Sea Collaborative Innovation Center of Marine Science and Technology School of Marine Science and Engineering Hainan University Department of Chemical and Environmental Engineering University of Nottingham Ningbo China

Methane, an abundant one-carbon（C1） resource, is extensively used in the industrial production of vital fuels and value-added chemicals. However, current industrial methane conversion technologies are energy-and carbon-intensive, mainly due to the high activation energy required to break the inert C–H bond, low selectivity, and problematic side reactions, including CO2emissions and coke deposition. Electrochemical conversion of methane（ECM） using intermittent renewable energy offers an attractive solution, due to its modular reactor design and operational flexibility across a broad spectrum of temperatures and pressures. This review emphasizes conversion pathways of methane in various reaction systems, highlighting the significance and advantages of ECM in facilitating a sustainable artificial carbon cycle. This work provides a comprehensive overview of conventional methane activation mechanisms and delineates the complete pathways of methane conversion in electrolysis contexts. Based on surface/interface chemistry, this work systematically analyzes proposed reaction pathways and corresponding strategies to enhance ECM efficiency towards various target products, including syngas, hydrocarbons, oxygenates, and advanced carbon materials. The discussion also encompasses opportunities and challenges for the ECM process, including insights into ECM pathways, rational electrocatalyst design, establishment of benchmarking protocols, electrolyte engineering, enhancement of CH4conversion rates, and minimization of CO2emission.

关键词： Activation energy

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Ru doping triggering reconstruction of cobalt phosphide for coupling glycerol electrooxidation with seawater electrolysis

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Journal of Energy Chemistry 2025年第1期100卷 317-326页

作者： Binglu Deng Jie Shen Jinxing Lu Chuqiang Huang Zhuoyuan Chen Feng peng Yunpeng liu School of Materials Science and Hydrogen Energy Foshan University School of Chemistry and Chemical Engineering Guangzhou University Guangdong Key Laboratory for Hydrogen Energy Technologies

Seawater electrolysis is a promising approach for sustainable energy without relying on precious ***,the large-scale seawater electrolysis is hindered by low catalytic efficiency and severe anode corrosion caused by the harmful *** contrast to the oxygen evolution reaction （OER）and chlorin ion oxidation reaction （ClOR）,glycerol oxidation reaction （GOR） is more thermodynamically and kinetically favorable ***,a Ru doping cobalt phosphide （Ru-CoP2） is proposed as a robust bifunctional electrocatalyst for seawater electrolysis and GOR,for the concurrent productions of hydrogen and value-added *** in situ and ex situ characterization analyses demonstrated that Ru doping featured in the dynamic reconstruction process from Ru-CoP2to Ru-CoOOH,accounting for the superior GOR *** coupling GOR with hydrogen evolution was realized by employing Ru-CoP2as both anode and cathode,requiring only a low voltage of 1.43 V at 100 mA cm-2,which was 250 m V lower than that in alkaline *** work guides the design of bifunctional electrocatalysts for energy-efficient seawater electrolysis coupled with biomass resource upcycling.

关键词： Anodes

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A General Association Test for High-Dimensional Random Vectors

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Acta Mathematica Sinica,English Series 2025年

作者： Yongshuai Chen peng lin Baoxue Zhang School of Statistics Capital University of Economics and Business

Testing the association of two high-dimensional random vectors is of fundamental importance in the statistical theory and applications. In this paper, we propose a new test statistic based on the Frobenius norm and subtracting bias technique, which is generally applicable to high-dimensional data without restricting the distributional assumptions. The limiting null distribution of the proposed test is shown to be a random variable combining a finite chi.squared-type mixture with a normal approximation. Our proposed test method can also be a normal approximation or a finite chi.squared-type mixtures under additional regularity conditions. To make the test statistic applicable, we introduce a wild bootstrap method and demonstrate its validity. The finite-sample performance of the proposed test via Monte Carlo simulations reveals that it performs better at controlling the empirical size than some existing tests, even when the normal approximation is invalid. Real data analysis is devoted to illustrating the proposed test.

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Profile of peng li

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Science chi.a(life Sciences) 2017年第1期60卷 44-45页

作者： li peng

Dr. peng li received her B.S. degree from Beijing Normal University （chi.a） in 1987. In 1988, she joined the De- partment of Biochemistry, University of Texas Southwest- ern Medical Center at Dallas （USA） as a CUSBEA （chi. na-United States Biochemistry Examination and Applica- tion） student. In 1995, she received her Ph.D. degree from University of California at San Diego （U.S.A）.

关键词：李鹏北京师范大学博士学位德克萨斯圣地亚哥加州大学达拉斯生化

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CaH2-promoted activity of Ni-carbonate interface for CO2 methanation

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Journal of Energy Chemistry 2025年第1期100卷 522-532页

作者： Jin-peng Wang Guo-Cui Mao Hui-lin Jiang Bao-Xia Dong Yun-Lei Teng School of Chemistry and Chemical Engineering Yangzhou University

Transition metal-carbonate interfaces often act as active sites in heterogeneous catalytic *** interface between transition metal and metal carbonate exhibits a dynamic equilibrium during the CO2hydrogenation reaction,involving surface carbonate hydrogenation and ***,there have been few reports on engineering the activity of the interface between transition metal and alkaline earth metal carbonate for catalytic *** work demonstrated that the incorporation of CaH2in Ni/CaCO3enhances the CO2methanation activity of the *** CO2conversion for Ni/CaH2-CaCO3reached 68.5%at 400°C,which was much higher than that of the Ni/CaCO3（31.6%） and Ni/CaH2-CaO （42.4%） ***,the Ni/CaH2-CaCO3catalysts remained stable during the stability test for 24 h at 400°C and 8 *** research revealed that CaH2played a crucial role in promoting the activity of the Ni-carbonate interface for ***2could modify the electronic structure of Ni and tune the structural properties of CaCO3to generate medium basic sites （OH groups）,which are favorable for the activation of H2and ***-situ Fourier transform infrared spectroscopy （FTIR） analysis combined with density functional theory calculations demonstrated that CO2activation occurs at the hydroxyl group （OH） on the CaH2-modified Ni-carbonate surface,leading to the formation of CO3H****,our study has confirmed that CO2methanation over the Ni/CaH2-CaCO3catalysts proceeds via the formate pathway.

关键词： CO 2 methanation Metal hydride Ni catalysts Carbonate Metal-carbonate interface

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Is dipole the only thing that matters for inverted perovskite solar cells?

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chi.ese Journal of Structural Chemistry 2024年第6期43卷 15-17页

作者： chi.li peng Gao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China Laboratory for Advanced Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021China University of chi.ese Academy of Sciences Beijing100049China

The rapid enhancement in the power conversion efficiency(PCE)of inverted(p-i-n)perovskite solar cells(PSCs)[1]is closely linked to the application of hole-selective self-assembled monolayers(SAMs)[2,3]in replacing or assisting the traditional organic/inorganic hole transporting *** to the dipolar nature of SAMs,these compact and well-ordered two-dimensional materials significantly impact the energy level alignment through their strong dipole moments[4,5].However,a similar case has not yet been observed in n-i-p-type *** success of SAMs in p-i-n PSCs raises the question of whether the dipole is the only thing that matters for inverted PSCs for efficient hole extraction.

关键词： dipole perovskite thin

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Determination of the shedding frequency of cavitation cloud in a submerged cavitation jet based on high-speed photography images

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Journal of Hydrodynamics 2021年第1期33卷 127-139页

作者： chi.peng Shou-ceng Tian Gen-sheng li State Key Laboratory of Petroleum Resources and Prospecting China University of Petroleum(Beijing)Beijing 102249China

To accurately determine the shedding frequency of the cavitation cloud in a submerged cavitation jet,the spectral analysis and the proper orthogonal decomposition(POD)for high-speed photography images are *** spectrums of 6 different kinds of image signals(the area-averaged gray level,the line-averaged gray level,the point gray level,the cavitation length,width,and area)are calculated and *** line-averaged gray level is found to be optimal in determining the shedding frequency but an accurate frequency can only be obtained in the stable-frequency zone where the cavitation cloud *** repeated experiments,the plateau-shape distribution of the main frequency is established with a deviation of 10.8%.A revised Reynolds number Re'is defined and the shedding frequency can be correlated to Re'by a power law when the cavitation number is less than *** relationship is validated by the experimental data in *** first mode of the POD characterizes the ensemble-average of the cavitation cloud while the second mode is the major part of the cavitation cloud transient *** modes 2-5 are organized in pairs,which confirms the periodic feature of the cavitation cloud in the submerged cavitation *** the nozzle exit,the modes 2-5 are symmetrically distributed in the jet shear *** shedding frequency of the cloud cavitation can also be precisely determined by performing the spectral analysis of the weighting coefficients of the mode *** paper shows that the two parameters,namely,the line-averaged gray level and the weighting coefficients of the mode 2,can be confidently used to calculate the shedding frequency of the cavitation cloud in a submerged cavitation jet.

关键词： Cavitation jet shedding frequency high-speed photography spectral analysis proper orthogonal decomposition(POD)

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Transforming waste particles into valuable adsorbents via amyloid-mediated molecular engineering

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Science chi.a Chemistry 2025年第1期68卷 317-328页

作者： Qingmin Yang Jian Zhao Yujia Zhang Xingyu Zhou Hao Ren Bowen Hu Zhongli Lei lixin Chen peng Yang School of Material and Chemical Engineering Bengbu University Anhui Provincial Engineering Laboratory of Silicon-Based Materials School of Chemistry and Chemical Engineering Northwestern Polytechnical University Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education School of Chemistry and Chemical EngineeringShaanxi Normal University Xi'an Key Laboratory of Polymeric Soft Matter School of Chemistry and Chemical Engineering Shaanxi Normal University International Joint Research Center on Functional Fiber and Soft Smart Textile School of Chemistry and Chemical EngineeringShaanxi Normal University

The high-value utilization of industrial solid waste using a facile and eco-friendly process is of great interest and significance in reducing environmental pollution and developing a green circular economy. Herein, we propose an amyloid-mediated molecular engineering strategy to transform particulate waste into valuable adsorbents for metal ions. Our method has the advantage of aqueous solution fabrication under mild conditions without the use of high-temperature hydrothermal methods and toxic chemical reagents. Amyloid-mediated molecular engineering manipulates the phase transition of bovine serum albumin(BSA)on particulate waste surfaces, resulting in a remarkable ～3.1 times improvement in the adsorption capacity of fly ash, a typical industrial solid waste for gold ions after modification with the phase-transitioned BSA(PTB). The resultant adsorption ability was 69–1,980 times higher than those of conventional and emerging adsorbent materials such as ion exchange resins, activated carbon(AC), covalent organic frameworks(COFs), and metal-organic frameworks(MOFs). We further demonstrated the application of our PTB-modified materials in the recovery of precious metals from low-grade gold ore and electronic waste leachates. Consequently, this strategy could increase the value of waste materials nearly 27 times. In addition, this method is generally extendable to other conventional industrial adsorbents such as resin, clay, and Al2O3, and enhances their adsorption capabilities at least twofold. Overall, this work provides a simple and green approach for improving the adsorption performance of solid particles, and is expected to develop into a universal strategy for transforming waste particles into high-value-added products.

关键词： amyloid-like protein aggregates surface engineering fly ash solid waste adsorption

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Low-cost and fluoride-free synthesis of MFI zeolite nanosheets with enhanced stability for benzene alkylation with ethanol

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Journal of Energy Chemistry 2025年第1期100卷 458-468页

作者： peng Zhu Cun liu Yiren Yu Guoshu Gao Yumeng Zhao Xiongfu Zhang Guodong liu Guohui Yang State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

Zeolite nanosheets with a short b-axis thickness are highly desirable in lots of catalytic reactions due to their reduced diffusion resistance. Nevertheless, conventional synthesis methods usually require expensive structure-directing agents(SDAs), pricey raw materials, and eco-unfriendly fluorine-containing additives. Here, we contributed a cost-effective and fluoride-free synthesis method for synthesizing high-quality MFI zeolite nanosheets through a Silicalite-1(Sil-1) seed suspension and urea cooperative strategy, only with inexpensive colloidal silica as the Si source. Our approach was effective for synthesizing both Sil-1 and aluminum-containing ZSM-5 nanosheets. By optimizing key synthesis parameters,including seed aging time, seed quantity, and urea concentration, we achi.ved precise control over the crystal face aspect ratio and b-axis thickness. We also revealed a non-classical oriented nanosheet growth mechanism, where Sil-1 seeds induced the formation of quasi-ordered precursor particles, and the(010)crystal planes of these particles facilitated urea adsorption, thereby promoting c-axis-oriented *** obtained ZSM-5 nanosheets exhibited exceptional catalytic performance in the benzene alkylation with ethanol, maintaining stability for over 500 h, which is 5 times longer than traditional ZSM-5 catalysts. Furthermore, large-scale production of ZSM-5 nanosheets was successfully carried out in a 3 L highpressure autoclave, yielding samples consistent with those from laboratory-scale synthesis. This work marks a significant step forward in the sustainable and efficient production of MFI nanosheets using inexpensive and environmentally friendly raw materials, offering the broad applicability in catalysis.

关键词： Aspect ratio

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Mixed Reality-based Interactive Technology for Aircraft Cabin Assembly

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chi.ese Journal of Mechanical Engineering 2009年第3期22卷 403-409页

作者： li Shiqi peng Tao WANG Junfeng XU chi School of Mechanical Science and Engineering Huazhong University of Science and Technology Wuhan 430074 China

Due to the narrowness of space and the complexity of structure, the assembly of aircraft cabin has become one of the major bottlenecks in the whole manufacturing process. To solve the problem, at the beginning of aircraft design, the different stages of the lifecycle of aircraft must be thought about, which include the trial manufacture, assembly, maintenance, recycling and destruction of the product. Recently, thanks to the development of the virtual reality and augmented reality, some low-cost and fast solutions are found for the product assembly. This paper presents a mixed reality-based interactive technology for the aircraft cabin assembly, which can enhance the efficiency of the assemblage in a virtual environment in terms of vision, information and operation. In the mixed reality-based assembly environment, the physical scene can be obtained by a camera and then generated by a computer. The virtual parts, the features of visual assembly, the navigation information, the physical parts and the physical assembly environment will be mixed and presented in the same assembly scene. The mixed or the augmented information will provide some assembling information as a detailed assembly instruction in the mixed reality-based assembly environment. Constraint proxy and its match rules help to reconstruct and visualize the restriction relationship among different parts, and to avoid the complex calculation of constraint＇s match. Finally, a desktop prototype system of virtual assembly has been built to assist the assembly verification and training with the virtual hand.

关键词： virtual assembly human-computer interaction mixed reality information augmentation constraints navigation

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