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Transport mechanism of eroded sediment particles under freeze-thaw and runoff conditions

Journal of Arid Land 2022年第5期14卷 490-501页

作者： WANG Tian li Peng HOU Jingming TONG Yu li Jing WANG Feng li zhanbin State Key Laboratory of Eco-hydraulics in Northwest Arid Region Xi'an University of TechnologyXi'an 710048China Key Laboratory of National Forestry Administration on Ecological Hydrology and Disaster Prevention in Arid Regions Xi'an University of TechnologyXi'an 710048China

Hydraulic erosion associated with seasonal freeze-thaw cycles is one of the most predominant factors,which drives soil stripping and transportation.In this study,indoor simulated meltwater erosion experiments were used to investigate the sorting characteristics and transport mechanism of sediment particles under different freeze-thaw conditions(unfrozen,shallow-thawed,and frozen slopes)and runoff rates(1,2,and 4 L/min).Results showed that the order of sediment particle contents was silt>sand>clay during erosion process on unfrozen,shallow-thawed,and frozen slopes.Compared with original soils,clay and silt were lost,and sand was deposited.On unfrozen and shallow-thawed slopes,the change of runoff rate had a significant impact on the enrichment of clay,silt,and sand particles.In this study,the sediment particles transported in the form of suspension/saltation were 83.58%–86.54%on unfrozen slopes,69.24%–84.89%on shallow-thawed slopes,and 83.75%–87.44%on frozen slopes.Moreover,sediment particles smaller than 0.027 mm were preferentially transported.On shallow-thawed slope,relative contribution percentage of suspension/saltation sediment particles gradually increased with the increase in runoff rate,and an opposite trend occurred on unfrozen and frozen slopes.At the same runoff rate,freeze-thaw process had a significant impact on the relative contribution percentage of sediment particle transport via suspension/saltation and rolling during erosion process.The research results provide an improved transport mechanism under freeze-thaw condition for steep loessal slopes.

关键词： freeze-thaw runoff conditions erosion process sediment particles transport mechanism

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Temporal and spatial variation characteristics of extreme precipitation on the Loess Plateau of China facing the precipitation process

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Journal of Arid Land 2023年第4期15卷 439-459页

作者： ZHANG Yixin li Peng XU Guoce MIN Zhiqiang li Qingshun li zhanbin WANG Bin CHEN Yiting State Key Laboratory of Eco-Hydraulic in Northwest Arid Region Xi'an University of TechnologyXi'an 710048China Key Laboratory of National Forestry and Grassland Administration on Ecological Hydrology and Disaster Prevention in Arid Regions Northwest Survey and Planning Institute of National Forestry and Grassland AdministrationXi'an 710048China State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau Chinese Academy of Sciences and Ministry of Water ResourcesYangling 712100China

The preceding and succeeding precipitation(PSP)often act together with extreme precipitation(EP),in turn,causing floods,which is an objective component that is often overlooked with regard to summer flood hazards in the arid region of Northwest China.In this study,event-based extreme precipitation(EEP)was defined as continuous precipitation that includes at least one day of EP.We analyzed the spatiotemporal variation characteristics of four EEP types(front EEP,late EEP,balanced EEP,and single day EEP)across the Loess Plateau(LP)based on data acquired from 87 meteorological stations from 1960 to 2019.Precipitation on the LP basically maintained a spatial pattern of"low in the northwest region and high in the southeast region",and EP over the last 10 a increased significantly.The cumulative precipitation percentage of single day EEP was 34%and was dominant for 60 a,while the cumulative precipitation percentage of front,late,and balanced EEP types associated with PSP accounted for 66%,which confirms to the connotation of EEP.The cumulative frequencies of front and late EEP types were 23%and 21%,respectively,while the cumulative frequency of balanced EEP had the lowest value at only 13%.Moreover,global warming could lead to more single day EEP across the LP,and continuous EEP could increase in the northwestern region and decrease in the eastern region in the future.The concept of process-oriented EP could facilitate further exploration of disaster-causing processes associated with different types of EP,and provide a theoretical basis for deriving precipitation disaster chains and construction of disaster cluster characteristics.

关键词： temporal and spatial variation climate change extreme precipitation(EP) event-based extreme precipitation(EEP) Loess Plateau

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Leaching kinetics of fluorine during the aluminum removal from spent li-ion battery cathode materials

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Journal of Environmental Sciences 2024年第4期138卷 312-325页

作者： Shengjie li Jianxin Zhu Research Center for Eco-Environmental Sciences Chinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China

The high content of aluminum(Al)impurity in the recycled cathode powder seriously affects the extraction efficiency of Nickel,Cobalt,Manganese,and lithium resources and the actual commercial value of recycled materials,so Al removal is crucially important to conform to the industrial standard of spent li-ion battery cathode materials.In this work,we systematically investigated the leaching process and optimum conditions associated with Al removal from the cathode powder materials collected in a wet cathode-powder peeling and recycling production line of spent li-ion batteries(liBs).Moreover,we specifically studied the leaching of fluorine(F)synergistically happened along with the removal process of Al,which was not concerned about in other studies,but one of the key factors affecting pollution prevention in the recovery process.The mechanism of the whole process including the leaching of Al and F from the cathode powder was indicated by using NMR,FTIR,and XPS,and a defluoridation process was preliminarily investigated in this study.The leaching kinetics of Al could be successfully described by the shrinking core model,controlled by the diffusion process and the activation energy was 11.14 kJ/mol.While,the leaching of F was attributed to the dissolution of liPF6and decomposition of PVDF,and the kinetics associated was described by Avrami model.The interaction of Al and F is advantageous to realize the defluoridation to some degree.It is expected that our investigation will provide theoretical support for the large-scale recycling of spent liBs.

关键词： Al removal F leaching Cathode powder Heating alkali leaching Leaching kinetics

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Additives strategies to improving cycling stability of li metal batteries by modifying electrode electrolyte interphases

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Progress in Natural Science:Materials International 2024年第2期34卷 338-344页

作者： Yuan li Pengfei Huang Chunyu Cui Xiaoyuan Ma li Chen Zekun li linhai li Yuhong Tian School of Biological and Chemical Engineering Guangxi University of Science and Technology School of College of Chemistry and Chemical Engineering Hunan University Isky Future Energy Institute

li metal batteries（LMBs） have attracted much attention due to the ultra-high theoretical capacity of the li metal anode（LMA）.However,the uncontrollable dendrites growth and low coulombic efficiency hinder their practical application.Here,we explore 3,5-difluoropyridine（2F-BD） as a novel electrolyte additive to enable highperformance LMBs.The 2F-BD additive participates in and modifies the solvation structure of li ions by reducing the coordinated number of PF6-at the electrode surface,leading to the formation of a liF and li3N-rich solid electrolyte interphase（SEI）.The liF component increases the robustness of SEI and suppresses the formation of li dendrites,while the li3N component facilitates the transportation and reaction kinetics of li ions.As a result,the li‖li symmetric cell presents a stable cycling performance of up to 500 h at a current density of 1 mA cm-2.After coupling with liFePO4cathode,the obtained full cell achieves high specific capacities of 106.06 mA h g-1and 84.98 mA h g-1at 2.55 mA cm-2and 5.10 mA cm-2,respectively,and maintains a high capacity retention of84.0% after 1000 cycles at 0.13 mA cm-2,with an average cycling CE of 99.58%.

关键词： Electrolyte additive li dendrites li metal batteries liF and li3N-Rich electrode-electrolyte interphase liFePO4 cathode

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构建我国现代化产业体系的六条路径

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理论探索 2024年第3期 18-25页

作者：李许卡张占斌中共河南省委党校/河南行政学院郑州450046 中共中央党校/国家行政学院北京100193

现代化产业体系是新质生产力在产业维度上的集中体现,呈现出高端化、智能化、绿色化、数字化等特征,加快发展新质生产力对我国现代化产业体系建设提出了创新性强、高端智能、绿色低碳、安全可控、融合度高和开放合作等新的理论和实践要... 详细信息

现代化产业体系是新质生产力在产业维度上的集中体现,呈现出高端化、智能化、绿色化、数字化等特征,加快发展新质生产力对我国现代化产业体系建设提出了创新性强、高端智能、绿色低碳、安全可控、融合度高和开放合作等新的理论和实践要求。系统构建现代化产业体系,应在不同维度采取针对性措施,横向上:以巩固提升传统产业为先导,聚力发展战略新兴产业和未来产业;纵向上:以产业融合发展和提升全要素生产率为着力点,加快推进三次产业结构和产业内部结构优化升级;核心要素层面:以多链深融为主要抓手,提升关键产业要素支撑作用;基本单元层面:以做大做强做优市场主体为主攻方向,驱动产业创新发展;物质基础方面:以推进产业基础高级化和补齐产业基础短板为重要依托,筑牢产业现代化底座;制度支撑方面:以完善产业政策和扩大产业开放合作为重要切入点,助推产业高质量发展。

关键词：现代化产业体系新质生产力战略新兴产业产业创新产业政策

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Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate li metal batteries

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Chinese Chemical Letters 2024年第6期35卷 239-243页

作者： Long li Kang Yang Chenpeng Xi Mengchao li Borong li Gui Xu Yuanbin Xiao Xiancai Cui Zhiliang liu lingyun li Yan Yu Chengkai Yang Key Laboratory of Advanced Materials Technologies International(HongKong Macao and Taiwan)Joint Laboratory on Advanced Materials TechnologiesSchool of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China College of Material Sciences and Chemical Engineering Harbin Engineering UniversityHarbin 150001China

Side reactions and dendrite growth triggered by the unstable interface and inhomogeneous deposition have become the biggest obstacle to the commercialization for lithium metal batteries.In this study,a highly-chlorinated organic-inorganic hybrid interfacial protective layer is developed by rationally tuning the interfacial passivation and robustness to achieve the convenient and efficient li metal anode.The polyvinyl chloride(PVC)can effectively resist water and oxygen,which is confirmed by density functional theory.The organic-dominant solid electrolyte interphases(SEI)with lithium chloride are investigated by the X-ray photoelectron spectroscopy(XPS)with little mineralization of oxide,such as li_(2)O and li_(2)CO_(3).With such artificial SEI,a uniform and dense lithium deposition morphology are formed and an ultra-long stable cycle of over 500 h are achieved even at an ultra-high current density of 10 m A/cm^(2).Moreover,the simple and convenient protected anode also exhibits excellent battery stability when paired with the liNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)and liFePO_(4)(LFP)cathode,showing great potential for the commercial application of lithium metal batteries.

关键词： Highly-chlorinated Water/oxygen resistance Stable interphase Dendrite-free lithium metal batteries High-rate

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Accelerating lithium-sulfur battery reaction kinetics and inducing 3D deposition of li2S using interactions between Fe3Se4 and lithium polysulfides

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Journal of Energy Chemistry 2024年第8期95卷 540-553页

作者： Yihan lin liheng li Longjie Tan Yongliang li Xiangzhong Ren Peixin Zhang Chuanxin He lingna Sun College of Chemistry and Environmental Engineering Shenzhen University

Although lithium-sulfur batteries（LSBs） exhibit high theoretical energy density,their practical application is hindered by poor conductivity of the sulfur cathode,the shuttle effect,and the irreversible deposition of li2S.To address these issues,a novel composite,using electrospinning technology,consisting of Fe3Se4and porous nitrogen-doped carbon nanofibers was designed for the interlayer of LSBs.The porous carbon nanofiber structure facilitates the transport of ions and electrons,while the Fe3Se4material adsorbs lithium polysulfides（liPSs） and accelerates its catalytic conversion process.Furthermore,the Fe3Se4material interacts with soluble liPSs to generate a new polysulfide intermediate,lixFeSycomplex,which changes the electrochemical reaction pathway and facilitates the three-dimensional deposition of li2S,enhancing the reversibility of LSBs.The designed LSB demonstrates a high specific capacity of1529.6 mA h g-1in the first cycle at 0.2 C.The rate performance is also excellent,maintaining an ultra-high specific capacity of 779.7 mA h g-1at a high rate of 8 C.This investigation explores the mechanism of the interaction between the interlayer and liPSs,and provides a new strategy to regulate the reaction kinetics and li2S deposition in LSBs.

关键词： Adsorption Catalysis Electrostatic spinning Interlayers li2S electrodeposition lithium-sulfur batteries Polysulfide intermediates

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Ultrathin organic solvent nanofiltration membrane with polydopamine-HKUST-1 interlayer for organic solvent separation

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Journal of Environmental Sciences 2024年第7期141卷 182-193页

作者： Haike li Xindong li Guozai Ouyang lijinhong Huang Lang li Wenhao li Wanfu Huang Duokun li Ganzhou Key Laboratory of Basin Pollution Simulation and Control Jiangxi University of Science and TechnologyGanzhou 341000China Innovation Center for Water Quality Security Technology at Ganjiang River Basin Jiangxi University of Science and TechnologyGanzhou 341000China School of Architecture and Design Jiangxi University of Science and TechnologyGanzhou 341000China WA School of Mines:Minerals Energy and Chemical EngineeringCurtin UniversityWA 6845Australia School of Materials Science and Engineering Tiangong UniversityTianjin 300387China

Polydopamine(PDA)and metal-organic skeleton HKUST-1 were co-deposited on the base membrane of hexamethylenediamine(HDA)-crosslinked polyetherimide(PEI)ultrafiltration membrane as the interlayer,and high-throughput organic solvent nanofiltration membrane(OSN)was prepared by interfacial polymerization and solvent activation reaction.The polyamide(PA)layer surface roughness from 28.4 nm in PA/PEI to 78.3 nm in PA/PDA-HKUST-10.6/PEI membrane,reduced the thickness of the separation layer from 79 to 14 nm,and significantly improved the hydrophilic,thermal and mechanical properties.The flux of the PA/PDA-HKUST-10.6/PEI membrane in a 0.1 g/L Congo Red(CR)ethanol solution at 0.6 MPa test pressure reached 21.8 L/(m^(2)·hr)and the rejection of CR was 92.8%.Solvent adsorption test,N,N-dimethylformamide(DMF)immersion experiment,and long-term operation test in ethanol showed that the membranes had high solvent tolerance.The solvent flux test demonstrated that,under the test pressure of 0.6 MPa,the flux of different solvents ranked as follows:methanol(56.9 L/(m^(2)·hr))>DMF(39.6 L/(m^(2)·hr))>ethanol(31.2 L/(m^(2)·hr))>IPA(4.5 L/(m^(2)·hr))>N-hexane(1.9 L/(m^(2)·hr)).The ability of the membranes to retain dyes in IPA/water dyes solution was also evaluated.The flux of the membrane was 30.4 L/(m^(2)·hr)and the rejection of CR was 91.6%when the IPA concentration reached 50%.This OSN membrane-making strategy is economical,environment-friendly and efficient,and has a great application prospect in organic solvent separation systems.

关键词： Interfacial polymerization Organic solvent nanofiltration Interlayer Metal-organic frameworks Polydopamine

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Boosting the performance of liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2) electrode by uniform li_(3)PO_(4) coating via atomic layer deposition

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Chinese Chemical Letters 2024年第5期35卷 499-503页

作者： Mingjiao Lu Zhixing Wang Gui Luo Huajun Guo Xinhai li Guochun Yan Qihou li Xianglin li Ding Wang Jiexi Wang School of Metallurgy and Environment Central South UniversityChangsha 410083China BASF ShanShan Battery Materials Co. Ltd.Changsha 410006China Engineering Research Center of the Ministry of Education for Advanced Battery Materials Central South UniversityChangsha 410083China Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy Central South UniversityChangsha 410083China School of Physics and Chemistry Hunan First Normal UniversityChangsha 410205China National and Local Joint Engineering Laboratory for lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China

Ultra-high nickel material is considered to be a promising cathode material.However,with the increase of nickel content,the interfacial side reactions between the cathode and electrolyte become increasingly serious.Herein,an atomically controllable ionic conductor li_(3)PO_(4)(LPO)coating is deposited on the liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2)(NCM9064)based electrode by the atomic layer deposition method.The results shows that the LPO coating is uniformly and densely covered on the surface of secondary particles of NCM9064,helping to prevent the direct contact between the electrolyte and cathode during the chargingdischarging process.In addition,the coating layer is electrochemically stable.As a result,the interfacial side reactions during the long cycle are effectively suppressed,and the solid electrolyte interphase layer at the interface is stabilized.The electrode with 20 layers of LPO deposition(ALD-LPO-20)exhibits an excellent capacity retention of 81%after 200 cycles in 2.8-4.3 V at 25℃,which is 18%higher than the unmodified material(ALD-LPO-0).Besides,the moderate LPO coating improves the rate capability and high temperature cycling performance of NCM9064.This study provides a method for the modification of ultra-high nickel cathode materials and corresponding electrodes.

关键词： Ultra-high nickel material liNi_(0.90)Co_(0.06)Mn_(0.04)O_(2) Atomic layer deposition li_(3)PO_(4) Ionic conductor

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Distribution characteristics of available trace elements in soil from a reclaimed land in a mining area of north Shaanxi,China

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International Soil and Water Conservation Research 2013年第1期1卷 65-75页

作者： li zhanbin Zhang Qinling li Peng Key Lab of Northwest Water Resources and Environment Ecology of MOE Xi'an University of Technology Xi'an 710048ShaanxiP.R.China State Key Laboratory of Soil Erosion and Dry-land Farming on the Lous Plateau Institute of Soil and Water ConservationChinese Academy of SciencesYangling 712100ShaanxiP.R.China Soil and Water Conservation Bureau in Shaanxi Province Xi'an 710042ShaanxiP.R.China

Through field and laboratory tests we studied the temporal and spatial variation in the soil content of four available trace elements:copper(Cu),iron(Fe),manganese(Mn)and zinc(Zn),to analyze their distribution characteristics in reclaimed mining land under different reclamation conditions.The available trace elements content varied considerably with different land reclamation patterns.Extended reclamation time was helpful for the recovery of the available trace element content in the soil,and after more than eight years of soil reclamation,the content of available trace elements was closer to or greater than that in soil under natural conditions.Various treatment measures significantly influenced the content and distribution of available trace elements in the soil,and reasonable artificial treatments,including covering the soil and growing shrubs and herbaceous plants,increased the content of available trace elements.

关键词： Available trace element Reclaimed land Reclamation time Treatment measure Mining area

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