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Light-activated tautomeric transition enhanced buried heterointerface for highly efficient and ultraviolet robust perovskite solar cells

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Science China Chemistry 2024年

作者： Sheng Jiang Shaobing Xiong Shuaifei Mao Yefan Zhang Dongyang Zhao Xiaomeng You Vladimir Gaishun dmitry Kovalenk Qinye Bao School of Physics and Electronic Science East China Normal University Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and Perception Institute of OptoelectronicsFudan University Institute of Functional Nano & Soft Materials (FUNSOM) Soochow University Shanghai Key Laboratory of Magnetic Resonance East China Normal University Department of Physics and Information Technologies Francisk Skorina Gomel State University Collaborative Innovation Center of Extreme Optics Shanxi University

The buried heterointerface of perovskite solar cells（PSCs） suffers from serious nonradiative recombination and ultraviolet（UV）light stress, relentlessly limiting further increase in their power conversion efficiency and operational stability. Herein, we develop an emerging strategy of incorporating a thin UV-activated tautomeric transition layer onto underlying charge transport layer and then depositing perovskite layer to construct an efficient hole-selective buried heterojunction. It is revealed that the UV-activated tautomeric transition interlayer not only improves upper perovskite crystallinity, diminishes thermionic loss for collecting hole and passivates defect site at such buried contact that significantly promote charge transport and suppress nonradiative recombination, but also effectively protects adjacent perovskite from UV degradation through “UV sunscreen”effect. As a result, we report a remarkably enhanced efficiency of 24.76% compared to 22.02% of the control device. More importantly, the achieved high-efficiency PSC features excellent resistance against UV radiation at 365 nm of 100 and 850 mW cm-2, which are approximately 21 and 184 times of UV flux(4.6 mW cm-2) under AM 1.5G solar illumination. This work provides a promising approach of strengthening buried heterointerface for simultaneous realization of highly efficient and UV robust PSCs.

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A systematic review of cytoreductive prostatectomy outcomes and complications in oligometastatic disease

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Asian Journal of Urology 2024年第2期11卷 208-220页

作者： Andrey Morozov Leonid Chuvalov Mark Taratkin Mikhail Enikeev Leonid Rapoport Nirmish Singla Eric Barret Elena Poddubskaya Maria Borodina Georg Salomon Juan Gomez Rivas dmitry Enikeev Institute for Urology and Reproductive Health Sechenov UniversityMoscowRussia Young Academic Urologists EAUthe Netherlands Department of Urology James Buchanan Brady Urological InstituteThe Johns Hopkins University School of MedicineBaltimoreUSA Department of Urology Institut Mutualiste MontsourisParisFrance Sechenov University MoscowRussia Hertsen Moscow Oncology Research InstituteMoscowRussia Hertsen Moscow Oncology Research Institute MoscowRussia Martini Clinic University Medical Center Hamburg-EppendorfHamburgGermany Department of Urology Clinico San Carlos University HospitalMadridSpain Department of Urology Medical University of ViennaViennaAustria

Objective: To analyze outcomes and complications of cytoreductive prostatectomy (CRP) for oligometastatic prostate cancer (PCa) in order to elucidate its role in this ***: We performed a systematic literature search using three databases (Medline, Scopus, and Web of Science). The primary endpoints were oncologic outcomes. The secondary endpoints were complication rates and functional ***: In all studies, overall survival was better or at least comparable variable in the groups with CRP compared to no local treatment. The greatest benefit from CRP in 5-year overall survival in one study was 67.4% for CRP versus 22.5% for no local treatment. Cancer-specific survival (CSS) showed the same trend. Several authors found significant benefits from CSS in the CRP group: from 79% vs. 46% to 100% vs. 61%. CRP was a predictor of better CSS (hazard ratio 0.264, p=0.004). Positive surgical margin rates differed widely from 28.6% to 100.0%. Urinary continence in CRP versus RP for localized PCa was significantly lower (57.4% vs. 90.8%, p<0.0001). Severe incontinence occurred seldom (2.5%-18.6%). Total complication rates after CRP differed widely, from 7.0% to 43.6%. Rates of grades 1 and 2 events prevailed. Patients on ADT alone also showed a considerable number of complications varying from 5.9% to 57.7%.Conclusion: CRP improves medium-term cancer control in patients with oligometastatic PCa. The morbidity and complication rates of this surgery are comparable with other approaches, but postoperative incontinence rate is higher compared with RP for localized disease.

关键词： Systematicreview Prostatecancer Oligometastatic Bone metastases Cytoreductive prostatectomy

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Author Correction: ITO-free silicon-integrated perovskite electrochemical cell for light-emission and light-detection

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Opto-Electronic Advances 2024年第3期7卷 50-50页

作者： Maria Baeva dmitry Gets Artem Polushkin Aleksandr Vorobyov Aleksandr Goltaev Vladimir Neplokh Alexey Mozharov dmitry VKrasnikov Albert GNasibulin Ivan Mukhin Sergey Makarov Alferov University Khlopina 8/3St.Petersburg 194021Russia Department of Physics and Engineering ITMO UniversityLomonosova 9St.Petersburg 197101Russia Institute of Automation and Control Processes(IACP) Far Eastern Branch of Russian Academy of SciencesUlitsa Radio 5Vladivostok 690041Primorsky KraiRussia Peter the Great St.Petersburg Polytechnic University Polytechnicheskaya 29St.Petersburg 195251Russia Skolkovo Institute of Science and Technology Nobel 3Moscow 121205Russia Qingdao Innovation and Development Center Harbin Engineering UniversityQingdao 266000China.

Correction to:Opto-Electronic Advances https://***/10.29026/oea.2023.220154 published online 26 April 2023 After the publication of this article1,it was brought to our attention that calculations of the PeLEC device elec-troluminescent(EL)efficiency contained a mistake,leading to an inaccurate quantity *** device’s maxim-um EL efficiency constitutes not‘~120 klm/W’but‘4.3 lm/W’*** details are listed below.

关键词： value. perovskite listed

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A rare case of cardiac and ophthalmic manifestations of meningococcal septicemia

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World Journal of Emergency Medicine 2024年第4期15卷 328-330页

作者： Svetlana Rachina Anastasia Shchendrygina Heshan Radeesha de Silva Svetlana Tarasenko Nadezhda Mukhina Irina Komarova Ludmila Fedina Elena Burmistrova Elvira Martens Sergey Sidorenko Vladimir Gostev dmitry Polev Alina Saitova Lyudmila Kraeva Nikita Goncharov Irina Zvetkova Department of Hospital Therapy I M Sechenov First Moscow State Medical UniversityMoscow 119048Russia Outpatient Clinic#64 Moscow 119048Russia Department of Cardiology City Clinical Hospital n.a.S.S.YudinMoscow 119048Russia Department of Medical Microbiology and Molecular Epidemiology Pediatric Research and Clinical Center for InfectiousDiseasesSaint Petersburg 197022Russia Department of Medical Microbiology North-Western State Medical University Named After I.I.MechnikovSaintPetersburg 191015Russia Department of Epidemiology Saint-Petersburg Pasteur InstituteSaint Petersburg 197101Russia

Acute pericarditis is usually a self-limiting disorder that commonly occurs due to viral etiology or unexplained *** pericarditis(MP)is a remarkably uncommon clinical entity that manifests as a complication during the acute or convalescent phase of meningococcal ***,its occurrence within the context of meningococcal septicemia has also been *** report a rare case of a previously healthy male patient who developed both acute pericarditis and uveitis as a presentation of meningococcal septicemia,with no characteristic skin rashes or meningeal signs.

关键词： acute Acute rare

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椭球形凹陷/凸起通道流动和传热特性研究

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机械科学与技术 2024年

作者：翟颖妮夏天 dmitry Bubnov 孔德海郭涛刘存良西北工业大学动力与能源学院西安建筑科技大学机电工程学院

发展高效低阻的内冷结构对于燃气涡轮发动机涡轮叶片高效冷却设计具有重要的意义。本文数值研究了雷诺数在10，000～60，000之间时椭球形凹陷/凸起矩形通道的流动传热特性，凹陷的深径比（h/D）为0.25，凸起的堵塞比（h/H）在0.18～0.2... 详细信息

发展高效低阻的内冷结构对于燃气涡轮发动机涡轮叶片高效冷却设计具有重要的意义。本文数值研究了雷诺数在10，000～60，000之间时椭球形凹陷/凸起矩形通道的流动传热特性，凹陷的深径比（h/D）为0.25，凸起的堵塞比（h/H）在0.18～0.25之间。分析了凹陷/凸起的类型、排列方式和排列间距对通道内流阻和平均传热特性以及综合热性能的影响。结果表明：流动再附着发生在椭球形凸起前缘、下游尾迹区及椭球形凹陷后缘，故椭球形凸起的高换热区位于其前缘以及下游尾迹区，椭球形凹陷的高换热区则位于后缘边界。V型排布的椭球形凸起表现出最佳的换热性能，其综合热性能和相对平均努塞尔数随雷诺数的增大而减小，相对摩擦因子随雷诺数的增大而增大。V型排布的椭球形凸起的综合热性能比平板高20%～40%、平均努塞尔数比平板高55%～73%、摩擦因子约为平板的两倍。排列间距减小时，椭球形凹陷/凸起的高换热区面积增大，低换热区面积减小，综合热性能增大。

关键词：涡轮叶片冷却结构强化换热流动结构综合热性能

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Expanded Porphyrin Exhibiting Off-Centered Out-of-Plane Coordination to Dysprosium

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CCS Chemistry 2024年第7期6卷 1731-1738页

作者： dmitry I.Nazarov Jorge Labella Alexey V.Kuzmin Maxim A.Faraonov Evgenii N.Ivanov Salavat S.Khasanov Tomas Torres Mikhail K.Islyaikin Dmitri V.Konarev Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS 142432 Chernogolovka Department of Organic Chemistry Universidad Autonoma de Madrid28049 Madrid Institute of Solid-State Physics RAS 142432 Chernogolovka Research Institute of Macroheterocycles Ivanovo State University of Chemistry and Technology15300 Ivanovo G.A.Krestov Institute of Solution Chemistry of the Russian Academy of Sciences 153045 Ivanovo Institute for Advanced Research in Chemical Sciences Universidad Autonoma de Madrid28049 Madrid IMDEA-Nanociencia 28049 Madrid

The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the development of advanced molecular *** this context,the use of expanded porphyrinoids remains elusive since their coordination chemistry is challenging to ***,taking inspiration from on-surface chemistry,we explored the coordination of Dy^(3+)to a six-membered porphyrinoid,namely,the hemihexaphyrazine ***,we observed the selective formation of a mono-nuclear off-centered,out-of-plane H_(2)Hhp-Dy^(3+)complex when performing the complexation under reductive *** this reaction,the oxidation state of the macrocycle did not *** X-ray diffraction analysis,we found that the coordination number of Dy in this complex was *** macrocycle cocrystallized with decamethylcobaltocene(Cp_(2)^(*)Co)molecules,giving rise to a wellordered solid-state packing,governed byπ-π*** a result of this organization,a small magnetic coupling between the neighboring molecules was *** in all,this work provides key insights into the coordination of magnetically active metals with expanded porphyrinoids,thus motivating the development of advanced spintronic devices.

关键词： porphyrins dysprosium macrocycle coordination chemistry magnetism

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Olefin Polymerization Behavior of Titanium(IV) Complexes with Fluorinated and Non-fluorinated Aliphatic Phenoxyimine Ligands

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Chinese Journal of Polymer Science 2024年第1期42卷 52-62,I0007页

作者： Vladislav A.Tuskaev Kasim F.Magomedov Svetlana Ch.Gagieva dmitry A.Kurmaev Yulia V.Nelyubina Evgenii K.Golubev Maria D.Evseeva Viktor G.Vasil'ev Galina G.Nikiforova Mikhail I.Buzin Vyacheslav S.Bogdanov Boris M.Bulychev Department of Chemistry M.V.Lomonosov Moscow State UniversityMoscow 119992Russian Federation A.N.Nesmeyanov Institute of Organoelement Compounds Russian Academy of SciencesMoscow119991Russian Federation Enikolopov Institute of Synthetic Polymer Materials Russian Academy of SciencesMoscow 117393Russian Federation

A series of Ti(Ⅳ) dichloride and dialkoxide com plexes with phenoxyimine ligands containing fluorinated and nonfluorinated aliphatic imine fragments have been *** molecular structures of complexes 1 and 4 were established by single-crystal X-ray diffraction *** complexes adopt a distorted octahedral coordination structure around the titanium atom and two oxygen atoms are situated in trans position while two nitrogen atoms and two outgoing ligands(Cl or iPrO) are situated in cis *** of activators(MMAO-12 and combinations Et_nAICl_(3-n)+Bu_(2)Mg) and outgoing ligand(Cl or iPrO) nature on the catalytic activity and properties of the resulting polymers was *** Ti complexes,despite the nature of the outgoing ligands(Cl or iPrO) in the presence of Al/Mg activators,was found to display a high ethylene polymerization activity in the range 1600-3830 kg_(polymer)·mol_(Ti)^(-1)·h^(-1)·atm^(-1) with a viscosity average molecular weight(M_v) value in the range 1.1×10~6-7.1×10~6 Dalton(Da).The resulting UHMWPE can be processed by a solventless method into high-strength and high-modulus oriented *** rheological characteristics of a polymer melt have been *** absence of a cross-over point did not allow to compare the values of the molecular weight distribution of polymers obtained on fluorinated and non-fluorinated pre-catalysts,however,the estimation of the entanglement density is in good agreement with the mechanical characteristics of oriented film *** activation with methylalumoxane,the activity of the com plexes decreased very significantly;however,a polymer with a molecular weight of about 12 million Da was *** the process of ethylene/octene-1 copolymerization,fluorine-containing precatalysts showed a clear advantage over non-fluorinated analogues both in activity and in comonomer content.

关键词： FI catalysts Titanium(IV) (Co)polymerization Al/Mg co-catalyst Ultra-high molecular weight polyethylene

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医院手术室中麻醉气体对碳排放影响及其防治措施探讨

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医用气体工程 2024年第1期4卷 1-6页

作者：马琪伟康瑞 dmitry Karablinov 徐哲懿阿特拉斯·科普柯医用气体事业部上海200000 中国医学装备协会医用气体装备及工程分会陕西西安710032

气候变化是全球共同关注的公共健康问题,医疗卫生机构内日常的运行也会产生大量的温室气体排放,尤其是资源集中的手术室,能耗高并产生大量的医用废物。这些都会对环境产生较大的影响。麻醉气体的排放对环境造成的影响常常容易被忽视。... 详细信息

气候变化是全球共同关注的公共健康问题,医疗卫生机构内日常的运行也会产生大量的温室气体排放,尤其是资源集中的手术室,能耗高并产生大量的医用废物。这些都会对环境产生较大的影响。麻醉气体的排放对环境造成的影响常常容易被忽视。我们通过对氧化亚氮(N2O)对环境影响的分析及措施建议,希望能够对减少医疗机构的碳排放提供帮助。

关键词：温室气体全球变暖潜能值麻醉气体卤化药物回收装置中心分解装置

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3,6-Bis-β-Dicarbonylsubstituted Carbazoles Bearing N-Spacers and Their Eu(III) Complexes as Immunofluorescent Labelling Agents

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International Journal of Organic Chemistry 2024年第1期14卷 20-31页

作者： dmitry E. Pugachev Georgy V. Zatonsky Tatyana S. Kostryukova Anna G. Shubina Nikolay V. Vasiliev Department of Biological Microanalysis FGUP State Research Institute of Biological Engineering Moscow Russia Department of Theoretical and Applied Chemistry State University of Education Mytishchi Russia

New reagents for immunofluorescence analysis of carbazole series containing fluorinated β-dicarbonyl fragments and carboxylic substituent groups separated by spacers of different lengths from the light-gathering carbazole scaffold have been developed. The markers in complex with Eu3+ ions possess stability in the aqueous phase, intense and prolonged luminescence (τ 550 - 570 μs) with characteristic emission maxima in the region of 615 nm and excitation wavelengths in the region of 380 - 390 nm, which distinguishes them from most of the analogs used. In the study of marker conjugation with streptavidin, a reagent containing 4 - 5 europium labeling complexes based on spacer-containing carbazole tetraketone was obtained. The marker-doped silicate nanoparticles exhibit intense and long-lived luminescence in the characteristic region.

关键词： Fluorescence Immunoassay Fluorinated β-Diketones Carbazole Europium Complexes Streptavidin Nanodispersions

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E-beam generation in discharges initiated by voltage pulses with a rise time of 200 ns at an air pressure of 12.5-100 kPa

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Plasma Science and Technology 2019年第4期21卷 52-60页

作者： Victor TARASENKO dmitry BELOPLOTOV Mikhail LOMAEV dmitry SOROKIN Institute of High Current Electronics Siberian Bran ch.Russian Academy of Sciences.Tomsk&34055.Russia National Research Tomsk State University.Tomsk 634050 Russia

The effect of air pressure(12.5,25,50,and 100 kPa)on the gen eration of runaway electron beams in a non-uniform electric field when applying voltage pulses(~35 kV)with a rise time of?200 ns has been *** results show that the discharge has various stages:streamer,diffuse,and ***,a wide streamer develops in the gap and a diffuse discharge is formed.A spark is formed u 100 ns after the *** current pulse of a supershort avalanche electron beam(SAEB)was measured with a collector at various pressures of *** show that there are two modes of generation of run away *** an air pressure of 25-100 kPa,a single SAEB current pulse with a full width at half-maximum(FWHM)of 120-140 ps is *** the air pressure of 12.5 kPa,two current pulses of the electron beam are *** of the first and second current pulses are ul40ps and u300 ps,*** current pulse amplitude of the second electron beam is higher than that of the first one,but the electron energy is less.

关键词： diffuse discharge runaway electrons streamer breakdown displacement current

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