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Rare Metals 2024年第9期43卷 4198-4221页

作者： Miao Ma Li-Xiao Shen Jing Liu Bin xu Yun-Long Zhang lei Zhao Zhen-Bo Wang school of Chemistry and Chemical engineering Harbin Institute of TechnologyHarbin 150001China College of Environmental and Chemical engineering Yanshan UniversityQinhuangdao 066004China Unipower Hydrogen Technology(Jiangsu)Corporation Changzhou 213176China

Proton exchange membrane fuel cells(PEMFCs)have been identified as a highly promising means of achieving sustainable energy conversion.A crucial factor in enhancing the performance of PEMFCs for further potential energy applications is the advancement in the field of catalyst engineering that has led to remarkable performance enhancement in facilitating the oxygen reduction reaction(ORR).Subsequently,it is important to acknowledge that the techniques used in preparation of membrane electrode assemblies(MEAs),the vital constituents of PEMFCs,also possess direct and critical influence on exhibiting the full catalytic activity of meticulously crafted ***,a succinct summary of the most recent advancements in Pt catalysts for ORR was offered and their underly catalytic mechanism were ***,both laboratory-scale and industrial-scale MEA fabrication techniques of Pt catalysts were ***,a detailed analysis of the connections between materials,process,and performance in MEA fabrication was presented in order to facilitate the development of optimal catalyst layers.

关键词： Pt catalysts Oxygen reduction reaction Membrane electrode assemblies MEA fabrication techniques

Bimetallic NiCoP catalysts anchored on phosphorus-doped lignin-based carbon for robust oxygen evolution performance

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Rare Metals 2024年第7期43卷 3084-3095页

作者： Ling-Ying-Zi Xiong Bo-Wen Liu lei Du Yue-Kuan Zhou xu-Liang Lin Huan Wang Guangdong engineering Technology Research Center for Sensing Materials&Devices Guangzhou Key Laboratory of Sensing Materials&DevicesSchool of Chemistry and Chemical EngineeringGuangzhou UniversityGuangzhou 510006China school of Chemical engineering and Light Industry Guangdong University of TechnologyGuangzhou 510006China Guangdong Provincial Laboratory of Chemistry and Fine Chemical engineering Jieyang Center Jieyang 515200China Sustainable Energy and Environment Thrust Function HubThe Hong Kong University of Science and Technology(Guangzhou)Guangzhou 511400China Division of Emerging Interdisciplinary Areas Department of Mechanical and Aerospace EngineeringThe Hong Kong University of Science and TechnologyHong Kong 999077China State Key Lab of Pulp and Paper engineering South China University of TechnologyGuangzhou 510640China

Oxygen evolution reaction(OER)catalysts are the key core materials that determine the performance of fuel cells,metal-air batteries,electrolytic water decomposition,and other *** this work,a green lignin-based non-precious metal OER catalyst was prepared by a simple ***,c arboxylated lignin was used to complex Ni and Co in situ,and then they were placed with sodium hypophosphite in the same tube furnace for upstream and downstream high-temperature calcination to construct a lignin carbon-based Ni-Co bimetallic OER catalyst(NiCoP@C).The synthesized catalyst is a porous bimetallic phosphide with a three-dimensional network structure and high-density electrochemical active ***@C exhibited favorable catalytic activity for the oxygen evolution reaction(OER)with overpotential of 280 mV at 10 mA·cm~(-2)and a Tafel slope of 77 mV·dec~(-1).Additionally,it exhibited remarkable durability during *** functional theory(DFT)calculations revealed that by leveraging the distinctive structure of transition metal phosphide nanoparticles incorporated into a reticulated substrate,the NiCoP@C catalyst offered an increased number of active sites for OER catalysis,significantly enhancing its stability during practical *** present study broadens the utilization pathways of biomass to"turn waste into treasure,"aligning the development concept of green sustainable development.

关键词： Oxygen evolution reaction Lignin Carbon-based catalyst Nickel-cobalt bimetal Metal phosphide

The influence of the leading-edge angle of subgrade on the aerodynamic loads of a high-speed train in a wind tunnel

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Transportation Safety and Environment 2024年第2期6卷 45-54页

作者： Zeyun Yang Gang xu Fan Wu lei Zhang Jian Du Dmitri Vainchtein Key Labor atory of Traffic Safety on Track Ministry of EducationSchool of Traffic&Transportation EngineeringCentral South UniversityChangsha 410075HunanChina CRRC Academy(Qingdao)Co. Ltd.Qingdao 266111ShandongChina CRRC Qingdao Sifang Co. Ltd.Qingdao 266111ShandongChina Nyheim Plasma Institute Drexel UniversityCamden 08103USA

The purpose of this study is to establish the correlation between the boundary layer over the subgrade and the aerodynamic loads act-ing on the train model in conventional wind tunnel ***,flow characteristics around the subgrade with different leading-edge angles(15°,30°and 45°)are investigated through the particle image velocimetry(PIV)experimental test ***,wind tunnel tests of the aerodynamic performance of a high-speed train are carried *** results are compared with previous experimental data obtained by moving model *** show that,due to the presence of a boundary layer,the pressure acting on the lower part of the train head decreases,while other locations are not significantly *** is the reason for the reduction of the aerodynamic drag and lift on the *** addition,the reduction effects become more obvious when the thickness of the boundary layer *** experimental results obtained could serve as a calibration of aerodynamic forces for wind tunnel tests on high-speed trains.

关键词： high-speed train ground effect aerodynamic performance wind tunnel test PIV experiment

Autoencoder-based conditional optimal transport generative adversarial network for medical image generation

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Visual Informatics 2024年第1期8卷 15-25页

作者： Jun Wang Bohan lei Liya Ding Xiaoyin xu Xianfeng Gu Min Zhang school of Software Technology Zhejiang UniversityNingboZhejiangChina College of Computer Science&Technology Zhejiang UniversityHangzhouZhejiangChina Department of Pathology Sir Run Run Shaw HospitalZhejiang University School of MedicineHangzhouZhejiangChina College of Biomedical engineering&Instrument Science Zhejiang UniversityHangzhouZhejiangChina Department of Computer Science State University of New York at Stony BrookStony BrookNYUSA

Medical image generation has recently garnered significant interest among ***,the primary generative models,such as Generative Adversarial Networks(GANs),often encounter challenges during training,including mode *** address these issues,we proposed the AECOT-GAN model(Autoencoder-based Conditional Optimal Transport Generative Adversarial Network)for the generation of medical images belonging to specific *** training process of our model comprises three fundamental *** training process of our model encompasses three fundamental ***,we employ an autoencoder model to obtain a low-dimensional manifold representation of real ***,we apply extended semi-discrete optimal transport to map Gaussian noise distribution to the latent space distribution and obtain corresponding labels *** procedure leads to the generation of new latent codes with known ***,we integrate a GAN to train the decoder further to generate medical *** evaluate the performance of the AE-COT-GAN model,we conducted experiments on two medical image datasets,namely DermaMNIST and *** model’s performance was compared with state-of-the-art generative *** show that the AE-COT-GAN model had excellent performance in generating medical ***,it effectively addressed the common issues associated with traditional GANs.

关键词： Medical image generation Mode collapse Mode mixing Optimal transport Generative adversarial networks

3D-printed MoS_(2)/Ni electrodes with excellent electro-catalytic performance and long-term stability for dechlorination of florfenicol

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Journal of Environmental Sciences 2024年第3期137卷 420-431页

作者： Jianhui xu Pengxu Wang Shenggui Chen lei Li Dan Li Yunfei Zhang Qi Wu Jinhong Fan LumingMa school of Environment and Civil engineering Dongguan University of TechnologyDongguan 523808China school of Art and Design Guangzhou Panyu PolytechnicGuangzhou 511483China National engineering Research Center for Urban Pollution Control State Key Laboratory of Pollution Control and Resources ReuseCollege of Environmental Science and EngineeringTongji UniversityShanghai 200092China Dongguan Institute of Science and Technology Innovation Dongguan University of TechnologyDongguan 523808China school of Mechanical engineering Dongguan University of TechnologyDongguan 523808China

Here,we report the production of 3D-printed MoS_(2)/Ni electrodes(3D-MoS_(2)/Ni)with longterm stability and excellent performance by the selective laser melting(SLM)*** a cathode,the obtained 3D-MoS_(2)/Ni could maintain a degradation rate above 94.0%for forfenicol(FLO)when repeatedly used 50 times in *** also found that the removal rate of FLO by 3D-MoS_(2)/Ni was about 12 times higher than that of 3D-printed pure Ni(3D-Ni),attributed to the improved accessibility of H^(*).In addition,the electrochemical characterization results showed that the electrochemically active surface area of the 3D-MoS_(2)/Ni electrode is about 3-fold higher than that of the 3D-Ni electrode while the electrical resistance is 4 times *** on tert-butanol suppression,electron paramagnetic resonance and triple quadrupole mass spectrometer experiments,a“dual path”mechanism and possible degradation pathway for the dechlorination of FLO by 3D-MoS_(2)/Ni were ***,we also investigated the impacts of the cathode potential and the initial pH of the solution on the degradation of ***,this study reveals that the SLM 3D printing technique is a promising approach for the rapid fabrication of high-stability metal electrodes,which could have broad application in the control of water contaminants in the environmental field.

关键词： 3D-print Electroreduction MoS_(2)/Ni Antibiotic Florfenicol

Synthesis,chemical bonding and reactivity of new medium-sized polyarsenides

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Chinese Chemical Letters 2024年第7期35卷 497-501页

作者： xu-Hui Yue Xiang-Wen Zhang Hui-Min He lei Qiao Zhong-Ming Sun State Key Laboratory of Element-Organic Chemistry Tianjin Key Lab for Institution Rare Earth Materials and ApplicationsSchool of Materials Science and EngineeringNankai UniversityTianjin 300350China Department of Physics Institute of Computational and Applied PhysicsTaiyuan Normal UniversityJinzhong 030619China

Gaining an understanding of the growth mechanism from single atoms to clusters and bulk materials continues to present a ***,it is important to explore the evolving trends of clusters in the structure and properties during the size *** this work,we report the synthesis and characterization of two medium-sized chain-like polyarsenic anions.[As_(21)]^(3-)represents a trimeric example of polyarsenic anion assembled through oxidative coupling of As_(7)^(3-)*** anion As_(18)^(4-)included in[As_(18)MO_(2)(CO)_(8)]^(4-)is regarded as formed by two realgar-type As_(8)subunits connected by a dinuclear AsAs *** As_(18)cluster was previously predicted by theory,and this is the first time successfully synthesized using wet chemistry ***,small-sized polyarsenides As_(2)^(2-)and As_(10)^(2-)were found in compound[K(18-crown-6)]_(3)[As_(10)]_(0.5)[As_(4){Mo(CO)_(3)}_(2)]_(0.5)·*** these,the former exhibits coordination with metal ***-crystal X-ray diffraction combined with quantum chemical calculations revealed the formation of double bonded As_(2)^(2-)stabilized by metal carbonyl *** work demonstrates a novel synthetic approach for the preparation of new polyarsenides and highlights their intriguing bonding characteristics,laying the foundation for the synthesis of such compounds and paving the way for their potential applications.

关键词： Polyarsenide Zintl anions Chain-like cluster DFT calculations AdNDP

Bionic lightweight design of limb leg units for hydraulic quadruped robots by additive manufacturing and topology optimization

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Bio-Design and Manufacturing 2024年第1期7卷 1-13页

作者： Huaizhi Zong Junhui Zhang lei Jiang Kun Zhang Jun Shen Zhenyu Lu Ke Wang Yanli Wang Bing xu The State Key Laboratory of Fluid Power and Mechatronic Systems Zhejiang UniversityHangzhou 310058China Unmanned Vehicle Research and Development Center China North Vehicle Research InstituteBeijing 100072China school of Mechatronic engineering Nanchang UniversityNanchang 330031China Auclean High-Tech Ltd. Wuxi 214108China

Galloping cheetahs,climbing mountain goats,and load hauling horses all show desirable locomotion capability,which motivates the development of quadruped *** various quadruped robots,hydraulically driven quadruped robots show great potential in unstructured environments due to their discrete landing positions and large *** the most critical movement unit of a quadruped robot,the limb leg unit(LLU)directly affects movement speed and reliability,and requires a compact and lightweight *** by the dexterous skeleton–muscle systems of cheetahs and humans,this paper proposes a highly integrated bionic actuator system for a better dynamic performance of an *** propose that a cylinder barrel with multiple element interfaces and internal smooth channels is realized using metal additive manufacturing,and hybrid lattice structures are introduced into the lightweight design of the piston *** addition,additive manufacturing and topology optimization are incorporated to reduce the redundant material of the structural parts of the *** mechanical properties of the actuator system are verified by numerical simulation and experiments,and the power density of the actuators is far greater than that of cheetah *** mass of the optimized LLU is reduced by 24.5%,and the optimized LLU shows better response time performance when given a step signal,and presents a good trajectory tracking ability with the increase in motion frequency.

关键词： Additive manufacturing Bionic lightweight design Limb leg unit Quadruped robot Trajectory tracking

Research on shell-side heat and mass transfer with multi-component in LNG spiral-wound heat exchanger under sloshing conditions

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Petroleum Science 2024年第2期21卷 1333-1345页

作者： xue-Ping Du Guang-lei Yu Ya-Cheng xu Zhi-Jie Chen Nai-Liang Li Huan-Guang Wang school of Low-carbon Energy and Power engineering China University of Mining and TechnologyXuzhou221116JiangsuChina Key Laboratory of Thermo-Fluid Science and engineering MOEXi'an Jiaotong UniversityXi'an710049ShaanxiChina Xi'an Aerospace Propulsion Test Technology Institute Xi'an710100ShaanxiChina

The spiral-wound heat exchanger(SWHE) is the primary low-temperature heat exchanger for large-scale LNG plants due to its high-pressure resistance, compact structure, and high heat exchange efficiency. This paper studied the shell-side heat and mass transfer characteristics of vapor-liquid two-phase mixed refrigerants in an SWHE by combining a multi-component model in FLUENT software with a customized multicomponent mass transfer model. Besides, the mathematical model under the sloshing condition was obtained through mathematical derivation, and the corresponding UDF code was loaded into FLUENT as the momentum source term. The results under the sloshing conditions were compared with the relevant parameters under the steady-state condition. The shell-side heat and mass transfer characteristics of the SWHE were investigated by adjusting the component ratio and other working conditions. It was found that the sloshing conditions enhance the heat transfer performance and sometimes have insignificant effects. The sloshing condition is beneficial to reduce the flow resistance. The comprehensive performance of multi-component refrigerants has been improved and the improvement is more significant under sloshing conditions, considering both the heat transfer and pressure *** results will provide theoretical support for the research and design of multi-component heat and mass transfer enhancement of LNG SWHE under ocean sloshing conditions.

关键词： Spiral-wound heat exchanger Sloshing conditions Two-phase flow Multi-component Heat and mass transfer

Dual-Functional Electrode Promoting Dendrite-Free and CO_(2) Utilization Enabled High-Reversible Symmetric Na-CO_(2) Batteries

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Energy & Environmental Materials 2024年第3期7卷 123-132页

作者： Changfan xu Jiajia Qiu Yulian Dong Yueliang Li Yonglong Shen Huaping Zhao Ute Kaiser Guosheng Shao Yong lei Fachgebiet Angewandte Nanophysik Institut für Physik&IMN MacroNanoTechnische Universität Ilmenau 98693Ilmenau Germany Central Facility for Electron Microscopy Electron Microscopy Group of Materials ScienceUlm UniversityUlm 89081Germany school of Materials Science and engineering Zhengzhou UniversityZhengzhou 450001China

Sodium-carbon dioxide(Na-CO_(2))batteries are regarded as promising energy storage technologies because of their impressive theoretical energy density and CO_(2)reutilization,but their practical applications are restricted by uncontrollable sodium dendrite growth and poor electrochemical kinetics of CO_(2)*** suitable multifunctional electrodes for dendritefree anodes and kinetics-enhanced CO_(2)cathodes is considered one of the most important ways to advance the practical application of Na-CO_(2)***,RuO2 nanoparticles encapsulated in carbon paper(RuCP)are rationally designed and employed as both Na anode host and CO_(2)cathode in Na-CO_(2)*** outstanding sodiophilicity and high catalytic activity of RuCP electrodes can simultaneously contribute to homogenous Na+distribution and dendrite-free sodium structure at the anode,as well as strengthen discharge and charge kinetics at the *** morphological evolution confirmed the uniform deposition of Na on RuCP anode with dense and flat interfaces,delivering enhanced Coulombic efficiency of 99.5%and cycling stability near 1500 ***,Na-CO_(2)batteries with RuCP cathode demonstrated excellent cycling stability(>350 cycles).Significantly,implementation of a dendrite-free RuCP@Na anode and catalytic-site-rich RuCP cathode allowed for the construction of a symmetric Na-CO_(2)battery with long-duration cyclability,offering inspiration for extensive practical uses of Na-CO_(2)batteries.

关键词： CO_(2)cathode dendrite free electrocatalysis Na metal anode symmetric CO_(2)batteries

Precipitating thermally reinforcement phase in aluminum alloys for enhanced strength at 400℃

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Journal of Materials Science & Technology 2024年第5期172卷 71-82页

作者： Xiang Su Yuan lei Yang Chen Hongjie Qu Zhixiang Qi Gong Zheng xu Liu Henggao Xiang Guang Chen National Key Laboratory of Advanced Casting Technologies MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials TechnologyEngineering Research Center of Materials Behavior and DesignMinistry of EducationNanjing University of Science and TechnologyNanjing 210094China school of Aviation and Mechanical engineering Changzhou Institute of TechnologyChangzhou 213032China

Heat-resistant aluminum alloys are widely used in aerospace and automotive fields for manufacturing hot components due to their advantages in lightweight design and energy ***,the high-temperature strength of existing cast aluminum alloys is always limited to about 100 MPa at 350℃due to coarsening and transformation of strengthening ***,we reveal that the yield strength and ultimate tensile strength of the T6 state Al-8.4Cu-2.3Ce-1.0Mn-0.5Ni-0.2Zr alloy at 400◦C increase by 34%and 44%after re-aging at 300℃for 100 h,and its thermal strength exhibits distinguished ad-vantage over traditional heat-resistant aluminum *** enhanced elevated-temperature strength is attributed to the reprecipitation of the Ni-bearing T-Al_(20)Cu_(2)Mn_(3)phase,whose number density increases over one *** significant segregation of Ni,Ce,and Zr elements at the interfaces helps improve the thermal stability of the T *** thermostable T phase effectively strengthens the matrix by in-hibiting dislocation ***,a highly interconnected 3D intermetallic network along the grain boundaries can still remain after long-term re-aging at 300℃,which is conducive to imposing a drag on the grain boundaries at high *** finding offers a viable route for enhancing the elevated-temperature strength of heat-resistant aluminum alloys,which could provide expanded opportunities for higher-temperature applications.

关键词： Aluminum alloys Precipitation Thermally reinforcement phase Re-aging treatment High-temperature strength