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Microbial extraction of nickel from chromite overburdens in the presence of surfactant

Transactions of Nonferrous Metals Society of China 2012年第11期22卷 2840-2845页

作者： Sunil Kumar BEHERA lala behari sukla CSIR-Institute of Minerals & Materials Technology

The effect of surfactant polyoxyethylenesorbitan monolaurate （Tween-20） on the nickel bioleaching from pre-treated chromite overburden （COB）, Sukinda with fungal strain Aspergillus niger, was examined in shake flasks. Along with the nickel recovery from COB by the fungal bioleaching, the effect of surfactant on the growth of the A. niger was also investigated. Results show that the addition of surfactant in low concentration was favorable for the recovery of nickel from pre-treated COB. Normally, the carbon source （sucrose） in the culture medium was utilized by the A. niger for its cellular metabolism and organic metabolites （bio acids） were produced, which were responsible for the bioleaching of minerals. However, the addition of surfactant （Tween-20） accelerated the rate of sucrose consumption by the fungi, and thus enhancing the extraction of nickel from pre-treated COB. During the study, around 39% nickel extraction was achieved in A. niger mediated bioleaching performed at 2% pulp density of pre-treated COB at 30 °C, in the presence of surfactant whereas only 24% nickel was extracted without surfactant.

关键词： nickel surfactant Tween-20 chromite overburden Aspergillus niger microbial extraction bioleaching cellularmetabolism organic metabolite

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Reductive Acid Leaching of Low Grade Manganese Ores

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Geomaterials 2012年第4期2卷 70-72页

作者： Alok Prasad Das Sarpras Swain Shriyanka Panda Nilotpala Pradhan lala behari sukla Centre of Biotechnology Siksha “O” Anusandhan University Bhubaneswar India Institute of Minerals and Materials Technology Bhubaneswar India

Manganese recoveries from low-grade ores using organic acids as reducing agents were investigated in the present work. The acid leaching potential of both oxalic acid and citric acid were estimated. Manganese leaching amount were measured by using standard manganese curve and estimated by titration method. Effects of various acid concentrations on leaching efficiency were studied. The observed result suggested prominent manganese recovery of 66% by oxalic acid at 2 M concentration whereas citric acid had less effect on leaching showing leaching percentage upto 40% in 6 days. Acid leaching of manganese ore with both the acids gave a comparative data stating that oxalic acid leached better than citric acid.

关键词： Low Grade Manganese ore Oxalic Acid Citric Acid Leaching

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Bioleaching of copper from pre and post thermally activated low grade chalcopyrite contained ball mill spillage

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Frontiers of Environmental Science & Engineering 2013年第2期7卷 281-293页

作者： Sandeep PANDA Nilotoala PRADHAN Umaballav MOHAPATRA Sandeep K. PANDA Swagat S.RATH Danda S. RAO Bansi D. NAYAK lala B. sukla Barada K. MISHRA CSIR-Institute of Minerals and Materials Technology Bhubaneswar 751013 India Department of Botany North Orissa University Baripada 757003 India Regional Center of Central Tuber Crops Research Institute Bhubaneswar 751019 India

Bioleaching of a low grade chalcopyrite （ball mill spillage material） was tested for copper recovery in shake flasks. The original samples （as received） were thermally activated （600℃, 30 min） to notice the change in physico-chemical and mineralogical characteristics of the host rock and subsequently its effect on copper recovery. A mixed culture of acidophilic chemolithotrophic bacterial consortium predominantly entailing Acidithiobacillus fer- rooxidans strain was used for bioleaching studies and optimization of process parameters of both original and thermally activated samples. Mineralogical characteriza- tion studies indicated the presence of chalcopyrite, pyrite in the silicate matrix of the granitic rock. Field emission scanning electron microscopy coupled with Energy dispersive spectroscopy （FESEM-EDS） and X-ray Fluor- escence （XRF） analysis indicated mostly SiO2. With pH 2, pulp density 10% w/v, inoculum 10% v/v, temperature 30~C, 150 ***-~, 49% copper could be recovered in 30 days from the finest particle size （- 1 ~ 0.75 mm） of the original spillage sample. Under similar conditions 95% copper could be recovered from the thermally activated sample with the same size fraction in 10 days. The study revealed that thermal activation leads to volume expansion in the rock with the development of cracks, micro and macro pores on its surface, thereby enabling bacterial solution to penetrate more easily into the body, facilitating enhanced copper dissolution.

关键词： ball mill spillage thermal activation bioleaching copper

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